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Tannin resin-boron associations: Leaching and biological resistance
2012 - IRG/WP 12-30587
The easy leaching of boron in wood preservation formulations has allowed to use this fungicide only for short term applications. The recently discovered adduct with flavonoids allows boron to resist longer periods of time within wood and consequently extend its life. Two different leaching treatments were compared and the fungal and termite decay was examined. The biological tests have shown extre...
G Tondi, S Wieland, N Lemenager, A Petutschnigg, A Pizzi, M-F Thevenon


Mold Control for Treated Lumber in Block-Stack Storage Conditions
2012 - IRG/WP 12-30588
The mold development and control for freshly treated and block-stacked wood have been evaluated using a green house mold testing method. The results for the mold resistance of several commonly used water boron preservative treatment systems, such as ACQ, Copper Azole, and borates with and without inclusion of mold inhibitors are presented. The data suggest that the different preservative treatme...
L Jin, P Walcheski, A Preston


Smart hydrogels from low molecular weight amphiphilic compounds: toward a solution to decrease leachability and increase efficacy of boron preservatives?
2012 - IRG/WP 12-30589
A new catanionic system associating amphiphilic carnosine (AlaHisC8) and lauric acid forms supramolecular hydrogel at very low concentration. This gel was investigated and we have checked the validity of the concept of hydrogels utilization to reduce boron leachability and to develop new wood protection treatments. Impregnation with 5% aqueous borax solution (w/w) and 0.3% gelator agent (...
F Obounou Akong, P Gérardin, C Gérardin-Charbonnier


Evaluation of Five Novel Organotin(IV) Complexes as Wood Preservatives
2012 - IRG/WP 12-30590
Three selected non durable tropical wood species namely Alstonia scholaris (pulai), Macaranga triloba (mahang) and Hevea brasiliensis (rubber) were chemically impregnated with five novel organotin(IV) complexes using vacuum-pressure treatment method. The objectives of this study were to determine the treatability and efficacy of novel organotin(IV) complexes against white and brown rot decay fungi...
M M Rahman, I Jusoh, M A Affan, A Husaini


Supercritical impregnation of wood with siloxane
2012 - IRG/WP 12-30595
This paper describes the effect of supercritical impregnation with siloxane on the water repellency of Scots pine (Pinus sylvestris) sapwood samples. Samples were impregnated with a low amount of siloxane dissolved in supercritical carbon dioxide using isopropanol as a co-solvent. Siloxane retention (i.e. weight percent gain (WPG)) of the treated samples was 1.3 % (w/w) as found by mass balance. T...
A Kjellow, F Imsgard, J Fernandes, O Henriksen, E Klaassen, R Wagner, J Delis


Effect of preservative treatment on dimensional stability of plywood made of treated simul (Bombax ceiba) veneer
2012 - IRG/WP 12-40575
The dimensional stability such as thickness swelling and water absorption of plywood made of treated simul (Bombax ceiba) veneers were investigated after 2 hours and 24 hours soaking under water. The veneers were treated with hot water and cold water solution of borax-boric acid (1:1), neem leaves and mahogany seeds of different concentration (1:10, 1:20, and 1:40) at different treatment duration....
K Akhter, M Mahabubur Rahaman, A Ara


Effects of Nano-Zycosil on Liquid and Gas Permeability of MDF
2012 - IRG/WP 12-40578
Effects were studied of zycosil nanoparticles, with size range from 30 to 90 nm, on liquid and gas permeability of medium density fiberboard. 100 g of nanozycosil was added to each kg of dry fibers. Density was kept constant at 0.67 g/cm3. The obtained results indicated that addition of zycosil to the mat resulted in a significant increase in gas permeability due to the lower fiber-content in the ...
H Reza Taghiyari, K Heidarhaee, P Noori, A Karimi


The effect of press time on springback and water absorption of acetylated particleboard
2012 - IRG/WP 12-40579
In this study the effect of press time on springback, thickness swelling and water absorption was investigated. After 24 hours soaking in acetic anhydride, in order to achieving WPG 17%, acetylated particles were heated in an oven at 120 0C for 360 minutes. Acetylated and nonacetylated (control) particleboards were produced with 10% melamine urea formaldehyde (based on the oven-dry weight of part...
F Bavaneghi, M Ghorbani, A Kargarfard


Water uptake of wood surfaces with and without coating: influence of weathering
2012 - IRG/WP 12-40580
The objective of this study was to compare liquid water absorption of wood surfaces with and without coating, before and after artificial weathering. Samples of spruce, oak and sapelli were exposed to the EN 927-6 cycle for 1500 and 1850 hours and to the weathering produced by the Garner wheel for 1000 hours. Two highly pigmented coatings (solventborne and waterborne) and two semi-transparent stai...
L Podgorski, S Collignan, J D Lanvin


Effects of nano-wollastonite impregnation on fire resistance and dimensional stability of Poplar wood
2012 - IRG/WP 12-40595
The fire-retardant properties of Nano-Wollastonite (NW) in poplar wood (Populus nigra) were determined in this study. Some physical properties such as water absorption, volumetric swelling and Anti-Swelling Efficiency (ASE) were also measured. Specimens were prepared according to the ISO 11925 standard for the fire-retarding properties, and ASTM D4446-2002 standard for the physical properties. Imp...
A Karimi, A Haghighi Poshtir, H Reza Taghiyari, Y Hamzeh, A Akbar Enayati


The Effects of Industrial-Scale Heat Treatment and Impregnation with Boron Compounds on Water Uptake and Tangential Swelling of Some Wood Species
2012 - IRG/WP 12-40599
This study evaluated the effects of boron impregnation and heat treatment on water uptake and tangential swelling of spruce (Picea orientalis), pine (Pinus nigra), beech (Fagus orientalis) and poplar (Populus deltoides) wood species. The samples (10 x 5 x 40 - tangential x radial x longitudinal cm) were impregnated with 4 % boric acid and 4 % borax according to the ASTM D-1413 standard method. Aft...
A Can, S Yildiz, Ü C Yildiz


The effect of nanozycosil on the water absorption and dimensional stability of Beech wood
2012 - IRG/WP 12-40606
Zycosil is a clear penetrating water repellent. This product works by penetrating into the substrate and modifying the surface tension to inhibit water intrusion. Beech wood (Fagus orientalis) was modified by treatment with nanozycosil. Then water absorption and dimensional stability in terms of volumetric swelling percent and anti-swelling efficiency were determined and found to be improved on t...
M Ghorbani, F Bavaneghi


Efficiency of the Amazon Forest Oils as Preservatives to the Attack of cellulolytic fungi in Pine Wood
2012 - IRG/WP 12-30599
The bobbins of wood are used for storage and field installation of cables from the electricity and telecommunications sectors. There are legal requirements governing the Brazilian ways of treating the wood used in these sectors, aimed at preventing pollution and protecting nature. When exposed to severe environmental conditions in Brazil these products are degraded and occurs many operational prob...
S Silveira, I M S Mendes, R S Paiva, J E Volponi, R C G Comar, R S Cruz


Effectiveness of CCA-C and CCB preservatives after a 30 years stake test
2012 - IRG/WP 12-30606
The objective of this experiment was to assess the durability of four pine species treated with waterborne preservatives. In order to determinate this, a stake field test, following the IUFRO (International Union of Forestry Research Organizations) recommendations, was installed at Experimental Station of Luiz Antonio (21º 32’ S and 47º 42’ W), State of São Paulo, Brazil. Species under t...
I PJankowsky, E S Lepage, C Salvela, J M Vidal, S Takeshita


The effect on moisture content of water trapped in wood joints
2012 - IRG/WP 12-40613
To predict the service life of a structure, a model where the exposure of a structure is compared to its resistance can be used. Which exposure and resistance parameters that are relevant depend on which materials the structure consist of. This approach, with an exposure and a resistance parameter, is similar to the one used in structural engineering where a load (exposure) is compared to the bear...
M Fredriksson, L Wadsö, P Johansson


Protective nanoparticle coating reducing water absorption of wood species
2012 - IRG/WP 12-40614
Nanoparticle coatings were deposited onto different tropical wood samples for controlling the surface hydrophobicity. The styrene(maleimide) nanoparticles were synthesized in aqueous dispersions under pure conditions or in combination with 70 wt.-% palm oil. A first evaluation of the non-coated wood surfaces indicates a high dependence between the water contact angles, the average surface roughnes...
P Samyn, A Paredes, G Becker, H Van den Abbeele, L Vonck, D Stanssens


Water absorption and desorption of non treated, pressure impregnated, and pine oil treated glulam made of small diameter Scots pine and Norway spruce
2012 - IRG/WP 12-40616
A growing proportion of harvested timber originates from the first or second commercial thinning stands in Finland, which means smaller average log volumes in comparison to final felling stands. Smaller log volume means challenging wood properties such as higher proportion of juvenile wood and sapwood. Due to these facts, products made of small diameter logs are prone to twist and check, and have ...
H Heräjärvi, V Möttönen, R Stöd


Developing Analytical Methods for Determination of Quaternary Ammonium Compounds (DDAC) using HPLC and HPLC-MS (Application to treating solution and preservatives treated wood)
2013 - IRG/WP 13-20516
Korea preservative treating industry has mainly used alkaline copper quaternary (ACQ) expected over 80% of market share in Korea. ACQ employs dodecyl dimethyl ammonium chloride (DDAC) and benzyl dimethyl dodecyl ammonium chloride (DBAC) for active ingredient along with copper. The strongly increasing domestic applications for wood preservatives require developing accurate and reproducible analytic...
Sung-Mo Kang, Kwon-Min Kim, Won-Mo Koo, Myeong-Won Cho


Micronized Copper Wood Preservatives: Strong Indications of the Reservoir Effect
2013 - IRG/WP 13-30609
Micronized copper wood preservative systems were launched commercially in May 2006. Now, over 75% of the residential lumber produced in the USA is treated with micronized wood preservative formulations. Although considered controversial at first, the mode of action of micronized copper has been clearly defined by multiple authors over the years, as well as a need for a co-biocide in water-borne sy...
M H Freeman, C R McIntyre


Preliminary testing of spiroborate esters as wood preservatives
2013 - IRG/WP 13-30614
Fungicide and insecticide properties of boric acid are known since 30’s of the last century, but high solubility and leachability of inorganic borates limit their use for only applications not directly exposed to liquid water. A number of attempts were made to fixate borate salts into the wood structure but this research topic is still up to date and undiscovered. Water insoluble organoboron est...
D Panov, N Terziev


The Effect of Water Repellent on Semi-Field Leaching of Active Substances from Metal Free Wood Preservative Formulation
2013 - IRG/WP 13-30615
The risk assessments for the use of wood preservatives proposed by the OECD and used under the Biocidal Products Directive (BPD) (98/8/EC) require the derivation of leaching rates for active substances. These rates are to be used as input data in to agreed exposure scenarios. A comparison of the leaching of active substances from wood treated with a metal free preservative formulation with and wit...
D G Cantrell


The effects of impregnation with secondary metabolite extracted from Ipe on durability of Japanese cedar and beech wood
2013 - IRG/WP 13-30618
Ipe wood is known for its high durability; it has been widely used in exterior structures that are exposed to the weather. In this paper, to increase the durability of less durable wood, Japanese cedar and beech specimens were impregnated with a secondary metabolite from Ipe. In a previous study, secondary metabolites extracted by a Soxhlet extraction method showed antifungal properties. Therefore...
T Iida, R Konuma, K Kawarada


Effect of Nano and Micronized Particles as Wood Preservatives for Termite Control
2013 - IRG/WP 13-30620
Subterranean termites are a major factor in the biodegradation of wood constructor products. In this study the efficacy of wood treated with micronized copper, zinc oxide and their mixture was compared to that of wood treated with soluble amine copper oxide with subterranean termites in a laboratory test. All of the formulations tested were effective in controlling wood degradation by the termites...
M Akhtari, D Nicholas, A Rowlen, M Arefkhani


State of progress of utilisation of supramolecular gels for formulations of water-soluble wood preservation salts
2013 - IRG/WP 13-30630
This article is a compilation of the work done so far concerning the utilization of supramolecular hydrogels, built on low-molecular-weight amphiphilic molecules and containing boron salts conferring fungicidal properties. Mixing boron with thermoreversible hydrogels allows the formation of a supra molecular network incorporating boron and important amount of water upon gelification of the solutio...
F Obounou Akong, P Gérardin, M-F Thévenon, C Gérardin-Charbonnier


Hygroscopicity of wood after polyethylene glycol (PEG) impregnation and/or heat treatment
2013 - IRG/WP 13-40623
The hygroscopicity of wood after polyethylene glycol (PEG) impregnation and/or heat treatment was investigated by testing the water uptake, equilibrium moisture content (EMC) at various relative humidity levels, and contact angle of the poplar wood surface. The results showed that: (1) At the first moment, the heat treatment at temperatures lower than 160 ℃ did not reduce the water uptake be...
Weiyue Xu Yuan Zhu, Jinzhen Cao


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