IRG Documents Database and Compendium


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Determination of Izod Impact Strength on Wood: A Suitable Method to Detect Fungal Decay in Protective Effectiveness-Screenings of Wood Preservatives
2012 - IRG/WP 12-20484
For testing a large number of different substances regarding fungicide properties, the reduction of the decay test duration is advantageous. In the present paper the suitability of a method for testing plastics using an impact testing machine was examined. The results clearly show that the fungal attack of European beech by the white-rot fungus Trametes versicolor leads to a decrease of izod imp...
H Delenk, M Zauer, A Wagenführ


Use of X-Ray Micro-Computed Tomography to Visualize Copper in Preservative Treated Wood
2012 - IRG/WP 12-20488
This study tests the hypothesis that X-ray micro-computed tomography will be able to visualize the distribution of copper in wood treated with a micronized wood preservative containing copper carbonate. A small wood block measuring 12 x 12 x 19 mm was cut from a 2.4 m x 51 mm x 51 mm southern pine batten that had been treated with a micronized wood preservative. Tomograms of the wood block were ob...
P D Evans, A Limaye, H Averdunk, M Turner, T J Senden, M A Knackstedt


Performance of Wood Protection Systems at Multiple Field Test Sites Using the Ground Proximity Test Method
2012 - IRG/WP 12-20499
A series of preservative systems were used to treat southern pine ground proximity test samples which were then exposed at a range of test sites located throughout the world. The sites were chosen on the basis of having vastly different Scheffer Climate decay indices. After almost 14 years exposure, distinct differences are apparent in how different preservative systems perform at the different ...
A Zahora, A Preston, L Jin


Effect of an antioxidant on the efficacy of organic wood preservatives in an accelerated soil contact decay test
2012 - IRG/WP 12-30583
In comparison to inorganic wood preservatives, organic biocides in transient carriers are considerably less effective when the treated wood is exposed to soil contact. Various oils are used in some formulations with pentachlorophenol to improve the efficacy. However, use of these oils imparts unacceptable properties to products used in residential applications. Consequently, there is a need to de...
D D Nicholas, J Shi, T P Schultz, L Sites


Tannin resin-boron associations: Leaching and biological resistance
2012 - IRG/WP 12-30587
The easy leaching of boron in wood preservation formulations has allowed to use this fungicide only for short term applications. The recently discovered adduct with flavonoids allows boron to resist longer periods of time within wood and consequently extend its life. Two different leaching treatments were compared and the fungal and termite decay was examined. The biological tests have shown extre...
G Tondi, S Wieland, N Lemenager, A Petutschnigg, A Pizzi, M-F Thevenon


Mold Control for Treated Lumber in Block-Stack Storage Conditions
2012 - IRG/WP 12-30588
The mold development and control for freshly treated and block-stacked wood have been evaluated using a green house mold testing method. The results for the mold resistance of several commonly used water boron preservative treatment systems, such as ACQ, Copper Azole, and borates with and without inclusion of mold inhibitors are presented. The data suggest that the different preservative treatme...
L Jin, P Walcheski, A Preston


Smart hydrogels from low molecular weight amphiphilic compounds: toward a solution to decrease leachability and increase efficacy of boron preservatives?
2012 - IRG/WP 12-30589
A new catanionic system associating amphiphilic carnosine (AlaHisC8) and lauric acid forms supramolecular hydrogel at very low concentration. This gel was investigated and we have checked the validity of the concept of hydrogels utilization to reduce boron leachability and to develop new wood protection treatments. Impregnation with 5% aqueous borax solution (w/w) and 0.3% gelator agent (...
F Obounou Akong, P Gérardin, C Gérardin-Charbonnier


Evaluation of Five Novel Organotin(IV) Complexes as Wood Preservatives
2012 - IRG/WP 12-30590
Three selected non durable tropical wood species namely Alstonia scholaris (pulai), Macaranga triloba (mahang) and Hevea brasiliensis (rubber) were chemically impregnated with five novel organotin(IV) complexes using vacuum-pressure treatment method. The objectives of this study were to determine the treatability and efficacy of novel organotin(IV) complexes against white and brown rot decay fungi...
M M Rahman, I Jusoh, M A Affan, A Husaini


Termite resistance of copper-based preservative supplemented aspen strandboards
2012 - IRG/WP 12-30594
Termite resistance of aspen strandboards treated with various copper-based preservative systems was evaluated in field exposure tests. Five copper-based chemicals or zinc borate were blended into aspen furnish at three retention levels prior to pressing. Tebuconazole or 4,5-dichloro-2-N-octyl-4-isothiazolin-3-one (DCOI) were added as co-biocides to selected copper-based treatments. Sections from...
J J Morrell, C Vidrine, A Preston, L Jin


Mobilized copper(II) concentrations in earlywood and latewood of micronized copper treated red pine
2012 - IRG/WP 12-30596
Electron paramagnetic resonance (EPR) was used in conjunction with energy dispersive x-ray spectroscopy (EDX) to quantify total copper and mobilized copper retentions in MCQ and MCA treated red pine. The MCQ treated red pine was found to have higher copper retention than that of the MCA treated one. Earlywood in general had higher total copper content than latewood. The mobilized and complexed cop...
Wei Xue, P Kennepohl, J N R Ruddick


KERUING and APITONG: A Timely Review of the Perfect Choice Wood Species for Crossarms and Brace Arms, Including Data on Copper Naphthenate Treatments
2012 - IRG/WP 12-40603
Apitong or the wood species more commonly known as Keruing is an important tropical hardwood known for its high strength to weight ratio and its reasonable durability and preservative treatability. This wood has been exported from managed permanent forest estates in Malaysia into the United States for over 4 decades for its widespread use in wooden utility industry brace arms and crossarms, yet cu...
A Wong, M Freeman


Scale-up of a chemical process for copper-based preservative-treated wood wastes recycling
2012 - IRG/WP 12-50286
In recent years, the development of appropriate wood waste disposal options has been encouraged by severe regulations and expensive fees associated with wastes landfilling or burning. An efficient and economically attractive leaching process was developed at laboratory scale (200 mL) for CCA-, ACQ- and CA-treated wood wastes recycling. This leaching process consisted of three leaching steps of 2 h...
L Coudert, L Gastonguay, J F Blais, G Mercier, P Cooper, P Morris, A Janin, N Reynier


Efficiency of the Amazon Forest Oils as Preservatives to the Attack of cellulolytic fungi in Pine Wood
2012 - IRG/WP 12-30599
The bobbins of wood are used for storage and field installation of cables from the electricity and telecommunications sectors. There are legal requirements governing the Brazilian ways of treating the wood used in these sectors, aimed at preventing pollution and protecting nature. When exposed to severe environmental conditions in Brazil these products are degraded and occurs many operational prob...
S Silveira, I M S Mendes, R S Paiva, J E Volponi, R C G Comar, R S Cruz


Copper naphthenate treatment for wood pols - a review and update
2012 - IRG/WP 12-30600
This paper reviews copper naphthenate (CuNap) and its utility as a treatment for wooden utility poles. One of the principal reasons that CuNap has gained market acceptance, in addition to its efficacy against decay fungi and wood-destroying insects, is its low mammalian toxicity. CuNap is a well-proven non-restricted use preservative, used extensively and specified for environmental reasons by ut...
J A Brient, M H Freeman


Effectiveness of CCA-C and CCB preservatives after a 30 years stake test
2012 - IRG/WP 12-30606
The objective of this experiment was to assess the durability of four pine species treated with waterborne preservatives. In order to determinate this, a stake field test, following the IUFRO (International Union of Forestry Research Organizations) recommendations, was installed at Experimental Station of Luiz Antonio (21º 32’ S and 47º 42’ W), State of São Paulo, Brazil. Species under t...
I PJankowsky, E S Lepage, C Salvela, J M Vidal, S Takeshita


A case study of investigating fungi that affect traditional Japanese shake roof with/without copper plates
2013 - IRG/WP 13-10810
A Japanese traditional shake roof is made from split logs. To keep the roof long, copper (Cu) plates are often inserted between the shakes. It has been thought that Cu elements from copper plates would flow out when a shake roof is exposed to rain and inhibit growth of wood rotting fungi. Actually there are some examples where the Cu plates seem to be effective in preventing fungal damage, but on ...
T Wada, Y Fujiwara, Y Fujii, R Kigawa


Developing Analytical Methods for Determination of Quaternary Ammonium Compounds (DDAC) using HPLC and HPLC-MS (Application to treating solution and preservatives treated wood)
2013 - IRG/WP 13-20516
Korea preservative treating industry has mainly used alkaline copper quaternary (ACQ) expected over 80% of market share in Korea. ACQ employs dodecyl dimethyl ammonium chloride (DDAC) and benzyl dimethyl dodecyl ammonium chloride (DBAC) for active ingredient along with copper. The strongly increasing domestic applications for wood preservatives require developing accurate and reproducible analytic...
Sung-Mo Kang, Kwon-Min Kim, Won-Mo Koo, Myeong-Won Cho


Preliminary testing of spiroborate esters as wood preservatives
2013 - IRG/WP 13-30614
Fungicide and insecticide properties of boric acid are known since 30’s of the last century, but high solubility and leachability of inorganic borates limit their use for only applications not directly exposed to liquid water. A number of attempts were made to fixate borate salts into the wood structure but this research topic is still up to date and undiscovered. Water insoluble organoboron est...
D Panov, N Terziev


Effect of soil contact on reacted copper(II) levels in micronized copper treated wood
2013 - IRG/WP 13-30616
Small 3 to 4 mm thick and approximately 80 to 100 mm long, samples were removed from wood treated with micronized copper quat (MCQ) or micronized copper azole (MCA) and buried full length in a soil bed. Samples were removed after 2, 4 and 8 weeks. The total copper was determined by x-ray fluorescence (XRF) spectroscopy and the amount of reacted micronized copper measured by electron paramagnetic r...
Wei Xue, P Kennepohl, Xingguo Jin, J N R Ruddick


Copper Coating on Wood: a New Way of Protecting Wood
2013 - IRG/WP 13-30617
Thermal spray metal coating technology was used to apply a thin layer of copper on the surfaces of a number of wood species. The adhesion of metal coating to mahogany, oak, soft maple, spruce, white pine and medium density fibreboard (MDF) was evaluated by pull off adhesion test. The resistance of copper coated wood samples to mildew were assessed in the lab. Also, the decay resitance and water re...
M Nejad, R Shafaghi, L Pershin, J Mostaghimi, P Cooper


The effects of impregnation with secondary metabolite extracted from Ipe on durability of Japanese cedar and beech wood
2013 - IRG/WP 13-30618
Ipe wood is known for its high durability; it has been widely used in exterior structures that are exposed to the weather. In this paper, to increase the durability of less durable wood, Japanese cedar and beech specimens were impregnated with a secondary metabolite from Ipe. In a previous study, secondary metabolites extracted by a Soxhlet extraction method showed antifungal properties. Therefore...
T Iida, R Konuma, K Kawarada


Preparation of Copper Rosinate Emulsion and Its Resistance against Wood Decay Fungi
2013 - IRG/WP 13-30619
A leaching-resistant water-borne copper preservative was prepared by means of the following three steps: (1) Gum rosin was saponified with potassium hydroxide. (2) The soap reacted with copper sulfate to form copper rosinate. (3) The copper rosinate was emulsified with a mixture of Tween 20 and Span 80. Poplar (Populus ussuriensis) wood was impregnated with 0.5%, 1.0%, 1.5%, or 2.0% of the copper ...
Mingxin Zhang, Shujun Li, Qian Wang, Bo Li, Qiong Wu


Copper leaching from copper-ethanolamine treated wood during exposure to terrestrial microorganisms
2013 - IRG/WP 13-30621
Copper-ethanolamine based wood preservatives are still the most important solutions for protection of wood in ground applications in Europe. Wood in ground is exposed to variety of organisms, which can act synergistically. In order to simulate these conditions in laboratory, Scots pine (Pinus sylvestris) specimens impregnated with copper-ethanolamine preservative of three different concentrations ...
M Humar, N Thaler, B Lesar


The Concept of Copper and Boron Synergy: Why Copper Naphthenate and Borates are a Couple Made in Heaven
2013 - IRG/WP 13-30622
Fungicides are often combined for four basic reasons:(1) to widen the spectrum of the fungicidal activity in which to broaden the spectrum of activity, (2) to exploit additive and synergistic activities between actives, and the activities are increased and thereby reducing the needs for the higher loadings of the active in the substrate, (3) to delay the resistance of one of the actives in the for...
M H Freeman


Performance of untreated wood and wood impregnated with copper-ethanolamine based preservative solutions in Northern Adriatic Sea
2013 - IRG/WP 13-30623
Sea water applications of wood are among the most challenging ones. Impregnated wood is exposed to leaching and to variety of marine borers, Limnoria sp. and Teredo sp. being the most important. In the present research, durability of pine wood impregnated with copper-amine based preservative solution (Silvanolin) of different concentrations, exposed to the sea water, was investigated according to ...
M Humar, M Petrič, J Adamek, B Lesar


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