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Water-Borne Copper Naphthenate: An Emerging Wood Preservative
2002 - IRG/WP 02-30280
Waterborne copper naphthenate (WB Cu-N) was used to treat southern yellow pine (Pinus spp) and red maple (Acer rubrum) stakes. The treated stakes were exposed in test sites located in Florida, Michigan and Mississippi for 3 to 6 years. Copper Chromium Arsenate (CCA), Ammoniacal Copper Quat (ACQ) and Oil-borne Copper Naphthenate (OB Cu-N) were also used to treat some stakes for comparison. Results...
P Nzokou, D P Kamdem, M H Freeman


Bioefficacy of Cunapsol® treated western cedar and southern yellow pine
1996 - IRG/WP 96-30120
Western red cedar and southern yellow pine sapwood were dip treated with a new formulation of waterborne copper naphthenate (Cunapsol®) which complies with VOC regulations. Cunapsol dip treated samples were oven dried at 50°C for 48 hours and then water leached for two weeks. Decay resistance and leachability of preservatives from dip treated specimens were evaluated according to AWPA (American ...
D P Kamdem, M H Freeman, T L Woods


Copper naphthenate-treated Southern Pine pole stubs in field exposure. -Part 2: Chemical characterization of full size pole stubs 12 years after treatment
2000 - IRG/WP 00-30246
This study examines the influence of pre-treatment and post-treatment steaming on the character and physio-chemical nature of copper naphthenate in hydrocarbon solvent treated pine in larger, pole diameter, pole stub-length samples. This work is the continuation of two projects that began almost a decade ago. Previous reports indicated that certain morphological changes might occur in small labora...
H M Barnes, D P Kamdem, M H Freeman


A field test with anti-sapstain chemicals on sawn pine timber in Finland
1986 - IRG/WP 3368
Fourteen formulations, each in two concentrations, were tested for effectiveness against sapstain, mould and decay on Scots pine (Pinus sylvestris L.) in a field test in South-Finland. The trial was commenced in June 1985 and finished in October 1985. During the test the boards were infected mainly by mould fungi. In kiln dried boards the protective effects of nine and in green boards of four trea...
L Paajanen


The effect of steam conditioning on Southern yellow pine treated with copper naphthenate
1997 - IRG/WP 97-40086
The current study was undertaken to investigate the influence of steam conditioning on Southern yellow pine treated with copper naphthenate (Cu-N). Pre-steamed and /or kiln-dried Southern yellow pine were pressure treated with Cu-N. After treatment, one group of samples were post-steamed. It was found that samples changed color from green to dark-brown after post-steaming. To elucidate the effect ...
Jun Zhang, D P Kamdem, M H Freeman, R D Arsenault


Copper naphthenate-treated Southern Pine pole stubs in field exposure: - Part 1: Gradient & biodeterioration analysis 12 years after treatment
2000 - IRG/WP 00-30242
Naphthenates have been used for the preservation of timber and cellulose since their original identification in Russia in the early 1880's as part of a series of petroleum characterizations. Later work in the development of copper naphthenate as a heavy-duty preservative for poles led to the development of various treating cycles similar to other oil-borne systems. Recent work concerning ...
H M Barnes, M H Freeman


Natural progression of decay in unrestrained, Southern pine sapwood exposed above ground
1995 - IRG/WP 95-20060
In this study, the natural progression of decay is being monitored in 2.4-m (8-ft) lengths of dimension lumber. The 2.4-m lengths are supported without restraint in a horizontal plane approximately 0.75 m above ground in a partially shaded field plot in southern Mississippi. The lumber is 100% sapwood. Prior to installation in the field, each piece was planed to exactly 38 by 89 mm² (1.5 by 3.5 i...
R C De Groot, R J Ross, W Nelson


Field Stake Performance of Parallel Strand Lumber Treated with Waterborne Copper Naphthenate
2008 - IRG/WP 08-40435
Wood and wood products have been considered a premium building material for residential and industrial structures for many centuries. More recently, structural composite lumber (SCL) products have played an increasing role in satisfying the needs of the building industry. However, both wood and wood composites are naturally biodegradable materials which require enhanced durability when used in ce...
G P Merrick, M H Freeman, J A Brient


Field trial with poles of Scots pine treated with six different creosotes
1996 - IRG/WP 96-30115
In the middle of the 50's field trials with creosote-treated poles were started in France, Germany and Sweden. The trials were initiated by WEI (Western-European Institute for Wood Preservation). Six different creosotes were used and 40 poles per creosote were installed at each test field. Results after 39 years of exposure in Simlangsdalen, Sweden are reported. Poles treated with a heavy...
Ö Bergman


Light organic solvent preservative treatment of glue-laminated radiata pine
1986 - IRG/WP 3380
The high permeability of radiata pine (Pinus radiata D. Don) is associated with ray-tissue and in particular the cross-field pits linking ray-tissue to tracheids. This pathway is absent in the tangential grain direction, leading to poor preservative penetration when treatment is restricted to the radial face - for example, timber fabricated into glue-laminated beams....
P Vinden


Comparative performance of pentachlorophenol and copper naphthenate in a long term field stake test
2000 - IRG/WP 00-30243
In this study the performance of copper naphthenate (Cu-Nap) and pentachlorophenol (Penta) treated pine stakes against decay and termite attack were compared at two test sites in Mississippi. Four different petroleum oils meeting AWPA Standard P9-A were used as carriers for these wood preservatives. After ten years exposure, the efficacy of Cu-Nap at a retention level of 0.05 pcf Cu was equivalent...
D D Nicholas, M H Freeman


Protection of Ochroma pyramidale from fungal decay with N,N-napthaloylhyroxylamine
1998 - IRG/WP 98-30182
Fungal decay of wood in service results in billions of dollars (U.S.) in losses annually. Recent environmental restrictions, both U.S. and international, are limiting and eliminating the use of broad-spectrum, heavy metal biocides for wood preservation. Restrictions result primarily from problems with disposal. New wood preservatives need to be developed and tested which specifically target key el...
F Green III, T L Highley


Oxalic acid production of fifteen brown-rot fungi in copper citrate- treated southern yellow pine
2001 - IRG/WP 01-10388
Non-arsenical copper-based wood preservatives have grown in number since the 1980's as a response to environmental concerns posed by arsenicals. Interest in copper tolerant decay fungi has increased accordingly. Oxalic acid (OA) production by brown-rot fungi has been proposed as one mechanism of copper tolerance. Fifteen brown-rot fungi representing the genera Postia, Wolfiporia, Serpula,...
F Green III, C A Clausen


Performance of chromated copper arsenate-treated aspen fence posts installed in Forintek's Eastern test plot from 1951 to 1963
1984 - IRG/WP 3272
Aspen poplar fence posts were pressure treated by the full cell process using three formulations of copper chrome arsenate wood preservative. A total of one hundred and fifty nine of the posts were installed in service in Forintek's Chalk River post plot from 1951 to 1962. During the 1982 general inspection of the post plot all 159 posts were still in service. A groundline inspection was ...
C D Ralph


Marine performance of preservative treated Southern pine panels. Part 2: Exposure at Mourilyan Harbour, Queensland, Australia
2000 - IRG/WP 00-10337
Southern yellow pine panels treated with ACQ type B, ACQ type A, CCA type C, creosote, and copper naphthenate have been exposed at Mourilyan Harbour, north Queensland, Australia for almost 6 years. These panels have been inspected and rated for fouling and attack by Teredinid, Limnoria, Martesia, and Sphaeroma during this exposure. After 70 months exposure, overall performance of ACQ type B was eq...
A R Zahora, A F Preston, K J Archer, S Kleinschmidt


Susceptibility of softwood bait stakes to attack by subterranean termites (Isoptera: Rhinotermitidae)
1994 - IRG/WP 94-20037
Sapwood stakes of Australian-grown Araucaria cunninghamii (hoop pine), Pinus elliotii (slash pine), Pinus radiata (radiata pine) and North American-grown Pinus sp. (southern yellow pine) were exposed to subterranean termite attack in an in-ground bioassay. Stakes in bait containers and bare stakes were attacked by Coptotermes acinaciformis and Schedorhinotermes intermedius. Basic susceptibility of...
B C Peters, R T Murray, C J Fitzgerald


In-ground evaluation of a copper azole wood preservative (Tanalithâ E) at a tropical Australian test site
1996 - IRG/WP 96-30100
A field trial to determine the in-ground termite and decay resistance of Pinus radiata D. Don impregnated with a copper azole formulation, TANALITHâ E, has been established at a tropical site in the Northern Territory of Australia. Four retentions of TANALITHâ E, containing 1.54, 2.08, 2.92 and 4.30 kg/m³ of Cu, are being evaluated. For comparison, Pinus radiata specimens treated to two retenti...
J W Creffield, J A Drysdale, N Chew


Ten year field test with a copper-borate ground line treatment for poles
1993 - IRG/WP 93-30017
A wood preservative paste consisting of borax and copper naphthenate has been tested to determine its efficiency in protecting wood from decay fungi and insects. The paste was applied to polyethylene-backed wraps that were fastened to the below-ground portions of unseasoned southern pine pole stubs. After 4 years of exposure in Mississippi, the untreated control stubs were completely deteriorated....
T L Amburgey, M H Freeman


Durability of wood in the area of wood-inhabiting termites in Slovenia
1981 - IRG/WP 1139
This report describes a research dealing with resistance and durability of five different species of wood. The experiment was made in natural conditions in the Slovene area of wood-inhabiting termites. The results of our experimental field, which correspond to the results of the former laboratory experiments, show a very weak resistance of spruce-wood, fir-wood, and beech-wood. They also show thei...
L Kervina


Biological control of sapstain fungi in wood
1996 - IRG/WP 96-10158
Sapstain fungi can cause serious damage to wood and wood products, resulting in a significant economic loss for the wood products industry. The purpose of the present investigation was to determine whether the sapstain in wood caused by sapstain fungi could be biologically controlled. Biological control of sapstain fungi in wood was demonstrated in field trials with nonpigmented isolates of Cerato...
S C Croan


Premature decay of CCA-treated pine posts in horticultural soils - An overview
1984 - IRG/WP 1241
The recent discovery in New Zealand of early decay in CCA-treated pine posts set in horticultural soils led to the establishment of a comprehensive research programme. The objectives and outline of this programme are presented together with an overview of research progress to date. Results suggest that premature decay of CCA-treated timber is restricted to material placed in highly cultivated soil...
J A Butcher


A Preliminary Report on the Properties of Engineered Wood Composite Panels Treated with Copper Naphthenate
2005 - IRG/WP 05-40294
This paper reports on our preliminary investigation of the properties of randomly oriented strandboard which had waterborne or powdered copper naphthenate (CuN) incorporated into the board during manufacture. When compared to zinc borate-treated controls (ZnB), the mechanical properties of strandboard (MOR, MOE, work-to-maximum load, internal bond strength) were not adversely affected by treatmen...
J W Kirkpatrick, H M Barnes


A study of decay type variability in variously treated Fagus sylvatica and Pinus radiata field test stakes exposed at a vineyard for 30 - 45 months
1998 - IRG/WP 98-10271
Pinus radiata test stakes were treated with 10 kg/m3 of CCA plus 4 lower retentions in a geometric series of 1.5. Fagus sylvatica was treated with 15 kg/m3 and 2 lower retentions. Both timber species were also treated with equivalent retentions of various new generation preservatives (P. radiata was also treated with creosote). Whilst these stakes were exposed at 11 sites in New Zealand (NZ) and 2...
R N Wakeling, A P Singh


Serviceability of copper naphthenate-treated poles
2000 - IRG/WP 00-30214
Copper naphthenate-treated poles in service were inspected for deterioration, penetration, retention, and serviceability. The study to date has included poles in all hazard zones in the United States. Poles installed by 12 different utilities and eight different treating companies are included in the survey. Both southern pine and Douglas-fir poles and distribution and transmission poles are inclu...
H M Barnes, M H Freeman, J A Brient, C N Kerr Jr


Some data on the activity of alternative fungicides for wood preservation
1985 - IRG/WP 3333
Data from laboratory tests against basidiomycete fungi are presented for 9 alternative fungicides in organic solvent formulations and also in water for one product. Results are compared with data for reference preservatives, tributyltin oxide, copper and zinc naphthenates and pentachlorophenol. Of special interest is the apparently better than additive effect of mixing tributyltin naphthenate and ...
A F Bravery, J K Carey


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