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Ammoniacal Copper Zinc Arsenate Preservative Treated Wood Ties Their Performance in Testing and Track
2014 - IRG/WP 14-30636
While not a new preservative system, Ammoniacal Copper Zinc Arsenate (ACZA), had not previously been used to protect crossties. Its performance in treating difficult or refractory species of wood has been documented through its wide range of uses approved in AWPA. The establishment of appropriate testing for railroad material use was put in place and includes laboratory, field as well as commercia...
T Carey


Cost effective extension of service life of bridge tie (sleepers) - Effectively applying borate during Boulton conditioning and treatment with copper naphthenate
2014 - IRG/WP 14-30637
Current longevity of creosote treated wooden bridge ties in the South Eastern US is about 15 to 25 years, which is well below of the average service life of 33-50 years of railroad ties. Such short service life increases costs associated with maintenance of railroads including bridge down time for tie replacement as well as the cost for the new ties themselves. Because of this, many railroads are...
J D Lloyd, T Chambers, J-W Kim


Copper naphthenate treatment for wood crossties and timbers
2014 - IRG/WP 14-30647
Copper naphthenate (CuN) has a long history in wood preservation and is recently finding increased usage as a treatment for wooden crossties and timbers. One of the principal reasons that CuN has gained market acceptance, in addition to its efficacy against decay fungi and wood-destroying insects, is its low mammalian toxicity and environmental impact. CuN is a well proven non-restricted use pres...
J Brient


Migration of copper from copper naphthenate treated Douglas-fir poles during storage
2014 - IRG/WP 14-50302
Preservative migration from treated wood products has raised concerns among regulators, especially when the biocides move into surface waters. In most cases, chemical levels are well below the acceptable minimum level, but can become a concern if large quantities of treated wood are stored in one location. One such case would be a location where utility poles are stored for use in emergency repai...
C S Love, C M Freitag, J J Morrell


Comparison of gauge and assay retention in crossties treated with copper naphthenate
2014 - IRG/WP 14-40667
Creosote has been the most widely used preservative for wooden railroad crossties or sleepers for over 100 years. Alternative preservatives such as copper naphthenate (CuN) have been shown to provide equivalent performance against decay fungi and wood destroying insects; however, the use and specification of CuN involves an education process for treaters and railroad customers alike. One differe...
J Brient, H Tomlinson, J Hughes


Ammoniacal zinc borate as solid wood preservative
2014 - IRG/WP 14-30659
Zinc borate, well-known for its fungicidal, insecticidal and flame resistant properties, is widely used in manufacture of lignocellulose particle board. This form of borate is the least water soluble form available providing advantages as well as disadvantages for use as a wood preservative. This form does not leach from wood under conditions of high humidity, but it is also very difficult to appl...
C Ibáñez, C Mantero, A Ibarra, M Rabinovich


Douglas-fir PSL Treated with Oilborne Copper Naphthenate – Treatment Experience & Efficacy
2014 - IRG/WP 14-40687
Treating characteristics, field stake efficacy and the results from treatment trials for oilborne copper naphthenate (CuNap) and Douglas-fir parallel strand lumber (PSL) are summarized in this paper. Treatment with a P9 Type-C based solution in laboratory tests showed full cross section penetration of large cross sections could be achieved. Commercial treatment trials using a P9 Type-A solution ...
G P Merrick


Recycling of used railroad ties via two-staged pyrolysis for fractionation of wood preservatives and bio-oil: pyrolytic characterization by TGA and Py-GC/MS
2015 - IRG/WP 15-50311
Creosote and copper naphthenate (CuNap) (in an oil carrier) treated railroad tie materials (crossties or sleepers) were initially heat-treated at 200 – 300 oC and subsequently pyrolyzed via thermogravimetric analysis (TGA) and pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) to recover wood preservatives and produce a higher quality bio-oil. Preservative-desorptive temperatures at 200 a...
Pyoungchung Kim, J Lloyd, Jae-Woo Kim, N Labbe


Accelerated Weathering Performance of Impregnated Wood Samples Coated with Zinc by Means of Plasma-Assisted Particle Deposition
2016 - IRG/WP 16-30682
Many different methods are currently applied for wood protection against outdoor conditions. The most important of these is the process of impregnation with liquid substances. However, this kind of wood preservatives cannot provide a long-term protection of wooden surfaces. Weathering-resistant surfaces can be obtained by applying UV absorbing agents. In this study, the influence of zinc particles...
A Can, H Sivrikaya


The termite resistance of wood impregnated with nano-zinc oxide and nano-zinc borate dispersions
2016 - IRG/WP 16-30691
In this work, the effects of the impregnation with nano-ZnO and nano-ZnB dispersions on the termite resistance of European beech wood were investigated. Three different concentrations (namely 0.5%, 1% and 2%) of the above two materials were tested. Water leaching effect was also investigated. It was concluded that a severe effect in terms of termite workers mortality is induced by the use of both ...
C Lykidis, T de Troya, M Conde, J Galván, G Mantanis


Incorporation of raw boron minerals to protect particleboard against decay and mold fungi, termites and insects
2016 - IRG/WP 16-40729
This paper evaluated the biological performance of particleboards incorporated with the raw boron minerals ulexite and colemanite against decay, mold fungi, termites and insect larvae in comparison with that of particleboards with zinc borate, or boric acid plus a borax mixture. The results showed that ulexite and colemanite were highly effective against the decay fungi and termite attack in labor...
S N Kartal, E Terzi, P Gerardin, C M Ibanez, T Yoshimura


Decay Resistance of MDF Manufactured with Huntite- Hydromagnesite and Zinc borate
2017 - IRG/WP 17-30710
The objective of this study was to evaluate the effectiveness of some mineral based fire retardants on decay resistance of Medium density fiberboard (MDF). Two mineral based chemicals containing (Huntite/Hydromagnesite) and zinc borate (ZB) were used at two different concentrations for panel manufacturing. Decay test of samples was performed according to EN 113 standard method. At the end of the t...
U E Başer, D Ustaömer, Ö Özgenç


Borate and Copper Naphthenate Dual Treatment of Bridge Timbers-Borate movement over time
2017 - IRG/WP 17-40795
Preservative treated wooden bridge ties in the South Eastern USA have a service life of about 15 to 20 years, which falls well below the average service life of 40 years of railroad cross ties (sleepers). It has been shown that cross tie life is significantly extended using borate dual treatment and this is now commercialized in bridge timbers using borate inserts. In previous research, it was dem...
J-W Kim, J D Lloyd


Dual Borate and Copper Naphthenate Treatment of Bridge Timbers:- Potential Performance Enhancements and Cost Savings
2017 - IRG/WP 17-40797
Dual treatment technology combining diffusible preservatives with oil borne preservatives, widely used for crossties in the USA, has now also been commercialized with bridge ties/timbers. In order to understand the implications of these changes, the historic service life of creosote treated bridge timbers in northern and southeastern USA were considered as well as field test data for both creosote...
J Lloyd, C Brischke, R Bennett, A Taylor


Five-year evaluation of a field trial of Eucalyptus grandis poles treated with zinc and boron
2017 - IRG/WP 17-30721
Round Eucalyptus wood treatment in sequential stages with inorganic borates and metal salts (zinc sulfate and boric acid+borax) was studied; the aims were to form an insoluble precipitate of zinc borate inside wood and to reduce treatment costs by performing the first treatment by simple ascent and diffusion of the preservative, at the same time as it was sought to impregnate the heartwood. The se...
C Ibáñez, A Camargo, C Mantero, M Rabinovich


Termite resistance of wood-plastic composites made with acetylated wood flour, coupling agent or zinc borate
2018 - IRG/WP 18-10917
There is little published scientific literature on the laboratory or field testing of wood-plastic composites (WPC) against termite attack. Therefore, the objective of this research was to investigate termite resistance (both laboratory and field) of 5 different extruded WPC blends of 50% western pine wood flour (WF) and high-density polyethylene (HDPE), and untreated pine solid wood. The study in...
R E Ibach, Y S Hadi, C M Clemons, S Yusuf


COPPER NAPHTHENATE: A Product for All Seasons: Protecting the Americas’ Infrastructure for Over 100 Years and Potential for Expanded Usage in Europe
2019 - IRG/WP 19-30738
This paper is a brief review of the history and use of the wood preservative Copper Naphthenate, with a focus on use patterns within the USA and opportunities for expansion in Europe and Canada. This paper reviews how copper naphthenate has performed to preserve and protect cellulosic and wooden items essential to critical infrastructure, and why it is the ideal choice for use in the replacement o...
M H Freeman, J A Brient, M Manning


Economic and Alternative Preservative Research with an Overview of its Impact on the Dynamics of Wood Tie Markets and Railroads
2019 - IRG/WP 19-30751
This presentation will discuss the Railway Tie Association’s (RTA) efforts in economic research for the North American wood tie industry, along with decades-long research into improving wood preservation processes and its resulting economic impact for railroads. Ongoing research is continuing to expand the knowledge-base by comparing existing standard creosote (C) and borate-creosote (B-C) dual...
J C Gauntt


Effect of damage to polyurea coatings on metal losses from ammoniacal copper zinc arsenate treated Douglas-fir pile sections
2019 - IRG/WP 19-40867
Metal-based preservatives remain the most widely used treatments for protecting wood in soil or water contact. While these treatments are highly effective, one drawback is a tendency for small amounts of metal to migrate into the surrounding environment. The greatest risk in this regard is copper because many organisms are highly sensitive to this metal. While post treatment practices can reduce ...
M J Konkler, J J Morrell


NewSiest-Enhancement of UV stability of thermally modified wood through envelope impregnation with nanobased stabilisers
2020 - IRG/WP 20-40909
Thermal modification is a process which improves the properties of wood, resulting in a material that can be disposed at the end of the product life cycle without presenting an environmental hazard. Thermally modified wood retains as a natural product and the grain, original colour variances and characteristics of wood are still present. However, exposure to daylight causes brightening or greying ...
K Srinivasa, M Petrič


Copper Naphthenate – A Data and Capability Update
2022 - IRG/WP 22-30771
The efficacy of copper naphthenate against wood decay fungi and wood destroying organisms has been well documented from international field tests as well as decades of commercial service. The use of copper naphthenate has been dramatically expanded due to its proven performance, non-restricted use, minimal environmental impact, and superior end of life options. Extensive demand and interest has al...
J-W Kim, J D Lloyd


Challenges in managing very long-term field tests
2023 - IRG/WP 23-30779
Field testing of wood preservatives has been on-going in Petawawa, Ontario, Canada since at least 1937. Many of the treated roundwood posts from these early experiments are still in test, and include preservatives still used today, including creosote, copper naphthenate, pentachlorophenol and CCA. Performance data from selected experiments more than 50 years old are reported and we discuss some of...
R Stirling, D Wong


Benefits of borate dual treatment
2024 - IRG/WP 24-20710
Treatment of railroad ties with borate followed by over-treatment with creosote or copper naphthenate, called dual treatment, has become standard practice for ties being installed in higher decay hazard areas of the U.S. This paper provides an overview of why that has happened. Borate preservative presents very low human health and environmental risk. It diffuses through even hard to treat hear...
S T Smith, J D Lloyd, S McKinney


Effectivity of zinc borate in medium density fiberboard (MDF) for ground proximity testing
2024 - IRG/WP 24-20723
Medium-density fiberboard (MDF) is one of the most used and versatile wood composites. Most of its use has been focused on interior applications. Adhesives such as p-MDI (polymeric methyl diphenyl diisocyanate) provide MDF with a better performance against moisture, but resistance against decay is also required for outdoor use. A mix of wood fibers, p-MDI, and 0.75%-1.5% of ZB was made to produce ...
S M Vega Gutierrez, T Olivadoti


Outdoor termite resistance performance of zinc borate (Borogard® ZB) treated parallel strand lumber (PSL) – 15 years field test results
2024 - IRG/WP 24-40999
This report discloses the outdoor termite resistance performance of PSL samples treated with zinc borate at a dosage of 0.85% BAE and 1.72% BAE in Wuxi, China. The outdoor field trial lasted for 15 years and observations were made after 6 months, 3 years, 5 years 1 month, 6 years 6 months and 15 years. The retaining rates of B2O3 and ZnO in the final samples were also tested, and the hypothesis wa...
S Shi, E Laval, K Lung, F Ascherl, R Williams, W Li, X Li


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