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Statistical analysis of 40 years of preservative in-ground stake testing in Australia
2014 - IRG/WP 14-20552
Wood is widely recognized as a valuable material, yet the natural durability of some wood species limits its use for certain outdoor purposes. For decades, a wide range of methods and chemicals have been developed to increase the resistance of wood against degrading microorganisms and termites. Preservative treatment has a long and widespread tradition in wood protection. Proper testing of the eff...
J Van den Bulcke, L J Cookson, I De Windt, W Li, J Van Acker


Effectiveness of Copper Indicators in Treated Wood Exposed to Copper Tolerant Fungi
2014 - IRG/WP 14-20554
Wood treated with a copper based wood preservative will typically turn a green color. While the depth of copper penetration can be readily discerned from the green color of the copper it is standard practice in research and commercial treating plants to make use of a color reagent such as Chrome Azurol S, Rubeanic acid or PAN indicator to reveal the penetration more clearly. When copper treat...
L Jin, K Brown, A Zahora, K Archer


Scanning Transmission X-ray Microscopy as a tool for examining chemical changes in wood cell walls due to enzymatic activity
2014 - IRG/WP 14-20556
As development of techniques for examining enzymatic activity on solid, complex biological materials, is considered to be an important factor in further development of enzyme applications and for understanding the decay of plant materials, this study explores applicability of Scanning Transmission X-ray Microscope (STXM) for determining chemical changes in enzymatically treated samples at the cell...
D Jeremic, R Goacher, R Yan, C Karunakaran, E R Master


Wood treatment with organosilanes – perspective for IPBC stabilization
2014 - IRG/WP 14-30641
The aim of the research was a new model preservative’s antifungal properties evaluation. The formulation contained 3-Iodo-2-propynyl butylcarbamate (IPBC) at the reduced concentration. The IPBC was combined with organosilicon compounds (i.e. alkilosilicones with amino groups or fluorine) for supporting its antifungal properties. Due to the fact, that IPBC can be easily destabilized under the in...
W Perdoch, B Mazela, A Waśkiewicz


Coconut shell pyrolytic oil as wood protectant against biodeterioration
2014 - IRG/WP 14-30648
Extensive research on various plant and microbial extracts has been conducted as an alternative to using synthetic or inorganic chemicals for wood protection. Development of effective and low environmental impact products and technologies for wood protection is imperative. In the present study, the efficacy of coconut shell pyrolytic oil as a wood protectant is analysed in terms of its antifungal,...
K S Shiny, O K Remadevi


Fire resistance of wood treated with potassium carbonate and silanes
2014 - IRG/WP 14-30657
This paper reports on the effect that organosilicon compounds and potassium carbonate and urea (PCU) have on wood flammability. The study focus on reducing wood flammability by promoting char formation through manipulation of the condensed phase decomposition chemistry. Potassium carbonate is known as an effective fire retardant, however it is easily leached out from wood and increases its hygrosc...
B Mazela, M Broda, W Perdoch


Ammoniacal Copper Zinc Arsenate Preservative Treated Wood Ties Their Performance in Testing and Track
2014 - IRG/WP 14-30636
While not a new preservative system, Ammoniacal Copper Zinc Arsenate (ACZA), had not previously been used to protect crossties. Its performance in treating difficult or refractory species of wood has been documented through its wide range of uses approved in AWPA. The establishment of appropriate testing for railroad material use was put in place and includes laboratory, field as well as commercia...
T Carey


CreoSub – New protection technology to substitute creosote in railway sleepers, timber bridges, and utility poles
2014 - IRG/WP 14-30644
Creosote oil is one of the oldest industrially used wood preservatives. Due to its toxic profile, the European Commission has restricted the use of creosote specific applications, but it is highly controversial within the European Commission. Its approval for use after 2018 is very questionable and may depend on derived research results until then, i.e., the viability of alternatives developed to ...
U Hundhausen, K-C Mahnert, A Gellerich, H Militz


Copper naphthenate treatment for wood crossties and timbers
2014 - IRG/WP 14-30647
Copper naphthenate (CuN) has a long history in wood preservation and is recently finding increased usage as a treatment for wooden crossties and timbers. One of the principal reasons that CuN has gained market acceptance, in addition to its efficacy against decay fungi and wood-destroying insects, is its low mammalian toxicity and environmental impact. CuN is a well proven non-restricted use pres...
J Brient


Resistance to Decay Fungi of Scots Pine Impregnated with Natural and Chemical Preservatives
2014 - IRG/WP 14-30650
In this study, heart-wood and sap-wood specimens of the Scots pine which is naturally grown in Turkey were treated with natural (valex) and some chemical preservatives such as CCA - C (Copper / Chrome / Arsenic), CBA - A (Copper / Boron / Azole). The wood protective efficacies of these preservatives were investigated by means of fungi decay test (EN 113). As a result of the study it was found t...
S Yildiz, U B Şimşek


Chemistry of copper preservative treated wood
2014 - IRG/WP 14-30651
The reaction chemistry of micronized copper wood preservatives is fundamentally different from any previous inorganic preservative system. In order to study the chemistry, analytical procedures had to be developed which allowed the determination of the total copper as well as the copper which reacted with the wood forming copper-wood complexes. With the success of this approach it also became poss...
Wei Xue, P Kennepohl, J N R Ruddick


Visualization of gold/silver nanostars in wood by surface enhanced Raman spectroscopy
2014 - IRG/WP 14-30653
Nanotechnology is a fast growing up-to-date technology and ventures expeditiously in the wood preservative market. However, there is still a huge lack of understanding about the interaction and incorporation of nanoparticles (NSs) in wood. Surface-enhanced Raman scattering (SERS) offers unique advantages as an analytical tool with a high selectivity and sensitivity without matrix interference. Her...
C Geers, L Rodríguez-Lorenzo, M Placencia Peña, P Brodard, T Volkmer, B Rothen-Rutishauser, A Petri-Fink


Study of the effectiveness of wood products for permanent protection against Fusarium circinatum
2014 - IRG/WP 14-30655
In Europe there exist a number of quarantine organisms that affect conifer forests, including Fusarium circinatum Nirenberg et O'Donnell (telemorph: Gibberella circinata Nirenberg et O'Donnell), a quarantine organism in Europe producing the disease known as pitch canker of pines. For a decade, the European Union has taken steps to locate and eradicate the pathogen with the aim of elimina...
M T Troya, M Conde, R Raposo, F Llinares, M Elvira-Recuenco


Influence of Exposure Direction on Leaching of a Biocide from Painted Wood Surfaces
2014 - IRG/WP 14-50303
The objective of this project was to investigate the influence different exposure directions – North, East, South and West on the cumulative quantity of a biocide leached from painted wood surfaces due to rainfall and the consequences for the risk assessment. The study included a solvent-borne primer without biocides and a topcoat protected with a biocidal active substance. Both products were a...
M Klamer


Hydroponic Phytoremediation of Chromated Copper Arsenate (CCA) and Copper Contaminated Water
2014 - IRG/WP 14-50304
The removal of selected metals by duckweed (Lemna minor) and parrotfeather (Myriophyllum aquaticum) from a simulated aqueous environment contaminated with Chromated Copper Arsenate (CCA) and copper sulfate was studied in a controlled laboratory experiment. The duckweed and parrotfeather’s tissues were analyzed to evaluate the removal of copper (Cu), chromium (Cr), and arsenic (As) from CCA cont...
C Keith, H Borazjani, S Diehl, Y Su, Fengxian Han, B Baldwin


Practical extraction of metals from CCA-treated wood
2014 - IRG/WP 14-50305
The extraction effects of acid concentration, reaction time and temperature in a microwave reactor on recovery of chromated copper arsenate (CCA)-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from CCA-treated southern pine wood samples with three different wood particle sizes (i.e., (1) 0.5 cm3, (2) 0.5x05x1.0 cm, and (3) 0.5x0.5x1.5 cm) was investigated using a m...
Bin Yu, Chung Y Hse, T F Shupe


VOC-free remedial treatment agent on organic solvent basis with surface cleaning by photocatalysis using titanium dioxide
2014 - IRG/WP 14-40651
Due to the EU Regulations according to the harmonisation of the European market of biocidal products and the EU Regulations regarding emissions of volatile organic compounds in residential properties a new VOC free yet organic solvent based remedial treatment agent is introduced including a potential method to clean up the wooden surface of remaining biocides after a remedial treatment using photo...
H Ahl, J Fromm, P Jüngel, E Melcher, M Pallaske


Nano-Zycosil in MDF. Part I: Gas and Liquid Permeability
2014 - IRG/WP 14-40652
Effects were studied of zycosil nanoparticles, with size range from 20 to 80 nm, on liquid and gas permeability of medium density fiberboard. Nanozycosil was used at four consumption levels of 0, 50, 100, and 150 g/kg dry wood fibers. Density of all treatments was kept constant at 0.67 g/cm3. The obtained results indicated that the addition of zycosil to the mat resulted in a significant increase...
H Reza Taghiyari, A Karimi, P M D Tahir, O Schmidt, E Bari, P Nouri , A Jahangiri


Effect of silver nanoparticles on the rate of heat transfer to the core of the medium-density fiberboard mat
2014 - IRG/WP 14-40653
Effect of silver nanoparticles on the rate of heat transferred to the core section of medium-density fiberboard (MDF) mat was studied here. A 400 ppm aqueous nanosilver suspension was used at three consumption levels of 100, 150, and 200 mL/kg based on the weight of dry wood fibers; the results were then compared with the control MDF panels. The size range of silver nanoparticles was 30-80 nm. Res...
H Reza Taghiyari, O Schmidt, E Bari, P M Tahir, A Karimi, P Nouri, A Jahangiri


Evaluation of vessel features on physical and mechanical properties of wood of Common black poplar (Populus nigra L.) grown at different elevations in the region with a continental climate
2014 - IRG/WP 14-40656
This study essentially examined the effect of elevation on the anatomical structure, and the physical and mechanical properties of Common black poplar (Populus nigra L.) wood. The scope of the study was to observe the variability of vessel element features on physical and mechanical properties of Common black poplar (Populus nigra L.) in relation to habitat at different elevations. For this purpos...
I Usta


The resistance of Accoya® and Tricoya® to attack by wood-destroying fungi and termites
2014 - IRG/WP 14-40658
The resistance of high acetyl WPG solid timber (Accoya®) and medium density fibreboard (Tricoya®) to attack by wood-destroying fungi and termites was investigated under both laboratory and field conditions. Laboratory decay studies were conducted in Australia and New Zealand. Field studies were conducted in Australia, Japan, New Zealand, Thailand and USA. The results of the laboratory and field ...
J Alexander, J Hague, F Bongers, Y Imamura, M Roberts


Full-scale impregnation of wood with siloxane using supercritical carbon dioxide
2014 - IRG/WP 14-40659
Full-scale impregnation of wood with siloxane was carried out using supercritical carbon dioxide as solvent. A batch of 3530 kg of Scots pine sapwood was impregnated to a retention of approximately 1.3% siloxane. The treatment also consisted of a simultaneous impregnation with organic biocides. The performance of the wood was evaluated in terms of capillary water uptake according to a modified EN ...
A Kjellow, F Imsgard, J Fernandes, R Wagner, J Delis


Termite resistance of wood modified with short- and long-chain siloxanes
2014 - IRG/WP 14-40660
Scots pine (Pinus sylvestris L.) sapwood specimens modified with short- and long-chain amino-functional siloxane emulsions were exposed to subterranean termites (Reticulitermes flavipes Kollar). Laboratory choice and no-choice tests following the standard EN 117 (2013) were conducted for 8 weeks in order to evaluate the influence of these silicon-based compounds on the termite resistance of treate...
P Gascón-Garrido, M-F Thévenon, H Militz, C Mai


Effect of Nano-Wollastonite on Water Absorption in Particleboard
2014 - IRG/WP 14-40662
Effects of wollastonite nanofibers on physical properties of particleboard were studied. Nano-wollastonite (NW) was applied at 5, 10, 15, and 20 g/kg, based on the dry weight of wood-chips, and compared with control specimens. Two application methods of NW were used: surface application (SA), and internal application (IA). Density was kept constant at 0.68 g/cm3 for all treatments. Tests were carr...
S Karimi, H Reza Taghiyari, A Karimi, P M Tahir, J Abdul Halip


Improving dimensional stability of thermally treated wood by secondary modification – potential and limitations
2014 - IRG/WP 14-40664
The potential of treating thermally modified wood with melamine resin to improve the dimensional stabilization is tested in this research. Two different boards of poplar (Populus ssp.) were cut into two halves. One half of each board was thermally modified (T1 and T2) in a commercial process, the other half was used as untreated reference material. The material was thermally modified using the vac...
G Behr, K-C Mahnert, S Bollmus, H Militz


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