Your search resulted in 71 documents. Displaying 25 entries per page.
Low polymer levels containing bioactive monomer polymerized in situ provide resistance to Gloeophyllum trabeum
1995 - IRG/WP 95-30066
Wood preservation based on in situ polymerization of potentially bioactive monomers has been studied. Tributyltin oxide acrylate (TBTOA) and pentachlorophenol acrylate (PCPA) were synthesized. Wood samples were treated at 2, 5, 10, 15 and 20% by weight solutions with varying amounts of crosslinker (trimethylolpropane trimethacrylate, TMPTM) and polymerized in situ in wood samples (2.54 x 2.54 x 0....
R E Ibach, R M Rowell
The formation of organotin carboxylates in bis(tributyltin) oxide - treated Pinus sylvestris sapwood
1990 - IRG/WP 3618
Tributyltin compounds have been successfully used for many years as wood preservatives, although their chemical nature in timber have not been fully elucidated. This study by 119Sn and 13C NMR spectroscopy has shown that, on impregnation into Pinus sylvestris sapwood, bis(tributyltin) oxide, (Bu3Sn)2O, is rapidly converted to tributyltin carboxylates, Bu3SnOCO·R, via reaction with components of t...
S J Blunden, R Hill
The chemical nature of bis(tributyltin) oxide in Pinus sylvestris sapwood
1989 - IRG/WP 3508
Tributyltin compounds have been used for many years as wood preservatives. This study has provided, for the first time, an explanation for the previously reported dealkylation and/or volatilisation of the tributyltin species in, and from, Scots pine (Pinus sylvestris) sapwood. Thus, 119 Sn nuclear magnetic resonance studies have shown that, on impregnation into this timber, bis(tributyltin) oxide ...
S J Blunden, R Hill
Termite and fungal resistance of in situ polymerized tributyltin acrylate and acetylated Indonesian and USA wood
2000 - IRG/WP 00-30219
Wood [Indonesian pine (IP), Indonesian Jabon (IJ) and USA southern yellow pine (USP)] was either in situ polymerized with tributyltin acrylate (TBTA) or acetylated and then exposed to termite and fungal degradation both in laboratory tests and field exposure. The TBTA woods had an average weight percent gain (WPG) of 11% for IP, 12% for IJ, and 10% for USP. The acetylated woods had a WPG of 15-27%...
R E Ibach, Y S Hadi, D Nandika, S Yusuf, Y Indrayani
The effect of preservative distribution in small blocks of Pinus sylvestris on the toxicity of tributyltin oxide to Reticulitermes santonensis Feytaud
1971 - IRG/WP 206
Small blocks of Pinus sylvestris (50x25x15 mm³) were treated by a full-cell method with various concentrations of tributyltin oxide in benzene. Replicate blocks were then freeze dried, rapidly air dried or slowly air dried and exposed to surface attack by the subterranean moistwood termite Reticulitermes santonensis Feytaud. At all concentrations it was found that the freeze-dried blocks were mor...
M P Levi, D N R Smith
Pentachlorophenol and tributyltin oxide - the performance of treated Pinus radiata after 12 years' exposure
1986 - IRG/WP 3361
Pinus radiata samples were impregnated with a range of light organic solvent preservatives and copper/chrome/arsenic salt and exposed with no surface coating both in and above ground for 12 years. Inspection of the test samples revealed that some formulations of light organic solvent preservatives will give good fungal protection and reduce splitting in Pinus radiata exposed externally without a s...
R S Johnstone
Experiments on the degradation of tributyltin oxide: A progress report
1984 - IRG/WP 3287
A variety of experiments designed to assess the chemical and physical factors affecting the degradation of tributyltin oxide in treated timber are described. Simple procedures in which temperature and oxygen availability were increased in the presence of wood and water suggest that the wood itself was of prime importance. Attempts to decrease degradation with antioxidants were unsuccessful but led...
R J Orsler, G E Holland
Co-operative studies on determining toxic values against wood-destroying Basidiomycetes: Progress report to May 1989
1989 - IRG/WP 2339
This document reports progress on the co-operative study between nine laboratories set up following the proposals contained in Document IRG/WP/2316. Results have been received from two laboratories. Toxic values data have been established successfully using the test fungus Coniophora puteana but problems have been encountered with the other test fungi....
A F Bravery, J K Carey
Laboratory decay test of Burmese in and kanyin treated with three wood preservatives
1982 - IRG/WP 3210
Laboratory decay tests were performed on samples of In (Dipterocarpus tuberculatus Roxb.) and Kanyin (Dipterocarpus alatus Roxb. and Dipterocarpus turbinatus Gaertn f.) pressure treated with three wood preservatives - copper arsenic additive (CAA - a variation of ammoniacal copper arsenate), Arquad C-33 (a waterborne quaternary ammonium formulation), and tributyltin acetate (TBTA) dissolved in eth...
J N R Ruddick, R S Smith, A Byrne
Studies of the distribution and degradation of tributyltin naphthenate in double-vacuum treated wood
1983 - IRG/WP 3230
The effects of forced solvent evaporation by kilning redwood (Pinus sylvestris) that has been double-vacuum treated with tributyltin naphthenate (TBTN) have been investigated. Contrary to previous studies reported, it has been shown that forced evaporation can have a considerable influence on the losses of the fungicide. It has been found that, whether the solvent is allowed to evaporate slowly or...
J Jermer, M-L Edlund, W Hintze, S V Ohlsson
Accelerated ageing of preservatives in treated wood
1988 - IRG/WP 3476
New preservatives are tested in the laboratory and often in field tests before they are used commercially. Some preservatives, however, tested in the laboratory do not show the expected stability when used in service. The differences between laboratory tests and practical use can never be completely eliminated but must be minimized as far as possible by relevant testing methods. Studies of the eff...
M-L Edlund, B Henningsson, B Jensen, C-E Sundman
Results of co-operative studies on determining toxic values against wood-destroying Basidiomycetes. Preliminary report to Sub-group members
1986 - IRG/WP 2271
A F Bravery, J K Carey
Detoxification of preservatives: Tri-n-butyltin oxide as a biocide
1982 - IRG/WP 1156
T E Dudley-Brendell, D J Dickinson
Rapid leaching test
1991 - IRG/WP 2367
An accelerated test which is suitable for measuring the extent of metal fixation in both chromium and non chromium containing preservatives is described....
J A Cornfield, M Bacon, A Lyman, C Waldie, M R Gayles
Testing wood in ground contact: An artificial soil
1977 - IRG/WP 280
This document is an interim report on the development of the artificial soil medium. It includes some information on the relationship between soil, wood and water which is of relevance in testing....
E F Baines, D J Dickinson, J F Levy
Movement of boron from fused boron rods implanted in Southern pine, Douglas fir, red oak, and white oak timbers
1995 - IRG/WP 95-30061
This paper reports the distribution of boron from fused boron rods installed into six-inch (15.2 cm) square timbers of Douglas-fir, Southern Pine, red oak and white oak exposed aboveground. The composition and size of rods was: sodium borate and sodium borate-copper oxide (8.5 x 100 mm²); sodium borate-copper, sodium borate and boric oxide-copper oxide (12 x 76 mm²). The boric acid equivalent wa...
T L Highley, L Ferge
Decay patterns observed in butylene oxide modified ponderosa pine attacked by Fomitopsis pinicola
1983 - IRG/WP 1183
Small blocks of ponderosa pine chemically modified by butylene oxide to three different weight percent gains (WPG) were decayed for 2 months with the brown rot fungus Fomitopsis pinicola. Wood substance loss and the type of decay pattern recognised were fairly similar both for control and blocks treated to 8 and 15 WPG. No difference in attack was observed between radial or tangential walls in lat...
T Nilsson, R M Rowell
An investigation into the stability of TBTO in LOSP-treated radiata pine
1987 - IRG/WP 3459
Nuclear magnetic resonance (NMR) spectroscopy and reverse phase paper chromatography were used to characterise the organotin compounds found in radiata pine treated with bis (tri-n-butyl) tin oxide (TBTO). Preliminary results indicate that the preservative is remarkably unstable in wood after light organic solvent preservative (LOSP) treatment. Significant decomposition of TBTO occurs in a matter ...
K J Archer, R Meder
Effect of fatty acid removal on treatability of Douglas-fir
1993 - IRG/WP 93-40008
Treatment of Douglas-fir with chromated-copper-arsenate (CCA) poses a major challenge. Several hypotheses based on the anatomical aspects as well as chemical reactivity of the preservative formulations with cell wall constituents and deposits have been proposed. Techniques to prevent pit aspiration or slow fixation reactions have, however, not significantly improved treatment. The presence of high...
S Kumar, J J Morrell
Fixation of CCA in Pinus sylvestris after kiln-drying
1990 - IRG/WP 3594
Tanalith C Paste is 98% fixed and Tanalith Oxide C is 99% fixed irrespective of whether treated Pinus sylvestris is kiln or air dried. A schedule suitable for kiln drying of CCA treated Pinus sylvestris is described....
P Warburton, J A Cornfield, D A Lewis, D G Anderson
Effect of sterilization method on germination of spores of wood decay fungi observed by contact agar block method
1978 - IRG/WP 2117
Previous studies of germination of spores of wood decay fungi on wood have generally concluded that method of wood sterilization has little significant effect on germination response. This study expands the numbers of test fungi as well as number of sterilization methods employed to determine the influence of sterilization method on spore germination response of decay fungi. Germination was assess...
E L Schmidt, D W French
Tests on preservation of wood against marine borers
1976 - IRG/WP 417
The Instituto del Legno has carried out for some years a series of trials about the biodeterioration of wood in the sea. The investigations included the settlement and activity of marine borers, the natural durability of indigenous and tropical woods and the preservation of wood for marine use. This paper reports the trials on the effectiveness of some preservatives in protecting wood against mari...
A Gambetta, E Orlandi
Resistance of painted pine sapwood to mould fungi. Part 1. The effect of waterborne paints and fungicides on mould growth
1997 - IRG/WP 97-10233
The efficacy of different fungicides in acrylate and alkyd paints to protect pine sapwood against mould fungi was studied. The acrylate and alkyd paint systems with and without a preservative dipping treatment prior to painting were also used. Differences in the efficacy of the fungicides to protect the paint film were found. The paint films with isothiazolon and IBPC were resistant against mould ...
H Viitanen, P Ahola
Decay patterns observed in butylene oxide modified ponderosa pine after exposure in unsterile soil
1982 - IRG/WP 3211
Small blocks of ponderosa pine (Pinus ponderosa Laws) chemically modified with butylene oxide to three different weight gains were exposed for 6 weeks in unsterile soil. Severe surface decay caused by soft rot fungi and tunnelling bacteria was observed in blocks with 8 weight percent gain. The soft rot attack was restricted to the outer parts of the radial walls in the latewood tracheids. Bacteria...
T Nilsson, R M Rowell