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A Green and Novel Technology for Recovering Copper and Wood from Treated Wood Waste – Part II: Optimization, copper metal recovery, and process design
2017 - IRG/WP 17-50326
The US consumes 70 million pounds of copper and produces 580 million cubic feet treated wood annually. The EPA disallows burning and reusing treated wood waste due to health/environmental concerns. Vast quantities of copper and wood are landfilled. Two safe and low cost extraction systems, citric acid and ammonium citrate, were identified in Part I of this study. In Part II of the study, effects o...
S Chen, R Patel


Review of Leaching Experiments of CCA-Treated Wood and Wood Treated with Copper-based Alternatives
2017 - IRG/WP 17-50330
The objective of this study was to compare leaching rates of various wood preservatives from treated wood and the tests used to gather this information. The preservatives compared included CCA and the copper-based alternatives, MCQ, ACQ, and MCA. The tests compared included AWPA E11, SPLP, TCLP, and environmental leaching tests. Among all of the tests evaluated, environmental tests most closely si...
A Jones, J Marini, H Solo-Gabriele


Exterior paint for the future - Will there be any dry-film preservatives left?
2017 - IRG/WP 17-50332
Wooden houses have a long tradition in several of the Nordic countries. Wood can be protected in various ways; constructional, chemically and by surface treatment. The use of various types of exterior paints as a surface treatment is a common way to prolong the durability of the wood. To further protect the painted surface against growth of fungi and algae, dry-film biocides remains an essential p...
H Jensen, M Sandve, S M Lystvet


Liquefied wood polyols: Ecofriendly bio-based preservative for sustainable protection of wood from Termite attack
2018 - IRG/WP 18-10916
The major problems encountered in both indoor and outdoor utilization of wood are biological decay due to termite. The modification of wood with liquefied wood polyols has been found to be effective against termite attack. The liquefaction of wood aims to utilize woody wastes which are being generated during primary and secondary processing of wood in wood based industry. One of promising approach...
A Kumar, A John, T S Mehra, A K Pandey, S Singh Chauhan


Certification system for treated wood and wood preservative in the relation to regulations in Japan
2018 - RG/WP 18-20639
Certification system about wood protection products in Japan is described to understand the interaction between regulations and certifying organizations. Major regulations are Building Standard Law, Chemical Substances Control Law, Poisonous Deleterious Substances Control Act, Japanese Industrial Standards, and Japanese Agricultural Standard (JAS). Treated wood products are certified with JAS mark...
K Yamamoto, I Momohara


Can CCA be substituted as reference preservative?
2018 - IRG/WP 18-20641
While field testing of wood protective formulations remains probably the best method to find out the effective preservative concentration, the use of chrome-copper arsenate (CCA) as reference becomes debatable due to environmental and legislative reasons. This emerges from the European standardization bodies who have discussed reference alternatives that can omit the use of CCA. The present debate...
N Terziev, M Jebrane, P Larsson Brelid, N Morsing, P-O Flaete, P Torniainen, J S Kim, G Daniel


Bio-preservative properties of technical lignins from South African pulp mills: An investigation towards a conceptualized development of natural compound-based wood preservatives
2018 - IRG/WP 18-30724
The depletion of naturally durable timber and the risk posed by some of the conventional wood preservatives to human health and the environment continue to drive research efforts towards developing new formulations that are benign. Furthermore, the global concept of environmental sustainability aims at optimal use of resources and to comprehensively include conversion of waste to value added produ...
A Alade, L Tyhoda, M Meincken


Liquefied wood polyols: a bio-based preservative for protection of wood from fungal decay
2018 - IRG/WP 18-30725
The liquefaction of wood is one of promising approaches in utilization of woody waste which is generated during primary and secondary processing of wood and liquefied wood having various application including bio-based preservatives. The biological degradation of wood due to fungi is the major problem encountered in indoor and outdoor utilization of wood. In this study, woody waste recovered from ...
A Kumar, G Vijaylakshmi, S Singh Chauhan


Improvement of analytical methods of wood preservatives and its validation with collaborative testing
2019 - IRG/WP 19-20655
This discussion paper presents on-going collaborative test of analytical methods of wood preservatives according to the standardization process of Japan Agricultural Standard (JAS) by the Ministry of Agriculture, Forestry and Fisheries (MAFF). Food and Agricultural Materials Inspection Center (FAMIC) in close cooperated organization with the MAFF, has wide range of tasks about inspections and anal...
T Miyauchi, K Yamamoto, N Shota, Y Akabori, M Ikeda, J Eisawa, K Kambara, T Osawa, C Igarashi, Y Baba, W Ohmura, M Shimizu, M Samejima


COPPER NAPHTHENATE: A Product for All Seasons: Protecting the Americas’ Infrastructure for Over 100 Years and Potential for Expanded Usage in Europe
2019 - IRG/WP 19-30738
This paper is a brief review of the history and use of the wood preservative Copper Naphthenate, with a focus on use patterns within the USA and opportunities for expansion in Europe and Canada. This paper reviews how copper naphthenate has performed to preserve and protect cellulosic and wooden items essential to critical infrastructure, and why it is the ideal choice for use in the replacement o...
M H Freeman, J A Brient, M Manning


Boron dual-treatments for Douglas-fir utility poles: Tracking boron migration over time
2019 - IRG/WP 19-30739
The potential for using boron pressure-treatment prior to over-treatment with conventional, heavy-duty wood preservatives to limit internal decay in-service was investigated in two field tests on Douglas-fir utility poles. Pole sections were pressure-treated with disodium octaborate tetrahydrate (DOT) and then over-treated with either pentachlorophenol or copper naphthenate in oil. Alternatively, ...
J Cappellazzi, M J Konkler, J J Morrell


Relative efficacy of various oxine copper formulations against brown-rot fungi
2019 - IRG/WP 19-30741
This paper investigates the relative resistance of three different oxine copper formulations (oil-borne, water-borne, water-borne with pH-adjustment) as a preservative treatment for wood against brown-rot fungi. Impregnated southern pine sapwood cubes were exposed to R. placenta and G. trabeum cultures in a soil-block test. After eight weeks, the weight losses of the cubes were examined in relatio...
M Petruch, J Lloyd, A Taylor


Performance of field cut preservatives above-ground and in ground contact exposures
2019 - IRG/WP 19-30742
Field cut preservatives are needed to protect cut ends and drill holes that expose the untreated interior of preserved wood. A series of field cut preservatives were assessed in ground contact and above-ground exposures. After 10 years in ground contact exposure, all of the untreated controls had failed or exhibited very advanced decay. In contrast, the copper naphthenate (2% Cu in mineral spirits...
R Stirling, D Wong


Effect ofNano-Copper Oxide on Decay Resistance of Pistachio Twig-Plastic Composite
2019 - IRG/WP 19-30750
The goal of our study was to investigate the decay resistance of pistachio twig-plastic composite treated with nano-copper oxide against the white rot fungus Trametes versicoloer and the brown rot fungus Coniophora puteana. For this purpose, wood–polypropylene composites (WPCs) containing different loadings of nano-copper oxide, namely 0, 1, 2 and 3 percent (W/W), were made from pistachio (Pista...
M R M Farahani,S Pourabdollah


Economic and Alternative Preservative Research with an Overview of its Impact on the Dynamics of Wood Tie Markets and Railroads
2019 - IRG/WP 19-30751
This presentation will discuss the Railway Tie Association’s (RTA) efforts in economic research for the North American wood tie industry, along with decades-long research into improving wood preservation processes and its resulting economic impact for railroads. Ongoing research is continuing to expand the knowledge-base by comparing existing standard creosote (C) and borate-creosote (B-C) dual...
J C Gauntt


Effect of damage to polyurea coatings on metal losses from ammoniacal copper zinc arsenate treated Douglas-fir pile sections
2019 - IRG/WP 19-40867
Metal-based preservatives remain the most widely used treatments for protecting wood in soil or water contact. While these treatments are highly effective, one drawback is a tendency for small amounts of metal to migrate into the surrounding environment. The greatest risk in this regard is copper because many organisms are highly sensitive to this metal. While post treatment practices can reduce ...
M J Konkler, J J Morrell


Effect of pretreatment of wood surfaces with a copper monoethanolamine solution on the natural weathering performance of semitransparent stains
2019 - IRG/WP 19-40881
Semitransparent stains for wood products are favored for outdoor applications in Japan because these finishes do not hide the wood grain. However, the photoprotective effects of wood surfaces are low, therefor there is a need to improve the weathering performance. We examined the natural weathering performance of semitransparent stains on wood pretreated with a copper monoethanolamine solution (Cu...
S Isaji, H Shibui, Y Hirabayashi


Monitoring of wood preservatives exposed to weathering: Extraction and analysis methods of organic biocides from treated wood and collected rain runoff
2020 - IRG/WP 20-30753
Weathering is the cause of numerous damages for outdoor joineries. Protection of wood using a preservative treatment covered with a coating is a process widely used to limit these damages. However, biocides from preservative treated wood are prone to degradation and leaching, having a direct influence on the joinery service life. This document deals with extraction and analytical methods for bioci...
O Ouali, K Le Ménach, E Raphalen, L Podgorski, S Legay, H Budzinski


Longterm Performance of Treated Timbers in Marine Exposures
2020 - IRG/WP 20-10969
The performance of preservative-treated or modified woods in marine exposures was evaluated at test sites in Newport, Oregon, USA and Brisbane, Queensland, Australia. All samples have exhibited excellent performance at the Newport, Oregon site, while attack was more aggressive at the sub-tropical Brisbane site. Acetylated wood as well as samples treated with 7.3% chromated copper arsenate (CCA-T...
M Konkler, A R Zahora, J Norton, J J Morrell


Potenzy of Azadirachta indica heart wood extracts as wood bio-preservative against termite attack
2020 - IRG/WP 20-10972
Extractives in wood are one of the main reasons for wood resistance against bio-degradation. The chemical compositions of extractives from matured Azadirachta indica that are known to be very resistant against bio-degradation were studied to assess their role as wood preservative. Ethanol and toluene were used in the extraction of these compounds from the heartwood of Azadirahcta indica. Chemical ...
L O Aguda, O B Olajide, O Y Aguda


Monitoring uptake and penetration of pesticides during impregnation of pine (Pinus sylvestris) and spruce (Picea abies) wood with bio-based microemulsion gel formulations
2020 - IRG/WP 20-30756
Even in dry state wood is susceptible to biological degradation. Preservation against biological decay in exposed conditions is conventionally achieved by impregnating the wood with pesticides applied at professional and industrial levels. Impregnation of wood with preservatives is a complex process that involves wood macro- and microstructure, and the physical characteristics of woods. Here we fo...
D Messaoudi, K Ruel, J-P Joseleau


Efficiency of three resin fractions from Aucoumea Klaineana Pierre, Canarium schweinfurthii Engl and Dacryodes edulis (G. Don) H. J. Lam from Gabon combined with Tebuconazole as wood preservatives
2022 - IRG/WP 22-10998
Pure resins from Aucoumea Klaineana, Canarium schweinfurthii and Dacryodes edulis were harvested and then hydro-distilled to obtain essential oils and purified resins fractions. Due to the potential leaching and volatility hazards of the compounds that constitute these fractions, resins and essential oils were combined with tebuconazole to produce both antifungal and anti-termite wood preservative...
W F Bedounguindzi, K Candelier, P Edou Engonga, S Dumarcay, M-F Thevenon, P Gerardin


Evaluation of ecotoxicological effects of different coniferous wood treatments on two marine bioindicator species
2022 - IRG/WP 22-10999
Coniferous wood panels (Picea abies) were treated with two concentrations of copper-based impregnating agent to increase its durability in marine and brackish environment. In order to assess the environmental compatibility of the treatments a laboratory experiment was conducted with two marine invertebrate species: bivalve Mytilus galloprovincialis and a gastropod Steromphala albida. The bioindica...
T Marčeta, N Nesto, I Guarneri, D Tagliapietra, V Moschino


Measurement of copper concentration in Cu-HDO treating solutions by handheld XRF
2022 - IRG/WP 22-20685
Copper based preservatives diluted in water dominate the wood preservative industry around the world. Periodically measurements and adjustments of the concentration of treating solutions must be performed as a part of the quality control at the treatment plant to achieve desired quality of the preservative treated wood. Many analytical methods are time consuming and must be performed under laborat...
P O Flaete


Discrimination of five commercial wood preservatives by handheld near-infrared spectrometers and Multivariate Data Analysis
2022 - IRG/WP 22-20686
Nowadays, the recycling potential of wood waste is still limited, because of a lack of reliable lack of a reliable and fast device allowing the discrimination of preservative-treated wood that contains organic or/and inorganic contaminants. The purpose of this study was to set up a methodology, based on a SCiO low-cost handheld NIR spectrometer, and multivariate data analysis (MDA). Spectra was ob...
M Rubini, P Dulucq, B Charrier


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