IRG Documents Database and Compendium


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Water repellency and dimensional stabilIty of wodd treated with waterborne resin acids/TOR
2007 - IRG/WP 07-40364
Wood used in above ground applications such as decking undergoes undesired dimensional changes leading to the lumber warping, cupping, splitting, etc. This is a major concern to consumers but it can be reduced by treating lumber with a water repellent. The ability of resin acids, hydrophobic compounds naturally present in southern yellow pines, was examined as a possible water repellent. A wate...
T P Schultz, D D Nicholas, J Shi


Detection of Anti-Fungal Sapwood Extractives in Non-Durable Scots Pine (Pinus sylvestris), Rubberwood (Hevea brasiliensis) and Jelutong (Dyera costulata)
2007 - IRG/WP 07-10634
A general laboratory bioassay method of Woodward and Pearce (1985) was adopted to detect anti-fungal activity of sapwood or heartwood extractives of 5 Malaysian hardwoods [dark red meranti heartwood (Shorea spp.), red balau heartwood (Shorea spp.), kulim heartwood (Scorodocarpus borneensis), jelutong sapwood (Dyera costulata) and rubberwood sapwood (Hevea brasiliensis), including the temperate Pin...
A H H Wong, R B Pearce


Validity of above ground testing according to ENV 12037
2008 - IRG/WP 08-20379
The standard ENV 12037 for testing of treated and untreated wood (lap-joint) exposed above ground was issued in 1996 by The European Committee for Standardization. A draft for the development of the standard was presented by CEN-TC 38/WG 25/DOC N 076 in 2002. For a test to become valid the median rating of decay for untreated control replicates (Scots pine sapwood) must be equal or greater than ...
Ö Bergman, U Råberg, N Terziev


Development of a Weatherometer to Accelerate the Surface Checking of Wood
2008 - IRG/WP 08-20388
There is significant interest in developing preservatives that are better at preventing wood from checking. Currently, however, there is no accepted test methodology for accelerating the development of checks in wood samples so information on the effectiveness of treatments at restricting checking can be obtained more quickly. This paper describes the development of a new type of weatherometer (Ac...
R Ratu, P D Evans


Micro-Distribution of Micronized Copper in Southern Pine
2008 - IRG/WP 08-30479
For copper-based preservatives to be used in ground contact, penetration of copper into the cell wall is believed to be important to protect the wood from soft rot fungi. Preservatives containing soluble copper are known to do this. It is not known whether preservatives containing particulate copper will also migrate into the cell wall in sufficient quantities to control soft rot decay. An AWPA st...
R Stirling, J Drummond, Jun Zhang, R J Ziobro


Surface Characteristics of Southern pine treated with Eastern red cedar oil
2008 - IRG/WP 08-40393
Treatment of wood with various chemicals play an important role on their surface characteristics including as roughness and hardness for further processing such as finishing and machining. The objective of this study is to evaluate surface roughness of Southern pine (Pinus taeda L.) treated with oil extracted from eastern redcedar (Juniperus viginiana L.). Both tangential and radial surfaces of...
S Hiziroglu


Bending Properties of Southern Pine Treated with Micronized Preservative Systems
2008 - IRG/WP 08-40414
This study indicates that treatment of southern pine with micronized copper systems have no deleterious effect on the residual strength property values. No statistical differences between wood treated with micronized systems and water-treated controls were noted when means were compared using either Tukey’s test or S-N-K mean comparison tests. Using the more discriminating Least Squares anal...
H M Barnes, G B Lindsey, J Hill, M Pompeo, R Hodge


Variations of Furfuryl alcohol and Wolmanit CX-8 treatability of pine sapwood within and between trees
2008 - IRG/WP 08-40421
The variations on the ratio of filling (RoF) were investigated on Norwegian grown Scots pine (Pinus sylvestris). The samples were taken from 10 different stands in south-east Norway, and treated with furfuryl alcohol and a copper-containing wood preservative. Both within tree variations, between tree variations and variations between stands were investigated for significant differences. Factors li...
E Larnøy, S Lande, G I Vestøl


Comparison of laboratory and natural exposure leaching of copper from wood treated with three wood preservatives
2008 - IRG/WP 08-50258
Standard and non-standard laboratory and field leaching tests were used to compare copper leaching from wood treated to above ground and ground contact specified retentions for three wood preservative systems, CCA-C, ACQ-D and a micronized copper formulation with quat DDAC as co-biocide. Copper leaching was highest for the ACQ formulation. Percent leaching was lowest for the micronized copper sy...
P A Cooper, Y T Ung


Re-Distribution of Copper in the Cell Walls of Wood Treated with Micronized Copper Quat
2009 - IRG/WP 09-30506
Wood treated with copper-based preservatives to be used in ground contact may fail to inhibit soft rot fungi if penetration of copper into the cell wall is insufficient. Preservatives containing soluble copper are known to penetrate the cell wall; however, it is not known whether preservatives containing particulate copper will also migrate into the cell wall in sufficient quantities to control so...
R Stirling, J Drummond


Component leaching from CCA, ACQ and a micronized copper quat (MCQ) system as affected by leaching protocol
2009 - IRG/WP 09-50261
Leaching results for Cu, Cr and As (CCA) and Cu (ACQ and MCQ) from southern pine are compared for laboratory tests (AWPA E11, and draft OECD methods I and II) and natural weathering of horizontally and vertically oriented lumber samples over two seasons. This paper expands on results and comparison of results presented at the IRG regional meeting in Costa Rica in Dec 2008 (Cooper and Ung 2008) a...
P A Cooper, Y T Ung


Rapid Microwave-Assisted Acid Extraction of Metals from Chromated Copper Arsenate (CCA)-Treated Southern Pine Wood
2009 - IRG/WP 09-50262
The effects of acid concentration, reaction time, and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with three different acids (i.e., acetic acid, oxalic acid, and phosphoric acid) was investigated using in microwave reactor. Oxalic acid wa...
Bin Yu, Chung Y Hse, T F Shupe


Wood properties influencing the penetration of Scots pine (Pinus sylvestris) sapwood with the wood modification agent furfuryl alcohol
2009 - IRG/WP 09-40470
The European standard EN 350-2 classifies Scots pine sapwood as class 1 (easy to treat). However large variations in sapwood penetration exist which affect a homogenous distribution of preservatives. Hence individual penetration schemes have to be developed and adjusted to the material most difficult to treat in order to provide adequate sapwood penetration. To ensure better economic process con...
K Zimmer, E Larnøy, G Koch


A comparison of the chemistry of alkaline copper and micronized copper treated wood
2010 - IRG/WP 10-30528
This paper discusses the chemistry of the reaction of alkaline copper and micronized copper with wood. The objective of this study is to examine the copper species produced in wood during the fixation reaction using electron paramagnetic resonance (EPR) spectroscopy. The initial experiments (phases 1 to 2) were designed to confirm the effect of time of treatment and solution concentration on the s...
Wei Xue, P Kennepohl, J N R Ruddick


Copper nanoparticles in southern pine wood treated with a micronised preservative: Can nanoparticles penetrate the cell walls of tracheids and ray parenchyma?
2010 - IRG/WP 10-30547
This study tests the hypothesis that copper nanoparticles can penetrate the cell walls of southern pine wood treated with a micronised preservative. We examined the nanodistribution of particles in tracheid and ray parenchyma cell walls using state-of-the-art HR (High Resolution)-TEM and HR-STEM (Scanning Transmission Electron Microscope)-EDX. These devices are capable of atomic-scale resolution. ...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans


Testing of decay resistance of sapwood and heartwood of thermally modified Scots pine and Norway spruce
2010 - IRG/WP 10-40523
Thermal modification at elevated temperatures changes the chemical, biological and physical properties of wood. One of the main targets of thermal modification is to increase the biological durability and decay resistance of wood. Although the effects of thermal modification on wood have been widely studied, the significance of sapwood and heartwood on the resistance of thermally modified wood has...
H Viitanen, S Metsä-Kortelainen


Microwave-Assisted Organic Acids Extraction of Chromate Copper Arsenate (CCA)-Treated Southern Pine
2010 - IRG/WP 10-50267
The extraction effects of acid concentration, reaction time and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with two different organic acids (i.e., acetic acid and oxalic acid) was investigated using a microwave reactor. Oxalic acid was e...
Bin Yu, Chung Y Hse, T F Shupe


Basidiomycete colonization of Scots pine sapwood quantified by qPCR and TGA
2011 - IRG/WP 11-10750
Scots pine (Pinus sylvestris L.) is an important softwood species in Northern Europe and is frequently used as material for various wood protection systems. In Europe, EN 113 is the standard basidiomycete laboratory durability test method, using mass loss as evaluation criteria. In this paper quantitative real-time PCR (qPCR) and thermogravimetric analysis (TGA) was used to characterize coloniza...
G Alfredsen, S Bollmus, T K Bader, K Hofstetter


The effects of acetylation level on the growth of Postia placenta
2011 - IRG/WP 11-10751
To understand the defence mechanisms utilized by decay fungi when exposed to different wood protection systems the study of gene expression can give us some answers. When the DNA sequences are known, primers can be designed to detect transcripts of genes with gene products related to basic cellular processes and hyphal growth. The characteristic gene products induced in different fungi by differen...
A Pilgård, G Alfredsen, C G Fossdal, C J Long II


The durability of acetylated radiata pine sapwood (Accoya). Results from five years testing
2011 - IRG/WP 11-30560
New Zealand grown radiata pine sapwood was modified using the Accsys PLC acetylation process (Accoya). Following treatment, various test samples were exposed in the Scion Accelerated Field Test facility (Fungus Cellar) and in exterior ground contact field tests. In the Fungus Cellar, performance was compared with that of radiata pine treated with CCA to Hazard Classes H3.2 (0.37% m/m Cu+Cr+As) and...
M Hedley, D Page, J van der Waals, K Nasheri, G Durbin


Copper Nanoparticles in Southern Pine Wood Treated with a Micronised Preservative: Nanodistribution of Copper in the Pit Membrane and Border of an Earlywood Bordered Pit
2011 - IRG/WP 11-30566
Copper nanoparticles can penetrate the cell walls of unlignified parenchyma cells in southern pine wood treated with a micronised wood preservative, but they are excluded from lignified tracheid walls. This paper extends these observations to include the cell wall layers of the bordered pit. Focused ion beam and ion milling were used to make an ultra-thin section of the cell wall layers of an earl...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans


The Effectiveness of Machined Profiles at Reducing the Checking of Wooden Decking
2011 - IRG/WP 11-40541
This study tests the hypothesis that ‘the ability of surface profiling to reduce checking of deck boards exposed to weathering will vary with wood species and profile type’. Southern pine (Pinus sp.) and Pacific silver fir (Abies amabilis) deck boards were machined to produce three different types of surface profiles: flat (control), ribbed (V-shaped grooves), and rippled (U-shaped grooves). B...
P Evans, I Cullis, P Morris


Acetylation Properties of Southern Pine and Radiata Pine
2011 - IRG/WP 11-40543
The chemical modification of wood via acetylation with acetic anhydride has been a well investigated technology and is of current commercial interest due to improved properties such as dimensional stability as well as resistance to termites and resistance to rot and decay fungi. Despite this, the acetylation of a board substrate requires further investigation in order to assess board properties a...
J Allen, T Guinn, J Dickerson


Further Studies on the Distribution of Copper in Treated Wood Using an XRF Microscope Technique
2011 - IRG/WP 11-40549
There are two distinct forms of copper in aqueous copper based wood preservative systems that are currently used in the United States for treatment of southern pine lumber. These are systems using either soluble copper (typically amine based) or the more recent particulate or “micronized” copper as the primary biocide. Studies reported last year showed that there were distinct differences in...
A Zahora


Quantification of mobile copper (II) levels in micronized copper treated wood
2011 - IRG/WP 11-40550
The purpose of this study is to quantify the mobile copper(II) levels in micronized copper treated wood using electron paramagnetic resonance (EPR) spectroscopy. A correlation between EPR and EDX intensities on mobile copper levels in a series of copper sulphate treated wood was created as a calibration standard. Laboratory treatments using micronized copper formulations were then carried out and ...
Wei Xue, P Kennepohl J N R Ruddick


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