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Determination of N-cyclohexyl-diazeniumdioxide (HDO) containing compounds in treated wood using GC-MS
2000 - IRG/WP 00-20201
Beside the biological effectiveness the approval of a chemical wood preservative requires also techniques for the analytical determination of active ingredients in different matrices. Fulfilling of the last requirement is particularly difficult in the case of impregnated timber treated with wood preservatives containing organic compounds. This paper describes a procedure for the determination of t...
P Jüngel, J Wittenzellner, E Melcher


Efficacy of Didecyl Dimethyl Ammonium Chloride (DDAC), Disodium Octaborate Tetrahydrate (DOT), and Chlorothalonil (CTL) against Common Mold Fungi
2004 - IRG/WP 04-30338
The fungitoxic properties of four fungicides, alone and in combination, against four different mold fungi commonly associated with indoor air quality problems were evaluated on two different wood species and sheetrock. The fungicides were chlorothalonil (2,4,5,6-tetrachloroisophthalonitrile) (CTL) in a 40.4% aqueous dispersion, disodium octaborate tetrahydrate (DOT) in two different forms - a ...
J A Micales-Glaeser, J D Lloyd, T L Woods


Alternative technologies for wood wastes recycling - Part A: Supercritical extraction of PAH compounds from wood wastes
1998 - IRG/WP 98-50101-18 a
Alternative technologies have been investigated to detoxify treated wood. Two classes of organic compounds are studied. Creosote-treated wood are classified in France as dangerous wood wastes. A conventional incineration could be provided for these wood wastes but the cost of this elimination could be very high (> 2000 FFR/ton). For these reasons, we have tested two kinds of new processes as al...
L Schrive, C Perre, G Labat


Removal of copper, chromium and arsenic from CCA treated wood using boron compounds
2005 - IRG/WP 05-50230
This study evaluates the copper (Cu), chromium (Cr) and arsenic (As) removal from CCA treated wood using boron compounds such as boric acid, borax (sodium tetraborate), and Timbor (DOT, disodium octaborate tetrahydrate) at varying (3 and 5%) concentrations. Remediation processes were taken at 1, 5 and 10 day intervals. Metals in remediated chips or sawdust were then analyzed using ICP and XRF. Res...
B Tarakanadha, T Hata, S N Kartal, W J Hwang, Y Imamura


Relationship between degradation of wood, cellulose or lignin-related compounds and production of hydroxyl radical or accumulation of oxalic acid in cultures of brown-rot fungi
1994 - IRG/WP 94-10062
The degradation activities of brown rot fungi against wood, cellulose, and lignin-related compounds were measured in cultures containing glucose or wood as a carbon source. Also the activities of one-electron oxidation and hydroxyl radical production and the amount of oxalic acid present in the cultures were measured. The degradation activities of the fungi against wood, crystalline cellulose and ...
S Itakura, T Hirano, H Tanaka, A Enoki


Effectiveness of some microbiocides against the development of molds and sapstain in Pinus elliottii
1981 - IRG/WP 3169
Eleven commercial biocidal formulations were tested in the field to determine their effectiveness in protecting logs and lumber of Pinus elliottii sapwood from sap stain and molds. Among these formulations 2-(thiocyanomethylthio) benzothiazole showed the best performance in controlling both types of fungi. Potassium N-hydroxymethyl-N-methyl dithiocarbamate and the mixture potassium N-methyl dithio...
S Milano


Water repellency of wood treated with alkylammonium compounds and chromated copper arsenate
2000 - IRG/WP 00-30231
The comparative water sorption properties of southern pine treated with CCA and several alkylammonium compounds was evaluated for freshly treated wood and for wood after exposure in a fungus cellar. It was found that CCA imparts considerable water repellency to wood which is reduced somewhat after exposure to wet soil. With the exception of a long chain (C20 -C22) compound, the alkylammonium compo...
D D Nicholas, A Kabir, A D Williams, A F Preston


Pentachlorophenol and tributyltin oxide - the performance of treated Pinus radiata after 12 years' exposure
1986 - IRG/WP 3361
Pinus radiata samples were impregnated with a range of light organic solvent preservatives and copper/chrome/arsenic salt and exposed with no surface coating both in and above ground for 12 years. Inspection of the test samples revealed that some formulations of light organic solvent preservatives will give good fungal protection and reduce splitting in Pinus radiata exposed externally without a s...
R S Johnstone


Antifeedant activities of flavonoids and their related compounds against the subterranean termite, Coptotermes formosanus Shiraki
1999 - IRG/WP 99-10305
Antifeedant activities of some flavonoids and their related compounds against the subterranean termite, Coptotermes formosanus Shiraki were examined with no-choice and two-choice tests. The activities of these compounds were considered in relation to their chemical structures. All flavonoids tested showed antifeedant activities whereas catechinic acid without A-ring and pyran ring in the molecule ...
W Ohmura, S Doi, M Aoyama, S Ohara


The identification of organic compounds in wood using thermal desorption GC-MS - possibilities and limitations
2001 - IRG/WP 01-20224
There is a clear need for the analytical characterisation and identification of organic compounds and their derivatives in different phases especially in timber. In this context the paper describes a rapid and powerful gas chromatographic method for the determination of insecticides, biocides and "other" organic substances in treated and/or modified wood. The main advantage of this procedure is th...
P Jüngel, E Melcher


Proposals for further co-operative studies on determining toxic values against wood-destroying Basidiomycetes
1985 - IRG/WP 2237
Document IRC/WP/2194 reported the status of the programme of co-operative experiments up to and including December 1982. During discussions at IRG-13 in Turkey members endorsed the decision to complete the programme of tests and conduct repeat tests. At IRG-14 in Brisbane the report was noted but no further action agreed. At IRG-15 in Sweden a number of interested parties in the European/Scandinav...
A F Bravery


Mechanistic aspects of the reactions of copper complexes with lignin in the presence of hydrogen peroxide and lipid hydroperoxide model compounds as proposed for white rot fungi
2001 - IRG/WP 01-10399
The structural principles and the oxidative reactions of the catalytic system consisting of copper, hydroperoxides, and copper coordination compounds that contain aromatic nitrogen atoms are similar to those of catalytic centers of oxidative enzymes involved in delignification reactions of white rot fungi. The system is capable of selectively degrading lignin and its low molecular weight would all...
K Fackler, P Lamaipis, E Srebotnik, M Humar, C Tavzes, F Pohleven, M Sentjurc, T Watanabe, K Messner


The quantitative determination of N-cyclohexyl-diazeniumdioxide (HDO) containing compounds in treated wood using TD-GC-MS
2001 - IRG/WP 01-20223
Last year we presented the paper (IRG/WP/00-20201) "Determination of N-cyclohexyl-diazeniumdioxide (HDO) containing compounds in treated wood using GC-MS". Based on the intensive discussion at the meeting, the first experiences made with the calibration of the system for this application will be reported. For the quantitative determination of N-cyclohexyl-diazeniumdioxide in treated wood, milled m...
P Jüngel, J Wittenzellner, E Melcher


A study on the effectiveness of didecyldimethylammonium chloride to protect wood from attack by termites
1993 - IRG/WP 93-30009
A laboratory bioassay was conducted on the ability of didecyldimethylammonium chloride (DDAC) to protect Pinus radiata D.Don wood specimens from attack by two of Australia's most economically important species of subterranean termite, Mastotermes darwiniensis Froggatt and Coptotermes acinaciformis (Froggatt). Sapwood specimens of Pinus radiata, treated to achieve nominal retentions of 0.5...
J W Creffield


Isolation and identification of non-decay fungi affecting the performance of alkylammonium compounds
1993 - IRG/WP 93-10020
The isolation of DDAC tolerant fungi was carried out on lumber treated with a range of antisapstain chemicals containing DDAC as one of their active ingredients. The tolerant fungi were selected by using malt media spiked with DDAC (100 and 2500 ppm). Isolations were tentatively identified into a range of fungi commonly found associated with wood deterioration (i.e. Penicillium sp. and Trichoderma...
A K Doyle, J N R Ruddick


Biological resistance of steam-compressed wood pretreated with boric compounds
1999 - IRG/WP 99-30190
Wood compression under heating is aimed to enhance dimensional stability and surface hardness. Preservative treatment with an appropriate chemical is additionally required for the protection of wood against biological agents under hazardous service conditions. Boron pretreatment of compressed wood was targeted to a mutual benefit of increasing biological resistance of compressed wood as boron was ...
M K Yalinkilic, W Dwianto, Y Imamura, K Tsunoda, M Takahashi


Development of threshold values for boron compounds in above ground exposures: Preliminary trials
1998 - IRG/WP 98-30179
Boron is increasingly used both as an initial and remedial treatment for protecting wood against fungal and insect attack. While establishing lethal dosages for boron against insects through feeding tests is relatively simple, establishing thresholds for fungal attack poses more of a challenge. Tests using boron dispersed in agar artificially surround the fungus with both boron and excess nutrient...
J J Morrell, C M Freitag, S Unger


The influence of staining fungi on the decay resistance of wood treated with alkylammonium compounds
1984 - IRG/WP 3308
Although found to be very effective in laboratory tests, alkylammonium compounds (AAC's) have failed to perform as well in field stake tests. Examination of leachability showed that this was not the cause. The present study investigated the possibility that staining fungi, (which have been observed to rapidly infect the field stakes), degrade the AAC wood preservative. Soil-blocks were tr...
J N R Ruddick


Analysis of volatile organic compounds (VOC's) from Trichoderma spp.: effect of media composition on VOC production and level of inhibition of wood decay fungi
1997 - IRG/WP 97-10207
Production of volatile organic compounds (VOC's) by two Trichoderma isolates grown on either malt extract or minimal media was examined and statistically assessed to identify which VOC's were predominantly produced on each of the two media types. The VOC's were captured onto chromatographic absorbent from above the cultures of the fungi before being analysed by integrate...
A Bruce, R E Wheatley, C Hackett, A Kundzewicz


Recovery of copper, chromium, and arsenic compounds from the waste preservative-treated wood
1991 - IRG/WP 3651
In Japan, about 40 percents of waste wood is incinerated and the residue is dumped into the landfill site. The waste preservative-treated wood, which is mixed in nontreated wood, is incinerated in the same way, too. However, it will cause the serious problems that the gases contained with high concentration arsenic compounds are discharged from the smokestacks of the incineration facilities and th...
A Honda, Y Kanjo, A Kimoto, K Koshii, S Kashiwazaki


Chemical and biological investigations of double-vacuum treated windows after 5 years in service
1983 - IRG/WP 3219
In 1980 The Swedish Wood Preservation Institute initiated an investigation to study the degradation of TBTO and possible fungal attack in double-vacuum treated window joinery in service during 5 years. A hospital in Gothenburg was chosen that was built during 1969 to 1976. Both untreated and double-vacuum treated windows of Pinus sylvestris were used. A brown alkyl oil type paint (Nordsjö system ...
J Jermer, M-L Edlund, B Henningsson, W Hintze, S V Ohlsson


Bibliography on the use of boron compounds for the preservation of wood
1973 - IRG/WP 315
This bibliography is based on an earlier literature survey prepared by J. Thornton and Wm. E. Bruce (O.E.C.D. Document No. 27/DAS/CSI/M/91) which was enlarged and revised for a meeting in Paris in October 1968 (Document 27/DAS/CSI/M554) by Professor W. Bavendamm of Reinbek. The latter (1968) document with its 166 references has now been extended and brought up to date. Acknowledgments are due to B...
R Cockcroft, J F Levy


The production of extracellular hydrogen peroxide by some brown-rot fungi
1990 - IRG/WP 1446
The role of hydrogen peroxide (H2O2) has been discussed in the degradation of wood by wood-rotting fungi. The production of extracellular hydrogen peroxide was studied by detecting the oxidation of the chromogen 2,2'-azinobis(3-ethylbenzthiazoline-6-sulphonic acid) (ABTS) by H2O2 and horse radish peroxidase (HPR). ABTS and HPR were added to a solid wood based culture media. In this study ...
A-C Ritschkoff, L Paajanen, L Viikari


Fungitoxic effect of the quaternary ammonium compounds wood preservatives against the Ascomycetes and Deuteromycetes
1997 - IRG/WP 97-30138
Results of investigation on fungitoxic value of the three formulations of wood preservatives based on the quaternary ammonium compounds (lauryldimethylbenzylammonium chloride, lauryldimethylbenzylammonium bromide, alkylbenzyldimethylammonium chloride) in relation to the surface wood colouring (moulds) and soft-rot fungi have been presented. The agar-plate (screening) and agar-wood plate for mouldi...
J Wazny, P Rudniewski


Reappraisal of some fungicides by the amended JWPA method
1992 - IRG/WP 92-3689
Organoiodine compounds which have been commercialized these years in Japan poorly performed as fungicides in the amended JWPA decay test (Standard 1, 1989) when applied to superficial treatment of timber. Because some parts of active ingredients seemed to disappear from the treated timber surface mainly due to the severe leaching cycles. This was prominently true for beech (Fagus crenata Blume) sa...
K Tsunoda


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