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Kiln drying of CCA-treated wood - Some safety and environmental considerations
1987 - IRG/WP 3443
Vapours and condensate from a condenser kiln in which CCA-treated wood was being dried have been collected and analysed. The concentrations of arsenic, copper and chromium found in the vapours from the drying process were well below Swedish threshold limit values. The contents of arsenic and chromium were also low in the condensate, although the copper content was fairly high. The latter result wa...
J Jermer, B Lundberg


CCA modifications and their effect on soft rot in hardwoods. Part 2
1983 - IRG/WP 3244
The work outlined in this document is a continuation of that presented in Document No: IRG/WP/3201. The findings described in the previous paper are summarised below: a double treatment of CCB followed by arsenic (CCB+A) is more effective than a double treatment of boron followed by CCA (B+CCA) or a single treatment of CCA, CCB or CCAB in controlling soft-rot due to Chaetomium globosum in birch. C...
S M Gray, D J Dickinson


Corrosion of zinc-coated nails used with preservative-treated western red cedar shakes in service
1982 - IRG/WP 3197
The corrosion of metal fasteners used with certain wood species and with preservative-treated woods can be a serious problem. The chemical reactivity of western red cedar (Thuja plicata Donn) extractives to iron and copper is well documented and wood preservative treatments containing copper, chromium, and/or ammonium hydroxide can be expected to similarly attack some metals. This problem is compo...
R S Smith, E L Johnson, A J Cserjesi


Assessment of the toxicity of some copper-, zinc- and boron-based wood preservatives to the cellar fungus Coniophora cerebella Schröet
1974 - IRG/WP 242
This article reports the use of a method based on the determination of the probability of the protection of timber against destruction by fungi. By converting the probability values to probit values and plotting them as a function of the amount of preservative retained in the timber, curves of the toxic effect are obtained, enabling any timber protection probability to be assessed....
V N Sozonova, D A Belenkov


Safe application of copper-chrome-arsenate preservatives
1975 - IRG/WP 377
All wood preservatives contain biologically active substances and must, by design, be in some measure toxic to man. There is nothing fundamentally difficult, however, about using a wood preservative with complete safety. It depends on knowing the risks to health and/or the environment, which the preservative may present, and planning application accordingly. In this paper we examine these and othe...
I N Stalker, P B Cornwell


Report on the burning of wood treated with wood preservatives containing copper, chromium and arsenic
1976 - IRG/WP 379
Mixtures of copper, chromium and arsenic salts are used extensively in the UK to preserve timber. This report is concerned with the fate of these metals when timber treated with these salts is burned. A large percentage of the arsenic present in the timber is shown to be volatilised during combustion and the potential environmental implications of this are assessed by comparison with the release o...
A J Dobbs, C Grant


Leaching of Arsenic from Mulch Made from Recycled Construction and Demolition Wood
2005 - IRG/WP 05-50232
Mulch made from recycled construction and demolition (C&D) wood has been reported to contain chromated copper arsenate (CCA)-treated wood and potentially release arsenic in the leachate by rainfall. Such recycled wood mulch is commonly masked with iron-oxide colorant, which is known to combine with arsenic. The objective of this study was to evaluate the levels of arsenic leaching from C&...
T Shibata, H M Solo-Gabriele, T G Townsend, B Dubey


Influence of pre-swelling conditioning on swellometer results for CCA and water repellent additive treated wood
1997 - IRG/WP 97-20125
The pre-test moisture content and conditioning history of wafers cut from wood treated with CCA and an emulsion water repellent additive can dramatically influence swelling curves generated using a standard swellometer apparatus. The rate of water uptake and swelling increased significantly as wafers were dried to lower moisture contents prior to immersion swelling. The pre-swelling conditioning h...
A R Zahora


Decay and mold resistance of borate modified oriented strandboard
2003 - IRG/WP 03-40260
Decay and mold resistance of zinc borate (ZB) and calcium borate (CB) modified oriented strandboard (OSB) from southern mixed hardwoods and yellow pine was investigated in this study. Tests were done with brown rot, Gloeophyllum trabeum, and white-rot, Trametes versicolar, fungi for 8 and 12 weeks, respectively. Wood species and fungus type had significant influence on the decay resistance. Decay...
Q Wu, S Lee, J P Jones


Durability of Wood Plastic Composites Relative to Natural Weathering and Preservative Treatment With Zinc Borate
2005 - IRG/WP 05-40316
Wood-Plastic Composites (WPCs) used for decking have experienced dramatic increases in North America, averaging 25% growth per annum since 1998. A key factor contributing to this growth has been the successfully communicated message that they are "virtually maintenance free". The common perception being that the wood fiber is completely encapsulated by the thermoplastic resin, minimizing the pot...
M E Mankowski, F M Ascherl, M J Manning


The influence of soil pH on leaching of CCA elements from pressure-treated Eucalyptus saligna sapwood: environmental implication
2003 - IRG/WP 03-50203
Evidence is accumulating as to poor distribution and fixation of CCA in tropical hardwoods, and there is therefore a necessity to investigate the permanency of CCA in tropical hardwoods. The relationship between soil pH and leaching of Cu, Cr and As from CCA pressure-treated sapwood of Kenyan-grown Eucalyptus saligna was tested under laboratory conditions. Small sapwood samples were pressure-tre...
R Venkatasamy, D N Okwara


Soft rot test of copper/chrome/arsenic treated heartwood of three Malaysian timbers
1991 - IRG/WP 2381
Standardized heartwood blocks of kempas (Koompassia malaccensis), keruing (Dipterocarpus sp.) and tualang (Koompassia excelsa) were impregnated with 0 to 6.3% (w/v) CCA and challenged to decay by a mixed inocula of Chaetomium globosum, Glenospora graphii, Humicola grisea, Petriella setifera and Trichurus spiralis in a containerized vermiculite-burial decay system according to draft CEN/TC 38 WG 4....
A H H Wong, R-D Peek


The implementation of restrictions on the use of arsenic and chromium based wood preservatives in Sweden
1995 - IRG/WP 95-50062
In 1992 the Swedish National Chemicals Inspectorate introduced restrictions on the use of wood treated with arsenic and/or chromium based wood preservatives. Such wood is now in principle only allowed for use in ground contact or in water. These restrictions have had considerable influence on the use of wood preservatives for sawn timber for the Swedish domestic market. Thus only 35% of the preser...
J Jermer, M-L Edlund, K Nilsson


Laboratory evaluation of metallic naphthenates as wood preservatives
1991 - IRG/WP 3654
Fungicidal and termiticidal efficacy of copper and zinc naphthenates was appraised according to Japanese standardized laboratory testing methods. Copper and zinc naphthenates succeeded in protecting wood from decay fungi at retentions of 0.5 and 1.0 kg/m³ as metal, respectively. [JIS A 9302 (1976)] when they were applied to vacuum/soak impregnation [JIS A 9301 (1976)]. With respect to the fungici...
K Tsunoda, M Sakurai


Studies on the mobility of arsenic, copper and chromium in CCA-contaminated soil
1990 - IRG/WP 3571
CCA contaminated soils from six Swedish preservation plants were investigated primarily to study the mobility of arsenic but also that of copper and chromium in the soils. The soil samples represented average types with different amounts of clay, organic matter, arsenic, copper, chromium and different pH. The total soluble amounts of the elements were measured. The pH dependent solubility and the ...
J Bergholm


An investigation of the effects of pre-steaming on the treatment of sawn spruce timber with Celcure A, a copper/chrome/arsenic preservative
1981 - IRG/WP 3180
Difficulties in the treatment of spruce using standard vacuum/pressure techniques with both water-borne and organic solvent preservatives are well known. The growth characteristics of spruces (Picea spp) make them attractive candidates for forestry schemes. In 1975 the UK Forestry Commission had about 400 000 hectares, about 20% of total UK forest area, planted with Sitka spruce (Picea sitchensis)...
C R Coggins


Fixation of copper-chrome-arsenic treated timber: A comparison of leaching methodologies
1996 - IRG/WP 96-50075
Five packs of kiln dried radiata pine heartwood were treated with copper-chrome-arsenic preservative treated, utilising a modified Bethell treatment schedule. Two methods of determining the level of preservative fixation were compared. These included the diphenylcarbazide method and simulated rainfall testing. The fixation levels were generally higher for tests involving simulated rain leaching. F...
S Walley, P R S Cobham, P Vinden


L-joint trials: Part 3: Relative performance of a range of preservative products
2002 - IRG/WP 02-30292
Long-term trials using the L-joints described in BS EN 330 and AWPA Standard E9-97 have been in progress at BRE since 1982. This paper records the current assessments of decay of L-joints in trials started between 1982 and 1994 with treatments applied to both Scots pine sapwood (Pinus sylvestris) and spruce (Picea sp.). Data are provided on a range of active ingredients including TnBTO, PCP, a...
J K Carey


Fungal remediation of CCA-treated wood
2004 - IRG/WP 04-50210
This study evaluates oxalic acid accumulation and bioremediation chromated copper arsenate (CCA) treated wood by three brown-rot fungi, Fomitopsis palustris, Coniophora puteana, and Laetiporus sulphureus and ten mold and staining fungi, Aspergillus niger, Aureobasidium pullulans, Gliocladium virens, Penicillium funiculosum, Rhizopus javanicus, Ceratocystis pilifera, C. peceae, Alternaria alternata...
S N Kartal, Y Imamura


Bait box technique for remedial subterranean termite contro
1995 - IRG/WP 95-10115
The bait box technique, as described in this paper, was first used as a method to apply the dust toxicant, arsenic trioxide, to large numbers of aggregated subterranean termites. Over the last twelve years or so the technique has been refined, and in recent years, gained acceptance as an alternative subterranean termite control measure by members of the Australian pest control industry. This baiti...
J R J French, B M Ahmed, D M Ewart


The mechanism of leaching of copper-chrome-arsenic preservatives from treated timber in saline waters
1976 - IRG/WP 374
A mechanism for the leaching of copper-chrome-arsenic preservatives is proposed on the basis of theoretical calculations and experimental studies using timber subjected to a range of water types of different ionic compositions. Complex formation by copper (II) and chromium (III) with chloride and hydroxide ions is shown to affect the leaching rate. Of even greater importance is the salt effect on ...
J Irvine, S-E Dahlgren


Economical analysis of the chemicals used on remediation copper, chromium and arsenic from out of service CCA-treated utility poles in Turkey
2004 - IRG/WP 04-50217
There are 20.7 million hectare forested area in Turkey. However, the wood products supplies do not meet demand. One of the wooden products is the utility poles. In Turkey, impregnation of utility poles has been started since 1960's and 5 million utility poles have been used until today since then. Although life time of the utility poles may vary depending on climatic conditions, average s...
E D Gezer, D Toksoy, Ü C Yildiz


Tendency of the preservative use for impregnation industries in Japan
1998 - IRG/WP 98-50101-05
In Japan, since 1997, the acceptable limit of the arsenic in the waste water become to 0,1 mg/l and the additional regional severer restriction can be established. In this reason, Japanese wood preservation industries intend to use other than CCA, like DDAC, ACQ, Tanalith CuAz, copper-naphthate and zinc-naphthenate, as replacing from CCA. In Jan-June 1997, the share of CCA preservatives was less t...
K Suzuki


Applications of the shower test. Part A: Results from CCA type C treated wood: influence of fixation process
1993 - IRG/WP 93-50009
This report outlines the results of shower tests conducted on CCA type C treated wood. The results indicate the inherent good fixation of CCA type C, as judged by the leaching limits within the Environmental Regulations. The shower test has proven to be a useful quality control and research test. It determines reasonably accurately the leaching under simulated conditions and, admittedly from a lim...
W J Homan, H Militz, D A Lewis


Incomplete fixation of chromium in the pre-treated wood with a solution of copper and arsenic compounds
1995 - IRG/WP 95-50052
Ponderosa pine wood thin sections were treated with a combination of chromium, copper, and arsenic chemicals. The wood sections was analyzed by electron spin resonance spectrometry (ESR) and X-ray photoelectron spectrometry (XPS) to elucidate the mechanism of fixation of the chromated-copper preservatives. The wood subjected to the two-step treatment with copper and arsenic followed by chromium ex...
J N R Ruddick, K Yamamoto, F G Herring, P C Wong, K A R Mitchell


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