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The examination of preservative-treated radiata pine using electron spin resonance spectroscopy
1987 - IRG/WP 3423
Electron spin resonance spectroscopy (ESR) may be used to characterise the molecular environment of chemical species containing unpaired electrons. These species include free radicals, bi-radicals, point defects in solids, localised crystal imperfections and many transition metal ions. ESR has previously been applied to the examination of wood weathering or wood pyrolysis and now FRI and Massey Un...
D V Plackett, E W Ainscough, A M Brodie


CCA-treated Wood Disposed in Landfills and Life-cycle Trade-Offs With Waste-to-Energy and MSW Landfill Disposal
2005 - IRG/WP 05-50231
CCA-treated wood as a solid waste is managed in various ways throughout the world. Although some wood is combusted for the production of energy in the U.S., more often than not, CCA-treated wood is disposed in landfills. In other countries, wood, often including CCA-treated wood, is combusted for the production of energy. This paper is presented in two parts. Part I evaluates the impact of CCA-tre...
J Jambeck, K Weitz, T G Townsend, H M Solo-Gabriele


Screening of the technical performance and aquatic toxicity of N-methylolacrylamide treated wood
2000 - IRG/WP 00-40166
In the course of the last decades chemical modification of wood species, with a limited natural durability, has been subjected to intensive research. As a possible alternative and supplementary treatment of non-durable wood in a range of applications it remains one of the major topics in the wood preservation world. Different modification systems have been scaled-up and are now in an industrialisi...
V Rijckaert, S De Geyter, J Van Acker, M Stevens


Effect of remediation on the release of copper, chromium, and arsenic from particleboard made from CCA treated wood
2001 - IRG/WP 01-50170
This study sought to determine the effect of remediation with oxalic acid (OA) extraction and Bacillus licheniformis fermentation on the release of copper, chromium, and arsenic from particleboard made from remediated wood particles and also investigates durability of the particleboard against white and brown- rot fungi. Particleboard samples were manufactured using untreated, CCA-treated, OA-extr...
S N Kartal, C A Clausen


Comparative performance of copper azole and copper-chrome-arsenate treated rubber wood in Australian, Malaysian and New Zealand tests sites
2000 - IRG/WP 00-30213
Rubberwood (Hevea brasiliensis) has been used for non-structural products where appearance is important. It has rarely been used for structural uses where preservative treatment is required. In order to evaluate the in-ground durability of preservative-treated rubberwood, test stakes (20 x 20 x 500 mm3) were treated to four retentions of CCA and copper azole (Tanalith® E) and installed in test si...
J A Drysdale, M E Hedley, E Loh, L T Hong


Termite resistance of treated wood in an above-ground field test
1985 - IRG/WP 2241
A field test method has been developed for evaluating the susceptibility of wood products to termites in protected situations above ground. In this method fungal attack on the wood products is minimal, though decay has been observed in conjunction with termite attack in some specimens. Preliminary results from exposure of replicate wood samples treated with preservatives in Florida to Reticuliterm...
A F Preston, P A McKaig, P J Walcheski


FTIR studies on the weathering of didecyldimethylammonium compound (DDAC) treated wood
1993 - IRG/WP 93-30013
Wood treated with alkylammonium compounds (AACs), such as DDAC, weathered more rapidly than untreated wood. In order to examine the influence of DDAC treatment of wood on its weathering, treated and untreated microtomed sections of southern yellow pine earlywood of various thicknesses, were prepared and weathered for approximately one month. The changes in these samples were monitored using FTIR. ...
R Liu, J N R Ruddick


Durability of Sugi (Cryptomeria japonica D.DoN ) wood treated in high temperature liquid paraffin
2002 - IRG/WP 02-40221
Sugi(Cryptomeria japonica D.DoN )wood was subject to a heat treatment in high-temperature liquid paraffin for the purpose of improving the resistance against fungi and termites without chemicals. The bath of paraffin liquid, which can provide a uniform heat transfer (±2?), was used at temperatures of 90?,120?and 150?.?ecay resistance according to JIS K 15711) was evaluated using a brown rot fungu...
Y Matsuoka, W Ohmura, S Fujiwara, Y Kanagawa


Recycling of CCA treated wood in the US
1998 - IRG/WP 98-50101-08
The production of CCA treated wood has increased dramatically in recent years. Previous estimates of the volume of treated wood to be removed were based on the assumed service life of the material, generally 20 to 25 years. This study based on a survey of contractors installing treated decks, determined that the actual service life of these decks is much shorter than their assumed functional servi...
J McQueen, J Stevens, D P Kamdem


Durability of some alternatives to preservative treated wood
2004 - IRG/WP 04-30353
The environmental discussion in Sweden has lead to an increasing use of naturally durable domestic wood species and wood treated according to alternative methods for use above ground. A number of these alternatives have been tested according to field- and laboratory tests and compared to wood treated with preservatives for above ground use. Seven untreated wood species, four alternative wood treat...
M-L Edlund


Termite resistance of treated wood in an above-ground field test
1986 - IRG/WP 1300
This paper provides an update on the results from an above ground field test evaluating the effectiveness of wood preservatives against subterranean termites. Results for the one and two year inspections of treated southern pine sapwood exposed in Hawaii to Coptotermes formosanus are presented. Chromated copper arsenate is providing excellent protection as is the pyrethroid deltamethrin. Borate an...
A F Preston, P A McKaig, P J Walcheski


Life Cycle Assessment of borate treated wood
2005 - IRG/WP 05-50224-12
Life Cycle Assessment (LCA) is being used increasingly around the world by decision-makers to help incorporate the environmental component of sustainability into their activities. U.S. Borax regularly assesses how its products contribute to sustainable development. Using data gleaned from LCA of its products, the company recently completed its first ISO 14040 compliant cradle-to-grave LCA of lum...
M J Manning


Present status of using treated wood and private house owner’s expectations in Bangladesh
2004 - IRG/WP 04-30329
In a developing country like Bangladesh more than 80 % of the total population lives in rural areas where building materials are mainly comprised of wood, bamboo, thatch grass, golpata, etc. All these materials, being cellulosic, are easily infected by deteriorating agencies like fungi, termites, beetles etc., as climatic condition of the country is ideal for their thrive. This is a great wastage ...
M A Islam, A K M A Bosunia, S C Ghosh, M O Hannan, A K Lahiry


Limnoria quadripunctata Holthuis - a threat to copper-treated wood
1983 - IRG/WP 4100
This paper presents the first reported attack by the crustacean marine wood-borer Limnoria quadripunctata Holthuis of CCA treated eucalypt piles. The attack occurred after 12 years service of the piles in the River Derwent at Hobart, Tasmania. Attack by both this borer and Limnoria tripunctata Menzies is also reported in CCA treated softwoods and hardwoods over periods ranging from 5 to 22.9 years...
J E Barnacle, L J Cookson, C N McEvoy


Depletion of preservatives from treated wood: Results from laboratory, fungus cellar and field test
1993 - IRG/WP 93-50001-07
This paper compares results of preservative component losses using a range of test procedures with several different water-borne preservatives. The data shows that laboratory leaching tests are in some cases comparable to, but in other cases significantly underestimate preservative component losses when compared with field or fungus cellar depletion tests. The results also suggest that preservativ...
L Jin, A F Preston


Leaching of Copper from ACQ treated wood exposed above ground
2004 - IRG/WP 04-50219
The leaching of chemicals of ACQ Type C treated wood exposed above ground for 16 months was studied. Commercially treated Hem-fir boards (Tsuga heterophylla Raf. and Amabilis fir Forb) of 37.5 mm by 87.5 mm were used. The amounts of chemical leached monthly by the rainfall were determined and the leachate was collected and analyzed. Also, the environmental factors influencing the leaching were ...
P A Chung, J N R Ruddick


The use of low cost X-ray fluorescence instruments in the determination of copper chromium and arsenic in preservative treated wood
1987 - IRG/WP 2278
Internal quality control in timber treatment plants can be pursued by analysis of preservative treatment solutions and treated timber. Treaters must proceed with costly and lengthy analyses through analytical laboratories. An alternative approach for the timber treater, is to use low cost analysers (L.C.A.'s) based upon x-ray fluorescence. Detailed comparisons have been made between stand...
J Norton, L E Leightley


Leaching Characteristics of Alder Wood Treated with Copper Based Wood Preservatives
2005 - IRG/WP 05-50225
In this study, it was designed for determining leaching characteristics of CCA and alternatives wood preservatives. Alder wood blocks were treated with CCA (1 % and 2 %), ACQ-1900 (2 % and 3 %), ACQ-2200 (1 % and 2 %), Tanalith E 3491 (2 % and 2.8 %), Wolmanit CX-8 (% 1 and 2 %). Leaching studies were conducted according to AWPA E11-97. Copper analyses of leachate were determined Atomic absorption...
A Temiz, Ü C Yildiz, E D Gezer, S Yildiz, E Dizman


A Novel Type of Multiple Cavity Attack in Wood Cell Walls of Heat-treated Timber Exposed in Seawater – Preliminary Observations
2004 - IRG/WP 04-10523
Samples of untreated and heat-treated Norway spruce and Douglas fir were submerged in Langstone Harbour, Portsmouth for 4 years at a depth of ca. 0.3 metres. The heat-treated samples had been prepared using the Plato process. Samples were initially assessed for the severity of marine borer damage and were then examined microscopically for evidence of microbial decay. Longitudinal and transverse wo...
R A Eaton, C Björdal, T Nilsson


Speciation of leachates from CCA-treated wood
2005 - IRG/WP 05-50224-27
Different species of arsenic and chromium are characterized by different toxicities and different mobilities. The environmental impacts of CCA-treated wood would therefore be a function of the chemical forms of the metal releases. As a consequence a series of tasks were undertaken to evaluate arsenic and chromium species from CCA-treated wood. The intent of these tasks was to quantify the total...
H M Solo-Gabriele, T G Townsend, Yong Cai, B I Khan, Jin-Kun Song, J Jambeck, B Dubey, Yong-Chul Jang


Leaching of components from CCF treated timber in ground contact
1998 - IRG/WP 98-50108
In order to investigate the depletion of different CCF-salts during service small stakes (10*10*450mm³) were treated with five water-borne wood preservatives and after fixation brought into ground contact for several years. After failing some of the broken down stakes were used to determine the remaining concentration of relevant ions and their distribution in different segments of the stakes. A...
E Melcher


CCA removal from treated wood by chemical, mechanical and microbial processing
1998 - IRG/WP 98-50101-26
Most preservative-treated wood produced and consumed in the U.S. is treated with toxic inorganic compounds containing copper, chromium, and arsenic. Because chromated copper arsenate (CCA) is fixed to the wood, treated wood has not been considered toxic or hazardous and is currently landfilled. Increasing public concern about environmental contamination from treated wood combined with increasing q...
C A Clausen, R L Smith


Determination of thermal degradation of isothiazolone treated wood
1997 - IRG/WP 97-30154
Wood treated with 4,5-dichloro-2-n-octyl-4-isothiazolin-3-one was the subject of thermal degradation study. The study included burning isothiazolone treated wood under various temperatures with and without oxygen. The result showed that no harmful combustion products, such as polychlorinated dibenzo-p-dioxins, polychlorinated dibenzo-p-furans and polychlorinated biphenyls, were detected. These fin...
Bing Yu


The extraction of boron from treated wood for quantitative analysis: A comparison of procedures
1992 - IRG/WP 92-2414
The extraction of boron preservative from treated rubberwood and scots pine samples was compared using methods based on refluxing and extraction in 1N NaOH or distilled water at 80°C. The extract solutions were analysed by Inductively Coupled Plasma spectroscopy (ICP/AES). A simple extraction procedure based on immersion of wood samples of approximate dimension 2 x 1 x 1 cm³ in distilled water a...
R J Murphy, D J Dickinson, P W McCormack, M K Lung


Long-Term Release of Arsenic, Chromium, and Copper from CCA-Treated Wood and Ash
2005 - IRG/WP 05-50227
In this study, laboratory long-term leaching studies were conducted to characterize the leaching behavior of arsenic, chromium, and copper from CCA-treated wood samples (block, chip, and sawdust) and CCA-wood ash and to determine the rate of release of the metals from the CCA wood products. The leaching solutions were periodically collected and analyzed for the concentrations of arsenic, chromium,...
Hyunmyung Yoon, Heeseok Kang, Yong-Chul Jang


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