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Methods for Studying Penetration Depth of Wood Protection Products
2010 - IRG/WP 10-20432
EN 152 is an accepted standard in Europe for measuring how deep a wood protection product penetrates into the surface of treated pine wood. The method has provided consumers with a wide assortment of products that meet the specifications outlined in the standard. Because the test takes 8 or more months to carry out, artificial ageing procedures have evolved in order to standardize and speed up the...
K Hansen, L Sites, D D Nicholas


Use of Internal Remedial Treatment to Extend Wood Life at the Fort Vancouver National Historic Site
2010 - IRG/WP 10-30525
The condition of wood in a reconstructed fur trading fort was assessed over a 30 year period. Poor initial treatment had resulted in the development of extensive early decay. While supplemental treatment with chloropicrin and methylisothiocyanate had arrested the attack, the results suggested that remedial treatments were unable to completely overcome the initial problems associated with treatmen...
C S Love, C Freitag, J J Morrell


A comparison of the chemistry of alkaline copper and micronized copper treated wood
2010 - IRG/WP 10-30528
This paper discusses the chemistry of the reaction of alkaline copper and micronized copper with wood. The objective of this study is to examine the copper species produced in wood during the fixation reaction using electron paramagnetic resonance (EPR) spectroscopy. The initial experiments (phases 1 to 2) were designed to confirm the effect of time of treatment and solution concentration on the s...
Wei Xue, P Kennepohl, J N R Ruddick


Assessment of Boracol 200RH (FrameSaver) as a remedial treatment to control decay in pre-decayed model timber frame units
2010 - IRG/WP 10-30529
Model timber frame units constructed from untreated radiata pine were pre-wetted to approximately 40% moisture content and inoculated with Coniophora puteana and Oligoporus placenta. Units were transferred to a controlled environment room maintained at 25°C and 95% RH for 7 and 10 weeks to allow two levels of decay to become established in units. Following pre-decay, units were disassembled, clea...
Mick Hedley, Dave Page, Jackie van der Waals


Copper nanoparticles in southern pine wood treated with a micronised preservative: Can nanoparticles penetrate the cell walls of tracheids and ray parenchyma?
2010 - IRG/WP 10-30547
This study tests the hypothesis that copper nanoparticles can penetrate the cell walls of southern pine wood treated with a micronised preservative. We examined the nanodistribution of particles in tracheid and ray parenchyma cell walls using state-of-the-art HR (High Resolution)-TEM and HR-STEM (Scanning Transmission Electron Microscope)-EDX. These devices are capable of atomic-scale resolution. ...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans


Microwave-Assisted Organic Acids Extraction of Chromate Copper Arsenate (CCA)-Treated Southern Pine
2010 - IRG/WP 10-50267
The extraction effects of acid concentration, reaction time and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with two different organic acids (i.e., acetic acid and oxalic acid) was investigated using a microwave reactor. Oxalic acid was e...
Bin Yu, Chung Y Hse, T F Shupe


Isolation and evaluation of Lactobacillus brevis from chilli waste for potential use as a wood preservative
2011 - IRG/WP 11-10749
Lactic acid bacteria were isolated from chilli waste and evaluated for their ability to arrest wood rotting basidiomycetes. In previous work a quick screening method using 96 well plates and measuring absorbance to determine fungal growth was developed specifically to investigate the efficacy of isolated bacteria against wood decay fungi. Using this method, one bacterium (isolate C11) was identif...
D O’Callahan, T Singh, I R McDonald


The effects of acetylation level on the growth of Postia placenta
2011 - IRG/WP 11-10751
To understand the defence mechanisms utilized by decay fungi when exposed to different wood protection systems the study of gene expression can give us some answers. When the DNA sequences are known, primers can be designed to detect transcripts of genes with gene products related to basic cellular processes and hyphal growth. The characteristic gene products induced in different fungi by differen...
A Pilgård, G Alfredsen, C G Fossdal, C J Long II


LOSP for glulam, when should the treatment be applied?
2011 - IRG/WP 11-30555
Treatment options for outdoor above-ground (H3) exposed glulam of Pinus radiata and P. elliottii were examined. Beams were treated with azole LOSP (containing a zinc tracer) aiming for retentions of 35-40 l/m3 or 70-80 l/m3. Treatment was conducted either before or after gluing. TBTN LOSP and CCA were included as comparative treatments. Test specimens for exposure were cut after treatment, while w...
L J Cookson


The durability of acetylated radiata pine sapwood (Accoya). Results from five years testing
2011 - IRG/WP 11-30560
New Zealand grown radiata pine sapwood was modified using the Accsys PLC acetylation process (Accoya). Following treatment, various test samples were exposed in the Scion Accelerated Field Test facility (Fungus Cellar) and in exterior ground contact field tests. In the Fungus Cellar, performance was compared with that of radiata pine treated with CCA to Hazard Classes H3.2 (0.37% m/m Cu+Cr+As) and...
M Hedley, D Page, J van der Waals, K Nasheri, G Durbin


Comparison of rates of wood decay from four different field test protocols following 4-5 years exposure at a site in New Zealand
2011 - IRG/WP 11-30565
The rate of decay of Pinus radiata was evaluated using four different field test protocols at a site near New Plymouth, New Zealand. The average Scheffer index was 86 over the five year period of testing. The field tests were an in-ground stake test (AWPA Std E7-01) and three above ground tests – lap-joint (AWPA Std E16-98), decking (AWPC protocol) and ground proximity tests (AWPA Std E18-06) T...
P Lobb, K Day, A Siraa


Copper Nanoparticles in Southern Pine Wood Treated with a Micronised Preservative: Nanodistribution of Copper in the Pit Membrane and Border of an Earlywood Bordered Pit
2011 - IRG/WP 11-30566
Copper nanoparticles can penetrate the cell walls of unlignified parenchyma cells in southern pine wood treated with a micronised wood preservative, but they are excluded from lignified tracheid walls. This paper extends these observations to include the cell wall layers of the bordered pit. Focused ion beam and ion milling were used to make an ultra-thin section of the cell wall layers of an earl...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans


The Effectiveness of Machined Profiles at Reducing the Checking of Wooden Decking
2011 - IRG/WP 11-40541
This study tests the hypothesis that ‘the ability of surface profiling to reduce checking of deck boards exposed to weathering will vary with wood species and profile type’. Southern pine (Pinus sp.) and Pacific silver fir (Abies amabilis) deck boards were machined to produce three different types of surface profiles: flat (control), ribbed (V-shaped grooves), and rippled (U-shaped grooves). B...
P Evans, I Cullis, P Morris


Acetylation Properties of Southern Pine and Radiata Pine
2011 - IRG/WP 11-40543
The chemical modification of wood via acetylation with acetic anhydride has been a well investigated technology and is of current commercial interest due to improved properties such as dimensional stability as well as resistance to termites and resistance to rot and decay fungi. Despite this, the acetylation of a board substrate requires further investigation in order to assess board properties a...
J Allen, T Guinn, J Dickerson


Further Studies on the Distribution of Copper in Treated Wood Using an XRF Microscope Technique
2011 - IRG/WP 11-40549
There are two distinct forms of copper in aqueous copper based wood preservative systems that are currently used in the United States for treatment of southern pine lumber. These are systems using either soluble copper (typically amine based) or the more recent particulate or “micronized” copper as the primary biocide. Studies reported last year showed that there were distinct differences in...
A Zahora


Quantification of mobile copper (II) levels in micronized copper treated wood
2011 - IRG/WP 11-40550
The purpose of this study is to quantify the mobile copper(II) levels in micronized copper treated wood using electron paramagnetic resonance (EPR) spectroscopy. A correlation between EPR and EDX intensities on mobile copper levels in a series of copper sulphate treated wood was created as a calibration standard. Laboratory treatments using micronized copper formulations were then carried out and ...
Wei Xue, P Kennepohl J N R Ruddick


Physical properties of Pinus radiata veneers modified with hexamethoxymethyl melamine prepolymers
2011 - IRG/WP 11-40551
Prepolymers containing hexamethoxymethyl melamine and either sucrose (Suc-HMMM) or polyvinyl alcohol (PVA-HMMM) were prepared by acid catalysis under reaction conditions optimised with respect to stiffening effect when introduced into Pinus radiata veneers by vacuum impregnation and cured by hot pressing at 150C. Maximum increases in MOE were 20% for Suc-HMMM (50% WPG), 22% for PVA-HMMM (...
C Molloy, W Rae, S Connor, T Henderson, A Siraa


Biological properties of Pinus radiata veneers modified with hexamethoxymethyl melamine
2011 - IRG/WP 11-40552
An investigation of the effects on decay and termite resistance of a wood modification process involving prepolymers of hexamethoxymethyl melamine (HMMM) was conducted using LVL as a model engineered wood product. Dry Pinus radiata veneers were vacuum-impregnated with a wood modification formulation containing a mixture (P-H:S-H) of two separate prepolymerisation reactions containing polyvinyl al...
A Siraa, S Millward, C Molloy


Copper Migration from Micronized Copper Preservatives Treated Wood in soil contact:
2011 - IRG/WP 11-50280
Emerging formulations of preservatives made with micronized basic copper carbonates with azoles and/or quat to control copper tolerant fungi have been used to replace formulations containing soluble copper to reduce the leaching of copper and the corrosion of metal in contact with wood. This study proposes to use laboratory soil leaching test AWPA standard (E20-08) to estimate the amount of copper...
Lei Wang, D P Kamdem


Performance of Creosote/Chlorothalonil Preservatives
2011 - IRG/WP 11-30580
The addition of chlorothalonil to P2 creosote was found to increase the durability of southern pine in a series of ground contact stake tests. At retentions lower than those specified in the AWPA Standards, performance was increased when the creosote was amended with chlorothalonil. This indicates that lower creosote retentions may be required for as good or better ground contact when the amende...
H M Barnes, M G Sanders, G B Lindsey, T L Amburgey


Preference of Reticulitermes flavipes (Kollar) for Southern Pine Blue-Stained Sapwood from Beetle-Killed Trees
2012 - IRG/WP 12-10763
Bark beetles and their associated Ophiostomatiod fungi are the major pests of pine forests in the southeastern USA, and termites are the major insect decomposers of dead trees and wood products in the southeastern USA. While both are the principal destructive insects of southern pine trees and southern pine lumber, respectively, no relationship between the two has apparently been reported in the ...
N S Little, J J Riggins, A J Londo, T P Schultz, D D Nicholas


Wood decay enzymatic ability of Fusarium circinatum
2012 - IRG/WP 12-10777
There exists pathogens that attack standing trees of forests, and do not usually thrive once the tree is felled. However, occasionally they can be present in a latent state in the wood and can spread and affect new areas with economic, ecological and social consequences. Fusarium circinatum is a fungus that causes “pitch canker” in pine species, and is considered a quarantine organism within t...
M T Troya, F Llinares, Y Serrano, M Conde


Novel microscopic approaches to visualise chitosan within impregnated wood
2012 - IRG/WP 12-20485
Chitosan, a deacetylated product of an abundant naturally occurring biopolymer chitin, has been used in a range of applications, particularly in food and health areas, as an antimicrobial agent. In the work reported here Pinus radiata wood was impregnated with chitosan as an environmentally compatible organic biocide. It is important to understand micro-distribution of bioprotectants in impregnate...
A Singh, T Singh


Accessibility of Wood Cell Walls to Well-defined Platinum Nanoparticles
2012 - IRG/WP 12-20494
Copper nanoparticles are found in the walls of parenchyma cells in southern pine sapwood treated with a micronised wood preservative, but they are absent from tracheid walls. Hence, we hypothesized that small nanoparticles can penetrate the walls of unlignified parenchyma cells, but are excluded from lignified tracheid walls. This paper tests this hypothesis by treating pine sapwood with an aqueou...
H Matsunaga, Y Kataoka, M Kiguchi, P D Evans


Supercritical impregnation of wood with siloxane
2012 - IRG/WP 12-30595
This paper describes the effect of supercritical impregnation with siloxane on the water repellency of Scots pine (Pinus sylvestris) sapwood samples. Samples were impregnated with a low amount of siloxane dissolved in supercritical carbon dioxide using isopropanol as a co-solvent. Siloxane retention (i.e. weight percent gain (WPG)) of the treated samples was 1.3 % (w/w) as found by mass balance. T...
A Kjellow, F Imsgard, J Fernandes, O Henriksen, E Klaassen, R Wagner, J Delis


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