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Imaging fungal deterioration of wood using x-ray microtomography
1997 - IRG/WP 97-10240
Nondestructive tomographic images of solid Southern yellow pine (SYP) wood and SYP during deterioration by wood decay fungi were obtained by using a new class of synchrotron X-ray computed microtomography (CMT). The CMT images will provide information about spatial relationship between degrading fungi and wood structures. Wood samples were scanned with synchrotron-generated X-rays at high resoluti...
B Illman, B A Dowd


A spectroscopic investigation of copper ethylenediamine fixation in wood
1999 - IRG/WP 99-20160
The fixation reaction which take place between copper ethylenediamine (Cu-en) solution and wood were expolored using X-ray photoelectron spectroscopy (XPS) and Fourier Transformed Infrared Spectroscopy (FTIR). The FTIR spectra revealed that copper reacts with the carboxylic acid and phenolic groups in wood to form stable complexes. The copper ethylenediamine complexes formed in wood were identifie...
Xiao Jiang, J N R Ruddick


The micro-distribution of copper/chrome/arsenate in Acer pseudoplatanus and Eucalyptus maculata
1973 - IRG/WP 319
The excellent field performance of copper-chrome-arsenate (CCA) treated timber has been accepted for many years. The preservative loadings used in practice have been based on field trial results, backed by service tests. The performance of treated hardwoods in trials and practice indicated that provided the required loading and penetration could be achieved the performance would be good. Recent un...
D J Dickinson


CCA type C depletion of Southern yellow pine utility poles
1995 - IRG/WP 95-50049
Depletion and redistribution of preservative components were evaluated on five CCA-C treated poles in service for over six years in Conley, Georgia. A statistical approach was taken in which retentions below ground were compared to retentions above ground due to a lack of initial data on individual poles. It was hypothesized that the below ground retentions should be lower than the corresponding a...
P D Osborne, R F Fox


Amenability of radial permeability of Sitka spruce (Picea sitchensis (Bong.) Carr.) as affected by aspects of cell ends in uniseriate ray parenchyma tissue
2003 - IRG/WP 03-40252
The principal objective of this article was to recognise and understand the amenability of ray parenchyma cell ends (end platform) in uniseriate ray tissue to influence the radial permeability of Sitka spruce (Picea sitchensis (Bong.) Carr.) by examination of most (Queen Charlotte Islands in Rhondda, South Wales) and the least (South Oregon in Dalby, North-East England) seed origins that grown in ...
I Usta, M D C Hale


Interactions between soft rot fungi and CCA preservatives in Betula verrucosa
1988 - IRG/WP 1367
Ultrastructural investigations were carried out to obtain information on the cell wall distribution of CCA elements during soft rot decay of 4% K33 CCA preservative treated birch (Betula verrucosa) wood. TEM observations on fibres at various stages of S2 cavity formation by mutabilis showed a distinct pattern of electron dense materials to occur within the S2 cell wall region. These materials (gra...
G F Daniel, T Nilsson


Direct analysis from wood of the blue stain fungi Aureobasidium pullulans and Hormonema dematioides by denaturing gradient gel electrophoresis
2006 - IRG/WP 06-10595
Aureobasidium pullulans and Hormonema dematioides are the two organisms used in the EN 152 laboratory method for determining the effectiveness of preservatives against blue stain in service. The literature concerning the disfigurement of surface coatings and exposed timber in-service states that A. pullulans is the dominant blue stain fungus, due to its frequent isolation from stained material. In...
M J Ray, D J Dickinson


Time-of-Flight Secondary Ion Mass Spectrometry Analysis of Polyethylene Glycol Penetration into Wood Cell Walls
2006 - IRG/WP 06-20328
Penetration of high molecular weight polyethylene glycol (PEG) into wood cell walls was investigated in red pine. PEG of different molecular weights (1000, 8000 and 20000) was labelled by bromination and treated samples were analyzed on Time-of-Flight Secondary Ion Mass Spectrometry (TOF-SIMS) in dynamic mode. Both negative and positive spectra of the samples were collected in high spatial (bunche...
D Jeremic, P Cooper, P Brodersen


The use of X-ray diffraction for analyzing biomodification of crystalline cellulose by wood decay fungi
2007 - IRG/WP 07-10622
X-ray diffraction (XRD) is based on the creation of an interference pattern by x-rays when they encounter a regularly spaced matrix. In wood, this process has been used to determine, among other things, the average width of the cellulose microcrystals, the percent of crystalline cellulose within the wood, and can be used to examine the changes in these parameters during degradation. Enhanced under...
C Howell, A C Steenkjær Hastrup, J Jellison


Assaying Pentachlorophenol-treated Wood Using XRF
2007 - IRG/WP 07-20362
A study was conducted to evaluate the effect of oil type on the performance of test posts treated with oil-penta and exposed in DeQueen, AR for forty years in ground contact. The original assays for the poles were done by lime ignition, a practice used sparingly today in treating plants or by independent inspectors, in part due to the complicated analysis procedure and chances for error. XRF ins...
H M Barnes, C R McIntyre, D W Bullock , M H Freeman, G B Lindsey


Micro-Distribution of Metals in Wood Treated with a Nano-Copper Wood Preservative
2007 - IRG/WP 07-40360
The microdistribution of copper in southern pine treated with a newly-developed nano-copper wood preservative was examined to determine if it differed from that reported for wood treated with conventional copper-based wood preservatives. Field Emission Scanning Electron Microscopy (FE-SEM) in combination with x-ray microanalysis (EDX) revealed the presence of nano-sized copper and iron particles i...
H Matsunaga, M Kiguchi, P Evans


White Rot in Eucalyptus Wood: Anatomical Changes and Density Variation by X-Ray Densitometry
2007 - IRG/WP 07-10631
Wood samples of the hybrid Eucalyptus grandis x urophylla attacked by white rot fungi were characterized. Microscopically, the colonization of the fungi was observed in the vessels and radial parenchyma, however the cell walls of the some fibers were attacked, indicating susceptibility to this fungi. Zone lines were observed as a result of interaction and compartmentalization of the fungi. Microsc...
M Tomazello Fo, S Brazolin, M P Chagas


Evaluating the Process of ACQ-Treated Woods with TGAand CEM Analysis
2007 - IRG/WP 07-20374
To provide an understanding of the fundamental thermal behaviour and the disposal-end products of ACQ-treated woods, this study is comprised of two categories of examination. The first is related to the use of TGA under different thermal decomposition conditions (nitrogen or air, and 5 or 40 oC/min), and the use of EDX to examine certain residual elements of the char. The second applies the CEM ...
Han Chien Lin, Tsang-Chyi Shiah, Jung Ting Tsai


Formation and Structure of Metal Azole Complexes
2008 - IRG/WP 08-30469
Divalent copper and zinc complexes with metal:azole ratio 1:2 were readily formed at room temperature with the fungicides tebuconazole and propiconazole. The structure of copper and zinc tebuconazole acetate and zinc cis-propiconazole chloride were examined by X-ray crystallography. In copper tebuconazole acetate, the copper atom lies on a crystallographic inversion centre and is coordinated to tw...
P D Evans, K J Schmalzl, C M Forsyth, G D Fallon, S Schmid, B Bendixen, S Heimdal


Radial flow of Bornmullerian fir (Abies bornmulleriana Mattf.) as affected by wood tapering and the condition of end wall structure of uniseriate ray parenchyma cells
2008 - IRG/WP 08-40441
Amenability to radial permeability of Bornmullerian fir (Abies bornmulleriana Mattf.) was studied on the base of the effects of wood tapering and the structure of end walls of uniseriate ray parenchyma cells. The results showed that the most remarkable culprits of the greatest fluid uptake (as the percentage of void volume filled by the fluid in the radial flow direction, RVVF%) are the lesser woo...
I Usta, S Aslan


New insights from NMR, FTIR, X-ray diffraction and physical chemistry into digestive processes in the wood-boring marine crustacean Limnoria quadripunctata
2010 - IRG/WP 10-10732
This paper summarises preliminary findings of a multi-technique exploration of the degradation of lignocellulose in the marine isopod Limnoria quadripunctata. Scanning electron microscopy revealed connections between the digestive gland and the hindgut that would permit the exchange of fluids between the two organs while the food mass is retained in place within the hindgut. This enables enzymes t...
G P Malyon, S LaBarre, N Kervarec, P Carey, J McGeehan, X Xie, A Klüppel, S M Cragg


Analyzing hyphal growth of the bio incising fungus Physisporinus vitreus with light-, confocal laser scanning- and, Synchrotron X-ray tomographic microscopy
2010 - IRG/WP 10-20438
Norway spruce wood is an important building material for the forest and wood industry. To improve wood permeability and uptake of wood modification substances Physisporinus vitreus is employed as a bioincising agent. In this study wood specimens were incubated with P. vitreus to assess hyphal colonisation and structural alterations of Norway spruce wood. After different incubation periods, semi-th...
C Stührk, M Fuhr, M Schubert, F W M R Schwarze


A Comparison of the Performance of Related Copper Based Preservatives against Soft Rot
2010 - IRG/WP 10-30540
The performance of pine and beech wood treated with either a soluble copper + quat (ACQ type D) preservative system or a particulate copper + quat system was evaluated in unsterile soil using the European standard ENV 807 soft rot decay test procedure. In addition, to compare soft rot performance of soluble and particulate copper directly without the influence of co-biocides, beech and pine test...
M Ray, D Dickinson, K Archer


Copper nanoparticles in southern pine wood treated with a micronised preservative: Can nanoparticles penetrate the cell walls of tracheids and ray parenchyma?
2010 - IRG/WP 10-30547
This study tests the hypothesis that copper nanoparticles can penetrate the cell walls of southern pine wood treated with a micronised preservative. We examined the nanodistribution of particles in tracheid and ray parenchyma cell walls using state-of-the-art HR (High Resolution)-TEM and HR-STEM (Scanning Transmission Electron Microscope)-EDX. These devices are capable of atomic-scale resolution. ...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans


Silicon compounds as additives improving alkyd-based wood coatings performance
2010 - IRG/WP 10-40531
The reactivity of cellulose with solvent-born alkyd-based wood coatings supplemented with organosilanes was analyzed. Structural analysis of cellulose subjected to the reaction with organosilanes and following extraction with water was performed using Fourier-transform infrared spectroscopy (FTIR). The analyzed IR spectra comprise bands 1250 cm-1 typical for the SiC group and 800 cm-1 typical for ...
B Mazela, I Ratajczak, K Wichłacz-Szentner, P Hochmańska


Non-destructive evaluation of wood decay
2011 - IRG/WP 11-20479
Evaluation of wood decay is often prone to subjective assessment. Standard rating scales are based on human perception of decay, often in addition to weight loss measurements. Especially the assessment of graveyard specimens or other long term testing material that has to be monitored regularly on a non-destructive basis, is challenging. In this paper two techniques are presented that can deliver ...
J Van den Bulcke, I De Windt, N Defoirdt, J Van Acker


Copper Nanoparticles in Southern Pine Wood Treated with a Micronised Preservative: Nanodistribution of Copper in the Pit Membrane and Border of an Earlywood Bordered Pit
2011 - IRG/WP 11-30566
Copper nanoparticles can penetrate the cell walls of unlignified parenchyma cells in southern pine wood treated with a micronised wood preservative, but they are excluded from lignified tracheid walls. This paper extends these observations to include the cell wall layers of the bordered pit. Focused ion beam and ion milling were used to make an ultra-thin section of the cell wall layers of an earl...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans


Further Studies on the Distribution of Copper in Treated Wood Using an XRF Microscope Technique
2011 - IRG/WP 11-40549
There are two distinct forms of copper in aqueous copper based wood preservative systems that are currently used in the United States for treatment of southern pine lumber. These are systems using either soluble copper (typically amine based) or the more recent particulate or “micronized” copper as the primary biocide. Studies reported last year showed that there were distinct differences in...
A Zahora


Use of X-Ray Micro-Computed Tomography to Visualize Copper in Preservative Treated Wood
2012 - IRG/WP 12-20488
This study tests the hypothesis that X-ray micro-computed tomography will be able to visualize the distribution of copper in wood treated with a micronized wood preservative containing copper carbonate. A small wood block measuring 12 x 12 x 19 mm was cut from a 2.4 m x 51 mm x 51 mm southern pine batten that had been treated with a micronized wood preservative. Tomograms of the wood block were ob...
P D Evans, A Limaye, H Averdunk, M Turner, T J Senden, M A Knackstedt


Plywood under the scanner: linking moisture dynamics and 3D structure
2012 - IRG/WP 12-20491
Plywood is highly esteemed as a construction material. Yet, the influence of moisture on both strength and durability are important factors. Especially the dynamics of moisture desorption and absorption should be taken into account when assessing the quality of a panel, which is a fact for all panel materials. This paper therefore focuses on the monitoring of the moisture dynamics of plywood subje...
J Van den Bulcke, I De Windt, N Defoirdt, J Van Acker


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