IRG Documents Database and Compendium


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The effects of zinc borate treatment of wood strands on some technological properties of oriented strandboard (OSB)
2008 - IRG/WP 08-40419
In this study, influences of zinc borate treatment on some technological properties of oriented strandboard (OSB), from aspen wood (Populus euroamericana cv.) were evaluated. Therefore, a total of nine panels with dimensions of 40 cm by 40 cm by 1.8 cm and with an average target density of 0.65 g/cm3 were manufactured under the laboratory conditions. Experimental panels were manufactured at two di...
A D Çavdar, H Kalaycioglu, G Nemli


Polymeric Betaine as a Wood Preservative
2008 - IRG/WP 08-30487
Didecyl polyoxyethyl ammonium borate (DPAB), also known as Polymeric Betaine, was developed as a co-biocide for chromium-free copper based wood preservatives in Europe in the 1980’s. This paper summarizes the properties of DPAB as a wood preservative. Unique properties related to the betaine nature of DPAB are discussed in terms of the structure-property relationship. Physical properties of D...
H Härtner, S Schmitt, Futong Cui, H M Barnes


Laboratory and field evaluation of Laminated Strand Lumber treated with Borogard® ZB against termites
2009 - IRG/WP 09-30498
A laboratory bioassay and subsequent field trial was undertaken to determine the termiticidal effectiveness of a Laminated Strand Lumber (LSL) composite when treated with Borogard® ZB. The bioassay and field trial were conducted against two of Australia’s most economically important species of termite, Mastotermes darwiniensis and Coptotermes acinaciformis. Against both species of termite, LSL ...
D K Scown and J W Creffield


Resistance to decay fungi of ammonium borate oleate treated wood
2009 - IRG/WP 09-30505
Ammonium borate oleate molecule (ABO) produced from reaction between boric acid, ammonia and oleic acid was tested as wood preservative treatment against brown and white rot fungi according to European standards. This compound was prepared according to a previous study which has proved existence of synthesis reaction and effectiveness against termites (Lyon et al. 2007b). Four solutions of ABO in ...
F Lyon, M-F Thevenon, A Pizzi, J Gril


Thermal behavior of zinc borate-treated wood
2009 - IRG/WP 09-30511
The objective of this study was to investigate the thermal behavior of zinc borate (ZnB)-treated solid wood by thermal analysis (TA). Thermogravimetry (TG) and differential thermogravimetry (DTG) curves obtained from TA showed that ZnB-treated wood specimens had higher char yields and lower maximum thermal decomposition temperature than untreated wood specimens. Reducing thermal decomposition temp...
E Terzi, H Sutcu, S N Kartal


Performance of Fasteners in Treated Wood: A Comparative Study
2009 - IRG/WP 09-40465
Fastener performance is an important property for treated wood. Published data on screw and nail performance for different preservative systems currently on the market are, however, limited. In this study, screw and nail withdrawal strength for southern pine wood treated with ACQ (above ground and ground contact), MCQ (above ground and ground contact), borate (disodium octaborate tetrahydrate – ...
Q Wu, T Shupe, J Curole, K Ragon, M Voitier, M Freeman, D Ring


Synthesis of novelty borate compounds for wood preservatives: Laboratory test of leachability and decay resistance
2010 - IRG/WP 10-30520
A novel series of ammonium tetraphenylborate (ATB) and borate chemical compounds (BBC) were synthesized as wood preservatives. The leaching rates and decay resistance of boron formulations containing ATB and BBC were conducted. The laboratory leaching results showed that boron leaching rate of treated wood by ATB formulations was from 2.1% - 6.7%, while that of BBC formulations from 23.3% -59.0%. ...
Zhiqiang Li, Mingliang Jiang, Xingxia Ma


Laboratory evaluation of borate amine: Copper derivatives in wood for fungal decay
2010 - IRG/WP 10-30543
The aims of this study were to evaluate borate: amine: copper derivatives in wood for fungal decay protection as well as the permanence of copper and boron in wood. Wood treated with each of four derivatives of borate:amine:copper prevented fungal decay. Disodium tetraborate ecahydrate (Borax):amine:copper derivatives with retentions of 0.61 to 0.63% after water leaching prevented decay by Gloeo...
G Chen


Ten Year Field Tests of Borate-Treated Wood Against Subterranean Termites
2011 - IRG/WP 11-30557
In the mid 1990s, Forintek Canada Corp. initiated a study of the termite resistance of borate-treated lumber above ground, protected from rain in Canada, Japan and Hawaii. Predominant termite species at three test were Reticulitermes flavipes in Canada, and Coptotermes formosanus in both Japan and Hawaii. The material included hemlock and amabilis fir lumber treated with disodium octaborate tetrah...
P I Morris, J K Grace, K Tsunoda


Fixed Borates Anyone?
2011 - IRG/WP 11-30563
The quest for a borate based preservative system that resists leaching or is “fixed” has long been a research goal. Boron fixation has been attempted with numerous strategies but there have been problems associated with past methods. This paper discusses new fixation systems based on bio-materials and presents up to five year outdoor exposure testing on full-size decks. Generally, the new f...
C R McIntyre, M A Lake


Effectiveness of Water Based Bentonite-Borate Slurry for In-situ Remedial Protection of Historic Wooden Piles: The Eurobor Protocol, Part 2
2011 - IRG/WP 11-30574
The study of the biocide product Eurobor®, water mixture of boric acid, borax and sodium bentonite, aimed to verify previous findings regarding borates penetration from a clay-water mixture of foundation timber. The product was applied on samples from 100 year old timber foundation from the city of Göteborg. Although in ground for this long the timber was in acceptable god condition due to groun...
M. Theorin, K. Fimmerstad, K-M. Bandh


Ambient-temperature borate dip-diffusion treatment of green railroad crossties
2011 - IRG/WP 11-40556
In the USA, borates are increasingly being applied prior to air seasoning and creosote treatment of railroad ties (railway sleepers). Borates are typically applied to green ties by vacuum pressure application at 1 to 10% disodium octaborate tetrahydrate (DOT) concentration or by traditional dip-diffusion treatments at elevated temperatures. Higher temperatures are used to maintain the 30 to 50% so...
Jae-Woo Kim, A M Taylor, C Köse


Performance of Zinc Borate-Treated Oriented Structural Straw Board against Mold Fungi, Decay Fungi and Termites–A Preliminary Trial
2011 - IRG/WP 11-40571
The performance of zinc borate (ZB)-treated oriented structural straw board (OSSB) against mold fungi, decay fungi and termites was examined in standard laboratory evaluations. OSSB was fabricated with split wheat straw and diphenylmethane diisocyante (pMDI) resin. The ZB was added during panel manufacture to achieve preservative levels (wt.%) of 1.0%, 1.5%, 2.0%, and 3.0%. Untreated (0.0% ZB) OSS...
Guangping Han, M Manning, Wanli Cheng, E Pierre, W Wasylciw


Life Cycle Assessment Comparison of Treated Wood to Alternate Materials – Overview, Results and Lessons
2011 - IRG/WP 11-50282
Life Cycle Assessment (LCA) has proven useful in documenting the “green” benefits of various treated products compared to the commonly used alternates. To date, six LCA comparisons have been done or are nearing completion using ISO14040 and 14044 principles and data from US EPA databases. In almost all cases, the impact indicators for treated wood products show considerably smaller adverse e...
T Stephen, P E Smith, C R McIntyre


Mold Control for Treated Lumber in Block-Stack Storage Conditions
2012 - IRG/WP 12-30588
The mold development and control for freshly treated and block-stacked wood have been evaluated using a green house mold testing method. The results for the mold resistance of several commonly used water boron preservative treatment systems, such as ACQ, Copper Azole, and borates with and without inclusion of mold inhibitors are presented. The data suggest that the different preservative treatme...
L Jin, P Walcheski, A Preston


Termite resistance of copper-based preservative supplemented aspen strandboards
2012 - IRG/WP 12-30594
Termite resistance of aspen strandboards treated with various copper-based preservative systems was evaluated in field exposure tests. Five copper-based chemicals or zinc borate were blended into aspen furnish at three retention levels prior to pressing. Tebuconazole or 4,5-dichloro-2-N-octyl-4-isothiazolin-3-one (DCOI) were added as co-biocides to selected copper-based treatments. Sections from...
J J Morrell, C Vidrine, A Preston, L Jin


Biological performance of wood- and bamboo-polypropylene composites: Effects of particle content, particle size and Zn borate
2012 - IRG/WP 12-40577
Particle content and size of wood material in wood plastic composites (WPCs) can affect efficacy of WPCs against fungi and termites. This study evaluated fungal and termite resistance of WPCs manufactured by using two different levels of particle content (50 and 70%) and three different particle sizes (30, 60, and 100 mesh). In fungal resistance tests, Tyromyces palustris, a standardized test fung...
S N Kartal, S Aysal, E Terzi, T Yoshimura, K Tsunoda


Pre-treatment decay and strength loss of railroad ties, and their prevention
2013 - IRG/WP 13-30610
Evidence of fungal decay in air-drying, untreated railway crossties is referred to as ‘stack burn’ in the industry. The deleterious consequences of stack burn on tie mechanical properties was confirmed by evaluating the impact bending toughness of wood samples taken from untreated tie stock air dried in the southern United States. These results suggest that careful consideration should be give...
A M Taylor, B Jordan, J D Lloyd


Conclusions and Summary Report on an Environmental Life Cycle Assessment of Borate-Treated Lumber Structural Framing with Comparisons to Galvanized Steel Framing
2013 - IRG/WP 13-50296
The Treated Wood Council has completed a quantitative evaluation of the environmental impacts associated with the national production, use, and disposition of borate (disodium octaborate tetrahydrate)-treated lumber structural framing and galvanized steel framing using life cycle assessment (LCA) methodologies and following ISO 14044 standards. The results for treated wood framing are significant....
AquAeTer, Inc.


Cost effective extension of service life of bridge tie (sleepers) - Effectively applying borate during Boulton conditioning and treatment with copper naphthenate
2014 - IRG/WP 14-30637
Current longevity of creosote treated wooden bridge ties in the South Eastern US is about 15 to 25 years, which is well below of the average service life of 33-50 years of railroad ties. Such short service life increases costs associated with maintenance of railroads including bridge down time for tie replacement as well as the cost for the new ties themselves. Because of this, many railroads are...
J D Lloyd, T Chambers, J-W Kim


Borate Redistribution in Glulam in an Above Ground Field Test
2014 - IRG/WP 14-30652
Researchers have refocused on the use of boratesin the wood protection industry in the last two decades due to their broad spectrum effectiveness against fungi and insects, and favourable environmental characteristics. This study was designed to determine borate distribution in a limited number of samples from a large field test of composites protected by a combination of coating and borate treatm...
P I Morris, A Temiz, J Ingram


Encapsulation Systems Combined with DOT Borate Treatments – The Future of Treated Crossties
2014 - IRG/WP 14-40670
Borates have been utilized in wood protection systems for many decades but only recently have been used in North America to treat crossties. This colorless, ordorless and very effective wood protection chemical has the ability to arrest and prevent the colonization of wood by both basidiomycete decay fungi and insects such as beetles and termites while ties are air seasoning or in service. Since ...
S C Kitchens, T L Amburgey


Borate treatment of green ties: An initial report on the effects on mechanical properties
2014 - IRG/WP 14-40686
Borates are increasingly used as components of wood preservative systems for railway cross ties (“sleepers”) in the USA. A variety of methods exist for incorporating the borate component; however, the so-called ‘two-step’ treatment, which involves treating the green tie in borate, followed by a pressure treatment with creosote or copper naphthenate after drying (‘seasoning’), offers th...
A M Taylor, J D Lloyd


Ammoniacal zinc borate as solid wood preservative
2014 - IRG/WP 14-30659
Zinc borate, well-known for its fungicidal, insecticidal and flame resistant properties, is widely used in manufacture of lignocellulose particle board. This form of borate is the least water soluble form available providing advantages as well as disadvantages for use as a wood preservative. This form does not leach from wood under conditions of high humidity, but it is also very difficult to appl...
C Ibáñez, C Mantero, A Ibarra, M Rabinovich


Steam accelerated borate diffusion: Optimizing dry tie treatment
2015 - IRG/WP 15-40713
A small laboratory study was carried out which demonstrated that dry wood dip treated in a high concentration borate solution could not be subsequently treated properly with oil borne copper naphthenate unless it was subsequently steam treated to accelerate borate penetration into the wood and re-dry the wood beforehand. A larger study with commercial sized cross ties (railway sleepers) was carri...
J-W Kim, J D Lloyd


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