Your search resulted in 966 documents. Displaying 25 entries per page.
Chemical modification of Scots Pine Sawdust by mixed anhydrides
2008 - IRG/WP 08-40439
By making react mixtures containing acetic-fatty anhydrides on Scots pine sawdust (SPS) without any solvent or catalyst; we synthesized mixed acetic-fatty esters of SPS. Such mixtures were synthesized by reaction between a carboxylic acid and acetic anhydride. These mixtures were obtained after reaction of acetic anhydride and a fatty acid that yields at equilibrium a mixture of five compounds: ac...
J Peydecastaing, E Borredon, S El Kasmi
Comparison of laboratory and natural exposure leaching of copper from wood treated with three wood preservatives
2008 - IRG/WP 08-50258
Standard and non-standard laboratory and field leaching tests were used to compare copper leaching from wood treated to above ground and ground contact specified retentions for three wood preservative systems, CCA-C, ACQ-D and a micronized copper formulation with quat DDAC as co-biocide. Copper leaching was highest for the ACQ formulation. Percent leaching was lowest for the micronized copper sy...
P A Cooper, Y T Ung
Durability and fungal colonisation patterns in wood samples after six years in soil contact evaluated with qPCR, microscopy, TGA, chitin- and ergosterol assays
2009 - IRG/WP 09-20402
There is a need to establish new objective and sensitive methods for early detection and quantification of decay fungi in wood materials. Molecular methods have proven to be a useful tool within wood protection issues, however, this field is still poorly explored and so far relatively few have used these methods within the field of wood deterioration. Among the techniques used in the indirect quan...
A Pilgård, G Alfredsen, I Børja, C Björdal
Wart Morphology can Distinguish White Cypress Pine from the Less Durable Species, Black Cypress Pine
2009 - IRG/WP 09-20406
White cypress pine (Callitris glaucophylla) wood is durable enough to be used outdoors, but occasionally there are reports of its premature failure in ground contact, which may be due to its substitution by the less durable species, black cypress pine (C. endlicheri). It has been difficult to prove this, however, because the woods of both species are very similar in structure and cannot be separat...
R Heady, R Cunningham, P Evans
Copper to quat ratio in alkaline copper quat (ACQ) wood preservative - Effects on fixation and leaching of preservative components in red pine
2009 - IRG/WP 09-30496
This study investigates the effect of the relative proportion of copper oxide (CuO) to didecy dimethyl ammonium carbonate (DDACb) in an alkaline copper quat (ACQ) formulation on the rate of copper fixation or stabilization and the resistance of treated wood to leaching of copper and quat (DDACb). Red pine samples were treated with ACQ, having CuO to DDACb ratios of 2:1 (the normal ratio for ACQ-D...
S Pankras, P A Cooper, T Ung, L Awoyemi
Re-Distribution of Copper in the Cell Walls of Wood Treated with Micronized Copper Quat
2009 - IRG/WP 09-30506
Wood treated with copper-based preservatives to be used in ground contact may fail to inhibit soft rot fungi if penetration of copper into the cell wall is insufficient. Preservatives containing soluble copper are known to penetrate the cell wall; however, it is not known whether preservatives containing particulate copper will also migrate into the cell wall in sufficient quantities to control so...
R Stirling, J Drummond
Component leaching from CCA, ACQ and a micronized copper quat (MCQ) system as affected by leaching protocol
2009 - IRG/WP 09-50261
Leaching results for Cu, Cr and As (CCA) and Cu (ACQ and MCQ) from southern pine are compared for laboratory tests (AWPA E11, and draft OECD methods I and II) and natural weathering of horizontally and vertically oriented lumber samples over two seasons. This paper expands on results and comparison of results presented at the IRG regional meeting in Costa Rica in Dec 2008 (Cooper and Ung 2008) a...
P A Cooper, Y T Ung
Rapid Microwave-Assisted Acid Extraction of Metals from Chromated Copper Arsenate (CCA)-Treated Southern Pine Wood
2009 - IRG/WP 09-50262
The effects of acid concentration, reaction time, and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with three different acids (i.e., acetic acid, oxalic acid, and phosphoric acid) was investigated using in microwave reactor. Oxalic acid wa...
Bin Yu, Chung Y Hse, T F Shupe
Microscopy evaluation of microbial decay patterns in wood stakes after 6 years in soil contact
2010 - IRG/WP 10-10715
Most studies on wood modification have so far been concerned with service life predictions rather than investigating the decay protection mechanism. Very little is known about the mode of action of these new treatments and about the strategies used by wood degraders in order to utilize the wood material despite a treatment. Access to such knowledge would allow further modification and improvement ...
A Pilgård, C G Björdal
Frequency of fungal decay in softwood windows in Germany
2010 - IRG/WP 10-10725
Knowing how often fungal decay occurs is a fundamental basis for general recommendations of preservative measures. To optimize the German recommendations for chemical wood preservation of windows made out of pine or spruce more than 2000 windows have been inspected. All windows had an opaque coating and were between 2 and 17 years old. The selection of the inspected windows was kept as randomly as...
D Lukowsky, O Moarcas, A Luette
Methods for Studying Penetration Depth of Wood Protection Products
2010 - IRG/WP 10-20432
EN 152 is an accepted standard in Europe for measuring how deep a wood protection product penetrates into the surface of treated pine wood. The method has provided consumers with a wide assortment of products that meet the specifications outlined in the standard. Because the test takes 8 or more months to carry out, artificial ageing procedures have evolved in order to standardize and speed up the...
K Hansen, L Sites, D D Nicholas
Use of Internal Remedial Treatment to Extend Wood Life at the Fort Vancouver National Historic Site
2010 - IRG/WP 10-30525
The condition of wood in a reconstructed fur trading fort was assessed over a 30 year period. Poor initial treatment had resulted in the development of extensive early decay. While supplemental treatment with chloropicrin and methylisothiocyanate had arrested the attack, the results suggested that remedial treatments were unable to completely overcome the initial problems associated with treatmen...
C S Love, C Freitag, J J Morrell
A comparison of the chemistry of alkaline copper and micronized copper treated wood
2010 - IRG/WP 10-30528
This paper discusses the chemistry of the reaction of alkaline copper and micronized copper with wood. The objective of this study is to examine the copper species produced in wood during the fixation reaction using electron paramagnetic resonance (EPR) spectroscopy. The initial experiments (phases 1 to 2) were designed to confirm the effect of time of treatment and solution concentration on the s...
Wei Xue, P Kennepohl, J N R Ruddick
Evaluation of ACQ-D treated Chinese fir and Mongolian Scots pine with different post-treatments after 20 months of exposure
2010 - IRG/WP 10-30530
The performance of alkaline copper quat-type D (ACQ-D) treated Chinese fir (Cunninghamia lanceolata Hook.) and Mongolian Scots pine (Pinus sylvestris Linn. var. mongolica Litv.) stakes after 20 months exposure in Chengdu and Guangzhou of southern China were evaluated according to AWPA standard E07-07. The ACQ-D treatments used two concentration levels (0.5 and 1.0%) and four different post-treatme...
Lili Yu, Jinzhen Cao, Wei Gao, Haitao Su
Treatment of Scots pine wood with oil in water and water in oil emulsion systems: Effects on boron leaching and water absorption
2010 - IRG/WP 10-30535
The aim of this study was to investigate the water absorption and water repellent efficiency of oils and oil water emulsions [oil-in-water (O/W) and water-in-oil (W/O)] and possibilities of reducing the amount of boron leaching from treated wood. Scots pine wood samples treated with waste or sunflower oil and water formulations contained 3%BA. The level of water absorption and water repellent effi...
E D Tomak, Ü C Yildiz, A Can
Copper nanoparticles in southern pine wood treated with a micronised preservative: Can nanoparticles penetrate the cell walls of tracheids and ray parenchyma?
2010 - IRG/WP 10-30547
This study tests the hypothesis that copper nanoparticles can penetrate the cell walls of southern pine wood treated with a micronised preservative. We examined the nanodistribution of particles in tracheid and ray parenchyma cell walls using state-of-the-art HR (High Resolution)-TEM and HR-STEM (Scanning Transmission Electron Microscope)-EDX. These devices are capable of atomic-scale resolution. ...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans
Biological degradation of acetylated wood after 18 years in ground contact and 10 years in marine water
2010 - IRG/WP 10-40522
This paper addresses the resistance to biological degradation of acetylated wood.
Firstly, it presents results from an EN 252 test after 18 years’ exposure. The test is still running in Nordic NWPC test fields, Simlångsdalen in Sweden and Viikki in Finland. Results from this test were presented after 5 years’ exposure ( IRG/WP 97-30139), and showed that the resistance of acetylated wood wit...
P Larsson Brelid, M Westin
Testing of decay resistance of sapwood and heartwood of thermally modified Scots pine and Norway spruce
2010 - IRG/WP 10-40523
Thermal modification at elevated temperatures changes the chemical, biological and physical properties of wood. One of the main targets of thermal modification is to increase the biological durability and decay resistance of wood. Although the effects of thermal modification on wood have been widely studied, the significance of sapwood and heartwood on the resistance of thermally modified wood has...
H Viitanen, S Metsä-Kortelainen
Microwave-Assisted Organic Acids Extraction of Chromate Copper Arsenate (CCA)-Treated Southern Pine
2010 - IRG/WP 10-50267
The extraction effects of acid concentration, reaction time and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with two different organic acids (i.e., acetic acid and oxalic acid) was investigated using a microwave reactor. Oxalic acid was e...
Bin Yu, Chung Y Hse, T F Shupe
Combined Effect of Boric Acid and Waste Oil Treatment on Boron Leaching
2010 - IRG/WP 10-50268
In this study it was aimed to investigate the boron leaching amounts in Scots pine wood samples treated with boric acid (BA) and waste oil (WO) alone or by dual treatment. The level of water absorption and water repellent efficiency were determined with cyclical wetting tests, total of 336 hours. Wood samples that have both covered and uncovered transversal section were impregnated with 3% boric a...
Ü C Yildiz, E Dizman
Basidiomycete colonization of Scots pine sapwood quantified by qPCR and TGA
2011 - IRG/WP 11-10750
Scots pine (Pinus sylvestris L.) is an important softwood species in Northern Europe and is frequently used as material for various wood protection systems. In Europe, EN 113 is the standard basidiomycete laboratory durability test method, using mass loss as evaluation criteria. In this paper quantitative real-time PCR (qPCR) and thermogravimetric analysis (TGA) was used to characterize coloniza...
G Alfredsen, S Bollmus, T K Bader, K Hofstetter
The effects of acetylation level on the growth of Postia placenta
2011 - IRG/WP 11-10751
To understand the defence mechanisms utilized by decay fungi when exposed to different wood protection systems the study of gene expression can give us some answers. When the DNA sequences are known, primers can be designed to detect transcripts of genes with gene products related to basic cellular processes and hyphal growth. The characteristic gene products induced in different fungi by differen...
A Pilgård, G Alfredsen, C G Fossdal, C J Long II
Sample Origin Influencing the Leachability of Wood Preservatives
2011 - IRG/WP 11-20474
The aim of this study is to see if the raw material influences fixation and leachability of wood preservatives. Moving towards more eco-friendly and –concious society, the wood industries must adjust itself to new rules and regulations. Greener solutions in wood protection are being tested and introduced, older systems are being improved, but questions still arise concerning some elements curren...
K Kängsepp. E Larnøy, P Meier
LOSP for glulam, when should the treatment be applied?
2011 - IRG/WP 11-30555
Treatment options for outdoor above-ground (H3) exposed glulam of Pinus radiata and P. elliottii were examined. Beams were treated with azole LOSP (containing a zinc tracer) aiming for retentions of 35-40 l/m3 or 70-80 l/m3. Treatment was conducted either before or after gluing. TBTN LOSP and CCA were included as comparative treatments. Test specimens for exposure were cut after treatment, while w...
L J Cookson
Copper Nanoparticles in Southern Pine Wood Treated with a Micronised Preservative: Nanodistribution of Copper in the Pit Membrane and Border of an Earlywood Bordered Pit
2011 - IRG/WP 11-30566
Copper nanoparticles can penetrate the cell walls of unlignified parenchyma cells in southern pine wood treated with a micronised wood preservative, but they are excluded from lignified tracheid walls. This paper extends these observations to include the cell wall layers of the bordered pit. Focused ion beam and ion milling were used to make an ultra-thin section of the cell wall layers of an earl...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans