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Some textile auxiliaries as wood protective agents
2007 - IRG/WP 07-30417
This study evaluated some textile auxiliaries applicable for wood protection. Commercial alkoxysilane quarternary ammonium formulation and fluorocarbon based water-oil repellent were tested for their ability to provide hydrophobicity and antifungal effect to solid wood samples. Scots pine (Pinus sylvestris L.) sapwood samples were impregnated with 25, 50 and 100 % concentrations of the above menti...
E Dizman, A Temiz, N Terziev, Ü C Yildiz


The effect of temperature on the rate of fixation of an alkyl ammonium compound (AAC) wood preservative
1984 - IRG/WP 3293
The rate of fixation of an alkyl ammonium compound wood preservative was measured by soaking samples of wood wool in various preparations of the preservative for arbitrary times followed by immediate leaching in water. The wood wool was then analysed for residual preservative. The results indicated that fixation was very rapid and increased at higher temperatures....
P Vinden


Evaluation of an alkyl ammonium compound as a fungicide to control sapstain and mould during diffusion storage
1984 - IRG/WP 3282
An alkyl ammonium compound ('Akzo' ES 255) was evaluated for its effectiveness against mould and sapstain during diffusion storage of boron-treated rubber wood. Though ES 255 at 1.0% concentration was effective against mould (71%) and sapstain (89%) it is less satisfactory compared to 0.5% sodium pentachlorophenoxide against mould (92%) and sapstain (98%)....
R Gnanaharan


Adsorption of ACQ and CuMEA Wood Preservatives in Red pine
2005 - IRG/WP 05-30374
The rates of stabilization or fixation of ACQ subcomponents (CuO, DDAC and MEA) in red pine (Pinus resinosa) were compared for different solution concentrations (0.75%, 1.5%, 2.25% and 3% ACQ-D) and post treatment conditioning temperatures. Preservative solutions were impregnated into red pine sapwood by a full-cell treatment. Copper and MEA adsorptions from copper monoethanolamine solutions witho...
C Tascioglu, P A Cooper, Y T Ung


Leachability of didecyldimethylammonium chloride (a quaternary ammonium compound) from four wood species
1982 - IRG/WP 3204
Sapwood blocks prepared from red pine, ponderosa pine, southern yellow pine and hem-fir (a commercial mixture of western hemlock and amabilis fir) were treated with didecyldimethylammonium chloride, (an alkylammonium compound, AAC). After oven drying the blocks were vacuum impregnated with distilled water and subjected to a static leach cycle for 48 hours. The leachate was analyzed and the amount ...
J N R Ruddick, A R H Sam


Movement of water through quaternary ammonium treated wood
1987 - IRG/WP 3440
Radiata pine sapwood stakes were treated with didodecyl methyl 1, 3 dichloropropenyl ammonium chloride and distearyl dimethyl ammonium chloride. Various ratios of these two chemicals were, tested to determine the extent of water movement through the treated wood. Measurements were taken of the amount of water moved through the wood, degree of wetting of various sectors of the stakes, and the distr...
P J Hayward, J Duff


Decay and termite resistance of wood treated with boron-containing quaternary ammonia compound, didecyl dimethyl ammonium tetrafluoroborate (DBF) incorporated with acryl-silicon type resin
2004 - IRG/WP 04-30334
This study evaluates the decay and termite resistance of surface-treated wood with didecyl dimethyl ammonium tetrafluoroborate (DBF) incorporated with acryl-silicon type resin emulsion. DBF is a quaternary ammonia compound and contains boric tetrafluoride (BF4-) as a counter ion in its chemical structure. In the study, DBF was incorporated with an acryl-silicon type resin to increase water-resista...
S N Kartal, W J Hwang, K Shinoda, Y Imamura


Effect of test site location on in-ground preservative performance after 6 years
2001 - IRG/WP 01-20231
Pinus radiata test stakes were treated with 4.1 kg/m3 of CCA and Fagus sylvatica with 6.1 kg/m3 of CCA. Both wood species were also treated with a copper plus triazole preservative (3 kg/m3 of copper) and chlorothalonil plus chlorpyriphos in oil (4.8 kg/m3 chlorothalonil). Furthermore, P. radiata was treated with ammoniacal copper plus a quaternary ammonium compound (2.6 kg/m3 copper) and a 60/40 ...
R N Wakeling


The effect of soil pre-exposure on the results of laboratory Basidiomycete testing
1991 - IRG/WP 2385
Scots pine sapwood blocks were treated with several concentrations of copper chrome arsenic (CCA), copper chrome boron (CCB) and a copper modified quaternary ammonium compound (CMAAC). Leached and unleached samples were exposed in a basidiomycete monoculture test using Coniophora puteana, a copper tolerant brown rot. Prior to testing half of the blocks were buried in unsterile soil for 4 weeks. Th...
S M Gray


Biological test, AAS and EPR study of copper monoethanolamine complex with quaternary ammonium compounds as a wood preservative
2003 - IRG/WP 03-30321
Experiments were carried out on the wood preservative with a strong fungicidal activity based on Cu(II) carbonate, 2-aminoethanol (monoethanolamine) and quaternary ammonium compound (QAC). The object of the performed investigations was sapwood of Scots pine (Pinus sylvestris L.) treated with Cu-EA-QAC formulation. Mycological investigations were carried out according to EN 113 and EN 84 standards....
B Mazela, I Polus, S K Hoffmann, J Goslar


Preliminary evaluation of new quaternary ammonia compound, didecyl dimethyl ammonium tetrafluoroborate for preventing fungal decay and termite attack
2005 - IRG/WP 05-30375
This study evaluates the decay and termite resistance of wood treated with didecyl dimethyl ammonium tetrafluoroborate (DBF), a recently developed quaternary ammonia compound containing boron. DBF contains boric tetrafluoride as a counter ion in its chemical structure. Laboratory decay resistance tests were performed using brown-rot fungus, Fomitopsis palustris and white-rot fungus, Trametes versi...
S N Kartal, W J Hwang, Y Imamura


The effect of stack height on the performance of preservatives used for the prevention of sapstain on seasoning wood
1997 - IRG/WP 97-10192
The performance of three anti-sapstain preservatives was investigated under field conditions in south east England. The preservatives under test were: copper-8-quinolinolate (Mitrol PQ8) trimethylalkylammoniumchloride and sodium hexanoate (Sinesto B) and chlorothalonil (Tuff Brite). The preservatives were tested on Corsican Pine grown in south east England. The field trial was set up to investigat...
J R Williams, D J Dickinson, J F Webber


Adsorption of ACQ components in wood
2010 - IRG/WP 10-30522
To investigate the chemical adsorption capacity of copper-monoethanolamine (Cu-Mea) components on wood, the Na+ cation exchange capacity (CEC) of red pine (Pinus resinosa Ait.) was determined and compared to the adsorption capacity of free Mea and Cu-Mea complexes. The CEC increased with increasing pH. Free Mea adsorption as a function of pH followed the sodium adsorption curve except at pH over 9...
Myung Jae Lee, P Cooper


Distribution and availability of preservative components in ACQ treated wood - effects of coatings and weathering
2010 - IRG/WP 10-30537
Copper and quaternary ammonium compound (quat) distributions across lumber (gradients) and availability, as measured by amount removed by intensive leaching of wood flour, were measured in ACQ treated southern pine lumber. Samples were evaluated just after treatment and stabilization, or after 3 years of laboratory storage, or after 3 years of natural weathering exposure. The objective was to in...
T Ung, M Nejad, P Cooper


Observations on the colonization of freshly-felled timber treated with prophylactic chemicals by mould and sapstain fungi
1989 - IRG/WP 1394
Field tests using freshly felled pine sapwood were set up to determine the effectiveness of a range of antisapstain compounds and to study the problems of colonization by mould and sapstain fungi. Differences were recorded both in the overall performance of the compounds and also their selectivity in controlling specific fungal types. These results were found to be useful in gaining a better under...
G R Williams, D A Lewis


The influence of previous anti-blue-stain preservative treatments on the fixation of CC in spruce
1997 - IRG/WP 97-30134
Freshly cut and kiln dried spruce boards were treated with 4 different anti-blue stain preservatives (ABP). After a period of 10 days allowing the samples to dry and fixate, the samples were treated with CC (chromium, copper formulation) using a vacuum pressure cycle. After impregnation the wood was steam fixed. A submersion leaching test showed differences in the leachable quantity of copper and ...
M Van der Zee, W J Homan


Kinetic modelling of adsorption of quaternary ammonium compounds by Scots pine wood sawdust (Pinus sylvestris L.)
2005 - IRG/WP 05-30369
The adsorption of new quaternary ammonium compounds from aqueous solutions onto Scots pine wood (Pinus sylvestris L.) sawdust was studied. The pseudo first- and second- order kinetic models were used for the mathematical description of the sorption dynamic process of QACs onto wood. The highest correlation coefficients were obtained for the pseudo-second order kinetic model, those suggest that che...
J Zabielska-Matejuk


Conditions for basidiospore production in the brown rot fungus Gloeophyllum separium in axenic culture
1984 - IRG/WP 1232
Attempts to control and optimize the production of hymenial structures and basidiospore production in Gloeophyllum sepiarium in axenic culture resulted in the proposal of the following conditions as being suitable. The dikaryotic mycelia originally isolated from basidiocarps could consistently be induced to produce hymenial structures and pure basidiospore collects if illuminated by near ultraviol...
J Bjurman


The performance of wood preservatives in soil-bed soft rot tests
1993 - IRG/WP 93-20007
Testing the efficacy of wood preservatives in soil is recognised as a fundamental part of the assessment of long-term wood protection in ground contact. Laboratory based tests can provide a hazardous environment in which a preservative can be challenged by a range of micro-organisms. This paper presents the results of tests carried out to investigate the performance of wood preservatives in a wet ...
G R Williams, S Caswell


Proposed degradation pathway for quaternary ammonium compounds by mould fungi
1996 - IRG/WP 96-10166
One group of chemicals that has attracted considerable attention as potential wood preservatives are the quaternary ammonium compounds (QACs). Based upon results of previous research this study confirmed the degradation pathway employed in QAC-tolerant fungi. For this experiment the two dialkylammonium compounds didecyldimethylammonnium chloride and dioctyldimethylammonium chloride were used. QAC-...
J L Bürgel, J Dubois, J N R Ruddick


Interaction mechanisms of F/Cr/As/B type preservative and wood
1981 - IRG/WP 3183
The paper reports results of investigations on the fixation of the components of a F/Cr/As/B preservative in wood and its lignin and cellulosic components....
N Ermush, I Andersone


A novel lipid-related compound, (Z)-1,7-nonadecadiene-2,3-dicarboxylic acid, produced by white-rot fungus Ceriporiopsis subvermispora
2001 - IRG/WP 01-10411
Lipid peroxidation is a possible oxidative process of lignin-degradation at a site far from the enzymes by selective white rot fungi. Production and peroxidation of saturated and unsaturated fatty acids by Ceriporiopsis subvermispora strongly suggests involvement of lipid peroxidation in its ligninolytic system. In this paper, a new aliphatic lipid-related fungal metabolite was isolated from wood ...
M Enoki, Y Honda, M Kuwahara, K Messner, T Watanabe


Effect of borate on uptake and efficacy of an anti-sapstain treatment
2005 - IRG/WP 05-30380
The potential for using borates to enhance uptake and efficacy of propiconazole-based anti-sapstain chemicals was assessed on ponderosa pine sapwood wafers. Borates had no consistent effect on either net solution absorption or propiconazole distribution in the wood. Even small amounts of borate, however, markedly improved the performance of propiconazole against fungal discoloration. These resul...
Jianju Luo, Hua Chen, J J Morrell


Antifungal properties of new quaternary ammonium and imidazolium salts against wood decay, staining and mould fungi
2004 - IRG/WP 04-30347
The biological activity of twenty-four potential wood preservatives – imidazolium and quaternary ammonium salts with a modified anion structure was determined employing screening agar-plate and agar-block methods. Experiments were carried out on Scots pine (Pinus sylvestris L.) wood. The aim of the performed studies was to investigate the effect of structure modification of IC and QAC with organ...
J Zabielska-Matejuk, W Wieczorek


Remedial treatment of joinery. Comparison of distribution of organic solvent preservative and ammonium bifluoride
1978 - IRG/WP 3115
It is some years since it was recognised in the United Kingdom that there was a problem of premature decay in untreated external joinery. Consequently, recommendations for preservative treatment were made by the Building Research Establishment, Princes Risborough Laboratory. In addition, the National House-Building Council has also included the preservative treatment of external joinery in its req...
J M Taylor


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