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Thermal behavior of zinc borate-treated wood
2009 - IRG/WP 09-30511
The objective of this study was to investigate the thermal behavior of zinc borate (ZnB)-treated solid wood by thermal analysis (TA). Thermogravimetry (TG) and differential thermogravimetry (DTG) curves obtained from TA showed that ZnB-treated wood specimens had higher char yields and lower maximum thermal decomposition temperature than untreated wood specimens. Reducing thermal decomposition temp...
E Terzi, H Sutcu, S N Kartal


The Form of Copper: Does It Really Matter?
2009 - IRG/WP 09-30513
In recent years, several micronized copper formulations for lumber treatment have supplanted the solubilized copper formulations that in turn replaced CCA after its voluntary relabeling in 2004. The micronized or dispersed copper systems use finely ground but solid copper particles and deposit those particles within the wood framework. In contrast, copper in the soluble formulations is relativel...
C R McIntyre, M H Freeman, T F Shupe, Q Wu, D P Kamdem


Mold-resistance Effect of Bamboo Wood Treated with CCC-organic Complexes
2009 - IRG/WP 09-30514
Mold resistant effect of CCA, ACQ, CuAz, CCC and the compound of CCC and propiconazole were researched on bamboo wood of Phyllostachys pubescens were reported in this paper. Results showed that all of the test fungicides could protect bamboo wood better from Penicillam citrinum than from Trichoderma viride and Aspergillus niger. The complex of CCC and propiconazole had the best resisting effect on...
Sun Fangli, Yang Le, Chen Anliang, Bao Binfu, Li Qiao


Potential of antifungal and antitermitic activity of several essential oils
2009 - IRG/WP 09-30515
In the recent years, there has been an increasing concern regarding the safety of wood preservatives. Many research groups have examined the potential of essential oils as biocide based on their biological activity. This paper described the antitermitic and antifungal activity of twenty four essential oils from different plant species. The termicidal activity was carried out with a no-choice test...
N Amusant, M-F Thévenon, N Leménager, E Wozniak


Synthesis of a rosin amide and its resistance to wood decay fungi
2009 - IRG/WP 09-30517
Rosin was reacted with diethyltriamine (DETA) after being modified by acryl acid with the weight ratio of 4.5:1 and a rosin amide (RA) derivative was produced at the conditions as follows: modified rosin and DETA mole ratio of 1:3.5, dimethylbenzene as water carrying agent, reaction temperature of 160-180°C, and reaction time of 8h. The chemical structure of the product as RA was identified by F...
Shuangyue Li, Shujun Li, Jing Wang


Micronized Copper Preservative Systems: Observations on the Release of Cupric ion (Cu2+) from Treated Wood and Performance against Wood Decay Fungi
2009 - IRG/WP 09-30519
In an attempt to address the mechanism of action of micronized copper preservatives, a 20-week continuous water leaching study was conducted. The leaching results indicated that, once impregnated in wood, micronized copper preservatives continuously release cupric ion, and the levels of cupric ion released from micronized copper treated wood are higher than those released from CCA treated wood, a...
J Zhang, R Ziobro


Colour change monitoring of photodegradation in Scots pine (Pinus sylvestris) – a short term focus
2009 - IRG/WP 09-40442
Colour change monitoring of photodegradation is a quick and easy method for monitoring rates of photodegradation in timber. A study was undertaken to compare this technique to other monitoring methods, including microtensile strength changes and weight loss. Colour changes due to accelerated sunlight exposure were monitored using a Datacolor check spectrophotometer and compared with a set of contr...
V Sharratt, C A S Hill, D P R Kint


Effectiveness of a superficial treatment of bifenthrin to protect softwood framing from damage by subterranean and drywood termites in Indonesia
2009 - IRG/WP 09-40443
Various experimental testing procedures were undertaken in Indonesia to determine the effectiveness of a superficial (envelope) treatment of bifenthrin to protect softwood framing from damage by two species of subterranean termite (Macrotermes gilvus and Coptotermes curvignathus) and one species of drywood termite (Cryptotermes cynocephalus). Lengths of framing (Pinus radiata sapwood) were commerc...
P Sukartana, J W Creffield, A Ismanto, N E Lelana


Enhanced uptake of wood modification agents in “bioincised” wood
2009 - IRG/WP 09-40445
The permeability of refractory wood species e.g. Picea abies and Abies alba is reduced resulting in a radial penetration of chemical solutions of only a few millimetres. Exploitation of these wood species is therefore not possible for many applications. A novel biotechnological method (European patent 05027812.6) based on the pre-treatment of wood with the white-rot fungus Physisporinus vitreus si...
F W M R Schwarze, M Schubert


Environmental Emission of Wood Preservatives: Interpretation of Data Relevant to BPD Risk Assessments
2009 - IRG/WP 09-50259
The risk assessments for the use of wood preservatives proposed by the OECD and used under the Biocidal Products Directive (BPD) (98/8/EC) require the derivation of leaching rates for active substances. These rates are to be used as input data in to agreed exposure scenarios. The leaching rates can be derived from laboratory testing and from field testing. The relationship between laboratory and f...
D G Cantrell


Rapid Microwave-Assisted Acid Extraction of Metals from Chromated Copper Arsenate (CCA)-Treated Southern Pine Wood
2009 - IRG/WP 09-50262
The effects of acid concentration, reaction time, and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with three different acids (i.e., acetic acid, oxalic acid, and phosphoric acid) was investigated using in microwave reactor. Oxalic acid wa...
Bin Yu, Chung Y Hse, T F Shupe


Factors affecting sodium hypochlorite extraction of CCA preservative components from out of service treated wood for recycling
2009 - IRG/WP 09-50263
Significant amounts of chromated copper arsenate (CCA) treated wood products such as utility poles and residential constructions remain in service. There is an increasing public concern about environmental contamination from CCA treated wood when it is removed from service for reuse or recycling, placed in landfills or burned in commercial incinerators. In this paper, we investigate the effects of...
E D Gezer, P A Cooper


Assessment of decay risk of airborne wood-decay fungi
2012 - IRG/WP 12-10787
The decay risk of airborne wood-decay fungi was investigated by using an air sampler. Japanese cedar disks measuring about 8 cm in diameter and 3 mm in thickness with moisture content at about 100 % were placed in a “BIOSAMP” air sampler and exposed to 1000 liters of air. Air sampling was carried out from June to September at the same sampling site in Tsukuba, Japan. The exposed disks were the...
I Momohara, Y Ota, K Sotome, T Nishimura


Modification of Wood by a Water-Repellent Compound Used in the Textile Industry: Boron Release and Termite Resistance
2009 - IRG/WP 09-40447
In the study, wood specimens were treated with disodium octoborate tetrahydrate (DOT) and a commercial water and oil repellent compound, FORGUARD M®, a weak cationic emulsion containing dipropylene glycol monomethylether, water and solids in its formulation and used in the textile industry. There were two different processes for preservative treatments: double and single treatments. The leaching ...
S N Kartal, E Terzi, B Erilkun, Y Imamura


The resistance of thermo-oil modified wood against decay and mould fungi
2009 - IRG/WP 09-40448
Thermally modified wood in comparison to natural wood demonstrates some advantageous functional properties like decreased hygroscopicity, higher dimensional stability. It also has increased durability and improved resistance to fungal decay. However thermal modification of wood may lead to reduced strength properties what may limit the use of wood in mechanically beared constructions. The changes ...
A Fojutowski, A Kropacz, A Noskowiak


Use of wax emulsions for upgrading of wood properties
2009 - IRG/WP 09-40451
Waxes are used for treatment of wood surfaces for several decades, predominately as surface treatments, because they did not penetrate into the wood. In order to overcome this issue, water emulsions were applied in present experiment. Five water emulsions of various concentration was used namely; two emulsions of montan wax (LGE, MW1), emulsion of polyethylene (WE1), emulsion of ethylene copolymer...
B Lesar, F Pohleven, M Humar


Vinyl Benzoate Photostabilizes Wood Whereas Vinyl Cinnamate and Vinyl 4-T-butylbenzoate are Less Effective
2009 - IRG/WP 09-40452
Thin wood veneers were esterified to different weight gains with three different aromatic vinyl esters, vinyl benzoate, vinyl cinnamate and vinyl 4-T-butylbenzoate and the photostability of the modified wood was examined. There was a linear relationship between the level of esterification of wood with vinyl benzoate and the photostability of the modified veneers exposed to natural weathering. Viny...
M Jebrane, G Sèbe, I Cullis P Evans


Tensile stress relaxation of wood impregnated in different ACQ formulations at various temperatures
2009 - IRG/WP 09-40456
The reactions between ammoniacal copper quat (ACQ) constituents and wood components were investigated by tensile stress relaxation approach. Small wood samples were stressed and impregnated in ACQ solutions with different formulation including the ethanolamine (MEA) to copper molar ratio, copper (as copper oxide) to quat (as DDAC) weight basis, treatment temperature and also the solution concentra...
Lili Yu, Jinzhen Cao


Estimating the heat treatment intensity through various properties of thermally modified timber (TMT)
2009 - IRG/WP 09-40459
The suitability of different measures for prediction of the heat treatment intensity was investigated. Therefore, the resistance to impact milling (RIM), the lightness L*, the equilibrium moisture content (EMC), the anti swelling efficiency (ASE) and the total amount of soluble carbohydrates (TSC) of heat treated specimens were correlated with corresponding fungal resistance achieved by heat treat...
C R Welzbacher, C Brischke, A O Rapp


Investigation of chemical changes in acetylated beech wood during weathering
2009 - IRG/WP 09-40460
In this study Beech wood (Fagus orientalis) acetylated and has been subjected to a variety of artificial weathering conditions (water only, light only, water and light together)in difference times (0,50,150 and 300 h), then wood surface analyzed using Fourier Transform Infrared spectroscopy (FTIR).Results shown that weathering process affected the functional groups on the wood surface. Light and w...
M Akhtari, M Arefkhani


Interactions between wood and propiconazole in supercritical carbon dioxide
2009 - IRG/WP 09-40461
Understanding the movement and deposition of biocides in wood is a fundamental aspect of the supercritical wood impregnation process and a key issue in developing the process e.g. to handle wood of larger dimensions. Previous research on supercritical wood impregnation frequently reports of a biocide concentration gradient in impregnated samples i.e. a lower concentration of biocides in the core o...
A W Kjellow, O Henriksen


Biological Performance of Boron-based Chemicals Treated Wood Composites
2009 - IRG/WP 09-40464
In this study, the biological performance of wood-based composites panels treated with boron containing chemicals against to a fungus was determined. Boric acid, borax, zinc borate and agricultural borate (Tarım-bor™), developed and patented by National Boron Research Institute, were mixed with wood chips or fibers and then particleboard, medium strand board and middle density fiberboar...
Ü C Yıldız, H Kalaycıoğlu, S Yıldız, A Temiz, E Tomak Dizman, A Çavdar Dönmez


Performance of Fasteners in Treated Wood: A Comparative Study
2009 - IRG/WP 09-40465
Fastener performance is an important property for treated wood. Published data on screw and nail performance for different preservative systems currently on the market are, however, limited. In this study, screw and nail withdrawal strength for southern pine wood treated with ACQ (above ground and ground contact), MCQ (above ground and ground contact), borate (disodium octaborate tetrahydrate – ...
Q Wu, T Shupe, J Curole, K Ragon, M Voitier, M Freeman, D Ring


Termite Resistant Properties of Wood and Natural Fiber Plastic Composites - AWPA E1 Test Data
2009 - IRG/WP 09-40466
This paper deals with resistance properties of wood plastic composites against Formosan Subterranean Termites (FSTs) based on the AWPA E1 test standard. Sixteen laboratory WPC formulations, four WPC commercial materials, and southern pine (Pinus sp.) wood control were tested for termite mortality, sample weight loss, and sample damage rating. The results show that FSTs did attack WPC products in ...
Q Wu, T Shupe, J Curole, K Ragon, M Voitier, M Freeman, D Ring


Weathering of Wood Modified with the N-Methylol Compound 1,3‑dimethylol-4,5-dihydroxyethyleneurea (DMDHEU)
2009 - IRG/WP 09-40467
Scots pine (Pinus sylvestris L.) sapwood boards were treated with a methylated 1,3‑dimethylol-4,5-dihydroxyethyleneurea (mDMDHEU) causing weight gains of approx. 25% and exposed to weathering for 18 months. Compared to untreated boards, treatment with mDMDHEU reduced surface discoloration mainly caused by staining fungi. Boards treated with mDMDHEU exhibited clearly lower moisture content th...
C Mai, Yanjun Xie, A Krause, K Urban, P D Evans, K Richter, H Militz


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