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Molecular dynamics investigation of wood modification with furfuryl alcohol
2022 - IRG/WP 22-40931
Molecular dynamics (MD) was applied to investigate and understand the structural characteristics and the interaction of cellulose and lignin with furfuryl alcohol for explaining the wood modification process. A single chain of cellulose polymer model and a softwood lignin model was considered to represent cellulose and lignin polymers. The obtained radial distribution function results revealed tha...
V Ponnuchamy, J Sandak, A Sandak


Optimized composition of alkyd emulsion with nanoparticles of iron oxide for enhancing protection of thermally modified wood
2022 - IRG/WP 22-40940
Thermal treatment is acknowledged as an environmentally friendly method to improve durability of wood and some of its properties, such as biological resistance, dimensional stability, reduced hygroscopy. Despite these improvements, when used outdoors, also thermally treated wood is subjected to the action of environmental factors, like solar radiation, moisture, precipitations, temperature, etc., ...
E Sansonetti, D Cīrule, I Andersone, B Andersons, E Kuka


Effect of densification of Eucalyptus nitens and E. obliqua on moisture uptake, swelling, decay resistance, and fire performance
2022 - IRG/WP 22-40946
Some Australian Eucalyptus species that are abundantly available have low natural durability and poor resistance to fire. These same species are also extremely difficult to treat with preservatives or fire retardants using conventional pressure treatment methods due to a large proportion of refractory heartwood. The aim of this research was to understand whether thermo-mechanical densification had...
B Hassan, J J Morrell, F Wiesner, W Wu, B Belleville, K C Wood


Moisture sorption behaviour of poplar and thermally modified poplar using dynamic vapour sorption (DVS)
2022 - IRG/WP 22-40947
The moisture sorption behaviour of wood has a critical impact on service life. In Europe, softwood is mostly used to manufacture engineered wood products such as cross-laminated timber (CLT) or glue-laminated timber (GLT or glulam). Yet fast-growing and widespread tree species such as hybrid poplar with or without modification, have potential to meet the increasing demand. This study shows the moi...
X Jiang, J Van den Bulcke, L De Boever, M Minsart, A Mignon, J Van Acker


Phenol formaldehyde modification and termite resistance under laboratory testing
2022 - IRG/WP 22-40952
The development of phenol formaldehyde (PF) resins as a means of impregnating solid wood is one that has been explored for several decades, both in terms of conventional impregnation processing (Impreg) or compressional impregnation (Compreg). However, it is only recently with advances in processing conditions that the method truly affords a means of achieving conventional modification for solid t...
L Nunes, A Pitman, M Duarte, B Stefanowski, D Jones


Novel bio-based tannin/furfurylic alcohol thermosets: application to wood preservation
2022 - IRG/WP 22-40959
This project is integrated within the overall context of sustainable development and targets the valorization the wood industry by-products such as polyphenolic extractives, and in particular tannins. The objective targets the use of the same polymer used for production of tannin-furanic foams, but here for wood preservation to avoid the utilization of biocides. The aims is to the design of copoly...
C Gérardin-Charbonnier, E Azadeh, A Pizzi, P Gerardin


Improvement of durability of Scots pine against termites by impregnation with citric acid and glycerol followed by in situ polyesterification
2023 - IRG/WP 23-30777
Scots pine (Pinus sylvestris) sapwood samples were impregnated with solution containing citric acid (CA) and glycerol (Gly) followed by heating 140 °C according to already described procedure (L'hostis et al. 2018). The resulting modified woods were then used to evaluate the effect of chemical modification on the durability against termites. Two kinds of experiments were conducted for this purpos...
M Mubarok, J Damay, E Masson, E Fredon, Y S Hadi, I W Darmawan, P Gerardin


Biological durability and wood-water interactions of sorbitol and citric acid modified wood – Effects on the expected service life
2023 - IRG/WP 23-40960
A high level of research activities on sorbitol and citric acid (SorCA) modified wood has been recognized in Europe over the last few years. As this treatment is close to entering an industrial-scale production, it is of interest to investigate how such treated wood performs upon long-term outdoor exposure. Hence, in this study Scots pine (Pinus sylvestris L.) sapwood was modified with aqueous sol...
K Kurkowiak, L Emmerich, H Militz


Field test methods as long-term aging – report of selective wood properties
2023 - IRG/WP 23-40962
Wood samples from a long-term field test are a valuable compendium of information about the material in the context of its aging processes. In the current work, wood samples from the round-robin test within the ECOMOD project were used as a material for the natural aging process (III and IV class of utility). The research scope was to determine selected properties of this wood which can be partial...
W Perdoch, M Benc, B Mazela, A Szulc, J Cegiela


Resistance of phenol formaldehyde impregnated beech (Fagus sylvativa L.) LVL against biodegradation in soil contact
2023 - IRG/WP 23-40965
Alternatives to preservative impregnation are emphasized in Germany and other European countries. Even though these treatments significantly improve wood's resistance to decay, they often do not have a beneficial impact on the dimensional stability. One alternative product, which may be used in ground contact for items like poles and railway sleepers, could be beech (Fagus sylvatica L.) laminated ...
M Slabohm, C Brischke, S Bicke, H Militz


Effect of impregnation modification treatment on properties of Paraserianthes falcataria wood
2023 - IRG/WP 23-40966
Modification treatment can improve the properties of wood, particularly those of fast-growing species. Paraserianthes falcataria, also known as batai, is a fast-growing species with low wood density. This species has piqued the interest of those involved in industrial wood processing as a promising alternative for construction. The aim of this study is to improve the dimensional stability of batai...
A S Yusoh, A S Boneka, M K Anwar U, S Salim, S H Lee


New wood-modification process based on grafted urethane groups: Durability of carbamamylated Scots pine (Pinus sylvestris L.) wood
2023 - IRG/WP 23-40974
Substituting commonly used toxic preservatives with wood modification treatments can make the wood material less prone to water and moisture uptake. This approach favours a more sustainable protection of wood against biodegradation. In this study, Scots pine sapwood was full-cell impregnated with an aqueous solution of urea (30%), dried at 40°C for 24h, and subsequently heat-treated at 150°C for...
C-F Lin, O Myronycheva, O Karlsson, D Jones, D Sandberg


The impact of pre-drying on treatment level variations of esterified solid wood analysed by X-ray densitometry
2023 - IRG/WP 23-40977
Wood modification requires homogenous treatment levels within the wood matrix to prevent insufficiently treated areas being subject to biodeterioration. Esterification of wood by citric acid and sorbitol can show differences in density caused by uneven chemical distribution during the curing phase and can be detected by x-ray densitometry. This study used density profiling to investigate the influ...
A Treu, S O Amiandamhem, E Larnoy


Effects of preservative impregnations on wettability and surface free energy properties of Eucalyptus grandis wood
2023 - IRG/WP 23-40978
Wettability and surface free energy (SFE) are crucial parameters for evaluating the adhesion thermodynamics of solid surfaces. Hence, this study investigated the effects of copper azole (CA) and disodium octaborate tetrahydrate (DOT) preservative impregnations on Eucalyptus grandis wood wettability and SFE. Wettability was determined in terms of contact angles with polar (water) and non-polar (dii...
A A Alade, C B Wessels, H Stolze, H Militz


CIOL Wood - towards industrial scale production
2023 - IRG/WP 23-40980
CIOL® is a new, low cost, non-toxic wood modification system, needed to replace traditional and non-sustainable alternatives with great potential. It’s important to find sustainable, environmentally friendly replacements to heavy metals and biocides. In the new European Bauhaus, Ursula Von der Leyen, president of the European commission, talks about how new living environment should be beautifu...
E Larnøy, J Biørnstad


Starch modified with silanes – high hydrophobic surface treatment for wood protection
2023 - IRG/WP 23-40981
The great potential of silanes for starch modification and their utility as surface wood protection is still not sufficiently assessed. The work aimed to analyze the crosslinking process's effect on starch modification with silane and tested the hydrophobic properties of surface-treated wood. The starch treatment was modified with methyltrimethoxysilane or N-octyltriethoxysilane. SEM-EDX with a cr...
W Perdoch, M Bajstok, B Mazela, I Siemińska, B Peplińska


Short-term absorption of water and coatings on thermally modified blue-stained spruce wood
2023 - IRG/WP 23-40984
The importance of wood has been increasing in the last decades. Among conifers, predominantly spruce (Picea abies) wood is often used in building constructions in Europe. Namely for construction and facades of buildings, decking and fences. Due to the increased public concerns about biocides, alternative techniques for protection, such as thermal modification and protection by construction, are ga...
R Hasanagic, M Bahmani, M Humar, L Fathi, L Cai


Properties of thermal modified wood of Pinus pinaster and Pinus radiata from Galicia, Spain
2023 - IRG/WP 23-40985
This article provides the results of a research about the properties of thermal modified wood of maritime pine (Pinus pinaster Ait.), radiata pine (Pinus radiata D.Don) and Scots pine (Pinus sylvestris L.) from Galicia, Spain, thermal treated in the industrial vacuum-heat autoclave plant of FINSA group in Galicia, Spain. These three pine wood species are used in different solid products but due th...
D Lorenzo, J Benito, J Arancón, J Crespo


Bio-inspired wood protection, modification and functionalization
2023 - IRG/WP 23-40989
Wood is a versatile, natural, and environmentally friendly resource that has attracted attention as a material for sustainable building for many years. Recent advances in materials research have delivered several innovative solutions for the construction sector. However, intrinsic properties of wood affects its operational durability, which is still a limiting factor in many applications and envir...
A Sandak, K Butina Ogorelec, F Poohphajai, A Gubenšek, R Herrera Diaz, O Gordobil


Modification of wood by fast pyrolysis bio-oil – the NewWave project concept for bio-based wood treatment
2023 - IRG/WP 23-40990
The NewWave project aims to contribute to building a circular economy by introducing sustainable raw materials in different manufacturing lines, replacing toxic chemicals and lowering the environmental footprint of the products. The raw materials are obtained from the thermochemical fractionation of biomass. This process converts biomass residues by fast pyrolysis into Fast Pyrolysis Bio-Oil (FPBO...
A Sandak, J Sandak, F Poohphajai, R Herrera Diaz, A Gubenšek, K Butina Ogorelec, L Kiezebrink, K J Swager, H Heeres, B van de Beld


Optimization of furfurylic alcohol/tannin ratio to improve the performance of biosourced thermoset resins for wood protection
2023 - IRG/WP 23-40994
This study concerns the chemical modification of wood with different ratios of tannin and furfuryl alcohol (FA) in the presence of maleic acid as catalyst. Tannins were used not only as cross-linking agents, but also as co-monomers to improve wood durability, while reducing the amount of FA used. Different aqueous formulations were prepared containing decreasing amount of FA (from 45.45% to 0%) an...
E Azadeh, A Pizzi, P Gérardin, C Gérardin-Charbonnier


Studies on the treatability of selected pine species and corresponding efficacies of a new non-biocidal treatment
2024 - IRG/WP 24-20721
Wood decay caused by fungi may reduce the service life of wood in outdoor applications. Since moisture conditions in wood occur as one of the most crucial parameters for fungal decay, chemical modifications, which affect the latter, may increase the resistance of wood against such organisms. Usually, pine sapwood is easier to chemically treat than heartwood, as the former generally shows good perm...
T R da Silva Lins, L Emmerich, H Militz, P H Gonzales de Cademartoni, R J Klizke, M Pereira da Rocha


Elevated pressure hybrid wood modification: Synergistic effects on durability performance
2024 - IRG/WP 24-20725
The combination of different wood modification technologies to obtain improved performance is increasingly receiving attention in research. In this study, Scots Pine was impregnated with furfuryl alcohol (FFA) in pure aqueous 20, 40 and 60% solution strength without adding any catalyst. In a second step, the FFA was polymerized while simultaneously performing thermal modification in a closed syste...
P Klaas, D Jones


Properties of thermal modified wood of Pinus pinaster, Pinus radiata and Pinus sylvestris from Galicia, Spain
2024 - IRG/WP 24-30800
This paper provides the results of a research about the properties of thermal modified wood of maritime pine (Pinus pinaster Ait.), radiata pine (Pinus radiata D. Don) and Scots pine (Pinus sylvestris L.) from Galicia, Spain, thermal treated in the industrial vacuum-heat autoclave plant of FINSA group in Galicia, Spain. These three pine wood species are used in different solid products but due the...
D Lorenzo, J Benito, J Arancon, J Crespo


Natural weathering of modified pine and Eucalyptus woods by surface charring
2024 - IRG/WP 24-30801
Within various wood modification techniques, surface charring is anticipated to extend the lifespan of wooden components in building facades; however, visual deterioration of charred cladding materials has become a notable concern. This study, conducted through international collaboration, aimed to assess the resistance of bio-based facade materials to weathering in the Turkish climate. The natura...
E E Soyturk, E N Kavakli, S N Kartal, C M Ibanez


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