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Depletion of preservatives from treated wood: Results from laboratory, fungus cellar and field test
1993 - IRG/WP 93-50001-07
This paper compares results of preservative component losses using a range of test procedures with several different water-borne preservatives. The data shows that laboratory leaching tests are in some cases comparable to, but in other cases significantly underestimate preservative component losses when compared with field or fungus cellar depletion tests. The results also suggest that preservativ...
L Jin, A F Preston


Leaching of Copper from ACQ treated wood exposed above ground
2004 - IRG/WP 04-50219
The leaching of chemicals of ACQ Type C treated wood exposed above ground for 16 months was studied. Commercially treated Hem-fir boards (Tsuga heterophylla Raf. and Amabilis fir Forb) of 37.5 mm by 87.5 mm were used. The amounts of chemical leached monthly by the rainfall were determined and the leachate was collected and analyzed. Also, the environmental factors influencing the leaching were ...
P A Chung, J N R Ruddick


The use of low cost X-ray fluorescence instruments in the determination of copper chromium and arsenic in preservative treated wood
1987 - IRG/WP 2278
Internal quality control in timber treatment plants can be pursued by analysis of preservative treatment solutions and treated timber. Treaters must proceed with costly and lengthy analyses through analytical laboratories. An alternative approach for the timber treater, is to use low cost analysers (L.C.A.'s) based upon x-ray fluorescence. Detailed comparisons have been made between stand...
J Norton, L E Leightley


LCA examination of preservative treated timber products and alternatives; initial results
1995 - IRG/WP 95-50040-04
Co-operative development of an LCA methodology suitable for application to preservative treated products has been carried out, based on scoping assessments of two products, CCA treated fenceposts and creosote treated distribution poles. The general results of these scoping exercices are described, based on the CCA case study. These include the identification of critical stages in the life-cycle on...
W Hillier, R J Murphy, D J Dickinson, J N B Bell


Leaching Characteristics of Alder Wood Treated with Copper Based Wood Preservatives
2005 - IRG/WP 05-50225
In this study, it was designed for determining leaching characteristics of CCA and alternatives wood preservatives. Alder wood blocks were treated with CCA (1 % and 2 %), ACQ-1900 (2 % and 3 %), ACQ-2200 (1 % and 2 %), Tanalith E 3491 (2 % and 2.8 %), Wolmanit CX-8 (% 1 and 2 %). Leaching studies were conducted according to AWPA E11-97. Copper analyses of leachate were determined Atomic absorption...
A Temiz, Ü C Yildiz, E D Gezer, S Yildiz, E Dizman


The effect of oil-borne preservative treatments on the shear strength of FRP/wood composite adhesive bonds
2003 - IRG/WP 03-40265
Reinforcement of structural wood components with Fiber Reinforced Polymer (FRP) will enhance the beam’s strength, but actual data on long-term durability is sparse, not well documented or not readily accessible. In this study, bond properties of FRP-wood composite materials were investigated following treatment with creosote or copper naphthenate preservatives. The properties investigated inclu...
B Herzog, B Goodell, R Lopez-Anido


Application of paint primers after light organic solvent preservative treatment
1986 - IRG/WP 3381
The application of three alternative paint primers is investigated, including a slow-drying oil-based primer, a fast-drying oil-based primer, and a fast-drying water-based primer. The treatment schedules employed, in particular the evacuation period after treatment, have a marked effect on subsequent paintability. Priming can potentially be carried out immediately after treatment with approved Tim...
P Vinden


Speciation of leachates from CCA-treated wood
2005 - IRG/WP 05-50224-27
Different species of arsenic and chromium are characterized by different toxicities and different mobilities. The environmental impacts of CCA-treated wood would therefore be a function of the chemical forms of the metal releases. As a consequence a series of tasks were undertaken to evaluate arsenic and chromium species from CCA-treated wood. The intent of these tasks was to quantify the total...
H M Solo-Gabriele, T G Townsend, Yong Cai, B I Khan, Jin-Kun Song, J Jambeck, B Dubey, Yong-Chul Jang


The use of organic wood preservatives in ground contact and the suitability of laboratory test procedures to determine their efficacy
1999 - IRG/WP 99-20175
Organic fungicides, such as propiconazole, have proven to be highly effective when used as a co-biocide in recently developed wood preservative formulations. They have however been ineffective when used as a stand alone preservative, particularly when used in ground contact (European Hazard class 4). Previous research, using the test methods of ENV 807 (1993), provided conflicting evidence regardi...
I J Herring, D J Dickinson


Leaching of components from CCF treated timber in ground contact
1998 - IRG/WP 98-50108
In order to investigate the depletion of different CCF-salts during service small stakes (10*10*450mm³) were treated with five water-borne wood preservatives and after fixation brought into ground contact for several years. After failing some of the broken down stakes were used to determine the remaining concentration of relevant ions and their distribution in different segments of the stakes. A...
E Melcher


CCA removal from treated wood by chemical, mechanical and microbial processing
1998 - IRG/WP 98-50101-26
Most preservative-treated wood produced and consumed in the U.S. is treated with toxic inorganic compounds containing copper, chromium, and arsenic. Because chromated copper arsenate (CCA) is fixed to the wood, treated wood has not been considered toxic or hazardous and is currently landfilled. Increasing public concern about environmental contamination from treated wood combined with increasing q...
C A Clausen, R L Smith


The effects of pH on leaching of copper-chrome-arsenate (CCA) from pressure-treated Kenyan-grown Eucalyptus saligna and Acacia mearnsii: Initial findings.
2002 - IRG/WP 02-30298
The effects of pH on leaching of CCA from pressure-treated Kenyan-grown Eucalyptus saligna and Acacia mearnsii were tested under laboratory conditions. Small samples of the two species (100mm x 30mm x 40mm) were smooth sawn from 8-year old trees to represent equal amounts of both sapwood and heartwood, air-dried to 12% moisture content, end-sealed, and pressure-treated at a commercial treatment p...
R Venkatasamy


Potential use of an emulsified tar oil fraction as a wood preservative: Preliminary technological and environmental assessment
1994 - IRG/WP 94-50028
In order to meet the recent environmental concern specifications of creosote are altered, the B[a]P content is limited and restrictions on the emission of volatile organic compounds (VOC) and higher polyaromatic hydrocarbons (PAH) are expected in some countries. Research has been conducted on an emulsion of a selected tar oil fraction. Using a waterborne formulation opens new perspectives for targ...
G M F Van Eetvelde, R Leegwater, M Stevens


Changes of copper and chromium content after leaching in wood impregnated with the CCB and CB preservatives
2000 - IRG/WP 00-50147
The objective of the study was impregnated with CCB and CB preservatives pine wood of moisture content varying from 12% to 55% subjected to leaching. Losses of copper and chromium were determined for individual layers of wood up to 3 cm from the girth. The results were compared to the total amount of metals determined in water extracts. The degree of leaching of metal ions from wood of 55% moistur...
B Mazela


Long-Term Release of Arsenic, Chromium, and Copper from CCA-Treated Wood and Ash
2005 - IRG/WP 05-50227
In this study, laboratory long-term leaching studies were conducted to characterize the leaching behavior of arsenic, chromium, and copper from CCA-treated wood samples (block, chip, and sawdust) and CCA-wood ash and to determine the rate of release of the metals from the CCA wood products. The leaching solutions were periodically collected and analyzed for the concentrations of arsenic, chromium,...
Hyunmyung Yoon, Heeseok Kang, Yong-Chul Jang


Leaching tests on CCA-treated wood using inorganic salt solutions
1984 - IRG/WP 3310
Pinus radiata sapwood treated to approximately 10 kg/m³ with Tanalith NCA or Tanalith C-type CCA preservatives was ground to a fine powder and samples were then leached with solutions of calcium chloride, calcium nitrate, magnesium nitrate, or a mixture of potassium di-hydrogen orthophosphate and di-potassium hydrogen orthophosphate, at 0.03M-1.00M solution concentrations. Leached wood samples we...
D V Plackett


Redistribution of boric acid in radiata pine during drying after preservative treatment
1993 - IRG/WP 93-40010
Samples of 100 x 50 mm² radiata pine were processed with a variety of options to produce dry, boron-treated wood. Concentrations of boric acid in the central one-ninth and in the whole of the wood cross-sections were determined by chemical analysis and compared. Diffusion treated material was dried by air, conventional kiln (70/60°C), or high temperature kiln (120/70°C). Four different predryin...
A J Bergervoet, D R Page, J A Drysdale


A determination of the toxic level of ACQ2100 wood preservative for the powder post borer Lyctus brunneus (Stephens)
1994 - IRG/WP 94-20029
The sapwood of two Lyctus susceptible Australian hardwoods, messmate (Eucalyptus obliqua L'Herit.) and black bean (Castanospermum australe A. Cunn. et Fraser ex Hook) were pressure impregnated with ACQ2100, a wood preservative, to produce replicates of a range of retentions. Preservative retentions were determined by solution weight uptake at treatment and chemical analyses of selected sa...
A R Moffat


Relating CCA fixation to leaching of CCA components from treated products
1995 - IRG/WP 95-50045
The relationship between chromium fixation in CCA-C treated wood, as determined by CrVI analysis of solution expressed from treated wood and the leaching of Cu, Cr, As and CrVI in a simulated rain test are evaluated for dimension lumber (2"x6") and pole sections. Leachate concentrations after 2 hour exposure to a misting spray (about 300 mm cumulative rainfall) decrease rapidly with increased degr...
P A Cooper, R MacVicar, Y T Ung


A new process for in situ polymerization of vinyl monomers in wood to delay boron leaching
1998 - IRG/WP 98-40110
Efforts were accelerated on effective use of boron compounds in wood preservation owing to their environmentally safe characteristics and relatively low costs in addition to their well-known high bioactivity and fire resistant properties. Although having these unique favorable properties, they are readily leachable from treated wood at humid conditions. Therefore, they had limited market for exter...
M K Yalinkilic, W Dwianto, Y Imamura, M Takahashi


Fixation of chromated wood preservatives through technical drying
1990 - IRG/WP 3623
Twin samples of sawn timber of Pinus sylvestris and Picea sp. were treated with copper-chromate-containing wood preservatives and subsequently kiln resp. air dried. After drying, the distribution of preservative and rate of fixation were determined. Drying of freshly treated wood in a condenser type kiln at temperatures of 60°C and 80°C and in a vacuum type kiln at 55°C with a pressure of about...
R-D Peek, H Klipp


Ecotoxicological effects of exposed CCA preservative treated wood in environments
2001 - IRG/WP 01-50173
For the evaluation of environmental effect of CCA treated wood exposd in the field, the simulated soil pot system of the laboratory was used. The effective components of preservatives were leached and determined after artificially conditioning a soil pot of CCA treated wood with more than 500mm water, the average monthly precipitation. As the water passed through the soil, As, Cr and Cu in the soi...
Dong-heub Lee, Dong-won Son


Experimental variations in the distribution of CCA preservative in lignin and holocellulose as a function of treating conditions (temperature, concentration, pH, species, and time)
1984 - IRG/WP 3277
The exact distributions between lignin and holocellulose and retentions on wood of copper, chromium and arsenic as a function of various sets of conditions in a 3x3x4x2 factorial experiment in which combinations of three temperatures of treatment, three CCA solution concentrations, four pH's of the initial CCA solution and two timber species, namely Pinus radiata and Eucalyptus grandis, a...
A Pizzi, E Orovan, M Singmin, A Jansen, M C Vogel


Fixation and leaching characteristics of Douglas-fir treated with CCA-C
2004 - IRG/WP 04-50213
Fixation and leaching characteristics of CCA-treated Douglas-fir was evaluated using the expressate method and the AWPA E11-97 leaching procedure. CCA fixation, as monitored by the chromium reduction, was much faster in heartwood than in sapwood; however, copper and arsenic fixation in heartwood appeared to be incomplete regardless of the extension of fixation time. This poor fixation of copper a...
Gyu-Hyeok Kim, Yun-Sang Song, Dong-heub Lee


Conforming to European standards on preservative treatment
1998 - IRG/WP 98-20150
New European standards require that specifications for the preservative treatment of timber are written in terms of the penetration and retention of preservative within the treated commodity that result from the treatment process. In order to check compliance with this type of specification, suitable methods of quantitative analysis must be available. This paper presents the results of a study by ...
E D Suttie, R J Orsler


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