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Current state of world standardization in the toxicometric methods for testing of wood preservatives
2007 - IRG/WP 07-20354
The paper presents an outline of the history of forming standardized toxicometric methods for testing of wood preservatives in the world during last 100 years. Numerous studies resulted in three main methods which are currently used for official and basis assessment of biocides: - agar-block method in Europe (EN 113); - soil-block method in the USA and Pacific countries (ASTM D 1413); - modifi...
J Wazny


Kd values of Cu, Cr, As in different soil matrix
2007 - IRG/WP 07-50247
Chromated copper arsenate (CCA), a long history of successful preservative, have raised environmental concerns. Adsorption characteristics of domestic soils for chromium, copper, and arsenic were assessed by measuring distribution coefficient (Kd) values of these metal components. The results revealed that Kd values were higher in chromium, followed by arsenic and copper in soil matrix. Different...
Sung-Mo Kang, Seung-Hun Shin, Ja-Oon Koo


A hypothesis on a second non-biocidal property of wood extractives, in addition to toxicity, that affects termite behavior and mortality
2008 - IRG/WP 08-10638
While it is has long been recognized that heartwood extractives affect termite behavior, the exact cause and relationship between total extractives, extractive types, and termite resistance remains unclear. Generally, researchers have proposed that the extractives are toxic and/or repel termites. We propose, based on the well known fact that many extractives have excellent antioxidant properties...
T P Schultz, K Ragon, D D Nicholas


Field Liners as physical barriers to prevent wooden utility pole decay in soil: An accelerated field simulation trial
2008 - IRG/WP 08-20384
Field Liners (FL’s), plastic sleeves used to protect in-ground wooden poles from fungal and termite damage, have been tested before as physical barriers to prevent contact between soil and wood and to retain wood preservative treatment. These earlier studies concentrated mostly on creosote preserved poles and early generation FL’s which were cumbersome in their application. The newer generatio...
A R Howgrave-Graham, L J Cookson, T Hale


Measurement of wood decay by dynamic MOE in an accelerated soil contact test
2008 - IRG/WP 08-20390
Current laboratory and field testing of preservatives involves various techniques to determine the extent of fungal attack, including visual inspection, mass loss, and static bending and compression strength measurements. The objective of this study was to compare decay measurement by conventional compression strength versus dynamic MOE, employing small wood stakes in an accelerated laboratory so...
Gan Li, D D Nicholas, T P Schultz


Biological Performance of micronized copper wood preservative formulations in field and laboratory tests
2008 - IRG/WP 08-30488
Micronized Copper wood preservative formulations with different co-biocides were exposed to brown rot fungi in an 8-week AWPA E10 soil block decay test and two AWPA E7 ground-contact decay tests in Hawaii. The micronized copper formulations performed well against decay at or above the AWPA UC3 and UC4 retentions stipulated by the ICC-ES. Micronized copper preservatives performed comparably to a ...
G M Larkin, J Zhang, D L Richter, R J Ziobro, P E Laks


Moisture adsorption isotherms of wood studies using a dynamic vapour sorption apparatus
2009 - IRG/WP 09-20398
Five types of wood including two Malaysian hardwoods acacia mangium (Acacia mangium) and sesenduk (Endospermum malaccense), two temperate softwoods, Sitka spruce (Picea sitchensis), radiata pine (Pinus radiata) and Accoya (commercially modified wood) were studied to determine their moisture sorption behaviour using a Dynamic Vapour Sorption (DVS) apparatus. The isotherm plot for each species teste...
J Zaihan, C A S Hill, S Curling


Durability and fungal colonisation patterns in wood samples after six years in soil contact evaluated with qPCR, microscopy, TGA, chitin- and ergosterol assays
2009 - IRG/WP 09-20402
There is a need to establish new objective and sensitive methods for early detection and quantification of decay fungi in wood materials. Molecular methods have proven to be a useful tool within wood protection issues, however, this field is still poorly explored and so far relatively few have used these methods within the field of wood deterioration. Among the techniques used in the indirect quan...
A Pilgård, G Alfredsen, I Børja, C Björdal


Microscopy evaluation of microbial decay patterns in wood stakes after 6 years in soil contact
2010 - IRG/WP 10-10715
Most studies on wood modification have so far been concerned with service life predictions rather than investigating the decay protection mechanism. Very little is known about the mode of action of these new treatments and about the strategies used by wood degraders in order to utilize the wood material despite a treatment. Access to such knowledge would allow further modification and improvement ...
A Pilgård, C G Björdal


Seasonal shifts of fungal community structure at the interface of treated or untreated wood and soil
2010 - IRG/WP 10-10721
Many wood species are degraded rapidly in soil by the fungal community. In order to preserve wood and structures in which it is used, chemical preservatives are used. Little is known about the interaction of treated wood and the surrounding soil fungal community. For this work, presented at IRG 41, wooden specimens (Pinus sylvestris sapwood, sizes 25 mm x 50 mm x 500 mm (longitudinal)) were treate...
M Noll, I Stephan


Structural changes, basidiomycete richness, enzyme activity and proteomic profiling of decay resistant and non-resistant woods over 18 months in soil contact
2010 - IRG/WP 10-10733
Wood decay fungi damage wood by production of enzymes that attack the structural components. The objective of this study was to better understand which suite of decay genes and proteins are expressed during biodeterioration of three different wood types in forest soil over time. Variation in decay genes and proteins were determined for pine (non-resistant), cedar (naturally durable), and ACQ-treat...
Youngmin Kang, S Diehl, L Prewitt, D Nicholas


Adsorption of ionic liquids by Scots pine wood (Pinus sylvestris L.) and beech (Fagus sylvatica L.): equilibrium and kinetic modeling
2010 - IRG/WP 10-20447
In this paper methods for the adsorption study of quaternary ammonium-based ionic liquids on Scots pine (Pinus sylvestris L.) and beech (Fagus sylvatica L) are presented. Kinetic and equilibrium adsorption of compounds were evaluated. The equilibrium data fitted very well to the Langmuir adsorption models. The highest correlation coefficients determined from the pseudo-second order kinetic model ...
J Zabielska-Matejuk, A Stangierska, M Kot


Adsorption of ACQ components in wood
2010 - IRG/WP 10-30522
To investigate the chemical adsorption capacity of copper-monoethanolamine (Cu-Mea) components on wood, the Na+ cation exchange capacity (CEC) of red pine (Pinus resinosa Ait.) was determined and compared to the adsorption capacity of free Mea and Cu-Mea complexes. The CEC increased with increasing pH. Free Mea adsorption as a function of pH followed the sodium adsorption curve except at pH over 9...
Myung Jae Lee, P Cooper


Copper preservative systems: A rapid investigation into effects of co-biocides and used treating solutions
2010 - IRG/WP 10-30541
The efficacy of various micronized and amine copper preservative systems was evaluated using soil block testing with the copper tolerant brown rot fungi, Postia placenta. The American Wood Protection Association E22 protocol was used to compare the relative efficacy of preservatives by monitoring compressive strength losses of the systems in southern pine wood. As information, the weight losses ...
T F Shupe, K Ragon, Q Wu, M H Freeman, C R McIntyre


Copper distribution in soil leached from full scale decking boards during one year
2010 - IRG/WP 10-50265
The distribution of copper in the soil under exposed decking boards after one year has been analysed. The decking boards were impregnated with copper HDO, copper quat and copper triazoles. The decking boards were pine sapwood and pressure treated in a full cell process, fixed by heating and then dried. The samples were not surface treated. Each decking sample of five boards (0.25 m2) was placed on...
F G Evans


The study of fungicidal values und sorption processes of ionic liquids- potential wood preservatives on soils
2011 - IRG/WP 11-30572
In the paper, the fungicidal activity of new ionic liquids structures, N,N-dimethylalkylamines derivatives, containing a spacer built of 7 or 10 methylene groups with nitrate(V) and tetrafluoroborate anions, didecyldimethylammonium and benzalkonium nitrate(V) were presented. The research was also conducted on the sorption of cations of ammonium ionic liquids on five types of podzolic, humic alluvi...
W Przybylska, J Zabielska-Matejuk, A Stangierska, A Skrzypczak


Adsorption boundary curve influenced by step interval of relative humidity investigated by Dynamic Vapour Sorption equipment
2011 - IRG/WP 11-40547
The adsorption of water vapour from dry conditions by Norway spruce sapwood has been investigated using Dynamic Vapour Sorption (DVS) instrumentation. This equipment allows a fast and easy data acquisition as well as enables detailed studies of sorption properties using very small sample masses. In this study, particular focus was paid to the effect of step size on the sorption isotherms. Furtherm...
E Tang Engelund, M Klamer, T Mark Venås


Durability of modified wood in UC3 and UC4. Results from lab tests and 5 years testing in 3 fields
2011 - IRG/WP 11-40562
In 2005 an extensive test program including field tests was set up in order to obtain more data on the durability and long term performance of modified wood and semi-durable wood species. One of the main challenges for modified wood is to predict accurate service life time in UC3 (use class 3, above ground) and UC4 (use class 4, in soil or fresh water contact). So far, data from in-service condi...
M Westin, G Alfredsen


Copper Migration from Micronized Copper Preservatives Treated Wood in soil contact:
2011 - IRG/WP 11-50280
Emerging formulations of preservatives made with micronized basic copper carbonates with azoles and/or quat to control copper tolerant fungi have been used to replace formulations containing soluble copper to reduce the leaching of copper and the corrosion of metal in contact with wood. This study proposes to use laboratory soil leaching test AWPA standard (E20-08) to estimate the amount of copper...
Lei Wang, D P Kamdem


Influence of soil moisture, Sarawak soil types and decay types on decay susceptibility of rubberwood and kelempayan
2012 - IRG/WP 12-10780
Wood and soils are important natural resources of the land, the former widely used as structural supports in contact with the latter. Many low durability wood species exposed to soil contact has reportedly high incidence of decay failures in poorly treated and untreated materials depending on soil types, properties and soil microbial virulence. This paper probes the relationship of the main soil t...
A H.H. Wong, P K.F. Chong, J Sabang


Effect of an antioxidant on the efficacy of organic wood preservatives in an accelerated soil contact decay test
2012 - IRG/WP 12-30583
In comparison to inorganic wood preservatives, organic biocides in transient carriers are considerably less effective when the treated wood is exposed to soil contact. Various oils are used in some formulations with pentachlorophenol to improve the efficacy. However, use of these oils imparts unacceptable properties to products used in residential applications. Consequently, there is a need to de...
D D Nicholas, J Shi, T P Schultz, L Sites


Evaluation of Five Novel Organotin(IV) Complexes as Wood Preservatives
2012 - IRG/WP 12-30590
Three selected non durable tropical wood species namely Alstonia scholaris (pulai), Macaranga triloba (mahang) and Hevea brasiliensis (rubber) were chemically impregnated with five novel organotin(IV) complexes using vacuum-pressure treatment method. The objectives of this study were to determine the treatability and efficacy of novel organotin(IV) complexes against white and brown rot decay fungi...
M M Rahman, I Jusoh, M A Affan, A Husaini


Biodegration of treated wood waste by native fungal communities of tropical soil in French Guiana
2012 - IRG/WP 12-50285
Woods have been protected with fungicides for a long time, and the effects of these fungicides on soil after being leached into the ground have turned out to be a true environmental issue. It is in this perspective that we are proposing to study fungal communities of these contaminated woods in a purpose of bioremediation. Most of precedent studies have focused on ability of some Basidiomycetes an...
A Zaremski, L Gastonguay, C Zaremski, F Chaffannel, J Beauchêne, G LeFloch


Activities of moulds on wood as a function of relative humidity during desorption and absorption processes
2013 - IRG/WP 13-10794
Three different types of indoor moulds: Penicillium brevicompactum, primary colonizer; Alternaria tenuissima, secondary colonizer and Trichoderma harzianum, tertiary colonizer, grown on wood were measured for their activities under different relative humidity levels. The activities were measured by isothermal calorimetry. The activities of the moulds changed with the change of the relative humidit...
Yujing Li, L Wadsö


Bioavailability of Bifenthrin and Fipronil against subterranean termites (Isoptera: Rhinotermitidae) in various soils
2013 - IRG/WP 13-10804
Present study was conducted to determine the toxicity and bioavailability of Biflex (Bifenthrin) and Fipronil (Phenyl pyrazole) termiticides against common termite species Heterotermes indicola (wasmann). Soil was collected from ten different areas of Lahore and was divided into sandy clay loamy (SLC) soil and sandy loamy (SL) soil after analysis. Laboratory bioassays (Topical application method a...
F Manzoor, P Mahnoor, B M Ahmed (Shiday)


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