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A bibliography of organic solvent-based wood preservatives
1973 - IRG/WP 313 E
H Alliot


The Chemical and Biological Properties of Polymeric Betaine
2009 - IRG/WP 09-30512
Didecyl polyoxyethyl ammonium borate (DPAB), also known as Polymeric Betaine, was developed as a co-biocide for chromium-free copper based wood preservatives in Europe in the 1980’s. DPAB as a wood preservative has been reported previously. This paper summarizes the chemical, physical, and biological properties of DPAB. ...
H Härtner, S Schmitt, Futong Cui, H M Barnes


Effects of terpene compounds on the growth and peroxidase activity of Phellinus pini
1979 - IRG/WP 2130
The volatile compounds myrcene, limonene, a-pinene, a-terpineol, D-fenchol and 1,8-cineole, present in the oleoresin fraction of coniferous wood, were tested individually and as mixtures for their effect on the growth and peroxidase activity of cultures of six strains of Phellinus pini (Fr.) A.Ames and one strain of Phellinus chrysoloma (Fr.) Donk (Phellinus pini var. abietis (Karst.) Pilát). Phe...
L Väisälä


Remedial treatment of joinery. Comparison of distribution of organic solvent preservative and ammonium bifluoride
1978 - IRG/WP 3115
It is some years since it was recognised in the United Kingdom that there was a problem of premature decay in untreated external joinery. Consequently, recommendations for preservative treatment were made by the Building Research Establishment, Princes Risborough Laboratory. In addition, the National House-Building Council has also included the preservative treatment of external joinery in its req...
J M Taylor


The hydrolysis of organo-boron compounds in treated particleborard
2000 - IRG/WP 00-40180
Standard particleboard (manufactured for interior applications) was treated with trimethylborate and modified trimethylborate and then left to hydrolyse for specified periods. The percentage residual trimethylborate was determined by placing samples in kerosene and analysing the kerosene for boron after 3 days of leaching. There was a significant correlation between the percentage hydrolysis of tr...
K M Filcock, P Vinden


Soft rot fungi as possible sources of odor in impregnated wood in buildings
1993 - IRG/WP 93-20013
Wood preservatives are frequently used inside houses. In several cases impregnated wood, particularly when used in crawlspaces or other near-ground constructions, has been found to be a source of odor. Mold fungi, soft rot fungi actinomycetes or bacteria growing on impregnated wood are possible producers of the odor. Analyses of volatile emissions from impregnated wood with odor and pure cultures ...
J Bjurman, J Kristensson


Decrease of the antidecay resistance of beech wood treated with organotin fungicides after its natural ageing
1998 - IRG/WP 98-30185
The antidecay resistance of beech-wood samples (120 x 8.5 x 8.5 (MM)) treated with tributyltin fungicides gradually decreased due to prolongation of their natural ageing: tributyltin fungicides (TBTO, TBTS, TBTCA, TBT-DEDTK were applied by pressure impregnation technique in ethanole solutions (c = 0. 1%, 0.33% or 1%); treated beech-wood samples were naturally aged without their contact with grou...
L Reinprecht


An investigation of organotin compounds in treated wood using Mössbauer spectroscopy
1983 - IRG/WP 3249
The influence of sample preparation on the 119mSn Mössbauer spectrum of tributyltin chloride in ponderosa pine was investigated. Initial studies with sawdust and compressed discs concluded that the latter were clearly superior. Further studies showed that compressed discs prepared from 0.4 g of treated wood and 0.1 g of cellulose were robust and gave excellent Mössbauer spectra. The possibility ...
J N R Ruddick, J K Ingram


UV-microspectrophotometry of lignin and accessory compounds in wood cell walls of conifers
1999 - IRG/WP 99-20171
The distribution of lignin in the cell wall of conifer tracheids was determined by UV-VIS microspectro-photometer. Wood sections of one micron thickness were measured between the wavelength 240 and 700 nm. Spectral analyses revealed that the conifer lignin associated with the tracheid secondary wall and middle lamella is composed of guiacylpropane units which exhibit a characteristic UV absorption...
G Kleist, G Koch, J Bauch


The treatment of sawn whitewood with organic solvent wood preservative
1982 - IRG/WP 3192
The impregnation schedules approved in the UK for the treatment of sawn European whitewood (Picea abies) with organic solvent borne preservatives result in comparitively high loadings relative to the limited depth of penetration they achieve. Results are presented, which show how substantial reduction in the overall loading may be achieved without concomitant reduction in penetration. A model for ...
L D A Saunders


Collaborative soft rot tests: Paper for discussion in Working Group II
1970 - IRG/WP II 5A
An account of the major part of the collaborative work on laboratory tests of toxicity of preservatives to soft rot fungi initiated by the European Homologation Committee at Delft in 1966 has been published in ‘Material und Organismen’ (1970) as a report of progress. The main objective of these collaborative tests, namely to establish a reliable and acceptable standard test method was not acco...
J G Savory, A F Bravery


An evaluation of the potential of ion mobility spectrometry for detection of organic wood preservative components in solutions and treated wood
1994 - IRG/WP 94-20038
For the disposal of wood waste under ecological sound conditions information about its hazardous potential is required. Until now, no highly sensitive rapid analytical methods are available for the detection of wood preservatives under industrial process conditions. Preliminary experiments showed that Ion Mobility Spectrometry (IMS) could be a promising method for rapid detection of organic preser...
A Voss, J N R Ruddick, W J Homan, H Militz, H Willeitner


The influence of wood moisture content on the fungitoxicity of methylisothiocyanate in Douglas fir heartwood
1987 - IRG/WP 3430
The fumigant methylisothiocyanate (MIT) effectively controls decay fungi in large wood structures, but the influence of environmental factors on its performance are not well understood. Experiments found wood moisture content to greatly influence the fungitoxicity and sorption of MIT in Douglas fir heartwood. At constant, low MIT vapor concentrations (less than 1 µg/cc air), wood at 10% MC bound ...
A R Zahora, J J Morrell


The chemical nature of bis(tributyltin) oxide in Pinus sylvestris sapwood
1989 - IRG/WP 3508
Tributyltin compounds have been used for many years as wood preservatives. This study has provided, for the first time, an explanation for the previously reported dealkylation and/or volatilisation of the tributyltin species in, and from, Scots pine (Pinus sylvestris) sapwood. Thus, 119 Sn nuclear magnetic resonance studies have shown that, on impregnation into this timber, bis(tributyltin) oxide ...
S J Blunden, R Hill


Chemical and biological studies of organotin treated and painted wood stakes after outdoor exposure
1987 - IRG/WP 3419
Organotin based wood preservatives containing tributyltin oxide (TBTO) or tributyltin naphthenate (TBTN) are used in Sweden mainly for double-vacuum treatments of window joinery of Pinus sylvestris. After impregnation the joinery is painted or stained in different colours. To evaluate this effect (different colours on the degree of degradation of TBTO and TBTN, effected by different temperatures i...
M-L Edlund, B Henningsson


Laboratory tests on light organic solvent preservatives for use in Australia. - Part 6: Soft rot resistance of three fully formulated preservatives on different timber substrates
2000 - IRG/WP 00-30245
The above-ground soft rot resistance of substrates treated with three fully formulated light organic solvent preservatives (Cuprivac Green WR, Impresol WR 205 and Vacsol) was studied using a modified vermiculite burial method. The substrates were sapwood of Pinus elliottii and P. radiata and heartwood of Eucalyptus regnans, Pseudotsuga menziesii, Shorea sp. (a lower and a higher density source) an...
G C Johnson, M A Tighe, J D Thornton


Properties of plywood and Oriented Strand Board manufactured with an organic insecticide incorporated in the adhesive formulation
2000 - IRG/WP 00-40174
The efficacy of Fipronil as an insecticide has been established by laboratory and field experiments and commercial use against a broad range of insect pests for various crops. It can be used by either foliar or soil application. Development is underway for the non-agricultural uses of fipronil. Research is ongoing for the control of ants, cockroaches, fleas, ticks, houseflies, mosquitoes, termites...
D P Kamdem, J H Hope, A Jermannaud


The environmental chemistry of chromium: Science vs. U.S. law
1993 - IRG/WP 93-50014
The cooperation which existed among chromium chemical producers, industrial health laboratories, and governmet agencies was destroyed after 1970 by the advent of environmental activism and regulatory legislation. As prewar plants had been found to pose a serious cancer risk, this fact was the basis of EPA regulations, especially during the term of Joe Califano in HEW under Jimmy Carter. However, a...
W H Hartford


Natural exposure weathering tests: Their role in the assessment of wood preservative efficacy
1993 - IRG/WP 93-20006
Previous work has demonstrated the potential and usefulness of natural ageing procedures in e evaluation of wood preservative efficacy. This results from the combination of physico-chemical influences and microbiological interactions with both substrate and wood preservative. In this paper, results are presented for a range of biocide types. Discussions are centred on the value of natural exposure...
G R Williams, J Brown


Improvement of some technological and biological properties of poplar wood by impregnation with aqueous macromolecular compounds
1992 - IRG/WP 92-3721
Poplars (Populus spp) belong to the most important tree species in afforestation programs of the Netherlands. Due to their rapid growth, the wood quality is usually low. Therefore, studies were performed to elucidate whether some technological properties and the resistance against fungal attack could be improved by impregnation with water-soluble resins. The results showed that swelling and shrink...
R D Peek, H Militz, J J Kettenis


The compatability of tributyltin fungicides and synthetic pyrethroid insecticides as wood preservatives
1987 - IRG/WP 3414
The stability of three synthetic pyrethroids, cypermethrin, deltamethrin and permethrin, to selected tributyltin compounds, Bu3SnX {where X = OSnBu3, Cl, 02CC6H5, O2C (Naphthenyl), OSO2Et}, (Bu3SnO)3PO and {NBu4} {Bu3SnCl2}, in toluene solution was investigated by infra-red spectroscopy over a six month period. It was found that only (Bu3Sn)2O reacted with the pyrethroids and that their order of r...
S J Blunden, R Hill


Contradiction between uptake of preservative in practical situation and laboratory testing
1992 - IRG/WP 92-2392
By brush treatment water- and solvent-based products were applied on boards of Scots pine and Norway spruce to achieve an uptake of 100 and 200 g/ml. In addition the scope of work to achieve the required uptake of preservative was determined under practical conditions for both product groups. EN 113 (RAL-GZ 830) tests were carried out to test the biological efficacy of products. After 18 months ex...
R Gründlinger, O Janotta, M Melzer


The fungal degradation of quaternary ammonium compounds in wood
1998 - IRG/WP 98-10263
This work focuses on the biodegradation of didecyldimethylammonium chloride (DDAC) by the mould fungus Gliocladium roseum within a woody matrix. Three sawdust types, distinguished by their treatment and amount of DDAC retained, were inoculated with the fungus and their DDAC loss was measured over 11 weeks. The rates of degradation varied depending on the sawdust; however, a significant loss of DDA...
J W Dubois, J N R Ruddick


Protection of rubberwood with modified creosote
1998 - IRG/WP 98-30165
Creosote is a renowned wood preservative but has certain disadvantages like obnoxius odour and colour, with its unpaintability and bleeding from wood surface may create environmental hazards. An effort has been made to isolate chemical fractions from creosote to obtain clean odourless preservative formulations by subjecting to steam distillation (SVC). Rubberwood treated with SVC and tested for it...
H C Nagaveni, H S Ananthapadmanabha, G Vijayalakshmi, M N Sharma, K H Shankaranarayana


In situ timber treatments by spraying. Distribution of preservative in wood
1991 - IRG/WP 3678
This study was carried out in order to make the Pest Control Operators able to achieve correct treatments and enhance their efficacy. It was carried out in two steps: 1) in laboratory, to learn the influence of various parameters like spraying pressure, use of repeated applications, distance from nozzle to wood; 2) in situ on roof timber of five buildings. In this case, the applications of the pre...
C Defoin, G Dupont, M Lamour, H Sageot, M-M Serment


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