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Chemical Analysis of Southern Pine Pole Stubs Thirty-Nine Months Following Treatment with Three Methylisothiocyanate-Based Fumigants
2004 - IRG/WP 04-30349
Agricultural fumigants have been commercially used in the United States for over 20 years to control internal decay in utility poles and other wooden structures. Of the four fumigants which are currently used in the remedial treatment of utility poles, three are based on methylisothiocyanate (MITC) as being the principal fungitoxic component. Two of these MITC-based fumigants, liquid metham sodi...
R J Ziobro, J Fomenko, D J Herdman, J Guzzetta, T Pope


Determination of total fluoride in preservative-treated wood by ion selective electrode, without steam distillation
1996 - IRG/WP 96-20086
An analytical method was developed to determine total fluoride in wood treated with aqueous fluoride or borate-fluoride formulations. Ground wood was mixed with 60% sodium hydroxide solution and oven-dried overnight before furnacing at 600°C. The cool fused product was dissolved in warm water before adding a powerful complexant/buffer solution containing sulphosalicylic acid and EDTA. Fluoride wa...
M J Kennedy


Sludge formation in timber treatment with CCA preservatives. Origin and elimination
1984 - IRG/WP 3276
The exact distributions between lignin and holocellulose and retentions on wood of copper, chromium and arsenic as a function of various sets of conditions in a factorial experiment in which combinations of three temperatures of treatment, three CCA solution concentrations, four pH's of the initial CCA solution and two timber species, namely Pinus radiata and Eucalyptus grandis, are repor...
A Pizzi, W E Conradie, A Jansen


Ammoniacal wood preservative for use in non-pressure treatment of spruce and aspen poplar. Part 1
1984 - IRG/WP 3273
End-matched lumber of Picea glauca (Moench)Voss (white spruce) and Populus tremuloides Michx. (aspen poplar) timbers was treated by a thermal diffusion process in open tank treating vessels using an ammoniacal copper-arsenate wood preservative. The process proved technically feasible with respect to controlling the vapourization of ammonia from open tanks during treatment at high temperatures. Tre...
C D Ralph, J K Shields


Preservative treatement of muli bamboo (Melocanna baccifera) by pressure process
2001 - IRG/WP 01-40194
This study was carried out in order to investigate the possibility of preservative treatment of split bamboo by pressure process. Whole bamboo is very difficult to treat by pressure process, which is the best and most dependable of all treating processes. Because it surface has a coat of impervious cutiular which make it very resistance to the penetration of liquid. Beside this it is prone to deve...
K Akhter, M Younusuzzaman, M H Chowdhury


The reliability of colouring methods for the determination of biflourides and boron in spruce wood
1994 - IRG/WP 94-20036
From practical reasons, qualitative spraying methods are widely used for the detection of bifluorides and boron in wood. The main aim of this research was to detect whether the concentration of the active ingredient in the coloured area is equal or greater than the toxic value against basidiomycetes. Both colouring methods, Z-A reagent for fluorides and curcuma reagent for boric acid, are a reliab...
R Grell, M G Sanders, W J Homan, H Militz


The dip diffusion treatment of tropical building timbers in Papua New Guinea
1972 - IRG/WP 310
In Papua New Guinea a dip diffusion process using a multi salt preservative developed by C.S.I.R.0. has been in commercial use for 8 years. Over 200 million super feet (236,000 m³ ) of timber has been treated during this period and current rate of treatment is 34 million super feet (80,400 m³ ) of timber per year in 70 licenced treatment plants. The process has been found to be simple to apply, ...
C R Levy, S J Colwell, K A Garbutt


Effects of heat treatment on water repellence and anti-swelling efficiency of beech wood
2002 - IRG/WP 02-40223
The heating of solid wood to higher temperatures is the simplest and the cheapest means for stabilizing its dimensions. For the investigation of the effect of thermal treatment on water repellency effectiveness and anti-swelling efficiency of beech wood (Fagus orientalis Lipsky), air-seasoned samples of beech wood were heated in presence of air at temperatures of 130 C, 150 C, 180 C and 200 C for ...
S Yildiz


Effect of treatment process on performance of copper-chrome-arsenate. Part 2: Field stake tests
1995 - IRG/WP 95-40046
Pinus radiata sapwood stakes 20 x 20 x 400 mm³ were treated with CCA Type C using a range of concentrations and three treatment processes; Bethell, Lowry and Rueping. Preservative retention was determined by chemical analysis of treated material. Following fixation stakes were installed in a randomised plot in the Whaka graveyard located on the FRI campus. Stakes were inspected at yearly interval...
M E Hedley, J Anderson, J B Foster, B E Patterson


Bending properties of TCMTB-treated Southern pine sapwood using supercritical carbon dioxide impregnation process
1997 - IRG/WP 97-40080
The effects of elevated pressure and treatment with thiocyanomethylthiobenzothiazole (TCMTB) on the bending properties of Southern pine sapwood were evaluated at pressures ranging from 1,800 to 3,600 psi. All bending properties were affected to some extent by supercritical fluid treatment. Modulus of elasticity and work to maximum load were not significantly affected by pressure levels. Modulus of...
Gyu-Hyeok Kim, S Kumar, E S Demessie, K L Levien, J J Morrell


An environmental assessment of timber treatment plants in Australia
1999 - IRG/WP 99-50124
Australian Standard AS 2843 Timber Preservation Plant Safety Code, sets the specifications for the design and operation of timber treatment plants in Australia. The Timber Preservers' Association of Australia has carried out an environmental survey of timber treatment plants throughout Australia using the operational checklist provided in Appendix C of Part 2 of the Standard. Third party ...
J Norton, K Riley


Decrease of the antidecay resistance of beech wood treated with organotin fungicides after its natural ageing
1998 - IRG/WP 98-30185
The antidecay resistance of beech-wood samples (120 x 8.5 x 8.5 (MM)) treated with tributyltin fungicides gradually decreased due to prolongation of their natural ageing: tributyltin fungicides (TBTO, TBTS, TBTCA, TBT-DEDTK were applied by pressure impregnation technique in ethanole solutions (c = 0. 1%, 0.33% or 1%); treated beech-wood samples were naturally aged without their contact with grou...
L Reinprecht


Study of the degradation of retified wood through ultrasonic and gravimetric techniques
1994 - IRG/WP 94-40030
One of the non-polluting processes that increase the natural durability of wood is a thermal treatment in an atmosphere poor in oxygen, producing what is normally denominated "retified wood". In this study the validity of a non-destructive technique (ultrasound) in order to determine the biodegradation suffered by wood across time has been studied. For this reason, the behavior of a wood species (...
D T De Troya, A M Navarrete


Bioefficacy of boric acid grafted onto wood
1999 - IRG/WP 99-30202
The use of borate treated wood in outdoor is limited because of the migration of borate. The objective of this study is to investigate the fixation of boric acid in wood using polyethylene glycol (PEG-400) to form polyester borate and isocyanato group as coupling agent. FT-IR was used to monitor the reaction between boric acid and PEG. Elemental analysis was conducted to evaluate the C, H, and N v...
Weining Cui, D P Kamdem


Albumin borate: A new non-toxic, wide-spectrum, long-term wood preservative
1998 - IRG/WP 98-30167
Boron, widely recognized for its broad range of activity towards both fungi and insects and for its low mammalian toxicity, can not provide long term protection to treated timber due to its high leachability. Boron, in the form of boric acid, can be partially fixed to timber by the formation of an association with egg albumin, which is insolubilized by heat-induced coagulation. Chemical investiga...
M-F Thévenon, A Pizzi, J-P Haluk


Sampling rates and the probability of detecting defective treatment in the sampling of preservative treated timber
1987 - IRG/WP 2277
When attempting to enforce standards of penetration and retention set for treated timber, the regulating authority must establish a sampling or inspection scheme which will prevent large quantities of substandard product entering the market. On the other hand, the scheme should not penalise treaters for the small quantities of such material which are inevitably produced by any industrial process. ...
M J Kennedy, L E Leightley


Treatment of wood with formaldehyde. Acid catalysis of the reaction between formaldehyde and wood
1980 - IRG/WP 3146
Formaldehyde reacts with the free OH-groups in wood forming cross-linking bonds. The reaction can be brought about without any catalyst but in that case the activation energy is very high and high temperatures and long reaction times are needed. Normally, the reaction is catalysed by different acids. Acid catalysts, however, tend to degrade the cellulose and the wood matrix causing reduction in th...
T Vihavainen, K Piispanen, P Mansikkamäki


Practical consequences of the clarification of the chemical mechanism of CCA fixation to wood
1983 - IRG/WP 3220
Practical consequences derived from the chemical investigation of the mechanism of fixation of CCA to the wood constituents are discussed. Among these, formulas for the calculation of the time of hexavalent chrome fixation are presented. Furthermore, three parameters are shown to be important to the long-term effectiveness of CCA-treated timber: (i) the temperature of treatment, (ii) the initial p...
A Pizzi


Applications of the shower test. Part B: Results from CC and CCB treated wood: influence of fixation process
1993 - IRG/WP 93-50010
This report outlines the results of shower tests conducted on CC and CCB treated wood. The results indicate the fairly good fixation of chromium and the reasonable fixation of copper in CC and CCB formulations, as judged by the leaching limits within the Environmental Regulations. In general boron leaches to a higher extent than chromium and copper. The shower test has proven to be a useful qualit...
W J Homan, H Militz


Serviceability modeling-Predicting and extending the useful service life of FRT-plywood roof sheathing
2000 - IRG/WP 00-20210
One of the most, if not the most, efficient methods of extending our existing forest resource is to prolong the service life of wood currently in-service by using those existing structures to meet our future needs (Hamilton and Winandy 1998). It is currently estimated that over 7 x 109 m3 (3 trillion bd. ft) of wood is currently in service within the United States of America (PATH 1999). Research ...
J E Winandy


Recent developments in the treatment of sawn spruce by double vacuum impregnation
1978 - IRG/WP 3114
The timbers used for building purposes in the U.K. and on the Continent of Europe are mainly softwoods. The two types of wood most used are redwood (Pinus sylvestris) and whitewood (Picea abies or Picea sitchensis). Other species are used to a lesser extent when considerations such as a long length requirement or width requirement demand the use of, for example, hemlock, Douglas fir or Parana pine...
C T Kyte, L D A Saunders


The treatment of sawn whitewood with organic solvent wood preservative
1982 - IRG/WP 3192
The impregnation schedules approved in the UK for the treatment of sawn European whitewood (Picea abies) with organic solvent borne preservatives result in comparitively high loadings relative to the limited depth of penetration they achieve. Results are presented, which show how substantial reduction in the overall loading may be achieved without concomitant reduction in penetration. A model for ...
L D A Saunders


Diffusion of a copper naphthenate/boron paste through Douglas fir heartwood
1991 - IRG/WP 3671
Groundline wraps are an important portion of the remedial treatment strategies for protecting utility poles in North America from surface decay. The compositions of these wraps have recently shifted away from pentachlorophenol and creosote to formulations containing copper naphthenate and boron. These formulations have not yet been extensively tested, although the chemicals have been used for many...
P G Forsyth, J J Morrell


Corrosion of zinc-coated nails used with preservative-treated western red cedar shakes in service
1982 - IRG/WP 3197
The corrosion of metal fasteners used with certain wood species and with preservative-treated woods can be a serious problem. The chemical reactivity of western red cedar (Thuja plicata Donn) extractives to iron and copper is well documented and wood preservative treatments containing copper, chromium, and/or ammonium hydroxide can be expected to similarly attack some metals. This problem is compo...
R S Smith, E L Johnson, A J Cserjesi


The efficacy of remedial treatments for controlling fungal decay in window millwork used in the United States
1987 - IRG/WP 3432
Conventional window millwork was subjected to basidiomycete decay by inoculation and sampled for active growth of the decay fungus before and eight months after remedial preservative treatment with fused disodium octaborate rods (IMPEL) at boric acid levels of 1.5 and 4.0 kg/m³ or liquid bifluoride injections (IMPROSOL) at 1 kg/m³. The elimination of decay fungus after remedial treatment was nea...
M G Dietz, E L Schmidt


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