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Preservatives stains as exterior wood finishes
1977 - IRG/WP 389
For many years wood preservatives and paints have been used as the only treatment for exposed wood surfaces. Because of the inherent color of the preservatives, such as creosote, the wood surface was stained as well as protected from attack by micro-organisms. Paints protect surfaces from weathering, but recently, with an increased interest in maintaining the more natural appearance of exterior wo...
D W French


The effect of boric acid on the protozoan numbers of the subterranean termite, Reticulitermes lucifugus
1996 - IRG/WP 96-10148
Lower termites harbor in their guts populations of microorganisms known to be indispensable for their survival, being responsible, at least partially, for the digestion of cellulose, the main item of termites'diet. The Reticulitermes species in particular harbor in their hindguts some unique intestinal fauna, for instance protozoa belonging to the genera Pyrsonympha, Dinenympha and Trycho...
L Nunes, D J Dickinson


Oxalic acid metabolism of Postia placenta
1992 - IRG/WP 92-1566
The oxalic acid metabolism of Postia placenta was studied in liquid culture in order to identify the metabolic pathways of biosynthesis and to determine whether oxalic acid physiology could be correlated with efficiency in wood decay. Oxalic acid production was determined for test strain MAD698 grown in a basal defined medium with a variety of different carbohydrate and nitrogen sources. The highe...
J A Micales


Investigation of copper fixation in timber by sodium nitrit
1992 - IRG/WP 92-3707
Solutions containing mixtures of water soluble copper salts and sodium nitrite have been shown to be capable of producing leach resistant copper treatments when impregnated into timber. A rapid leaching trial showed that copper fixation levels of 85-90% were possible which compared well with the fixation level obtained with conventional hexavelant chromium containing systems in the same test regim...
C Waldie, J A Cornfield


Treatment of wood by diffusion of salts
1976 - IRG/WP 368
A brief survey is given on the treatment of wood by diffusion of salts. The compounds used for this process, mainly boron and fluorine compounds, are mentioned and the factors influencing diffusion described. The main pre-condition is a high moisture content of the wood of above 40%. Fields of application are fresh roundwood, remedial treatment of poles and sleepers, preservation of posts and espe...
G Becker


Serpula lacrymans the dry rot fungus. Revue on previous papers
1989 - IRG/WP 1393
It is found that the Dry rot fungus Serpula lacrymans grows in houses only because of its need for basic materials to neutralize the oxalic acid production or heavy metals which celate the oxalic acid. The average distance from the mycelium to the basic materials is found in average to be 14.2 cm with a variation from 0-100 cm. In contrast to Serpula lacrymans the Coniophora puteana and the Rigido...
J Bech-Andersen


Biological resistance of furfuryl alcohol-treated wood
1992 - IRG/WP 92-3703
Biological resistance of FFA (furfuryl alcohol)-treated wood was investigated in relation to the rise of ASE (anti-swelling efficiency) resulting from the treatment. Sapwood blocks of Japanese red pine, cedar and beech were vacuum-impregnated with various concentrations of aqueous FFA solutions to get the target levels of% (w/w) RL (resin loading). Air-dried blocks were kept in an oven at 120°C f...
J Y Ryu, Y Imamura, M Takahashi


Chemically modified tannin and tannin-copper complexes as preservatives for wood
2001 - IRG/WP 01-30271
The efficacy of Mimosa tannin, chemically modified tannin, and tannin-copper complexes as wood preservatives was studied. When the tannin-ammonia-CuCl2 solutions were impregnated into wood specimens in a one-step procedure, a large quantity of the tannin-copper complex was fixed in the specimens. Little of the complex was leached from specimens by a weathering treatment, and these specimens showed...
H Yamaguchi


Amine copper reaction with wood components: acidity versus copper adsorption
1997 - IRG/WP 97-30161
The bonding sites for copper in wood from CCA, as well as ammoniacal/amine based systems, has long been a topic of investigation. Both phenolic and carboxylic functional groups have been discussed as potential bonding sites for copper. However, no consensus on the adsorption mechanism has been realized. Thus, the selective adsorption of copper in southern yellow pine from ethanolamine-copper solut...
S M Thomason, E A Pasek


Oral toxicity of TIM-BOR®, Bora-Careä, boric acid and ethylene glycol against the formosan subterrean termite and easter subterrean termite
1993 - IRG/WP 93-10045
Oral toxicities (LD50) of boric acid, TIM-BOR® (disodium octaborate tetrahydrate: DOT) and BORA-CAREä (40% DOT in ethylene glycol) and ethylene glycol (ca. 80% monoethylene and ca. 20% polyethylene glycol) were estimated. Oral toxicities of BORA-CAREä were significantly higher (LD50: 256.2 µg/g DOT and 304.9 mg/g BAE) than TIM-BOR® alone (LD50: 408.2 µg/g DOT and 485.7 µg/g BAE); indicating...
M Tokoro, N-Y Su


The degradation of wood surfaces by dilute acids
1985 - IRG/WP 3326
Thin radial/longitudinal sections(~100 µ) of Corsican Pine (Pinus nigra) and Lime (Tilia vulgaris), were exposed to Sulphuric, Sulphurous, nitric, acetic, and formic acid at 40°C in the pH range 2-6. After about 3 months exposure to Sulphuric, nitric, acetic and formic acid at pH 2.0 Pine lost some 20-25% of its tensile strength. Losses in tensile strength due to sulphurous acid were greater bei...
P D Evans, W B Banks


Interaction of copper-amine complexes with wood: Influence of copper source, amine ligands and amine to copper molar ratio on copper retention and leaching
1999 - IRG/WP 99-30203
The absorption and leachability of copper in copper amine (Cu-EA) treated wood are influenced by the formulation and the composition of copper amine treating solutions. The sources of copper used, Cu(OH)2, CuCO3, CuSO4 and Cu(NO3)2, in the copper amine complex formulation affect the leachability of copper. Data show that copper amine from CuSO4 and Cu(NO3)2 treated wood has less copper loss during...
Jun Zhang, D P Kamdem


A model for attack at a distance from the hyphae based on studies with the brown rot Coniophora puteana
1995 - IRG/WP 95-10104
In timber infested by brown rot fungi, a rapid loss in strength is attributed to production of hydroxyl radicals (HO·) at a distance from the hyphae. The immediate precursor is Fenton's reagent (Fe(II)/H2O2), but the pathways leading to Fe(II) and H2O2 have remained unclear. Cellobiose dehydrogenase, purified from cultures of Coniophora puteana, will couple oxidation of cellodextrins to ...
S M Hyde, P M Wood


Detrimental effects of boric acid on symbiotic protozoa in Reticulitermes flavipes (Kollar) and Coptotermes formosanus Shiraki (Isoptera: Rhinotermitidae)
2000 - IRG/WP 00-10366
In laboratory choice bioassays, Reticulitermes flavipes (Kollar) and Coptotermes formosanus Shiraki were offered a tunneling soil consisting of boric acid (BA) mixed with sterilized soil at concentrations of 0.05, 0.25, 0.50, 1.00, 2.00, or 4.00 percent AI (wt:wt). Termites could choose to remain in their main nest that contained non-treated artificial substrate and adequate food, or tunnel throug...
B M Kard


Anti-sapstain chemicals for diffusion treatment of rubber wood
1986 - IRG/WP 3367
Performance of Sinesto B and Akzo EN 494, two formulated products of alkyl ammonium compounds, was tested as fungicidal additive in the boron solution to control mould and stain during diffusion storage of rubber wood. Sinesto B at 2.0% (a.i.) concentration has given good control over mould and its protection against sapstain was only satisfactory. Akzo EN 494 at 0.7% (a.i.) concentration has give...
R Gnanaharan


Removing Cu, Cr and As from CCA treated yellow pine by oleic acid
2003 - IRG/WP 03-50202
In this study, CCA treated yellow pine utility poles were cut into three different dimensions and 4 different pH levels (2, 2.5, 3.5 and 5) of Oleic acid was used. The leached wood samples were collected at the end of the 1, 3, 7 and 14 days to determine the remaining Cu, Cr and As concentrations. The concentrations of Cu, Cr and As were determined by X-RF. The effects of pH, dimension and duratio...
E D Gezer, Ü C Yildiz, S Yildiz, E Dizman, A Temiz


The future for chromium in wood preservation
1985 - IRG/WP 3332
Most water-borne preservatives contain CrVI compounds, originally to reduce corrosion although now also to improve toxicant fixation. Chromium contributes to preservation and this is recognised in, for example, New Zealand and USA where chromium contents are included in calculations of overall preservative activity of CCA formulations, but chromium may also have anti-stain and joinery (millwork) p...
B A Richardson, T R G Cox


CCA removal from treated wood by chemical, mechanical and microbial processing
1998 - IRG/WP 98-50101-26
Most preservative-treated wood produced and consumed in the U.S. is treated with toxic inorganic compounds containing copper, chromium, and arsenic. Because chromated copper arsenate (CCA) is fixed to the wood, treated wood has not been considered toxic or hazardous and is currently landfilled. Increasing public concern about environmental contamination from treated wood combined with increasing q...
C A Clausen, R L Smith


The efficacy of boron preparations
1987 - IRG/WP 3400
The toxicity threshold of boric acid for egg larvae of Hylotrupes bajulus Linné is approx. 0.4 kg/m³ of wood (71 g B/m³) over a 12-week test period, and approx. 0.3 kg/m³ of wood (53 g B/m³) over a 6-month test period. The corresponding values for borax are 0.5-0.6 kg/m³ of wood (56-68 g B/m³) and 0.3-0.4 kg/m³ of wood (34-45 g B/m³). The values are somewhat lower in the case of the egg l...
J T De Jonge


Redistribution of boric acid in radiata pine during drying after preservative treatment
1993 - IRG/WP 93-40010
Samples of 100 x 50 mm² radiata pine were processed with a variety of options to produce dry, boron-treated wood. Concentrations of boric acid in the central one-ninth and in the whole of the wood cross-sections were determined by chemical analysis and compared. Diffusion treated material was dried by air, conventional kiln (70/60°C), or high temperature kiln (120/70°C). Four different predryin...
A J Bergervoet, D R Page, J A Drysdale


A comparison of fatty acid and molecular profiles for identification of wood colonizing basidiomycota
2003 - IRG/WP 03-20278
Two methods that are currently being employed to detect and identify wood decay fungi are Fatty Acid Methyl Ester (FAME) analysis and Restriction Fragment Length Polymorphism (RFLP) analysis. A FAME library and RFLP library for 9 species and up to 10 strains within each species have been developed. The profiles generated by these methods have been compared for each species and strain to test for...
T C McElroy, L Prewitt, S V Diehl


Kinetics and mechanism of fixation of Cu-Cr-As wood preservatives. Part 4: Conversion reactions during storage
1974 - IRG/WP 332
Precipitates simulating those produced in wood by preservative fixation reactions were prepared by the reduction of Boliden K 33 and Celcure AP solutions with hydrogen peroxide and hydrazine. The pH changes on aging at 20 and 50°C were studied and related to the chemistry of fixation previously described. Hydrolysis of copper arsenates may render arsenic acid temporarily water soluble pending pre...
S-E Dahlgren


Effects of the sulfuric acid modification of CCA treating solution
1987 - IRG/WP 3415
Sulfuric acid modification of CCA treating solution is often used to control the formation of sludges and undesirable deposits on the surface of treated wood. The consequences of sulfuric acid addition are examined in this work and negative effects are shown to far outweigh any benefits. Major risks include the loss of copper due to leaching from treated wood and the accelerated corrosion of treat...
R F Fox, H J Fry, E A Pasek, A S Ross


A combined method for drying and preserving wood in a single step process
2000 - IRG/WP 00-40183
Based on a convective dryer, this process allows to dry and treat wood blocks with diffusible preservatives in the same time. A boric acid solution (heated to fix the wet temperature of the system) is pumped and introduced in the flow system through a venturi, where the air coming back from the drying cell also arrives. The role of the venturi is to create a dispersion of boric acid solution micro...
O Colin, C Dupuis, E Mougel, A Zoulalian, M-F Thévenon


Effects of hard water, sea water and humic acid on the release of CCA components from treated wood
2005 - IRG/WP 05-50228
Leaching medium is an important factor affecting release of preservative components from treated wood because physical and chemical characteristics of medium increase or decrease the solubility of fixed preservative components. This study evaluated the leaching properties of copper, chromium and arsenic elements from chromated copper arsenate (CCA)-treated wood specimens subjected to laboratory le...
S N Kartal, W J Hwang, Y Imamura


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