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Influence of surface coating on the leachability of boric acid and bifluorides from spruce wood
1995 - IRG/WP 95-50050
In the Netherlands, window joinery made from non-durable timber species (spruce) are widely protected with preservative rods. These rods contain non-fixing wood preservatives (e.g. bifluorides or boric acid). This reseach was performed to show the possible influence of a coating system to hinder the leaching of the active ingredients. The results of the leaching tests show, that bifluorides and ev...
W J Homan, H Militz


Dutch national environmental policy strategy (NMP): Implications throughout the life cycle of treated timber and for the Dutch preservation industry
1993 - IRG/WP 93-50001-31
All overview of relevant environmental legislation and instruments for control is given for each stage of the life cycle of treated timber. Recent policy in the Netherlands has been focused around the "National Environmental Policy Strategy", in which a general policy with regard to reduction of pollution to the air, soil and water is described. The principle is one of an "Integrated Chain of Cont...
P Esser, D A Lewis, A J Pendlebury


Experiments on the degradation of tributyltin oxide: A progress report
1984 - IRG/WP 3287
A variety of experiments designed to assess the chemical and physical factors affecting the degradation of tributyltin oxide in treated timber are described. Simple procedures in which temperature and oxygen availability were increased in the presence of wood and water suggest that the wood itself was of prime importance. Attempts to decrease degradation with antioxidants were unsuccessful but led...
R J Orsler, G E Holland


Effect of thickened boron in preventing conidial germination of sapwood-inhabiting fungi
1994 - IRG/WP 94-30059
We evaluated the efficacy of thickened boron preservative "Diffusolä" in preventing conidia germination of sapwood-inhabiting fungi using plate bioassay, Southern Yellow Pine and sweetgum block tests, and green pine log sections. The test fungi were sapstain fungi Ceratocystis coerulescens, Ceratocystis minor, and Aureobasidum pullulans and mold fungi, Aspergillus niger, Penicillium spp, and Tric...
S C Croan


Practical experiments with Boracol 10 Rh used as a fungicide in the repair process after attack by the dry rot fungus (Serpula lacrymans)
1987 - IRG/WP 3458
The test is carried out in an old house in Nyhavn, Copenhagen. The roof and the walls close to were heavily attacked by dry rot fungus (Serpula lacrymans) because damage to the zinc covering the frontspice were letting in water to the wood and wall construction. An attack by the dry rot fungus is more complicated to repair compared with other wood destroying fungi because beside the damage on wood...
J Bech-Andersen


The effect of of sorbitol on the decay of boric acid treated Scots pine
1991 - IRG/WP 1509
The tetra-hydroxy borate ion is known to undergo complexation with polyols of biological importance and probably protects treated timber by this action. The inhibitory effect of boric acid upon fungal growth and dehydrogenases has been shown to be prevented by the addition of certain polyols. This work was extended, with a study of the effects of a polyol on the performance of boric acid in treate...
J D Lloyd, D J Dickinson, R J Murphy


In search of excellence - A necessary challenge
1990 - IRG/WP 3567
Consumerism and environmentalism are gaining much influence. At national and E.C.-level the policy conducted is based on prevention of pollution through "sound" wood preservatives. Supposing that "environmental friendly" products do not exist it is understood that "sound" products have least effect on the environment during their whole life cycle. In the past only the effectiveness was paramount, ...
G Rustenburg


Environmental consequences of various materials in utility poles - A life cycle analysis
1992 - IRG/WP 92-3726
A model for environmental life cycle analysis, LCA, has been created to compare environmental impact from transmission poles, made alternatively of concrete, steel, aluminium and pine wood treated with CCA type B or creosote. The main pollution sources and energy use are included in the LCA. One pole size, 12 meters long, is presented in the study, a so called "45 kV" pole. Poles of different mate...
M Erlandsson, K Ödeen, M-L Edlund


Biological resistance of steam-compressed wood pretreated with boric compounds
1999 - IRG/WP 99-30190
Wood compression under heating is aimed to enhance dimensional stability and surface hardness. Preservative treatment with an appropriate chemical is additionally required for the protection of wood against biological agents under hazardous service conditions. Boron pretreatment of compressed wood was targeted to a mutual benefit of increasing biological resistance of compressed wood as boron was ...
M K Yalinkilic, W Dwianto, Y Imamura, K Tsunoda, M Takahashi


The lasting dehydration of wood treated by bifluorides worked up in Diffusec noticed by a continual drying of the wood
1999 - IRG/WP 99-30196
After an immersion of sound wood in a solution of Diffusec, in which a combination of acid potassium and ammonium bifluorides = FHF- in dissociated form is present, their potassium and ammonium fluoride ions together with the bifluoride ion = (FHF-) diffuse into the wood. They make use of the woodmoisture available as O-H-O bonds directly attached to the cellulose in the wood fibres to attract the...
H F M Nijman


Silicic acid-Boric acid complexes as wood preservatives
2001 - IRG/WP 01-30273
A silicic acid monomer aqueous solution (SAMS) or colloidal silicic acid solution (CSAS) was combined with various metal compounds or boric acid. Agents where SAMS or CSAS was combined with boric acid gave good protection against decay caused by the brown-rot fungus Fomitopsis palustris, the treated wood (Cryptomera japonica D. Don) specimens after the leaching test maintained a high resistance to...
H Yamaguchi


Comparison of the inhibitory effects of borate, germanate, tellurate, arsenite and arsenate on 6-phosphogluconate dehydrogenase
1991 - IRG/WP 1508
Sodium borate inhibits the enzymatic activity of many dehydrogenases, and it is thought that this is due to the complexation of the borate anion with the coenzyme nucleotide. It has been suggested in the past that complexation of this type, leading to enzyme inhibition and other biological effects, is responsible for the inhibition of fungal growth and consequently the protection of boron treated ...
J D Lloyd, D J Dickinson


Environmental evaluation of products by life cycle analysis [La problématique de lévaluation environnementale des produits à partir de l'analyse de leur cycle de vie et de leur "écobilan"]
1993 - IRG/WP 93-50002
In the last years a significant evolution in terms of industrial environment emerged. It has been realized that regulations on specific pollutants, controls on industrial sites, although indispensable actions, had to be completed with extended approaches based on the assessment of products and integrated substance chain management. To take into account such an approach, methodological researches h...
G C Landrieu


Occupational exposure risk assessment at a commercial treatment plant using copper azole preservative
1998 - IRG/WP 98-50101-15
Experience with traditional water-based preservatives such as chromated copper arsenate (CCA) applied in closed system vacuum pressure impregnation plants has shown that operator atmospheric exposure is low during normal operation. TANALITH E is a commercially available copper azole wood preservative introduced as a chrome and arsenic-free alternative to CCA based on the actives copper, tebuconaz...
A S Hughes, M Connell


Assessment of the environmental impacts in life cycle analysis
1995 - IRG/WP 95-50040-31
Evaluation of environmental impacts is of crucial importance nowadays but it is a complex problem. Different methodologies have been proposed for the last 20 years such as the "Life Cycle Assessment" (LCA) approach. Life Cycle Assessment is an evalution tool of the impacts on the environment of a system including the whole activities associated with, from the extraction of the raw materials to the...
I Blanc-Sommereux


Production, function and neutralization of oxalic acid produced by the dry rot fungus and other brown rot fungi
1987 - IRG/WP 1330
The formation of oxalic acid by the wood-destroying fungi causing brown rot, is found to be the key which by hydrolysing the hemicellulose brings the cellulose in the tracheid wall in contact with the cellulase enzymes and yeld watersoluble sugars leaving only a lignin skeleton. To control the pH in the substrate the excess oxalic acid is precipitated to water insoluble calcium oxalate by the dry ...
J Bech-Andersen


The effect of acid rain on CCA treated timber
1990 - IRG/WP 3579
The effect of acid precipitation on the leaching of copper, chromium and arsenic from timber treated with different CCA preservatives was studied in the presence of three types of soil under simulated field conditions. Pine sapwood, embedded in soil, was subjected to simulated rainfall at three different levels of acidity. The CCA preservative formulations tested were:- American Wood Preservers&am...
R J Murphy, D J Dickinson


Hydrolysis of bordered pits during colonization of conifers by brown-rot fungi
1995 - IRG/WP 95-10103
Brown-rot decay results in rapid reduction in degree of polymerization (DP) of holocellulose with concomitant strength loss (MOR) without removing lignin. Development of new methods of wood protection will require focusing on early events in the sequence of depolymerization. Bordered pit membranes (sapwood) represent a readily available source of non-lignified carbohydrate, ie. pectin and cellulos...
F Green III, J L Tschernitz, T A Kuster, T L Highley


Biological degradation resistance of wood acetylated with thioacetic acid
1983 - IRG/WP 3223
Chemically, modification of wood is being considered as an alternative to conventional preservation by toxic chemicals. Acetylated wood has been reported to be quite resistant to most biodegrading organisms at weight percent gains (WPG) around 15-19. The conventional acetylation techniques with acethic anhyrdride result in generation of acetic acid. However, acetylation with thioacetic acid overco...
S Kumar, S C Agarwal


An anti-termite formulation for soil treatment with natural products and its efficacy against Coptotermes formosanus Shiraki
2003 - IRG/WP 03-30319
An anti-termite formulation of an environmental conservation type for soil treatment was developed. The formulation was composed of decanoic acid (n-capric acid, an fatty acid derived from coconut oil with ten carbons) as an active ingredient and other natural products. Experiments to examine the efficacy of the formulation against Coptotermes formosanus Shiraki were conducted at the termite field...
S Yoshida, T Nakagaki, A Igarashi, A Enoki


The effect of boric acid on the protozoan numbers of the subterranean termite, Reticulitermes lucifugus
1996 - IRG/WP 96-10148
Lower termites harbor in their guts populations of microorganisms known to be indispensable for their survival, being responsible, at least partially, for the digestion of cellulose, the main item of termites'diet. The Reticulitermes species in particular harbor in their hindguts some unique intestinal fauna, for instance protozoa belonging to the genera Pyrsonympha, Dinenympha and Trycho...
L Nunes, D J Dickinson


Proposal for a method aiming at the quantification of the impact of wood extraction in Life Cycle Assessment
1998 - IRG/WP 98-50113
Life Cycle Assessment has been accepted as an instrument for the assessment of the environmental impact of products. Characterisation factors for impact assessment of emissions from products have been established. To date no characterisation factor exists for the extraction of biotic resources, for example wood. Since the main disadvantage of using wood as a material lies in the extraction of reso...
P Esser, E Van der Voet


Oxalic acid metabolism of Postia placenta
1992 - IRG/WP 92-1566
The oxalic acid metabolism of Postia placenta was studied in liquid culture in order to identify the metabolic pathways of biosynthesis and to determine whether oxalic acid physiology could be correlated with efficiency in wood decay. Oxalic acid production was determined for test strain MAD698 grown in a basal defined medium with a variety of different carbohydrate and nitrogen sources. The highe...
J A Micales


Investigation of copper fixation in timber by sodium nitrit
1992 - IRG/WP 92-3707
Solutions containing mixtures of water soluble copper salts and sodium nitrite have been shown to be capable of producing leach resistant copper treatments when impregnated into timber. A rapid leaching trial showed that copper fixation levels of 85-90% were possible which compared well with the fixation level obtained with conventional hexavelant chromium containing systems in the same test regim...
C Waldie, J A Cornfield


Serpula lacrymans the dry rot fungus. Revue on previous papers
1989 - IRG/WP 1393
It is found that the Dry rot fungus Serpula lacrymans grows in houses only because of its need for basic materials to neutralize the oxalic acid production or heavy metals which celate the oxalic acid. The average distance from the mycelium to the basic materials is found in average to be 14.2 cm with a variation from 0-100 cm. In contrast to Serpula lacrymans the Coniophora puteana and the Rigido...
J Bech-Andersen


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