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Investigations into the use of Maleic Anhydride/Sodium Hypophosphite as a Wood Modification Process
2020 - IRG/WP 20-40891
The formation of crosslinked bonds between wood constituents is believed to be an effective way to stabilize wood against wet conditions. The possibility to use maleic anhydride (MA) combined with sodium hypophosphite (SHP) as crosslinking agents was studied, using Scots pine sapwood and a model compound. The modified wood showed weight gain and bulking effect after treatment and subsequent Soxhle...
I Kim, D Jones, O Karlsson, D Sandberg, O N Antzutkin, F Ullah Shah


Sterilization of Large Timbers during Preservative Treatment: How Quickly We Forget
2020 - IRG/WP 20-40902
Air seasoning is a common method of moisture management in utility poles and is done de facto during pole storage prior to treatment. However, extended air drying prior to treatment encourages fungal attack and can facilitate establishment of decay fungi in poles before a protective preservative barrier is applied. This problem can be mitigated by proper air-seasoning methods coupled with heat ste...
G Presley, J Cappellazzi, M Konkler, K Maguire, R Nelson, J J Morrell


Dynamics of fungi colonization on the surface of Scots pine wood during natural weathering in different European climate zones
2022 - IRG/WP 22-10984
Wood The presence of fungi leads to biomaterial decay and/or changes in aesthetical appeal. The start of fungi colonization as well as the following growth on wood are primarily influenced by four factors: ambient temperature, moisture history of the object, access to oxygen, and intrinsic properties of the exposed wood, considered here as a source of nutrients for microorganisms. A prevalence of ...
F Poohphajai, O Myronycheva, O Karlsson, L Rautkari, J Sandak, A Sandak


Biological assessment of bio-based phase change materials in wood for construction applications
2022 - IRG/WP 22-40935
Solid wood can serve multi-functionality for energy savings in buildings. The study reveals the results of bio-deterioration and degradation of solid Scots pine wood used to incorporate single or multicomponent fatty acid mixtures as bio-based phase change materials (BPCMs). The sapwood samples were impregnated with capric acid (CA), methyl palmitate (MP), lauryl alcohol (LA) and a mixture of coco...
S Palanti, A Temiz, G Köse Demirel, G Hekimoğlu, A Sari, M Nazari, J Gao, M Jebrane, T Schnabel, N Terziev


Improvement of durability of Scots pine against termites by impregnation with citric acid and glycerol followed by in situ polyesterification
2023 - IRG/WP 23-30777
Scots pine (Pinus sylvestris) sapwood samples were impregnated with solution containing citric acid (CA) and glycerol (Gly) followed by heating 140 °C according to already described procedure (L'hostis et al. 2018). The resulting modified woods were then used to evaluate the effect of chemical modification on the durability against termites. Two kinds of experiments were conducted for this purpos...
M Mubarok, J Damay, E Masson, E Fredon, Y S Hadi, I W Darmawan, P Gerardin


New wood-modification process based on grafted urethane groups: Durability of carbamamylated Scots pine (Pinus sylvestris L.) wood
2023 - IRG/WP 23-40974
Substituting commonly used toxic preservatives with wood modification treatments can make the wood material less prone to water and moisture uptake. This approach favours a more sustainable protection of wood against biodegradation. In this study, Scots pine sapwood was full-cell impregnated with an aqueous solution of urea (30%), dried at 40°C for 24h, and subsequently heat-treated at 150°C for...
C-F Lin, O Myronycheva, O Karlsson, D Jones, D Sandberg


Confocal laser scanning microscopy of a novel decay in preservative treated radiata pine in wet acidic soils
1997 - IRG/WP 97-10215
Light microscopy of radiata pine (Pinus radiata D. Don) field test stakes (20x20x500mm3) exposed in wet acidic (pH 3-4) soil for 12 - 24 months showed predominance of an unusual type of decay characte-rised by tunnelling attack of wood cell walls. After two years decay was moderate to severe in wood treated to ground contact CCA specifications and also equivalent retentions of creosote, and a numb...
R N Wakeling, Ying Xiao, A P Singh


Screening potential preservatives against stain and mould fungi on pine timber in Zimbabwe
1995 - IRG/WP 95-30063
The search for environmentally and toxicologically safer chemicals for use in the timber preservative industry against stain and mould fungi has been intensified during the past few years. Results of field tests with two chemicals previously evaluated in the laboratory are presented. The conventional sodium pentachlorophenate was the more efficacious chemical against stain and mould fungi, providi...
A J Masuka


Dimensional stability and decay resistance of hot-melt self-bonded particleboard by surface benzylated pine chips
1991 - IRG/WP 3652
Akamatsu (Pinus densiflora Sieb. et Zucc: Japanese red pine) particles were pretreated with 40% NaOH solution and benzylated with benzyl chloride, and the surface of particle was converted into meltable materials. Hot-melt self bonded particleboard having smooth and high glossiness surface was prepared by hot pressing at 150°C and 1.96 MPa without using any conventional adhesives. Dimensional sta...
M Kiguchi, K Yamamoto


Strength loss associated with steam conditioning and boron treatment of radiata pine framing
1987 - IRG/WP 3438
The combined effect of included defects and wood moisture content on the strength loss of second rotation radiata pine framing following conventional steam conditioning is investigated. The green Modulus of Elasticity (MOE) is reduced by approximately 13% after steaming. When dried after steaming, however, neither the MOE nor MOR is significantly different from unsteamed dried controls....
M J Collins, P Vinden


Types of decay observed in CCA-treated pine posts in horticultural situations in New Zealand
1984 - IRG/WP 1226
The few reported failures of 11-12-year-old horticultural posts in New Zealand in 1982 were caused by brown-rot. A subsequent survey of CCA-treated posts in all the major horticultural areas has revealed decay of many posts. A microscopic examination of these posts has shown decay by brown-rot, white-rot, soft-rot and bacteria. Several types of bacterial decay have been observed....
J A Drysdale, M E Hedley


Light organic solvent preservative treatment schedules for New Zealand-grown radiata pine
1986 - IRG/WP 3379
The influence of pressure differential and treatment time on preservative uptake and distribution in radiata pine heartwood and sapwood is investigated. Treatment schedules are defined which minimise solvent usage but ensure complete sapwood penetration and optimise heartwood penetration....
P Vinden


Termite resistance of pine wood treated with chromated copper arsenates
1997 - IRG/WP 97-30128
Two four-week, no-choice laboratory tests were performed with CCA-treated southern yellow pine and radiata pine against Formosan subterranean termites, Coptotermes formosanus. CCA retentions as low as 0.05 kg/m3 (0.03 pcf) provided protection from all but light termite attack (rating of 9 on a 10-point visual scale). Similar and consistent light attack on wafers containing retentions as high as 6....
J K Grace


Durability of pine modified by 9 different methods
2004 - IRG/WP 04-40288
The decay resistance was studied for pine modified by nine methods of wood modification: 1) Acetylation, 2) Treatment with methylated melamine resin (MMF), 3) Acetylation followed by post-treatment with MMF-resin, 4) Thermal modification, 5) Furfurylation, 6) Maleoylation (using water solution of MG or ethanol solution of maleic anhydride), 7) Succinylation, 8) NMA-modification and 9) modification...
M Westin, A O Rapp, T Nilsson


Performance of Tebbacop in laboratory, fungus cellar and field tests
2000 - IRG/WP 00-30222
A novel organo-copper wood preservative ("Tebbacop") has been exposed to 12 years fungus cellar testing and 6 years above ground field testing. In the fungus cellar, Tebbacop at a retention of 0.053% Cu m/m oven dry wood out-performed CCA at a retention of 0.55% m/m oven dry wood. In above ground tests, L-joints treated to a Tebbacop retention of 0.012% Cu are performing as well as joints treated ...
M E Hedley, D R Page, B E Patterson


Creosoted radiata pine by non-pressure methods
1988 - IRG/WP 3486
Posts of Pinus radiata have been impregnated with creosote by immersion for 1, 3, and 7 days, and by hot-and-cold open tank with hot bath temperatures at 40°C and 60°C. On the basis of the retention rates obtained, suitable procedures are described for wood elements that are going to be in ground contact, and an analysis is made of the way in which the variables tested affect the results....
M V Baonza Merino, C De Arana Moncada


Light organic solvent preservative treatment of glue-laminated radiata pine
1986 - IRG/WP 3380
The high permeability of radiata pine (Pinus radiata D. Don) is associated with ray-tissue and in particular the cross-field pits linking ray-tissue to tracheids. This pathway is absent in the tangential grain direction, leading to poor preservative penetration when treatment is restricted to the radial face - for example, timber fabricated into glue-laminated beams....
P Vinden


Dimensional stabilization of wood with dimethylol compounds
1987 - IRG/WP 3412
This study showed that a substantial degree of dimensional stability can be imparted to wood by crosslinking with low concentrations of dimethyloldihydroxyethyleneurea. It was demonstrated that by selecting the right catalyst system the cure temperature can be reduced to the point that strength loss of the treated wood is minimized....
D D Nicholas, A D Williams


Steam conditioning of partially dried radiata and Corsican pine roundwood
1988 - IRG/WP 3499
The effect of partial air drying prior to steam conditioning and its effect on subsequent preservative treatment by the Bethell treatment process was investigated. A high standard of preservative treatment was obtained in both radiata and Corsican pine, irrespective of whether a period of partial drying was imposed before or after steam conditioning....
P Vinden, D R Page, K Nasheri


The effect of treatment method on CCA efficacy in Corsican pine
1992 - IRG/WP 92-3723
As part of a study into the influence of application method on preservative efficacy Corsican pine (Pinus nigra) samples (50 x 50 x 400 mm³) were treated with a CCA formulation using Bethel, Steam/Bethel or Lowry processes. Full penetration of the preservative at a gross level was confirmed using a copper disclosing reagent. The preservative was allowed to fix and then samples were converted into...
P R Newman, R J Murphy


Movement of boron from fused boron rods implanted in Southern pine, Douglas fir, red oak, and white oak timbers
1995 - IRG/WP 95-30061
This paper reports the distribution of boron from fused boron rods installed into six-inch (15.2 cm) square timbers of Douglas-fir, Southern Pine, red oak and white oak exposed aboveground. The composition and size of rods was: sodium borate and sodium borate-copper oxide (8.5 x 100 mm²); sodium borate-copper, sodium borate and boric oxide-copper oxide (12 x 76 mm²). The boric acid equivalent wa...
T L Highley, L Ferge


Above ground performance of CCA-treated fingerjointed lumbe
1993 - IRG/WP 93-40003
Studs made from short lengths by finger jointing are becoming more commonly used in North America. Recently Forintek has received enquiries about the performance of such material in a treated form. Treated and untreated nominal 2x4 inch² spruce-pine-fir (SPF) studs exposed above ground for 12 years in southwestern British Columbia were evaluated for evidence of decay. Despite shallow preservative...
P I Morris, G E Troughton


Blue-stain fungi (Ceratocystis spp.) found in Spain on pine woods
1989 - IRG/WP 1410
So far, there is only a very limited reported description of the different Ceratocystis spp. present on fresh wood in Spain. So, the main goal of this work has been the identification of species of this genus causing blue-stain on Pinus pinaster A. Ait. and Pinus sylvestris L. woods. We have also investigated the relationship between the species found and their propagation vectors (insects and win...
M T De Troya, A M Navarrete


Study of the natural durability and impregnability of a metropolitan species of tree
1986 - IRG/WP 2261
The current and predictable evolution of construction timber supply conditions is motivating research for a more efficient utilization of native woods. It is now important to determine statistically reliable impregnability values on a national scale, and to evaluate the natural durability of woods recently introduced in France, or economically important native woods....
M E Mathieu


CCA fixation experiments. Part 2
1989 - IRG/WP 3505
CCA fixation in wood was measured by both squeezing solution from treated wood that had not been dried and analyzing the solution for copper, chromium and arsenic, as well as using a chromotropic acid test to detect the presence of chromium VI. Both methods provide useful information on the CCA fixation process and illustrate that chromium VI disappears as CCA becomes fixed within wood....
W S McNamara


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