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Micro-Distribution of Metals in Wood Treated with a Nano-Copper Wood Preservative
2007 - IRG/WP 07-40360
The microdistribution of copper in southern pine treated with a newly-developed nano-copper wood preservative was examined to determine if it differed from that reported for wood treated with conventional copper-based wood preservatives. Field Emission Scanning Electron Microscopy (FE-SEM) in combination with x-ray microanalysis (EDX) revealed the presence of nano-sized copper and iron particles i...
H Matsunaga, M Kiguchi, P Evans


Effect of barriers on moisture content of treated and non-treated utility poles
2007 - IRG/WP 07-40369
The potential for non-biocidal barriers to slow moisture sorption was investigated using butt treated western redcedar poles immersed in either water or moist soil over a 2 year period. Moisture sorption was initially slowed by the barriers, but openings at the bottoms of the barriers eventually allowed moisture to migrate upward. Moisture levels in wrapped poles eventually reached those found in...
C S Love, J J Morrell


The Role of Moisture Content in Above-ground Leaching
2007 - IRG/WP 07-50245
This paper reviews previous reports on the moisture content of wood exposed above ground and compares those values to moisture contents obtained using simulated rainfall and immersion methods. Laboratory leaching trials with CCA-treated specimens were also conducted and the results compared to published values for leaching of CCA-treated specimens exposed above ground outdoors. Previous researcher...
S Lebow, P Lebow


The effect of additives on copper losses from alkaline copper treated wood
2007 - IRG/WP 07-50246
The replacement of chromated copper arsenate (CCA) by alkaline copper compounds has heightened awareness of the potential impact of copper losses on aquatic organisms. While there remains a healthy debate concerning the actual risk of copper leaching from wood preservatives into aquatic ecosystems, it is clear that reducing these losses will be necessary to avoid continued regulatory actions aga...
J Mitsuhashi, J J Morrell, L Jin, A F Preston


Durability of some alternatives to preservative-treated wood. Progress report 2: Results from field tests after 5 years’exposure
2007 - IRG/WP 07-30442
A number of alternatives to preservative-treated wood have been tested according to EN 252 (stake test) and a specially designed ground-proximity field test, the latter in Sweden as well as in Hawaii, USA. Seven untreated wood species and four alternative wood treatments labelled as environmentally friendly (acetylation, linseed oil, heat treatment, vinyl polymer) were included in the study. Four ...
M-L Edlund, J Jermer


Development of preservative treatment method using sub and super critical carbon dioxide
2007 - IRG/WP 07-40385
Significant efforts have been devoted for developing biocide impregnation method into wood materials using supercritical fluid. Developing better understandings of fluid phase and its effect on treatment results would facilitate a more rational development of supercritical fluid (SCF) impregnation. In this project, the preservative treatabilities under super- and sub-critical fluid conditions we...
Myeung-Won Cho, Sung-Mo Kang, Gyu-Hyeok Kim


Development of boron/linseed oil combined treatment as a low-toxic wood protection. Evaluation of boron fixation and resistance to termites according to Japanese and European standards
2007 - IRG/WP 07-30448
Combinations of boric acid as a first step of treatment and linseed oil as a second step have been performed in order to enhance boron retention to leaching and wood resistance to termites. Classic leaching and termites resistance standards are inappropriate to evaluate this combination which can be considered as both a wood core preservation treatment and a coating. Japanese Industrial Standard...
F Lyon, M-F Thevenon, Y Imamura, J Gril, A Pizzi


Performance of softwood preservative treated stakes after 4 years exposure in-ground to decay fungi and termites in tropical Australia
2008 - IRG/WP 08-10643
This field study was based on the 1993 IUFRO method and designed as a graveyard (in-ground) test in the tropical region of the Northern Territory to examine the efficacy of novel preservative formulations developed as alternative protection for softwood timber against decay fungi and termites for Hazard Class 3 and 4. This study was supported by the Forest and Wood Products Research and Develop...
B M Ahmed (Shiday), J R J French, S R Przewloka, P Vinden, J A Hann, P Blackwell


Influence of Polyvinyl acetate emulsion (PVA) on boron leaching and fungicidal properties
2008 - IRG/WP 08-30451
Boron compounds are very effective fungicides, but unfortunately they leach from wood. In order to improve boron fixation, boric acid, borax were combined with polyvinyl acetate emulsion (PVA). For comparison copper salts were included into this research as well. Selected preservative solutions were chosen for impregnation of Norway spruce wood specimens (Picea abies). Wood blocks were exposed to ...
M Humar, B Lesar, P Kralj


Primary Study on Compressed Preservative-treated Wood (CPW) for Outdoor Applications
2008 - IRG/WP 08-40412
In this study, the compressed wood samples pre-treated with hot water bath or water spraying were immersed in the ammoniacal copper quat –type D (ACQ-D) preservative solution to get compressed preservative-treated wood (CPW). The liquid absorption and the recovery rate of compression deformation of the compressed wood was determined, as well as the surface hardness, the distribution of density a...
Jinzhen Cao, Jia Mao


The role of chromium in wood preservatives under BPD - a review and the current situation in Europe
2008 - IRG/WP 08-30468
Already during the IRG-meeting in Trømso a paper was presented to give an overview regarding the situation on chromium (JÜNGEL et al. 2006). Already in that year there was an increased attempt to achieve a science-based correct and harmonised solution in Europe regarding the chromium-question by the European Commission. Nevertheless the competent authorities (CAs) and the industry were similarly...
P Jüngel, S Hellkamp


Formation and Structure of Metal Azole Complexes
2008 - IRG/WP 08-30469
Divalent copper and zinc complexes with metal:azole ratio 1:2 were readily formed at room temperature with the fungicides tebuconazole and propiconazole. The structure of copper and zinc tebuconazole acetate and zinc cis-propiconazole chloride were examined by X-ray crystallography. In copper tebuconazole acetate, the copper atom lies on a crystallographic inversion centre and is coordinated to tw...
P D Evans, K J Schmalzl, C M Forsyth, G D Fallon, S Schmid, B Bendixen, S Heimdal


Depletion and Redistribution of Boron in Bundles of Commercially Treated Lumber Exposed to Artificial and Natural Rainfall
2008 - IRG/WP 08-30474
The depletion and redistribution of boron from stacks of Southern Yellow Pine lumber pressure treated with disodium octaborate tetrahydrate (DOT) and exposed to artificial and natural rainfall was examined. When the lumber was exposed to periodic simulated rainfall, 5.7-8.1% of the measured boron present leached from the lumber after exposure to over 300 mm of rainfall. In tests which exposed bo...
M E Mankowski, M J Manning


Preservative treatment of strips of Bambusa balcooa by soaking process using Borax-Boric acid
2008 - IRG/WP 08-30478
Bamboo strips made from Borak bamboo (Bambusa balcooa) were treated with 10% borax-boric acid aqueous solution by soaking process. The moisture contents of the bamboo strips were 12%, 20% and 30%. The strips were soaked for one, two, three, four and five days. The penetration of the solution was investigated by colour test after soaking and drying. Full penetration was observed after three days ...
K Akhter, M W Sheikh, M M Rahman, T A Chowdhury, M H Chowdhury


Bending Properties of Southern Pine Treated with Micronized Preservative Systems
2008 - IRG/WP 08-40414
This study indicates that treatment of southern pine with micronized copper systems have no deleterious effect on the residual strength property values. No statistical differences between wood treated with micronized systems and water-treated controls were noted when means were compared using either Tukey’s test or S-N-K mean comparison tests. Using the more discriminating Least Squares anal...
H M Barnes, G B Lindsey, J Hill, M Pompeo, R Hodge


The effect of treatments in boron steaming medium on boron leaching and strength properties of wood
2008 - IRG/WP 08-40409
The combined effect of boric acid impregnation together with boron steaming and steaming heat treatments were evaluated in this study. Boric acid pre-treated wood samples and untreated ones subjected to steaming heat and direct steaming treatment in a close reactor at 13 bar pressure and 180 ºC for 30 minutes. Compression strength parallel to grain of wood samples, leaching test and pH measuremen...
E D Tomak, Ü C Yildiz, S Yildiz, E Pesman


Thermochemical Remediation of Preservative-Treated Wood
2008 - IRG/WP 08-50254
Remediation methods continue to be developed and refined for CCA-treated wood in order to divert this material from landfills and create secondary products from the wood fiber. A two-step thermochemical remediation method was developed to assess the efficiency of metal removal from CCA-treated spruce flakes. Nearly all the metals (As, Cr, and Cu) were thermochemically extracted from chromated copp...
R Sabo, C A Clausen, J E Winandy


Measurement of wood decay by dynamic MOE in an accelerated soil contact test
2008 - IRG/WP 08-20390
Current laboratory and field testing of preservatives involves various techniques to determine the extent of fungal attack, including visual inspection, mass loss, and static bending and compression strength measurements. The objective of this study was to compare decay measurement by conventional compression strength versus dynamic MOE, employing small wood stakes in an accelerated laboratory so...
Gan Li, D D Nicholas, T P Schultz


Above Ground Field Testing – Influence of test method and location on the relative performance of various preservative systems
2008 - IRG/WP 08-20393
Standardized above ground tests such as the lap-joint or test deck methods can be very slow in producing useful information on the relative performance of wood preservative systems. It often requires many years for decay to develop in wood treated to sub-optimal concentrations of standardized preservatives, making relative comparisons of performance between new systems and established preservativ...
A Zahora


Effectiveness of MOQ® OX 50 (CCB-Oxide) wood preservative – Part 2: Field tests
2008 - IRG/WP 08-30483
MOQ® OX 50 is a chromated copper borate preservative known around the world as CCB. In Brazil, this product is the only CCB-oxide type preservative with fungicide and insecticide properties registered at the Brazilian Institute for the Environment and Renewable Resources (IBAMA) that complies with the requirements of the Brazilian and European markets for preserved wood. For over five decades, s...
A Gandolfi Jr, C Salvela, D R Macedo, J M Vidal


A Comprehensive Review of Copper as a Biocide, with a Focus on Micronized Copper
2008 - IRG/WP 08-30486
This paper reviews the wood preservative biocide active ingredient copper and delvers into new and previously unpublished data regarding the new micronized formulations which are now in vogue and widespread use in N. America in all residential treated lumber markets. Included in this review is the overall discussion of copper containing formulations used for pressure treated wood used over the las...
M H Freeman, C R McIntyre


Polymeric Betaine as a Wood Preservative
2008 - IRG/WP 08-30487
Didecyl polyoxyethyl ammonium borate (DPAB), also known as Polymeric Betaine, was developed as a co-biocide for chromium-free copper based wood preservatives in Europe in the 1980’s. This paper summarizes the properties of DPAB as a wood preservative. Unique properties related to the betaine nature of DPAB are discussed in terms of the structure-property relationship. Physical properties of D...
H Härtner, S Schmitt, Futong Cui, H M Barnes


Biological Performance of micronized copper wood preservative formulations in field and laboratory tests
2008 - IRG/WP 08-30488
Micronized Copper wood preservative formulations with different co-biocides were exposed to brown rot fungi in an 8-week AWPA E10 soil block decay test and two AWPA E7 ground-contact decay tests in Hawaii. The micronized copper formulations performed well against decay at or above the AWPA UC3 and UC4 retentions stipulated by the ICC-ES. Micronized copper preservatives performed comparably to a ...
G M Larkin, J Zhang, D L Richter, R J Ziobro, P E Laks


Alkaline copper treated wood for use in residential decking
2008 - IRG/WP 08-30490
Alkaline copper quaternary ammonium compound (ACQ) treated decking was exposed in a field experiment and the mobile copper assessed based on that collected in the leachate. The amount of copper which leached was modeled after 4 years. The results showed that boards which leached most chemical initially provided the greatest loss over four years. The reduction in the mobility of copper with time wa...
J N R Ruddick


Comparison of laboratory and natural exposure leaching of copper from wood treated with three wood preservatives
2008 - IRG/WP 08-50258
Standard and non-standard laboratory and field leaching tests were used to compare copper leaching from wood treated to above ground and ground contact specified retentions for three wood preservative systems, CCA-C, ACQ-D and a micronized copper formulation with quat DDAC as co-biocide. Copper leaching was highest for the ACQ formulation. Percent leaching was lowest for the micronized copper sy...
P A Cooper, Y T Ung


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