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The role of chromium in wood preservatives under BPD - a review and the current situation in Europe
2008 - IRG/WP 08-30468
Already during the IRG-meeting in Trømso a paper was presented to give an overview regarding the situation on chromium (JÜNGEL et al. 2006). Already in that year there was an increased attempt to achieve a science-based correct and harmonised solution in Europe regarding the chromium-question by the European Commission. Nevertheless the competent authorities (CAs) and the industry were similarly...
P Jüngel, S Hellkamp


Formation and Structure of Metal Azole Complexes
2008 - IRG/WP 08-30469
Divalent copper and zinc complexes with metal:azole ratio 1:2 were readily formed at room temperature with the fungicides tebuconazole and propiconazole. The structure of copper and zinc tebuconazole acetate and zinc cis-propiconazole chloride were examined by X-ray crystallography. In copper tebuconazole acetate, the copper atom lies on a crystallographic inversion centre and is coordinated to tw...
P D Evans, K J Schmalzl, C M Forsyth, G D Fallon, S Schmid, B Bendixen, S Heimdal


Penetration Depth of Borates in Historic Wooden Structures in Virginia City Montana
2008 - IRG/WP 08-30475
Virginia City, Montana contains some of the best preserved examples of gold boom construction in the United States. Unfortunately, even the dry climate and fortuitous lack of fire have not prevented decay from claiming parts of the historic fabric. This project aims to determine if borates should be integrated into the preservation plan of the Montana Heritage Commission. Solutions of disodium ...
A A Turner


Treatment of Selected Lesser Used Timber Species against Subterranean Termites using Heartwood Extracts from Teak (Tectona grandis) and Dahoma (Piptadeniastrum africanum)
2008 - IRG/WP 08-30476
Lesser used timber species represent a valuable material for all-purpose uses. However, most of them are not durable. They are, for effective utilization, often treated with all manner of toxic synthetic substances to enhance their natural durability, especially in the tropics where conditions favour their deterioration. Most of these toxic synthetic substances often pose a threat to the environme...
A Asamoah, C Antwi-Boasiako, K Frimpong-Mensah


Effect of wood polymers degradation during heat treatment on extracellular enzymatic activities involved in beech degradation by Trametes versicolor
2008 - IRG/WP 08-40392
Effect of heat treatment on extracellular enzymes involved in wood degradation by Trametes versicolor was investigated. Heat-treated and untreated beech blocks were exposed to T. versicolor on malt agar medium and extracellular enzymatic activities investigated. A strong ABTS oxidizing activity has been detected during the first stage of colonization in both cases, while cellulase activities are m...
S Lekounougou, G Nguila Inari, M Pétrissans, S Dumarçay, J P Jacquot, E Gelhaye, P Gérardin


Heat treatment, thermal treatment, thermal degradation of wood, carbon nanotubes and Damascus steel swords. What do they all have in common?
2008 - IRG/WP 08-40399
Thermal degradation of wood is a well known phenomenon. Yet heat-treatment of wood can also provide protection for wood against certain environmental hazards. This paper explores some of the aspects of thermal degradation of wood fiber at relatively low temperatures with a surprising result. Carbon nanotubes (CNTs) were produced when a specific heating regime was used to carbonize the wood fiber. ...
Xinfeng Xie, B Goodell, Yuhui Qian, G Daniel


Accelerated fixation of ACQ-D treated Chinese fir with different post-treatments
2008 - IRG/WP 08-40400
With the enhanced focus on the environmental impact of the preservative-treated wood in recent years, it is necessary to perform some post treatments to prevent contamination of soil and ground water and reduce copper losses from ACQ treated wood in service. In this study, the potential of hot air, hot water, steaming and microwave post treatments to accelerate the fixation of copper in ACQ-D trea...
Lili Yu, Jinzhen Cao, P A Cooper


Effects of acetic acid and nitric acid pre-treatment on copper content of spruce wood treated with CBA-A and CCA
2008 - IRG/WP 08-40406
This work investigates the effects of nitric acid and acetic acid on compression strength values and copper retention contents of refractory spruce wood (Picea oriental L.) treated with the waterborne preservative Copper azole, (CBA-A, Tanalith-E 3492) and copper / chrom / arsenic (CCA). Before the CBA-A and CCA treatment, the samples were immersed in 500 ml of nitric and acetic acid solutions for...
S Yildiz, E Dizman, Ü C Yildiz


Thermal treatment of Nigerian-grown Albizzia zygia and Funtumia elastica wood in soy oil medium.
2008 - IRG/WP 08-40413
Thermal treatment in soy oil medium is one of the techniques used as a substitute to the chemical treatment in wood preservation. However, the effects of this technique vary from one species to another and hence the need to investigate the response of individual species to it. Thermal treatment of air-dried Nigerian-grown Albizzia zygia and Funtumia elastica wood was carried out in a vessel contai...
L Awoyemi


Bending Properties of Southern Pine Treated with Micronized Preservative Systems
2008 - IRG/WP 08-40414
This study indicates that treatment of southern pine with micronized copper systems have no deleterious effect on the residual strength property values. No statistical differences between wood treated with micronized systems and water-treated controls were noted when means were compared using either Tukey’s test or S-N-K mean comparison tests. Using the more discriminating Least Squares anal...
H M Barnes, G B Lindsey, J Hill, M Pompeo, R Hodge


The Effect of Heat Treatment on Water Absorption and Dimensional Stability of Anatolian Chestnut (Castanea sativa Mill.) wood
2008 - IRG/WP 08-40407
The heat treatment of wood is an environment-friendly method for wood preservation. This process improves wood’s resistance to decay and its dimensional stability. However, mechanical properties decrease in different ration because of density loss as a result of heat treatment. In this study, the effect of heat treatment on water absorption and dimensional stability at different relative humidit...
G Gunduz, D Aydemir


The effect of treatments in boron steaming medium on boron leaching and strength properties of wood
2008 - IRG/WP 08-40409
The combined effect of boric acid impregnation together with boron steaming and steaming heat treatments were evaluated in this study. Boric acid pre-treated wood samples and untreated ones subjected to steaming heat and direct steaming treatment in a close reactor at 13 bar pressure and 180 ºC for 30 minutes. Compression strength parallel to grain of wood samples, leaching test and pH measuremen...
E D Tomak, Ü C Yildiz, S Yildiz, E Pesman


Changes in hygroscopic, mechanical and surface properties of Scottish-grown Sitka Spruce (Picea sitchensis) wood subjected to dry heat treatment
2008 - IRG/WP 08-40415
Heat-treatment is a wood modification method which has been used to some extent in improving timber quality. However, the main limitation in the use of this technique despite its numerous advantages is the adverse effects on the various properties associated with the use of wood as an engineering material. Dry heat treatment of Scottish-grown Sitka spruce (Picea sitchensis) wood was carried out at...
L Awoyemi, M C Jarvis, A Hapca


Effects of CCB on wood strength of Eastern spruce (Picea orientalis L.)
2008 - IRG/WP 08-40416
The effects of CCB (chromate copper boron) on the static bending properties of Eastern spruce (Picea orientalis L.) based on MOE (modulus of elasticity) and MOR (modulus of rupture) were evaluated after full-cell vacuum/pressure treatment using a 3.0 % concentration followed by kiln-drying at 15 and 30 % moisture contents with heating the preservative at 30 and 40 ºC. The results showed that MOE ...
I Usta, M Hale


Bi-oleothermal treatment of wood at atmospheric pressure: resistance to fungi and insects, resistance to weathering and reaction to fire results
2008 - IRG/WP 08-40418
Bi-oleothermal process is a simple treatment which has been developped by CIRAD in cooperation with FCBA. It allows a deep impregnation of wood with hydrophobic products using cheap facilities. The process includes two steps at atmospheric pressure. The first one is a dipping of wood samples in a hot oil bath (between 110 °C and 200°C) which creates an overpressure inside the wood. The second on...
L Podgorski, I Le Bayon, I Paulmier, J-D Lanvin, V Georges, D Grenier, H Baillères, J-M Méot


The effects of zinc borate treatment of wood strands on some technological properties of oriented strandboard (OSB)
2008 - IRG/WP 08-40419
In this study, influences of zinc borate treatment on some technological properties of oriented strandboard (OSB), from aspen wood (Populus euroamericana cv.) were evaluated. Therefore, a total of nine panels with dimensions of 40 cm by 40 cm by 1.8 cm and with an average target density of 0.65 g/cm3 were manufactured under the laboratory conditions. Experimental panels were manufactured at two di...
A D Çavdar, H Kalaycioglu, G Nemli


Effect of steam on fixation of Cu-amine preservative treated wood
2008 - IRG/WP 08-50251
The rates of copper fixation in copper amine preservative treated wood were investigated with different fixation conditions (20° with drying and 50° without drying) and post-steaming. We also measured the degree of leaching for other biocide components (azoles, quatz, and Cu-HDO). Treatments conditioned at 20° with drying required 50 days or more to fix in woods. While copper was stabilized i...
Sung-Mo Kang, In-Yong Hwang, Suk-Kuwon Kim


Thermochemical Remediation of Preservative-Treated Wood
2008 - IRG/WP 08-50254
Remediation methods continue to be developed and refined for CCA-treated wood in order to divert this material from landfills and create secondary products from the wood fiber. A two-step thermochemical remediation method was developed to assess the efficiency of metal removal from CCA-treated spruce flakes. Nearly all the metals (As, Cr, and Cu) were thermochemically extracted from chromated copp...
R Sabo, C A Clausen, J E Winandy


Measurement of wood decay by dynamic MOE in an accelerated soil contact test
2008 - IRG/WP 08-20390
Current laboratory and field testing of preservatives involves various techniques to determine the extent of fungal attack, including visual inspection, mass loss, and static bending and compression strength measurements. The objective of this study was to compare decay measurement by conventional compression strength versus dynamic MOE, employing small wood stakes in an accelerated laboratory so...
Gan Li, D D Nicholas, T P Schultz


Above Ground Field Testing – Influence of test method and location on the relative performance of various preservative systems
2008 - IRG/WP 08-20393
Standardized above ground tests such as the lap-joint or test deck methods can be very slow in producing useful information on the relative performance of wood preservative systems. It often requires many years for decay to develop in wood treated to sub-optimal concentrations of standardized preservatives, making relative comparisons of performance between new systems and established preservativ...
A Zahora


Chemical Analysis in Production Quality Control at Wood Treatment Plants
2008 - IRG/WP 08-20396
Analysis methods for quality control analysis in wood treatment plants have evolved with the changes in treatment preservative chemistries and analytical instrument technology. The basic hydrometer specific gravity measurements used for solution strength and classic wet chemistry methods for wood have given way to instrumental techniques such as X-ray fluorescence, automatic titrator, and HPLC. No...
P Walcheski, L Jin


Effectiveness of MOQ® OX 50 (CCB-Oxide) wood preservative – Part 2: Field tests
2008 - IRG/WP 08-30483
MOQ® OX 50 is a chromated copper borate preservative known around the world as CCB. In Brazil, this product is the only CCB-oxide type preservative with fungicide and insecticide properties registered at the Brazilian Institute for the Environment and Renewable Resources (IBAMA) that complies with the requirements of the Brazilian and European markets for preserved wood. For over five decades, s...
A Gandolfi Jr, C Salvela, D R Macedo, J M Vidal


Polymeric Betaine as a Wood Preservative
2008 - IRG/WP 08-30487
Didecyl polyoxyethyl ammonium borate (DPAB), also known as Polymeric Betaine, was developed as a co-biocide for chromium-free copper based wood preservatives in Europe in the 1980’s. This paper summarizes the properties of DPAB as a wood preservative. Unique properties related to the betaine nature of DPAB are discussed in terms of the structure-property relationship. Physical properties of D...
H Härtner, S Schmitt, Futong Cui, H M Barnes


Biological Performance of micronized copper wood preservative formulations in field and laboratory tests
2008 - IRG/WP 08-30488
Micronized Copper wood preservative formulations with different co-biocides were exposed to brown rot fungi in an 8-week AWPA E10 soil block decay test and two AWPA E7 ground-contact decay tests in Hawaii. The micronized copper formulations performed well against decay at or above the AWPA UC3 and UC4 retentions stipulated by the ICC-ES. Micronized copper preservatives performed comparably to a ...
G M Larkin, J Zhang, D L Richter, R J Ziobro, P E Laks


Performance of dip and pressure treated wood in termite ground proximity exposures in Hilo, HI, and Colombia
2008 - IRG/WP 08-30491
A number of preservative systems were evaluated for their ability to control termite attack when applied as both dip and pressure treatments. With dip treatments, better performance was observed with southern pine than spruce-pine-fir using the same solution strength treatment, probably as a result of the about 50% greater uptake with southern pine and associated deeper preservative penetration. B...
P Walcheski, A Zahora


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