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Rapid Microwave-Assisted Acid Extraction of Metals from Chromated Copper Arsenate (CCA)-Treated Southern Pine Wood
2009 - IRG/WP 09-50262
The effects of acid concentration, reaction time, and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with three different acids (i.e., acetic acid, oxalic acid, and phosphoric acid) was investigated using in microwave reactor. Oxalic acid wa...
Bin Yu, Chung Y Hse, T F Shupe


Microwave Surface Modification of Radiata Pine Peeler Cores for Preservative Treatment
2009 - IRG/WP 09-40453
Radiata pine peeler cores are classified as a by-product derived from the cores of logs left over after the veneer peeling process. The core can be potentially developed for value added solid wood products as it is abundantly available and has a constant diameter. However, the core needs to be preservative treated because of low durability in ground contact. An additional problem is that the wood ...
K Sugiyanto, G Torgovnikov, P Vinden


Methods for Studying Penetration Depth of Wood Protection Products
2010 - IRG/WP 10-20432
EN 152 is an accepted standard in Europe for measuring how deep a wood protection product penetrates into the surface of treated pine wood. The method has provided consumers with a wide assortment of products that meet the specifications outlined in the standard. Because the test takes 8 or more months to carry out, artificial ageing procedures have evolved in order to standardize and speed up the...
K Hansen, L Sites, D D Nicholas


Use of Internal Remedial Treatment to Extend Wood Life at the Fort Vancouver National Historic Site
2010 - IRG/WP 10-30525
The condition of wood in a reconstructed fur trading fort was assessed over a 30 year period. Poor initial treatment had resulted in the development of extensive early decay. While supplemental treatment with chloropicrin and methylisothiocyanate had arrested the attack, the results suggested that remedial treatments were unable to completely overcome the initial problems associated with treatmen...
C S Love, C Freitag, J J Morrell


A comparison of the chemistry of alkaline copper and micronized copper treated wood
2010 - IRG/WP 10-30528
This paper discusses the chemistry of the reaction of alkaline copper and micronized copper with wood. The objective of this study is to examine the copper species produced in wood during the fixation reaction using electron paramagnetic resonance (EPR) spectroscopy. The initial experiments (phases 1 to 2) were designed to confirm the effect of time of treatment and solution concentration on the s...
Wei Xue, P Kennepohl, J N R Ruddick


Evaluation of ACQ-D treated Chinese fir and Mongolian Scots pine with different post-treatments after 20 months of exposure
2010 - IRG/WP 10-30530
The performance of alkaline copper quat-type D (ACQ-D) treated Chinese fir (Cunninghamia lanceolata Hook.) and Mongolian Scots pine (Pinus sylvestris Linn. var. mongolica Litv.) stakes after 20 months exposure in Chengdu and Guangzhou of southern China were evaluated according to AWPA standard E07-07. The ACQ-D treatments used two concentration levels (0.5 and 1.0%) and four different post-treatme...
Lili Yu, Jinzhen Cao, Wei Gao, Haitao Su


Copper nanoparticles in southern pine wood treated with a micronised preservative: Can nanoparticles penetrate the cell walls of tracheids and ray parenchyma?
2010 - IRG/WP 10-30547
This study tests the hypothesis that copper nanoparticles can penetrate the cell walls of southern pine wood treated with a micronised preservative. We examined the nanodistribution of particles in tracheid and ray parenchyma cell walls using state-of-the-art HR (High Resolution)-TEM and HR-STEM (Scanning Transmission Electron Microscope)-EDX. These devices are capable of atomic-scale resolution. ...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans


Chemical protection of historic timber structures: Results and future needs
2010 - IRG/WP 10-40487
The paper concentrates on the analysis of the effectiveness of chemical protection for timber structures in the Russian State Museums “Kizhi” (Karelia) and “Vitoslavlitsy” (Novgorod). The condition of historic timber was tested at the monuments treated with PCP, borax, potassium carbonate, boric acid, Pinotex chemicals in the 1970-80. Long-term analysis revealed that in many cases the...
M Kisternaya, V Kozlov


Fungal decay resistance and mechanical properties of plywood panels made from maritime pine (Pinus pinaster) and bonded with cornstarch-quebracho tannin-phenol formaldehyde adhesive
2010 - IRG/WP 10-40490
The aim of this work is to demonstrate the performances of cornstarch-quebracho tannin-based resins designed as adhesive in the plywood production. In this way, the cornstarch and quebracho tannin was introduced in the classic adhesive formulation in order to supply a part of phenol-formaldehyde (PF). In order to evaluate the mechanical performances of optimal cornstarch-quebracho tannin-PF, plywo...
F Charrier, A Moubarik, A Allal, A Pizzi, B Charrier


Combined Effect of Boric Acid and Waste Oil Treatment on Boron Leaching
2010 - IRG/WP 10-50268
In this study it was aimed to investigate the boron leaching amounts in Scots pine wood samples treated with boric acid (BA) and waste oil (WO) alone or by dual treatment. The level of water absorption and water repellent efficiency were determined with cyclical wetting tests, total of 336 hours. Wood samples that have both covered and uncovered transversal section were impregnated with 3% boric a...
Ü C Yildiz, E Dizman


Basidiomycete colonization of Scots pine sapwood quantified by qPCR and TGA
2011 - IRG/WP 11-10750
Scots pine (Pinus sylvestris L.) is an important softwood species in Northern Europe and is frequently used as material for various wood protection systems. In Europe, EN 113 is the standard basidiomycete laboratory durability test method, using mass loss as evaluation criteria. In this paper quantitative real-time PCR (qPCR) and thermogravimetric analysis (TGA) was used to characterize coloniza...
G Alfredsen, S Bollmus, T K Bader, K Hofstetter


Comparison of rates of wood decay from four different field test protocols following 4-5 years exposure at a site in New Zealand
2011 - IRG/WP 11-30565
The rate of decay of Pinus radiata was evaluated using four different field test protocols at a site near New Plymouth, New Zealand. The average Scheffer index was 86 over the five year period of testing. The field tests were an in-ground stake test (AWPA Std E7-01) and three above ground tests – lap-joint (AWPA Std E16-98), decking (AWPC protocol) and ground proximity tests (AWPA Std E18-06) T...
P Lobb, K Day, A Siraa


Copper Nanoparticles in Southern Pine Wood Treated with a Micronised Preservative: Nanodistribution of Copper in the Pit Membrane and Border of an Earlywood Bordered Pit
2011 - IRG/WP 11-30566
Copper nanoparticles can penetrate the cell walls of unlignified parenchyma cells in southern pine wood treated with a micronised wood preservative, but they are excluded from lignified tracheid walls. This paper extends these observations to include the cell wall layers of the bordered pit. Focused ion beam and ion milling were used to make an ultra-thin section of the cell wall layers of an earl...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans


Biological and mechanical performances of particleboard panels made from maritime pine (Pinus pinaster) and glued with cornstarch-mimosa tannin-urea formaldehyde adhesive
2011 - IRG/WP 11-40542
The objective of this work was to demonstrate the utility of cornstarch-mimosa tannin-based resins designed for application as an adhesive in the particleboard production. Bond qualities of cornstarch-mimosa tannin- urea formaldehyde (UF) (10:4:86, weight ratios) resins and commercial UF resin were assessed by using an automatic bonding evaluation system, prior to production of particleboard panel...
A Moubarik, F Charrier, A Pizzi, A Allal, B Charrier


Acetylation Properties of Southern Pine and Radiata Pine
2011 - IRG/WP 11-40543
The chemical modification of wood via acetylation with acetic anhydride has been a well investigated technology and is of current commercial interest due to improved properties such as dimensional stability as well as resistance to termites and resistance to rot and decay fungi. Despite this, the acetylation of a board substrate requires further investigation in order to assess board properties a...
J Allen, T Guinn, J Dickerson


Further Studies on the Distribution of Copper in Treated Wood Using an XRF Microscope Technique
2011 - IRG/WP 11-40549
There are two distinct forms of copper in aqueous copper based wood preservative systems that are currently used in the United States for treatment of southern pine lumber. These are systems using either soluble copper (typically amine based) or the more recent particulate or “micronized” copper as the primary biocide. Studies reported last year showed that there were distinct differences in...
A Zahora


Quantification of mobile copper (II) levels in micronized copper treated wood
2011 - IRG/WP 11-40550
The purpose of this study is to quantify the mobile copper(II) levels in micronized copper treated wood using electron paramagnetic resonance (EPR) spectroscopy. A correlation between EPR and EDX intensities on mobile copper levels in a series of copper sulphate treated wood was created as a calibration standard. Laboratory treatments using micronized copper formulations were then carried out and ...
Wei Xue, P Kennepohl J N R Ruddick


Treatability variation of scots pine heartwood from Northern Europe
2011 - IRG/WP 11-40563
Scots pine (Pinus sylvestris L.) is one of the most common construction materials for general exterior applications in northern Europe. It has a wide natural geographical distribution, a good availability and it is low-priced compared to other materials. According to EN 350-2 Scots pine heartwood is considered being “untreatable” and having durability class 3. This means that its durability co...
G Behr, E Larnøy, C-T Bues


Copper Migration from Micronized Copper Preservatives Treated Wood in soil contact:
2011 - IRG/WP 11-50280
Emerging formulations of preservatives made with micronized basic copper carbonates with azoles and/or quat to control copper tolerant fungi have been used to replace formulations containing soluble copper to reduce the leaching of copper and the corrosion of metal in contact with wood. This study proposes to use laboratory soil leaching test AWPA standard (E20-08) to estimate the amount of copper...
Lei Wang, D P Kamdem


Using an accelerated laboratory method to evaluate Aureobasidium pullulans colonization on painted surfaces and underlying wood substrate
2012 - IRG/WP 12-20480
Mold growth on painted surfaces can lead to premature paint film failure and is unsightly. Aureobasidium pullulans has been identified as a major cause of black stain on surfaces painted with acrylic or latex paints. In this study, an accelerated laboratory method developed by Zabel and Horner (1981) was used with modifications to the type of agar used and sample evaluation methods. A study was ...
C Schauwecker, L Burns, A Preston


Accessibility of Wood Cell Walls to Well-defined Platinum Nanoparticles
2012 - IRG/WP 12-20494
Copper nanoparticles are found in the walls of parenchyma cells in southern pine sapwood treated with a micronised wood preservative, but they are absent from tracheid walls. Hence, we hypothesized that small nanoparticles can penetrate the walls of unlignified parenchyma cells, but are excluded from lignified tracheid walls. This paper tests this hypothesis by treating pine sapwood with an aqueou...
H Matsunaga, Y Kataoka, M Kiguchi, P D Evans


Supercritical impregnation of wood with siloxane
2012 - IRG/WP 12-30595
This paper describes the effect of supercritical impregnation with siloxane on the water repellency of Scots pine (Pinus sylvestris) sapwood samples. Samples were impregnated with a low amount of siloxane dissolved in supercritical carbon dioxide using isopropanol as a co-solvent. Siloxane retention (i.e. weight percent gain (WPG)) of the treated samples was 1.3 % (w/w) as found by mass balance. T...
A Kjellow, F Imsgard, J Fernandes, O Henriksen, E Klaassen, R Wagner, J Delis


Correlation of %Acetyl and Fiber Saturation in Acetylated Southern Pine Boards
2012 - IRG/WP 12-40598
Wood acetylation represents a chemical modification that increases the hydrophobicity of wood. The level of acetylation in the wood structure determines the extent of hydrophocity with higher levels providing reduced moisture affinity. Due to the reduced hygroscopic nature of acetylated wood, performance features such as dimensional stability, resistance to termites, and resistance to rot and de...
J Dickerson, E Cwirko, J Allen


Efficiency of the Amazon Forest Oils as Preservatives to the Attack of cellulolytic fungi in Pine Wood
2012 - IRG/WP 12-30599
The bobbins of wood are used for storage and field installation of cables from the electricity and telecommunications sectors. There are legal requirements governing the Brazilian ways of treating the wood used in these sectors, aimed at preventing pollution and protecting nature. When exposed to severe environmental conditions in Brazil these products are degraded and occurs many operational prob...
S Silveira, I M S Mendes, R S Paiva, J E Volponi, R C G Comar, R S Cruz


Tar-oil uptake vs time in immersion treatment of short pine posts: A simple technique applicable to rural communities of Papua New Guinea
2012 - IRG/WP 12-40608
Pinus caribaea and Araucaria cunninghamii logs ca. 100 mm in diameter were shortened to lengths 25-30 cm, conditioned to at/below fibre saturation point (FSP) for immersion/dip treatment using a hot- and- cold bath open- tank process. Before oven-drying and subsequent treatment, individual test specimens were numbered, their green weights and volumes, and dry weights recorded for basic density, vo...
B K Gusamo, R Tulo


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