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Non-stochiometric oxidation and ROS generation promoted by guaiacol lignin structures and lignocelluose surfaces may be a component of brown rot fungal degradation mechanisms
2019 - IRG/WP 19-10937
Model guaiacol compounds representing lignin monomers, as well as DHP-lignin and wood flour of controlled particle size were used to assess iron reduction at the pH of the natural wood cell wall. All compounds functioned as electron donors for ferric iron, with the lignin monomers demonstrating capacity for non-stochiometric reduction of iron with multiple moles of ferric ion reduced per mole of l...
Y Tamarua, M Yoshidaa, L D Eltisb, B Goodell


Difference of wood decay manner between brown-rot species
2019 - IRG/WP 19-10938
Wood blocks (Cryptomeria japonica) which were decayed by a Polyporales white-rot fungus (Trametes versicolor) and brown-rot fungi (Fomitopsis palustris, F. pinicola, and Wolfiporia cocos), respectively, were analyzed by X-ray diffraction and infrared spectroscopic methods followed by multivariate analysis. In the analyses, the differences in the cellulose crystallinities and infrared spectral patt...
R Kondo, Yo Horikawa, S Nakaba, K Ando, M Yoshida


Decay and water resistance of Siberian and European larch wood
2019 - IRG/WP 19-10941
The occurrence of larch wood is rather frequent in civil engineering. Namely, in building façades, terraces and balcony fences. In Slovenia and other central European countries, the use of the Siberian larch is especially popular. In this research, the durability against decay fungi in laboratory conditions and water exclusion ability of plantation-grown and naturally grown Siberian larch (Larix ...
B Lesar, D Krzisnik, M Humar


Natural durability of four Tunisian Eucalyptus wood species and their respective compositions in extractives
2019 - IRG/WP 19-10942
In the 50’s, Tunisia government introduced more than 11 Eucalyptus wood species. Eucalyptus species were planted in Tunisia in different arboreta throughout the country for close observation and adaptation to climate and soil. These fast-growing wood species were mainly used as fire wood, for the production of mine wood and to fight against the erosion. These tree species were adapted themselve...
S Ben Ayed, M T Elaieb, S Dumarçay, B De Freitas Homen De Faria, M-F Thévenon, P Gerardin, K Candelier


From fungal detoxification systems to wood durability in neotropical forests
2019 - IRG/WP 19-10946
White-rot fungi are able to mineralize all the wood components due in particular to an efficient detoxification system. We hypothesised that components of this detoxification systems, glutathione transferases, could be used as tools to explore the natural durability of neotropical wood species. Analysis of the interactions between six glutathione transferases of Trametes versicolor and extracts of...
T Perrot, G Salzet, N Amusant, J Duchene, E Gelhaye


Characterization of Pectinases from Brown-rot Fungus Fomitopsis palustris
2019 - IRG/WP 19-10951
Brown-rot fungi occur on softwood used as building materials and cause destructive breakdown of wood structure. Therefore, a more accurate understanding is important from the perspective of wood protection. Previous studies have reported that hyphae of brown-rot fungi go through bordered pits on tracheids when the fungi grow into softwood [Francis W.M.R.Schwarze (2007)], and torus existing in the ...
Y Tanaka, N Konno, T Suzuki, N Habu


Performance of wood decking after 5 years of exposure: verification of the combined effect of wetting ability and durability
2019 - IRG/WP 19-20647
Wood is one of the most important construction materials and its use in building applications has further expanded in recent decades. In order to enable even more extensive and reliable use of wood, factors affecting wood’s service life need to be understood. More recently, a new concept to characterize the durability of wood-based materials and to predict the service lives of wood was proposed,...
M Humar, D Krzisnik, B Lesar, C Brischke


Chemical composition, antitermite and antifungal activity of Dacryodes edulis oleoresin
2019 - IRG/WP 19-20653
Damages to wood structures and other cellulosic materials caused by wood destroying insects and fungi are estimated to several billions of dollars each year in the world. Among these, termites are considered as one of the most economically important pests for wooden structures. In the past, several wood protection chemicals like CCA, creosote, lindane or pentachlorophenol have been used. However, ...
W F Bedounguindzi, K Candelier, P E Engonga, Se Dumarcay, M-F Thevenon, P Gerardin


Hydroxyl accessibility - A brief review of deuterium exchange studies on modified wood
2019 - IRG/WP 19-20656
Wood modification imparts dimensional stability and decay resistance. The mechanism(s) by which this occurs are thought to be related to the bulking of the wood cell wall and subsequent moisture exclusion. Hence, quantification of accessible hydroxyl (OH) groups is of great interest when evaluating and increasing the understanding of the performance of modified wood. The aim of this study was to b...
G Beck, C Hill, G Alfredsen


Biocidic effect of nano metal fluorides against brown-rot fungi
2019 - IRG/WP 19-30732
Metal fluoride nanoparticles are promising because of their low water solubility, which reduces the need for fixatives required in widely used active ingredients in wood preservatives such as copper and boron. The effectiveness of nano metal fluorides was compared to sodium fluoride treated wood samples. Wood specimens treated with homo-dispersed sols of MgF2 and CaF2 were tested against brown-rot...
S M Usmani, K Klutzny, I Stephan, E Kemnitz


The development of a suitable fire retardant for Radiata pine and other species
2019 - IRG/WP 19-30744
The use of fire retardant chemicals, with the overarching aim of creating a safer environment is not a new one, however it is generally under-developed and is often afflicted with an image of environmental and health issues and misperceived high costs. There is an ever-increasing need and desire for effective fire retardancy in timbers to inhibit or suppress the combustion process. This is paramou...
B R Derham, M R Fortune


Effect ofNano-Copper Oxide on Decay Resistance of Pistachio Twig-Plastic Composite
2019 - IRG/WP 19-30750
The goal of our study was to investigate the decay resistance of pistachio twig-plastic composite treated with nano-copper oxide against the white rot fungus Trametes versicoloer and the brown rot fungus Coniophora puteana. For this purpose, wood–polypropylene composites (WPCs) containing different loadings of nano-copper oxide, namely 0, 1, 2 and 3 percent (W/W), were made from pistachio (Pista...
M R M Farahani,S Pourabdollah


Using X-ray scattering to elucidate the mechanisms behind the moisture and fungal decay resistance of epoxybutene modified wood
2019 - IRG/WP 19-40854
Chemical modification of the hydroxyl groups of wood can improve the properties of wood by providing moisture and biological resistance, as well as dimensional stability. Southern pine solid wood was chemically modified to various weight percentage gains (WPG) with epoxybutene (EpB, 8%-38% WPG). After modification, specimens were extracted with a toluene: ethanol (2:1) solution for 2 hours or wate...
R E Ibach, N Plaza


Development of beech wood thermo-chemical modification treatments based on different vinylic derivatives of glycerol and polyglycerol
2019 - IRG/WP 19-40855
In this study, a combination between chemical and thermal wood modification has been investigated. Seven types of a low concentration of 10% aqueous additive solution of vinylicglycerol [glycerol-maleic anhydride (Gly-MA), glycidyl methacrylate (GM), and Glycerol methacrylate-maleic anhydride (GM/MA(2eq))], vinylicpolyglycerol [polyglycerol-maleic anhydride (PG-MA), polyglycerol methacrylate (PGM...
M Mubarok, S Dumarcay, H Militz, K Candelier, M-F Thevenon, P Gerardin


Dimensional stability and decay resistance of montmorillonite- furfuryl alcohol modified wood
2019 - IRG/WP 19-40856
Poplar (Populus cathayana) wood was impregnated successively by organo-montmorillonite (OMMT; in concentration of 2%) and furfuryl alcohol (FA, in concentrations of 15%, 30% and 50%) in a two-step method to prepare OMMT-FA modified wood. The modified wood samples were characterized using X-ray diffraction (XRD) and field emission scanning electron microscopy (FE-SEM). Moreover, wood physical and a...
L Zhang, J Cao


Thermal performance and fire safety properties of traditional circumferential log-cabin walls
2019 - IRG/WP 19-40872
The paper describes the experiment of fire resistance of a circumferential log-cabin wall fragment using various structural modification of the gap between two log members. The influence of the gap structural modification on the criterion of fire resistance E (envelop integrity) and I (insulation) is evaluated. The evaluating criteria are represented by the development of temperatures measured in ...
S Jochim, L Makovicka Osvaldova, M Zachar, Z Danihelova


Novel approaches for improvement of dimensional, photo- and thermal stability of wood through liquefied wood polyols impregnation
2019 - IRG/WP 19-40884
The major problems encountered in both indoor and outdoor utilization of wood are due photo instability and dimensional instability. The modification of Melia dubia wood for ultraviolet resistance and dimensional stability with liquefied wood has been carried out through impregnation method under solvent free conditions. The level of impregnation in modified wood was estimated by weight perc...
A Kumar, A John, T S Mehra


Different levels of acetylation lead to groupwise upregulation of non-enzymatic wood degradation genes of Rhodonia placenta during initial brown-rot decay
2020 - IRG/WP 20-10958
Rhodonia placenta, often used as a model fungus to represent brown rot fungi, uses a two-stepped degradation mechanism to degrade wood. Regarding the overcoming of wood protection systems the initial degradation phase seems to be the crucial point. A new laboratory test enables the separation of the non-enzymatic oxidative and the enzymatic degradation phases, which has previously been proven chal...
M Kölle, R Ringman, A Pilgård


FTIR analysis of wood blocks decayed by brown-rot fungi
2020 - IRG/WP 20-10959
Calibration curves of the relative lignin contents in Cryptomeria japonica decayed by brown-rot fungi were developed with Infrared Spectroscopy and Klason technique. First, wood decay test was conducted using brown-rot fungi (Fomitopsis palusris, F. pinicola, Wolfiporia cocos, Gloeophyllum trabeum, and Neolentinus suffrutescens) and white-rot fungus (Trametes versicolor) was used as a comparison. ...
R Kondo, Y Horikawa, R Kose, M Yoshida


Performance of bio-based building materials – durability and moisture dynamics
2020 - IRG/WP 20-20666
When exposed to conditions favourable for decay, bio-based building materials can be susceptible to degradation. Their ability to withstand deterioration over time (performance) depends on the intrinsic or enhanced durability of the material as well as its wetting and drying behaviour. The effect of fungicidal components in wood is known since long. Other material characteristics, such as the mate...
L De Ligne, J Caes, S Omar, J Van den Bulcke, J M Baetens, B De Baets, J Van Acker


Resistance against marine borers: About the revision of EN 275 and the attempt for a new laboratory standard for Limnoria
2020 - IRG/WP 20-20669
Wood protection technology in the marine environment has changed over the last decades and will continue to do so. New active ingredients, newer formulations, and novel wood-based materials including physically- and chemically-modified wood, together with increasing concerns over environmental impacts of wood preservatives, urgently demand a major revision of EN 275 “Wood preservatives – Deter...
S Palanti, S Cragg, R Plarre


Limiting Polysaccharide Motion Protects Wood From Decay
2020 - IRG/WP 20-40890
It is well known that chemical modifications to improve decay resistance also reduce the equilibrium moisture content (EMC) of wood. The mechanism of this action, however, has been the subject of much debate. Several groups have suggested that decay resistance is a result of lower diffusion rates of fungal degradation agents through the wood cell wall. A recent paper explained the fundamental prin...
C G Hunt, S L Zelinka, J E Jakes


Biological durability of sapling wood
2020 - IRG/WP 20-10967
Sapling-wood products from different wood species such as willow (Salix spp.) and Common hazel (Corylus avellana) are frequently used for gardening and outdoor decoration purposes. Remaining bark is suggested to provide additional biological durability. Even for temporary outdoor use it seemed questionable that durability of juvenile sapwood can provide acceptably long service lives of horticultur...
C Brischke, L Emmerich, D G B Nienaber, S Bollmus


Validating a short-term laboratory method to assess the resistance of timber to biodegradation by marine wood-borers
2021 - IRG/WP 21-10975
Novel approaches to protecting wood in coastal and marine environments are needed as the use of traditional broad-spectrum biocides are now restricted. Wood is widely utilised in marine environments where it can be rapidly degraded by wood-boring organisms, causing billions of dollars of damage per annum. Biocidal compounds such as CCA and creosote have been popular treatments for timber products ...
L S Martin, J R Shipway, G P Malyon, S M Cragg


Experience Experience from over 20 years of field trials of resin treated wood – Marine borer resistance of MMF and DMDHEU modified wood
2021 - IRG/WP 21-10976
In 1999 a field test of Scots pine treated with MMF (Methylated Melamine Formaldehyde) resin and acetylated Scots pine post treated with MMF resin was started. Six years later a commissioned full NWPC test for BASF of Belmadur® (DMDHEU resin treated wood) was started at the same site. The testing, according to European Standard EN 275, was done in a bay by Kristineberg Marine Research Station o...
M Westin, P Larsson Brelid, A O Rapp, J Habicht


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