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Copper based water-borne preservatives: The biological performance of wood treated with various formulations
1987 - IRG/WP 3451
Wood samples treated with the various components of CCA preservative singly and in combination were tested against a soft rot organism, a copper tolerant brown rot organism and in soil burial both unleached and after leaching. The results suggest that, of the elements tested, fixed copper is essential for preventing soft rot attack and fixed arsenic is essential for preventing attack by a copper t...
S M Gray, D J Dickinson


Proposed degradation pathway for quaternary ammonium compounds by mould fungi
1996 - IRG/WP 96-10166
One group of chemicals that has attracted considerable attention as potential wood preservatives are the quaternary ammonium compounds (QACs). Based upon results of previous research this study confirmed the degradation pathway employed in QAC-tolerant fungi. For this experiment the two dialkylammonium compounds didecyldimethylammonnium chloride and dioctyldimethylammonium chloride were used. QAC-...
J L Bürgel, J Dubois, J N R Ruddick


Lignin-copper, a new wood preservative without arsenic and chromium
1992 - IRG/WP 92-3702
A more environmentally sound treatment for wood with preservatives containing no arsenic or chromium, has been developed and studied on a laboratory scale. The method involves a first step impregnation with an aqueous solution containing modified, water-soluble kraft lignin followed by a second step involving impregnation with a copper salt solution to give fixation of the lignin into a water-inso...
B Ohlsson, R Simonson


Rapid leaching test
1991 - IRG/WP 2367
An accelerated test which is suitable for measuring the extent of metal fixation in both chromium and non chromium containing preservatives is described....
J A Cornfield, M Bacon, A Lyman, C Waldie, M R Gayles


Copper binding capacity of modified wood flour
1992 - IRG/WP 92-3709
Wood flour was modified by reaction with oxidising agents and CCA preservative. The copper chromium and arsenic were removed from the CCA treated wood flour by an acid leaching procedure. The modified wood flours were allowed to react with copper acetate solution and the level of copper fixation achieved was determined. The modified wood flours had greater affinity for copper ions present in solut...
N C Milowych, W B Banks, J A Cornfield


The use of chlorothalonil for protection against mold and sapstain fungi. Part 1: Laboratory evaluation
1989 - IRG/WP 3515
Laboratory screening of chlorothalonil alone and in combination with other fungicides was conducted against six mold and sapstain fungi. The most promising treatments appear to be chlorothalonil supplemented with CCA or copper-8-quinolinolate. Field tests have been implemented....
J A Micales, T L Highley, A L Richter


Assessment of contamination of soil and water at a CCA treatment plant: A demonstration project
1996 - IRG/WP 96-50067
Soil, sludge, dust and water samples were collected at a copper/chromium/arsenic wood preservation plant. Contamination of soil, sludge, dust and surface water with copper, chromium and arsenic was detected. Levels of contamination were sufficiently high to require remediation. Contamination originated from preservative solution dripping from recently treated wood. Migration of contaminants was vi...
P N Durrant, D C R Sinclair, G M Smith


The effective control of moulds on freshly impregnated wood
2004 - IRG/WP 04-30352
Beside natural timber it is known, that moulds can also groth at the surface of impregnated wood. This material shows “defects” like resistant dark spots or color changes and causes complaints. During the last years, the problem by moulds seems to increase. Laboratory studies were carried out to show the effect of impregnations against moulds. Wood samples (Pinus sylvestris L.) were impregn...
G Cofta, K Lutomski, P Jüngel


Oxalic acid production of fifteen brown-rot fungi in copper citrate- treated southern yellow pine
2001 - IRG/WP 01-10388
Non-arsenical copper-based wood preservatives have grown in number since the 1980's as a response to environmental concerns posed by arsenicals. Interest in copper tolerant decay fungi has increased accordingly. Oxalic acid (OA) production by brown-rot fungi has been proposed as one mechanism of copper tolerance. Fifteen brown-rot fungi representing the genera Postia, Wolfiporia, Serpula,...
F Green III, C A Clausen


Use of the Pilodyn to assess deterioration of treated aspen waferboard after 30 months of outdoor exposure
1986 - IRG/WP 2254
Samples of preservative treated aspen waferboard exposed outdoors for 30 mo. were compared using pin penetrations of the 6 Joule Pilodyn. These results correlated well with rankings of treatment performance based on more laborious standard mechanical tests, and demonstrate the potential for use of the Pilodyn as a tool to evaluate wood composites in test exposures with minimal destruction....
E L Schmidt, M G Dietz


Recycling of impregnated timber: Part 2: Combustion trial
1999 - IRG/WP 99-50132
Totally 270 m3 (61,3 t) of CCA impregnated wood was chipped and incinerated at the combustion plant of Jalasjärvi. After the normal gas cleaning venture scrubbers were tested. After the trial a metal balance was calculated. Ash was treated at the copper smelter of Outokumpu Harjavalta Metals Oy. Condensate waters were transfered to the Outokumpu's CCA production plant and utilized by the...
L Lindroos


Metal carboxylates for wood pest control
1996 - IRG/WP 96-30109
Metal carboxylates have been used as wood preservatives for more than fifty years. Predominantly salts of naphtenic acids have been commercially applied so far. They have water repellent as well as fungicidal and insecticidal properties. In the last years, metal carboxylates of saturated fatty acids were introduced. Fatty acids with 7-10 carbon atoms already have fungicidal activity by themselves....
F Pohleven, M Petric


Performance of chromated copper arsenate-treated aspen fence posts installed in Forintek's Eastern test plot from 1951 to 1963
1984 - IRG/WP 3272
Aspen poplar fence posts were pressure treated by the full cell process using three formulations of copper chrome arsenate wood preservative. A total of one hundred and fifty nine of the posts were installed in service in Forintek's Chalk River post plot from 1951 to 1962. During the 1982 general inspection of the post plot all 159 posts were still in service. A groundline inspection was ...
C D Ralph


Literature survey on the permanence and distribution of salt-type wood preservatives
1969 - IRG/WP III 1B
The objective of this survey is generally to review some of the more important published work dealing with the distribution and permanence of salt-type waterborne wood preservatives in treated timber. The survey is limited to the major chrome-containing formulations and the classification system proposed by Becker (1964) has been adopted throughout. CK - chromium, copper (copper, chrome); CKA - c...
Anonymous


Migration of Metals from Douglas-fir Lumber Treated with ACZA or Pentachlorophenol Using Best Management Practices: Preliminary Tests
2005 - IRG/WP 05-50224-4
The potential for migration of preservative components from ammoniacal copper zinc arsenate (ACZA) and pentachlorophenol treated Douglas-fir lumber in non-soil contact exposure was assessed in a simulated rainfall device. Metal levels from ACZA treated wood were elevated for the first 30 minutes of rainfall and then declined sharply. Repeated cycles of rainfall led to declines in initial metal l...
J J Morrell, Hua Chen, J Simonsen


Contribution of wood components on the absorption of copper amine
2000 - IRG/WP 00-30216
The contribution of wood components on the absorption of copper amine was investigated. Holocellulose, lignin and xylan absorbed significant amount of copper. The amount of copper absorbed by cellulose was almost negligible. The removal of extractive also decreased the amount of copper absorption. This study clearly indicates the importance of lignin, hemicellulose in the absorption of copper amin...
D P Kamdem, Jun Zhang


Copper based water-borne preservatives: The use of a thin section technique to compare the protection of wood by copper based preservatives against soft-rot and bacterial decay
1987 - IRG/WP 2286
This paper describes the techniques developed and gives examples of results obtained for the performance of copper based wood preservatives against both the bacterial and fungal hazards....
A M Wyles, D J Dickinson


The Effect of Heat on the Retention of Ammoniacal Copper Quat (ACQ-AB) onto Scots Pine (Pinus Sylvestris L.) Wood
2008 - IRG/WP 08-40390
In this study, the sapwood of Scots pine (Pinus sylvestris L.) were treated with ammonical copper quat type (ACQ-AB), which is one of the environmentally friendly wood preservatives, by using soaking method as a functions of various temperatures and time. The results indicated that the retention behaviour of ACQ onto the wood was considerably affected by temperature of ACQ solution and treatment t...
M Hakki Alma, A Mukremin Kara


A study of salt imbalances observed in recycled copper/chrome/arsenic preservative solutions in commercial practice
1987 - IRG/WP 3461
The study reported monitored tank solutions, sludge and other by-products using a standard CCA solution, when recycled. This recycling of the CCA solution is quite usual in between any commercial treatment schedules. Salt imbalances were observed and the possible reasons for such phenomena were studied. The paper discusses the procedure followed, the method of sampling the liquid after the charge ...
V R Sonti, S Sonti, B Chatterjee


Treatability of Siberian larch and spruce with chromated copper arsenate
1996 - IRG/WP 96-40060
Heartwood of Siberian larch (Larix gmelini) and spruce (Picea jezoensis) was pressure treated with chromated copper arsenate (CCA) Type B using a full cell process. Larch heartwood was somewhat difficult to treat than the spruce, although both species did not meet a minimum requirements of penetration and retention specified by the American Wood Preservers' Association (AWPA) for difficul...
Gyu-Hyeok Kim, Woo-Gue Jee, Jae-Jin Kim


EPR investigations of interactions between ammoniacal Cu(II) octanoate and wood
1996 - IRG/WP 96-30110
Ammoniacal solutions of copper(II) octanoate [ C u . h l f . 2 . r h l f.(O2CC7H15)4], interactions of these solutions with wood and wood components, and leaching of copper(II) octanoate from impregnated wood samples, have been studied by electron paramagnetic resonance (EPR) method. It is still not clear if in the Cu(II) octanoate - water - ammonia system, Cu(II) remains in a (copper(II) octanoat...
F Dagarin, M Petric, F Pohleven, M Sentjurc


Fungi associated with groundline soft rot decay in copper/chrome/arsenic treated heartwood utility poles of Malaysian hardwoods
1992 - IRG/WP 92-1567
Copper-chrome-arsenic treated heartwood from Malaysian hardwood utility poles in service for 8-23 y at two localities in the wet tropical Peninsula Malaysia were surveyed for soft rot in the ground-contact region. Soft rot decay was detected in all the poles. Isolation studies indicated the ability of a variety of microfungi and basidiomycetes to colonize treated heartwood. Most isolates exhibited...
A H H Wong, R B Pearce, S C Watkinson


The Chemical and Biological Properties of Polymeric Betaine
2009 - IRG/WP 09-30512
Didecyl polyoxyethyl ammonium borate (DPAB), also known as Polymeric Betaine, was developed as a co-biocide for chromium-free copper based wood preservatives in Europe in the 1980’s. DPAB as a wood preservative has been reported previously. This paper summarizes the chemical, physical, and biological properties of DPAB. ...
H Härtner, S Schmitt, Futong Cui, H M Barnes


The Effect of Soil pH on the pH of Treated Southern Pine in Ground Contact after 12 Months
2011 - IRG/WP 11-50281
Southern pine samples treated with soluble and particulate copper solutions were subjected to three soils that had been amended to provide acidic, neutral and alkaline conditions. Wood pH was measured prior to, and after 6 and 12 months after being placed in the soil to determine the effect of soil pH on wood pH....
L Jin, C Schauwecker, C Vidrine, P Walcheski, A Preston


Antifungal properties of new quaternary ammonium and imidazolium salts against wood decay, staining and mould fungi
2004 - IRG/WP 04-30347
The biological activity of twenty-four potential wood preservatives – imidazolium and quaternary ammonium salts with a modified anion structure was determined employing screening agar-plate and agar-block methods. Experiments were carried out on Scots pine (Pinus sylvestris L.) wood. The aim of the performed studies was to investigate the effect of structure modification of IC and QAC with organ...
J Zabielska-Matejuk, W Wieczorek


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