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Formation and Structure of Metal Azole Complexes
2008 - IRG/WP 08-30469
Divalent copper and zinc complexes with metal:azole ratio 1:2 were readily formed at room temperature with the fungicides tebuconazole and propiconazole. The structure of copper and zinc tebuconazole acetate and zinc cis-propiconazole chloride were examined by X-ray crystallography. In copper tebuconazole acetate, the copper atom lies on a crystallographic inversion centre and is coordinated to tw...
P D Evans, K J Schmalzl, C M Forsyth, G D Fallon, S Schmid, B Bendixen, S Heimdal


The efficacy of commercial silicones against blue stain and mould fungi in wood
2008 - IRG/WP 08-30471
Scots pine (Pinus sylvestris L.) wood samples were vacuum pressure impregnated with quatsilicone micro emulsion (<40 nm particle size), aminosilicone macro emulsion (110 nm) and silicone macro emulsion with alkyl modified side groups (740 nm) and the resulting material properties were studied. Quatsilicone micro emulsion resulted in maximum bulking (4.8%) and anti-swelling efficiency (21.8%) in...
S C Ghosh, C Mai, H Militz


Micro-Distribution of Micronized Copper in Southern Pine
2008 - IRG/WP 08-30479
For copper-based preservatives to be used in ground contact, penetration of copper into the cell wall is believed to be important to protect the wood from soft rot fungi. Preservatives containing soluble copper are known to do this. It is not known whether preservatives containing particulate copper will also migrate into the cell wall in sufficient quantities to control soft rot decay. An AWPA st...
R Stirling, J Drummond, Jun Zhang, R J Ziobro


Radial flow of Bornmullerian fir (Abies bornmulleriana Mattf.) as affected by wood tapering and the condition of end wall structure of uniseriate ray parenchyma cells
2008 - IRG/WP 08-40441
Amenability to radial permeability of Bornmullerian fir (Abies bornmulleriana Mattf.) was studied on the base of the effects of wood tapering and the structure of end walls of uniseriate ray parenchyma cells. The results showed that the most remarkable culprits of the greatest fluid uptake (as the percentage of void volume filled by the fluid in the radial flow direction, RVVF%) are the lesser woo...
I Usta, S Aslan


Re-Distribution of Copper in the Cell Walls of Wood Treated with Micronized Copper Quat
2009 - IRG/WP 09-30506
Wood treated with copper-based preservatives to be used in ground contact may fail to inhibit soft rot fungi if penetration of copper into the cell wall is insufficient. Preservatives containing soluble copper are known to penetrate the cell wall; however, it is not known whether preservatives containing particulate copper will also migrate into the cell wall in sufficient quantities to control so...
R Stirling, J Drummond


Protection mechanisms of modified wood against decay by white and brown rot fungi
2010 - IRG/WP 10-10713
The resistance of beech and pine wood blocks treated with 1,3-dimethylol-4,5-dihydroxyethylene urea (DMDHEU) against T. versicolor and C. puteana increased with increasing WPG. Full protection (mass loss below 3%) was reached at WPGs of approximately 15% (beech) and 10% (pine). Metabolic activity of the fungi in the wood blocks was assessed as heat or energy production determined by isothermal mic...
C Mai, P Verma, Yanjun Xie, J Dyckmans, H Militz


New insights from NMR, FTIR, X-ray diffraction and physical chemistry into digestive processes in the wood-boring marine crustacean Limnoria quadripunctata
2010 - IRG/WP 10-10732
This paper summarises preliminary findings of a multi-technique exploration of the degradation of lignocellulose in the marine isopod Limnoria quadripunctata. Scanning electron microscopy revealed connections between the digestive gland and the hindgut that would permit the exchange of fluids between the two organs while the food mass is retained in place within the hindgut. This enables enzymes t...
G P Malyon, S LaBarre, N Kervarec, P Carey, J McGeehan, X Xie, A Klüppel, S M Cragg


The Use of Micro-Tensile Testing to Assess Weathering Decay and Oxidative Degradation of Wooden Items
2010 - IRG/WP 10-20433
This paper presents a method to study the weathering performance of wooden items and to assess the oxidative degradation of wood via the Fenton reaction. Weathering resistance and photo-stability of wood was tested using pine wood (Pinus sylvestris) veneer strips measuring approximately 60 µm in thickness. The veneer strips were treated using a reactive chemical to impart surface protection. The ...
C Mai, Yanjun Xie, Zefang Xiao, P D Evans, H Militz


Analyzing hyphal growth of the bio incising fungus Physisporinus vitreus with light-, confocal laser scanning- and, Synchrotron X-ray tomographic microscopy
2010 - IRG/WP 10-20438
Norway spruce wood is an important building material for the forest and wood industry. To improve wood permeability and uptake of wood modification substances Physisporinus vitreus is employed as a bioincising agent. In this study wood specimens were incubated with P. vitreus to assess hyphal colonisation and structural alterations of Norway spruce wood. After different incubation periods, semi-th...
C Stührk, M Fuhr, M Schubert, F W M R Schwarze


A Comparison of the Performance of Related Copper Based Preservatives against Soft Rot
2010 - IRG/WP 10-30540
The performance of pine and beech wood treated with either a soluble copper + quat (ACQ type D) preservative system or a particulate copper + quat system was evaluated in unsterile soil using the European standard ENV 807 soft rot decay test procedure. In addition, to compare soft rot performance of soluble and particulate copper directly without the influence of co-biocides, beech and pine test...
M Ray, D Dickinson, K Archer


Copper nanoparticles in southern pine wood treated with a micronised preservative: Can nanoparticles penetrate the cell walls of tracheids and ray parenchyma?
2010 - IRG/WP 10-30547
This study tests the hypothesis that copper nanoparticles can penetrate the cell walls of southern pine wood treated with a micronised preservative. We examined the nanodistribution of particles in tracheid and ray parenchyma cell walls using state-of-the-art HR (High Resolution)-TEM and HR-STEM (Scanning Transmission Electron Microscope)-EDX. These devices are capable of atomic-scale resolution. ...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans


Copper Nanoparticles in Southern Pine Wood Treated with a Micronised Preservative: Nanodistribution of Copper in the Pit Membrane and Border of an Earlywood Bordered Pit
2011 - IRG/WP 11-30566
Copper nanoparticles can penetrate the cell walls of unlignified parenchyma cells in southern pine wood treated with a micronised wood preservative, but they are excluded from lignified tracheid walls. This paper extends these observations to include the cell wall layers of the bordered pit. Focused ion beam and ion milling were used to make an ultra-thin section of the cell wall layers of an earl...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans


Further Studies on the Distribution of Copper in Treated Wood Using an XRF Microscope Technique
2011 - IRG/WP 11-40549
There are two distinct forms of copper in aqueous copper based wood preservative systems that are currently used in the United States for treatment of southern pine lumber. These are systems using either soluble copper (typically amine based) or the more recent particulate or “micronized” copper as the primary biocide. Studies reported last year showed that there were distinct differences in...
A Zahora


Use of Variable Pressure Scanning Electron Microscopy for in situ Observation of Degradation of Wood Surfaces during Artificial Weathering
2012 - IRG/WP 12-20489
Variable pressure scanning electron microscopy (VPSEM) is capable of observing electrically non-conductive materials like wood without the need to render the surface conductive by applying a coating of gold, platinum or carbon. Hence, there is the possibility that VPSEM could be used to non-destructively follow the structural changes occurring at wood surfaces during weathering, because specimens ...
F Hatae, Y Kataoka, M Kiguchi, H Matsunaga, J Matsumura


Accessibility of Wood Cell Walls to Well-defined Platinum Nanoparticles
2012 - IRG/WP 12-20494
Copper nanoparticles are found in the walls of parenchyma cells in southern pine sapwood treated with a micronised wood preservative, but they are absent from tracheid walls. Hence, we hypothesized that small nanoparticles can penetrate the walls of unlignified parenchyma cells, but are excluded from lignified tracheid walls. This paper tests this hypothesis by treating pine sapwood with an aqueou...
H Matsunaga, Y Kataoka, M Kiguchi, P D Evans


Nano structural properties of La2O3-Beech Wood Flour With XRD technique
2012 - IRG/WP 12-40607
This research was considered to study various properties of the Lanthana mixed with beech wood flour (BWF), as a new structure. For this purpose, La2O3 powders in the BWF have been obtained by sol-gel method using simultaneous gelation of all cations. La2O3 - BW samples are analysed by X-ray diffraction .The obtained results showed the formation of nano crystalline La2O3 phases. The average crys...
M Ghorbani Kokandeh, I Bahamni, A Bahari


Scanning Transmission X-ray Microscopy as a tool for examining chemical changes in wood cell walls due to enzymatic activity
2014 - IRG/WP 14-20556
As development of techniques for examining enzymatic activity on solid, complex biological materials, is considered to be an important factor in further development of enzyme applications and for understanding the decay of plant materials, this study explores applicability of Scanning Transmission X-ray Microscope (STXM) for determining chemical changes in enzymatically treated samples at the cell...
D Jeremic, R Goacher, R Yan, C Karunakaran, E R Master


Non-destructive monitoring of structure and moisture dynamics of plywood exposed outdoors to improve service life prediction and fit-for-purpose design
2015 - IRG/WP 15-20570
Plywood is an important construction material yet prone to water uptake, which can decrease strength and increase decay risk. To predict service life and improve fit-for-purpose design, it is crucial to understand the moisture behavior and structural changes of plywood. In this research, several plywood specimens were exposed outdoors for approximately one year. During this period, the moisture di...
W Li, J Van den Bulcke, I De Windt, M Dierick, J Van Acker


Effect of natural variability of European Oak wood on heat treatment process and potential implication on wood durability
2015 - IRG/WP 15-40693
Environmental pressures appeared in France and in most European countries during the last decade has led to the development of more environmentally acceptable preservation methods. In this context, wood heat treatment has been one of the most investigated alternative method during the last years. Treated at temperatures ranging between 180 and 220°C, wood components undergo more or less important...
J Hamada, A Pétrissans, F Mothe, M Pétrissans, P Gérardin


Impact of early lignification of ray parenchyma cells on the treatability of Scots pine sapwood
2015 - IRG/WP 15-40706
The wood anatomy of Scots pine sapwood can influence its treatability. A microscopic analysis on the wood material from four different stands in Northern Europe was performed using tangential sections from the outer part of Scots pine sapwood. Single correlations of the ray composition and lignification state of the ray parenchyma showed the influence of these factors on radial penetration depth a...
K Zimmer, A Treu


Preparation of Calibration Standards for the Analysis of Pentachlorophenol in Treated Wood by X-ray Fluorescence
2016 - IRG/WP 16-20591
The primary purpose of this project was to develop a method for preparing calibration standards that can be used by the wood treating industry to calibrate X-ray fluorescence instrumentation. Calibration standards of penta/P9-oil in southern yellow pine that cover the retention range of 0.2 to 0.9 pcf (0.6 to 1.9 %) were successfully prepared. A detailed procedure for mixing penta in treating sol...
L L Ingram Jr, H M Barnes, R Shmulsky, D Jeremic


Resistance of heat treated Ash wood under steam pressure: rot fungi, soil micro-organisms and termites
2016 - IRG/WP 16-40724
Thermal modification processes have been developed to increase the biological durability and dimensional stability of wood. The aim of this paper was to study the influence of ThermoWood® treatment intensity on wood decay resistance improvement against soil-inhabiting micro-organisms, brown/white rots and termite’s exposures. All of the tests were carried out in the laboratory with two differen...
K Candelier, S Hannouz, M-F Thévenon, D Guibal, P Gérardin, M Pétrissans, R Collet


Nondestructive analysis of oviposition of the bamboo powderpost beetle Dinoderus minutus using acoustic emission and X-ray CT
2017 - IRG/WP 17-10889
The bamboo powderpost beetle Dinoderus minutus is a major pest of dry bamboo culms in Japan. In this study, acoustic emission (AE) and X-ray computed tomography (CT) was applied to the nondestructive analysis of the ovipositional behavior of adult D. minutus beetles inside bamboo pieces. Newly mated adult females were individually exposed to oviposition bamboo pieces prepared from culms of Phyllos...
H Watanabe, Y Yanase, Y Fujii


Controlled deposition of copper nanoparticles using wood inherent architecture as natural template
2017 - IRG/WP 17-40783
As one of the most abundant renewable biomass resources, wood can be used as templates for synthesizing functional nanoparticles with controlled shapes and sizes. In this study, copper nanoparticles were synthesized with controlled shapes and sizes using poplar wood as the natural inexpensive and renewable templates. The crystal structure and morphologies of the copper nanoparticles were character...
Youming Dong, Kaili Wang, Yutao Yan, Jianzhang Li, M Hughes, Shifeng Zhang


Use of x-ray microdensitometry for assessing the resistance to the fungus C puteana of a hybrid larches population
2018 - IRG/WP 18-10923
The aim of this research was to utilize the X-ray microdensitometry to determine the natural durability and its variability of a hybrid larch population. The method was applied on slices obtained by increment cores collected on standing trees before cutting them down. The methodology was discussed also in order to propose as a new screening method especially suited for trees populations. X-ray mic...
S Palanti, F Alderighi, F Stefani, J P Charpentier, L E Pâques


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