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Chemical analysis for TBTN in LOSP-treated wood and preservative fluids
1994 - IRG/WP 94-20027
Tributyltin napthenate (TBTN) is being substituted for tributyltin oxide (TBTO) in LOSP preservative formulations because its lower reactivity/better stability allows co-formulation with synthetic pyrethroids. Better stability may reduce molecular degradation both in-service and during analysis. It was considered necessary to check whether TBTO analysis methods were suitable for use on TBTN treate...
D P Wraight, M J Kennedy


Long term performance of CCA preservatives in ground contact
2000 - IRG/WP 00-30223
Copper-chrome-arsenate (CCA) preservatives have been use extensively in New Zealand since the mid-1950s for a wide range of ground contact uses, radiata pine being the main species treated. They have been the subject of a comprehensive field testing programme in up to five sites in New Zealand, the earliest tests being established in 1955. Main factors affecting performance have been formulation t...
M E Hedley, D R Page, B E Patterson


Leaching of copper, chromium and arsenic from CCA-treated slash pine heartwood
1994 - IRG/WP 94-50020
Drying green slash pine with any of three high temperature drying schedules produced a product in which both the sapwood and the heartwood could be penetrated with CCA using a modified Bethell treatment schedule. Required H3 retentions were achieved in both sapwood and heartwood, from 200 litres per m³ charge uptake. Post-treatment fixation/drying was accomplished by three different regimes, incl...
M J Kennedy, G Palmer


Acetylation of lignocellulosic materials
1989 - IRG/WP 3516
A simplified procedure for the acetylation of lignocellulosic materials has been developed. The acetylation is done with a limited amount of liquid acetic anhydride without the addition of a catalyst or an organic co-solvent. Dimensional stability and biological resistance are both much improved by the acetylation. Equilibrium moisture content in acetylated material is considerably lower than in u...
P Larsson, A-M Tillman


Artificial drying of impregnated wood
1987 - IRG/WP 3448
Sawn timber (Pinus Sylvestris) of dimension 50x150 mm was impregnated with CCA by a full-cell process. The timber was then dried in a conventional kiln or a special vacuum kiln where the timber was dried by circulating superheated steam. Drying time was 16 days and 2 days respectively. The aim of the investigation was to compare the physical appearence of the wood after drying by the two methods w...
M-L Edlund


Relative performances of DNBP and CCA wood preservatives in accelerated decay tests
1988 - IRG/WP 3496
The effectiveness of 2-sec-butyl-4,6-dinitrophenol (DNBP) was compared with that of CCA. Test blocks of Pinus patula and Eucalyptus grandis were impregnated to precisely known retentions of approximately 3, 6, and 10 kg/m³ CCA and solvent-borne DNBP respectively. They were then challenged in decay tests comprising soil burial and exposure to monocultures of Chaetomium globosum, Coriolus versicolo...
W H Schnippenkoetter, L D Abraham, A A W Baecker


Estimation of effective diffusion path lengths in wood by swelling studies
1989 - IRG/WP 3524
The effective average distance that a solute must diffuse to penetrate the cell wall matrix following pressure treatment is estimated from the rate of swelling of wood, vacuum treated with water. It is assumed that the diffusion paths are similar for water and a solute such as a wood preservative component. Since bound water diffusion coefficients for water in wood have been estimated by others, t...
P A Cooper, R Churma


The yeast Pichia sp. As a short-term biological control agent to fungal spoilage of sawn softwood timber
2000 - IRG/WP 00-10362
Previous work has found isolates of the yeast Pichia to be a successful biological control agent toward moulding of fruits. An isolate was tested for the ability to protect sapwood of Pinus sylvestris timber against visual degrade by surface growth of moulds and staining fungi. Successful protection of autoclaved wood sprayed with a mixture of common wood moulding fungi was achieved when the yeast...
C Payne, H J Staines, A Bruce


Testing method for the treatability of wood
1994 - IRG/WP 94-40031
In order to test and classify the treatability of wood species in pressure treatment processes with water-based solutions, a laboratory method was developed which allows the testing of small samples and limited sections of a stem, e.g. sapwood. The penetration of different liquids was determined separately concerning the three anatomical directions of wood. The common parameters for pressure impre...
A O Rapp, R-D Peek


Remedial treatment of joinery. Comparison of distribution of organic solvent preservative and ammonium bifluoride
1978 - IRG/WP 3115
It is some years since it was recognised in the United Kingdom that there was a problem of premature decay in untreated external joinery. Consequently, recommendations for preservative treatment were made by the Building Research Establishment, Princes Risborough Laboratory. In addition, the National House-Building Council has also included the preservative treatment of external joinery in its req...
J M Taylor


Influence of the peeling on the absorption in the sap displacement method
1990 - IRG/WP 3626
Results of tests on the Eucalyptus and pine fenceposts treated by sap displacement method are presented. Freshly cut post 2 m in length and 8 to 16 cm in diameter were placed for 6 days with their butt ends down in water soluble preservative solution (CCF) to a depth of about 65 cm, and these were inverted and kept in the same way for 3 days more. The treatment began a few hours after felling. The...
M V Baonza Merino


The use of immunofluorescence labelling for detecting Ophiostoma piceae in radiata pine
1998 - IRG/WP 98-10268
The primary objective of the current investigation is to understand fungal interactions of dominant sapstaining fungi in radiata pine using confocal laser scanning microscopy (CLSM). In the current paper, an immunofluorescence labelling technique was developed for detection of Ophiostoma piceae using a monoclonal antibody. The primary antibody was labelled with Oregon green 514 Goat anti-mouse Ig...
Ying Xiao, B Kreber, C Breuil


Decay types observed in small stakes of pine and Alstonia scholaris inserted in different types of unsterile soil
1990 - IRG/WP 1443
The attack of various wood-degrading microorganisms occurring in mini-stakes of pine and Alstonia scholaris buried in various types of unsterile soil was studied. Attacks by white rot, brown rot, soft rot, erosion bacteria, tunnelling bacteria and actinomycetes were found. Soft rot occurred in all soils, whereas attack by white rot and especially brown rot and erosion bacteria was rare. The type o...
T Nilsson, G F Daniel


Soft rot decay of Eucalyptus maculata Hook. in different soils from Queensland, Australia
1980 - IRG/WP 1113
In the present work, different Queensland soils were chosen and their gross effects on the decay of treated and untreated Eucalyptus maculata examined. The soils were also amended with various levels of phosphate to study the response of the wood decay mycota to an increasing supply of this nutrient. Phosphate amendment was chosen because of the wide-scale use of superphosphate on Queensland soils...
L E Leightley, I W Russell


Effects of boron treatments on partially decayed oak and pitch pine heartwood
1996 - IRG/WP 96-30106
This paper reports results of borate based preservative treatment and leaching experiments on partially decayed oak and pitch pine heartwood. Previous experiments have shown little damage is caused to sound timber of these types when treated with Polybor and Boracol 20 preservatives. This experiment was carried out to assess the suitability of selected borate based preservatives for use in histori...
S McCutcheon, G M Smith, J W Palfreyman, P Durrant


Chromium on the surface of CCA-treated wood
1978 - IRG/WP 386
Chromium in solutions of CCA preservatives is predominantly in the hexavalent state (Cr VI). It is well known that Cr VI is associated with dermatitis and skin ulceration in workers handling chromium containing products and processes. When reduced to the trivalent state, however, chromium is considerably safer. An essential part, therefore, of safety procedures in any chromium - using industry is ...
C R Coggins, P Hiscocks


Retention and distribution of copper/chrome/arsenic (CCA) in pressurised sap-displaced UK grown spruce and pine
1986 - IRG/WP 3366
Increment cores were taken from UK grown Scots pine (Pinus sylvestris L.), Corsican pine (Pinus nigra var. maritima Ait), Sitka Spruce (Picea sitchensis (Bong) Carr), and Norway spruce (Picea abies (L) Karst) distribution poles treated by pressurised sap-displacement using a 1.8% copper, chrome, arsenic (CCA) solution. Each increment core was sectioned radially and the copper, chrome, and arsenic ...
P D Evans, G M Smith, B King


The volatilization of arsenic on burning copper-chrome-arsenic (CCA) treated wood
1978 - IRG/WP 3111
Small scale burning experiments are described involving copper-chrome-arsenic treated wood. Approximately 20 per cent of the arsenic was volatilised when the wood was burned in air but 60 per cent when burned in an oxygen-enriched atmosphere, this increase is attributed to an increase in combustion temperature. Although a small increase in arsenic evolution was found with an increased concentratio...
A-J Dobbs, C Grant


A potential anti-sapstain chemical for sawmills
1984 - IRG/WP 3300
Several biocidal formulations were tested under laboratory conditions in order to discover an alternative antisapstain chemical to chlorophenoxides. The formulations tested were experimental water solutions containing a quaternary ammonium chloride, a commercial fungicide and/or a sodium salt of some carboxylic acids. The effect of sodium carbonate and borax decahydrate in mixture with a quaternar...
I A Linderborg


Initial microbial colonisation of CCA-treated, creosote-treated and untreated Pinus sylvestris L. blocks in seawater
1996 - IRG/WP 96-10171
CCA-treated, creosote-treated and untreated Pinus sylvestris sample blocks were immersed in a seawater through-flow system for periods of between 1 and 265 hours. Samples were fixed immediately on removal and examined both qualitatively and quantitatively using the scanning electron microscope. This study of primary microbial colonisation showed differences between treatments in the diversity of m...
K Sturgess, A J Pitman


Effects of Trichoderma harzianum on enzyme activity and oxalic acid production of Gloeophyllum trabeum in ponderosa pine sapwood blocks
1992 - IRG/WP 92-1550
The effect of a bioprotectant, Trichoderma harzianum, on the activity of Gloeophyllum trabeum was investigated using a wood wafer sandwich method. Wood weight loss was greatest with Gloeophyllum trabeum exposed wafers, intermediate with those exposed to both the bioprotectant and decay fungus, and lowest with the bioprotectant exposed wafers. Extracts of wood wafers after 2, 4, or 6 weeks of funga...
C M Sexton, J J Morrell


Movement and persistence of Dazomet and pellected methylisothiocyanate in wrapped Douglas fir and southern pine timbers
1991 - IRG/WP 1496
The movement and persistence of Dazomet (tetrahydro-3,5-dimethyl-2 H-1,3,5 thiadiazine-6-thione) and pelleted methylisothiocyanate (MIT) was evaluated in wrapped Douglas-fir and Southern Pine timbers. MIT pellets did not impart a fungistatic effect to any of the timbers. Failure of MIT was probably due to loss of MIT from pellets prior to application. Fungistatic effect of Dazomet was consistently...
T L Highley


Preliminary field and laboratory findings regarding the efficacy of a novel anti-marine wood borer agent
2000 - IRG/WP 00-10380
Blocks of sapwood of Pinus nigra were treated by vacuum impregnation with Biocide A to retentions of 0.5, 1 and 2 kg m-3. Similar blocks were vacuum-pressure impregnated with CCA to retentions of 2, 24 and 38kg m-3. The blocks were exposed subtidally in Mourilyan Harbour (Queensland, Australia). After 5 and 10 months exposure, blocks were removed, examined for superficial signs of attack by wood b...
A Praël, S M Cragg, R A Eaton


Moisture condition in treated wood exposed outdoors. A progress report after 5 years
1992 - IRG/WP 92-3720
Wood treated with water-borne preservatives, mainly CCA (copper, chromium and arsenic) and CCB (copper, chromium and boron) is often said to absorb more water than untreated wood. In laboratory tests this statement has not been confirmed (Johansson 1977). In 1986 a project was started to compare water absorption during outdoor exposure between wood stakes of pine, Pinus sylvestris L, and spruce, P...
M-L Edlund


Dynamics of pressure changes in wood during impregnation
1990 - IRG/WP 3615
Conventional methods of impregnation have to be improved for achieving better penetration of refractory wood species. Basic requirements for an adjustment of treatment schedules are, amoung others, a profound knowledge of the course of pressure changes in the wood during treatment. A new method of pressure measurement was developed which supplies exact and reproducible data. The results show that ...
R D Peek, S Goetsch


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