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Biological test, AAS and EPR study of copper monoethanolamine complex with quaternary ammonium compounds as a wood preservative
2003 - IRG/WP 03-30321
Experiments were carried out on the wood preservative with a strong fungicidal activity based on Cu(II) carbonate, 2-aminoethanol (monoethanolamine) and quaternary ammonium compound (QAC). The object of the performed investigations was sapwood of Scots pine (Pinus sylvestris L.) treated with Cu-EA-QAC formulation. Mycological investigations were carried out according to EN 113 and EN 84 standards....
B Mazela, I Polus, S K Hoffmann, J Goslar


Inorganic preservative levels in soil under treated wood decks after 8 years natural exposure in Borås, Sweden
2005 - IRG/WP 05-50233
Inorganic preservative components (Cu, Cr and As) were measured to a depth of 150 mm under deck structures made with Scots pine lumber treated with several different wood preservatives and installed in Borås Sweden 8 years ago. Higher contaminant levels were observed mainly under the drip lines and in the top 50 mm of soil. Under CCA treated decks, soil arsenic concentrations increased from ba...
P A Cooper, Y T Ung, M-L Edlund, J Jermer


Laboratory versus field tests for evaluating wood preservatives: A scientific view
1995 - IRG/WP 95-20076
The relative merits of field tests versus laboratory tests for evaluating wood preservatives are discussed. Many of the problems involved in interpretation of the results are similar for both types of test. One major problem is to select field sites or laboratory tests that are representative for the practical use of treated timber in ground contact. Decay tests with treated wood in unsterile soil...
T Nilsson, M-L Edlund


Performance criteria for approving new wood preservatives for ground contact
1994 - IRG/WP 94-20021
Protocols for testing novel formulations prior to approval or registration as wood preservatives are being developed in a number of countries, e.g. Australia, New Zealand, USA. One aspect which must be addressed is the effectiveness in tests relative to that of currently approved formulations which would be acceptable to approving authorities. It is assumed that natural exposure testing is a prere...
M E Hedley


Pollution in wood preservation - Aspects and problems
1973 - IRG/WP 55
In the field of wood preservation too, pollution problems have to be considered. They originate with the wood preservatives used. The extent of pollution differs widely with the type of preservative and the treatment process used. Per unit of impregnated timber, pollution will be lower if treatment is performed in treating plants than in distributed places. It will be highest for the old type Bouc...
H Willeitner


Preservatives stains as exterior wood finishes
1977 - IRG/WP 389
For many years wood preservatives and paints have been used as the only treatment for exposed wood surfaces. Because of the inherent color of the preservatives, such as creosote, the wood surface was stained as well as protected from attack by micro-organisms. Paints protect surfaces from weathering, but recently, with an increased interest in maintaining the more natural appearance of exterior wo...
D W French


Inter-laboratory comparison of assessment methods for wood preservatives against subterranean termites: Determination of protection threshold limits for CCA
1999 - IRG/WP 99-10317
In 1996, several institutes conducted laboratory bioassays on the efficacy of unleached Pinus radiata specimens treated with copper-chromium-arsenic (CCA) and copper naphthenate (Cu Naph) at retentions of 0.5, 1.0, 2.0 and 4.0 kg/m3 (total salt for CCA; elemental copper for Cu Naph) against a range of species of subterranean termites (IRG/WP/96-10174). Each participant employed the standard test m...
J W Creffield, M Lenz


Evaluation of wood preservatives for Nordic wood preservation class AB
2002 - IRG/WP 02-30297
In the Nordic countries there are restrictions in the use of wood preservatives based on chromium and arsenic. For above ground use, class AB according to the Nordic system, only copper based preservatives are allowed in Sweden. Thus several new preservatives, copper based or metal free are now used. They have been approved by the Nordic Wood Preservation Council after passing laboratory tests ag...
M-L Edlund, J Jermer


Ecotox Testing of Leachates as an Alternative Approach for Environmental Impact Assessment of Wood Preservatives
2002 - IRG/WP 02-50185
Driven by the implementation of the EU Biocidal Product Directive (BPD) in the environmental assessment of treated wood different methodologies and test strategies are at present under discussion within industry, regulatory authorities and standardizing comittees. Test procedures for the analytical determination of emissions to different environmental compartments according to exposure scenario...
H-W Wegen


Future insecticidal treatments for wood products
1980 - IRG/WP 3140
Protective measures involving chemical treatment of wood use only a narrow range of toxic materials which are divisible into two groups, (i) those that are water-soluble, (ii) those that are soluble only in organic solvents. It is generally true to say that, as far as protection against insects is concerned, the former are stomach poisons while the latter are largely (though not exclusively) conta...
D J Cross


Method to determine the depth of penetration of the biologically active components of wood preservatives
1978 - IRG/WP 2108
A time-saving method for determining the depth of penetration of the biologically active components of wood preservatives is described. The test specimens were obtained by cutting thin slices from the wood either parallel or perpendicular to the treated surface. The slices were then exposed to fungal attack. A good correlation was found between the test results obtained by the modified German Stan...
H-P Sutter


International standardisation: a hypothetical case study with stand-alone borate wood preservatives
1998 - IRG/WP 98-20147
The possibility of developing wood preservation standards with a global remit has a number of obvious advantages as well as far reaching ramifications, many of which are undefined as yet. The commercial implications of adopting international standards are clearly considerable, but equally, such a development is likely to focus attention on the conceptual differences in the way that different regio...
M W Schoeman, J D Lloyd


The wood preservative performance of biocide mixtures containing chlorpyrifos
1994 - IRG/WP 94-30055
Chlorpyrifos (O,O-diethyl[3,5,6trichloro-2-pyridyl]phosphorothioate) was evaluated as a wood preservative insecticide in two long term field tests. In the first project, pine sapwood blocks treated with chlorpyrifos (CPF) were exposed to Coptotermes formosanus using an above-ground test format. CPF is effective in protecting wood from attack by this termite, but its activity appears to decrease wi...
P E Laks


Administration of wood preservative usage in New Zealand
1977 - IRG/WP 395
Principal administration of the preservative treatment of timber in New Zealand is by the Timber Preservation Authority (TPA). The TPA was established in 1955 by Act of Parliament and is under the jurisdiction of the Minister of Forests who appoints its members. Its field staff are Forest Service employees. The Authority comprises twelve members and includes representatives of timber trade associa...
M E Hedley


A comparison of fungal strains used in the bioassay of wood preservatives
1984 - IRG/WP 2220
Previously published data are presented relating to a number of strains of wood-destroying basidiomycetes (Coniophora puteana, Coriolus versicolor, Gloeophyllum abietinum, Gloeophyllum sepiarium, Gloeophyllum trabeum, Lentinus lepideus, Poria placenta, Fibroporia vaillantii and Serpula lacrymans) commonly used as test fungi in the bioassay of wood preservatives. The data, which has not been statis...
J Wazny, H Greaves


Field test of wood preservatives with Nasutitermes rippertii RAMBUR in Cuba
1996 - IRG/WP 96-10181
A field test of wood preservatives was carried out with Nasutitermes rippertii RAMBUR in the vicinity of the Material Testing Centre „Alexander von Humboldt" in Santiago de las Vegas/ Havana (Cuba) for 12 and 24 months. Test specimens of Pinus sylvestris L., Picea abies (L.) Karst. and Fagus sylvatica L. with dimensions of 25 x 25 x 490 mm³ were arranged vertically or horizontally in a circle o...
W Unger


Changes of EPR spectra of wood, impregnated with copper based preservatives, during exposure to Antrodia vaillantii
2000 - IRG/WP 00-10355
Spruce wood (Picea abies) samples were impregnated with two different aqueous solutions: copper(II) octanoate with ethanolamine or copper(II) sulfate (cCu = 1,0 x 10-2 mol/l). Impregnated and unimpregnated test pieces were exposed to wood rotting fungus Antrodia vaillantii. Some strains of this fungus are known as copper tolerant. After four weeks of exposure to A. vaillantii, we could not detect ...
M Humar, M Petric, F Pohleven, M Šentjurc


Three-year field trials of polymeric formulations which provide a new basis for the invention and design of non-toxic wide-spectrum wood preservatives
1994 - IRG/WP 94-40029
Three types of non-toxic polymeric formulations invented using a new approach to wood preservation were challenged with termites and fungi in three-year ground-contact field trials in the sub-tropical climate of Natal. These formulations were copper soaps of carboxylic acid groups of unsaturated fatty acids of waxes and edible vegetable oils; of resin acids of rosin, and, of synthetic unsaturated ...
A A W Baecker, A Pizzi


Technologies for the Management of Wood Waste Containing Metals-Based Preservatives
2005 - IRG/WP 05-50224-16
Disposal of the metals from preservative treated wood can occur through two general strategies: “removal and confinement” or “dilution”. The acceptability of each of these two choices is typically dictated through the disposal regulations of a particular region. A considerable amount of research has been conducted to develop new and innovative “removal and confinement” technologies...
H M Solo-Gabriele, T G Townsend


Wood preservatives treatment of black spruce
1997 - IRG/WP 97-40092
A representative sample of black spruce logs from Central Newfoundland was harvested and processed to dressed 2"x4" lumber. Over 400 pieces of lumber were then incised and treated with ACQ preservative in a semi-industrial retort. 9 charges of 20 samples were used to determine treating parameters and 11 charges of 20 pieces were treated using the optimized process. This material was inspected by a...
A R Zahora, J P Hösli


Chemically modified tannin and tannin-copper complexes as preservatives for wood
2001 - IRG/WP 01-30271
The efficacy of Mimosa tannin, chemically modified tannin, and tannin-copper complexes as wood preservatives was studied. When the tannin-ammonia-CuCl2 solutions were impregnated into wood specimens in a one-step procedure, a large quantity of the tannin-copper complex was fixed in the specimens. Little of the complex was leached from specimens by a weathering treatment, and these specimens showed...
H Yamaguchi


Detoxification of salt impregnated wood by organic acids in a pulping process
1993 - IRG/WP 93-50012
The paper descibes a novel method to detoxify pine wood (Pinus silvestris L.) treated with CCB-, CCF- CC-, and Cu-HDO-type salt preservatives. In the process of biological detoxification organic acids produced by strains of Antrodia vaillantii and other brown rot fungi are used for the dissolution of the previously fixed inorganic compounds. These findings are the basis for applying an acid pulpin...
I Stephan, H H Nimz, R D Peek


Copper based wood preservative - A new approach using fixation with resin acids of rosin
2000 - IRG/WP 00-30249
Copper soaps with carboxylic acid groups of resin acids of rosin were shown to be potential long-term wood preservatives. The principle involved is the attachment of copper to the network formed by the inorganic part of the preservative (rosin) through the -COOH groups. The mechanisms of fixation have been studied, and it has been shown that this association could be obtained : (1) by forming the ...
C Roussel, J P Haluk, A Pizzi, M-F Thévenon


Experiences with environmental risk assessment within the Biocidal Products Directive
2005 - IRG/WP 05-50224-21
The Biocidal Products Directive (98/8/EC, the BPD) aims to authorize biocidal products based on risk assessment for both man and the environment. Active substances for wood preservation products and rodenticides were selected for the first list under the review program (Regulations EC 1896/2000 and EC 2032/2003) because several member states had experience with the evaluation and authorization of ...
P Blancquaert


A spectroscopic investigation of copper ethylenediamine fixation in wood
1999 - IRG/WP 99-20160
The fixation reaction which take place between copper ethylenediamine (Cu-en) solution and wood were expolored using X-ray photoelectron spectroscopy (XPS) and Fourier Transformed Infrared Spectroscopy (FTIR). The FTIR spectra revealed that copper reacts with the carboxylic acid and phenolic groups in wood to form stable complexes. The copper ethylenediamine complexes formed in wood were identifie...
Xiao Jiang, J N R Ruddick


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