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Results of co-operative studies on determining toxic values against wood-destroying Basidiomycetes. Preliminary report to Sub-group members
1986 - IRG/WP 2271
A F Bravery, J K Carey


Tests on preservation of wood against marine borers
1976 - IRG/WP 417
The Instituto del Legno has carried out for some years a series of trials about the biodeterioration of wood in the sea. The investigations included the settlement and activity of marine borers, the natural durability of indigenous and tropical woods and the preservation of wood for marine use. This paper reports the trials on the effectiveness of some preservatives in protecting wood against mari...
A Gambetta, E Orlandi


An investigation of organotin compounds in treated wood using Mössbauer spectroscopy
1983 - IRG/WP 3249
The influence of sample preparation on the 119mSn Mössbauer spectrum of tributyltin chloride in ponderosa pine was investigated. Initial studies with sawdust and compressed discs concluded that the latter were clearly superior. Further studies showed that compressed discs prepared from 0.4 g of treated wood and 0.1 g of cellulose were robust and gave excellent Mössbauer spectra. The possibility ...
J N R Ruddick, J K Ingram


Marine trials with water-borne salts and organotin compound
1986 - IRG/WP 4128
Pinus sylvestris blocks treated with water-borne salts (CCA, CCB, CCF) and organotin compounds (TBTO, TBTCl) were submerged in the sea at Follonica station. The results obtained after 12 years of immersion are presented. The samples treated with CCA, CCB and CCF at the lowest concentration (2%) were destroyed after 7-9 years and the samples treated with CCB and CCF at the highest concentrations (4...
A Gambetta, E Orlandi


A field evaluation of modified and unmodified alkylammonium compounds
1987 - IRG/WP 3436
Laboratory soil block studies of alkylammonium compounds (AAC's) at Forintek and other research establishments have shown that they can prevent decay by standard wood-destroying fungi. Their performance in field tests, however, has been disappointing. Following investigation of possible causes for this poor field performance, stakes treated with modified AAC's were installed at W...
J N R Ruddick


A comparison of soft rot, white rot and brown rot in CCA, CCP, CCF, CCB, TCMTB and benzalkonium chloride treated Pinus radiata IUFRO stakes, after 9-15 years exposure at five test sites in New Zealand
1991 - IRG/WP 1485
The aim of this study was to determine if decay type varies significantly between five field trial test sites of different soil type, aspect and climate in 9-15 year old, replicate CCA, CCF, CCP. CCB, TCMTB and AAC treated IUFRO stakes. A visual on-site assessment of decay type on every test stake was made and observations confirmed by microscopical examination. Regression analyses were used to de...
R N Wakeling


Co-operative studies on determining toxic values against wood-destroying Basidiomycetes: Progress report to May 1989
1989 - IRG/WP 2339
This document reports progress on the co-operative study between nine laboratories set up following the proposals contained in Document IRG/WP/2316. Results have been received from two laboratories. Toxic values data have been established successfully using the test fungus Coniophora puteana but problems have been encountered with the other test fungi....
A F Bravery, J K Carey


Laboratory decay test of Burmese in and kanyin treated with three wood preservatives
1982 - IRG/WP 3210
Laboratory decay tests were performed on samples of In (Dipterocarpus tuberculatus Roxb.) and Kanyin (Dipterocarpus alatus Roxb. and Dipterocarpus turbinatus Gaertn f.) pressure treated with three wood preservatives - copper arsenic additive (CAA - a variation of ammoniacal copper arsenate), Arquad C-33 (a waterborne quaternary ammonium formulation), and tributyltin acetate (TBTA) dissolved in eth...
J N R Ruddick, R S Smith, A Byrne


Studies of the distribution and degradation of tributyltin naphthenate in double-vacuum treated wood
1983 - IRG/WP 3230
The effects of forced solvent evaporation by kilning redwood (Pinus sylvestris) that has been double-vacuum treated with tributyltin naphthenate (TBTN) have been investigated. Contrary to previous studies reported, it has been shown that forced evaporation can have a considerable influence on the losses of the fungicide. It has been found that, whether the solvent is allowed to evaporate slowly or...
J Jermer, M-L Edlund, W Hintze, S V Ohlsson


Patent on the use of tannic acid and ferric chloride against marine borers, etc
1982 - IRG/WP 495
R Mitchell, T D Sleeter


Laboratory study on the effectiveness on photostable pyrethroids formulated with benzalkonium chloride to be used on furniture
1985 - IRG/WP 3346
The first results are presented of a study on the effectiveness of photostable pyrethroids formulated with banezalkonium chloride. Initially the products were submitted to preliminary tests and then the more efficient formulations were tested with a new essay that tries to simulate a dry-wood termite attack on furniture....
A M F Oliveira, A T De Lelis


The effect of didecyldimethylammonium chloride on growth of different strains of mould fungus Gliocladium roseum
1995 - IRG/WP 95-10105
The tolerance and degrading ability of different strains of Gliocladium roseum towards didecyldimethylammonium chloride (DDAC) were studied. All four of the strains of Gliocladium roseum were tolerant to DDAC and after their growth on amended malt agar, the retention of DDAC in the medium was reduced....
Yu Zheng, J N R Ruddick


Accelerated ageing of preservatives in treated wood
1988 - IRG/WP 3476
New preservatives are tested in the laboratory and often in field tests before they are used commercially. Some preservatives, however, tested in the laboratory do not show the expected stability when used in service. The differences between laboratory tests and practical use can never be completely eliminated but must be minimized as far as possible by relevant testing methods. Studies of the eff...
M-L Edlund, B Henningsson, B Jensen, C-E Sundman


Cytochemical localization of hydrogen peroxide in brown rot fungus Tyromyces palustris by cerium chloride technique
1999 - IRG/WP 99-10299
Cerium chloride (CeCl3) was used to localize H2O2 cytochemically for studying relationship between ultrastructural and functional characteristics of cellulose degradation by brown rot fungi. This technique proved very useful in localizing discrete electron-densereactionproducts at high resolution with minimal nonspecific deposition. The cytochemical localization of extracellular H2O2 by CeCl3 usin...
Yoon Soo Kim, Seung-Gon Wi


An investigation into the stability of TBTO in LOSP-treated radiata pine
1987 - IRG/WP 3459
Nuclear magnetic resonance (NMR) spectroscopy and reverse phase paper chromatography were used to characterise the organotin compounds found in radiata pine treated with bis (tri-n-butyl) tin oxide (TBTO). Preliminary results indicate that the preservative is remarkably unstable in wood after light organic solvent preservative (LOSP) treatment. Significant decomposition of TBTO occurs in a matter ...
K J Archer, R Meder


The formation of organotin carboxylates in bis(tributyltin) oxide - treated Pinus sylvestris sapwood
1990 - IRG/WP 3618
Tributyltin compounds have been successfully used for many years as wood preservatives, although their chemical nature in timber have not been fully elucidated. This study by 119Sn and 13C NMR spectroscopy has shown that, on impregnation into Pinus sylvestris sapwood, bis(tributyltin) oxide, (Bu3Sn)2O, is rapidly converted to tributyltin carboxylates, Bu3SnOCO·R, via reaction with components of t...
S J Blunden, R Hill


The Role of Coformulants in Preventing Bacterial Biotransformation of IPBC
2002 - IRG/WP 02-10436
The inhibitory effects of disodium tetraborate decahydrate and benzalkonium chloride (BAC), two common coformulants of IPBC in antisapstain treatments, on an IPBC-transforming enterobacterial isolate ‘W1’ were determined by their effect on the specific growth rate constant in vitro. The IC50s of IPBC, BAC and borate were found to be 0.46, 0.026 and 5.7 mM respectively. The IC50 of the Arch ant...
S R Cook, D J Dickinson


The effect of temperature on the rate of fixation of an alkyl ammonium compound (AAC) wood preservative
1984 - IRG/WP 3293
The rate of fixation of an alkyl ammonium compound wood preservative was measured by soaking samples of wood wool in various preparations of the preservative for arbitrary times followed by immediate leaching in water. The wood wool was then analysed for residual preservative. The results indicated that fixation was very rapid and increased at higher temperatures....
P Vinden


Investigation of the fixation in wood of chromated zinc chloride and copperised chromated zinc chloride preservatives
1976 - IRG/WP 372
A biological method of evaluating the extent to which CZC and CCZC preparations are retained in wood in terms of the potential protection which they afford against destruction by Merulius lacrymans (dry rot) is given. CCZC is recommended for protection of wood under moderate leaching conditions, while the use of CZC under such conditions is not recommended....
V N Sozonova, D A Belenkov


Variation in Canadian bluestain fungi: Tolerance to DDAC and DOT
1999 - IRG/WP 99-10303
Bluestain in Canadian wood products results in significant and unpredictable losses each year. In order to develop rational methods to eliminate or reduce the sapstain problem, a more complete knowledge of the causal organisms must be gained. This includes a knowledge of the variability in tolerance of different fungal species and strains to commercially used chemicals. In British Columbia, the ma...
J Dubois, A Byrne, J E Clark, A Uzunovic


The preliminary evaluation of selected sulfonium salts for use in wood preservation
1984 - IRG/WP 3278
Five sulfonium compounds, including two sulfonium methosulfates, one sulfonium bromide and two amphoteric sulfonium propanesulfonates, were prepared in crude form and subjected to various biocidal screening tests. A rapid screening test in which treated Pinus radiata pulp pellets were exposed to one of three wood-decaying fungi growing on malt agar revealed that dodecyl dimethyl sulfonium methosul...
D V Plackett


Effect of borate on uptake and efficacy of an anti-sapstain treatment
2005 - IRG/WP 05-30380
The potential for using borates to enhance uptake and efficacy of propiconazole-based anti-sapstain chemicals was assessed on ponderosa pine sapwood wafers. Borates had no consistent effect on either net solution absorption or propiconazole distribution in the wood. Even small amounts of borate, however, markedly improved the performance of propiconazole against fungal discoloration. These resul...
Jianju Luo, Hua Chen, J J Morrell


Stability and performance of tributyltin compounds
1984 - IRG/WP 3275
Based on the critical examinations of the disputable permanence of tributyltin compounds in wood, this paper deals with a number of examinations of the relative evaporation, thermal stability and oxidation stability of some TBT-compounds. While thermal and oxidative stability is high for all TBT-species, the relative evaporation at elevated temperature is highly variable, and lowest for the TBT-es...
F Imsgard, B Jensen, H A B Landsiedel, H Plum


Photo-discoloration and Degradation of Wood and its Stabilisation by Modification with Benzoyl Chloride
2004 - IRG/WP 04-40274
Photo degradation of Pinus roxburghii (chir pine) and Hevea brasiliensis (rubber wood) was studied under artificial accelerated weathering conditions in a Xenon test chamber. The irradiated samples were analyzed for color changes and chemical changes. Analysis of colour changes in wood surfaces by UV-Vis. irradiation was carried out using a colour measuring (CIELAB) system and chemical changes ...
K K Pandey


Issues Facing Wood Preservation in New Zealand Today
2003 - IRG/WP 03-30326
In New Zealand, the three major issues facing the wood preservation industry today are: Extension of use of LOSP preservatives, chiefly tributyltin naphthenate, for treatment of products in Hazard Class H3 exposed to the weather for which LOSP have not been traditionally used. Concerns have been expressed about the long-term durability of such products. Restrictions on the use of CCA preservativ...
M E Hedley


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