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Preservative treatment of wood-based composites with a mixture formulation of IPBC-silafluofen using supercritical carbon dioxide as a carrier gas
2003 - IRG/WP 03-40251
Wood-based composites treated with a mixture formulation of a fungicide, 3-iodo-2-propynyl butylcarbamate (IPBC) and a termiticide, silafluofen using supercritical carbon dioxide (SC-CO2) as a carrier solvent were tested for their resistance to decay and termite attack in the laboratory. The treatment solution was prepared by mixing both biocides (IPBC 10 + silafluofen 1) with a co-solvent, ethano...
K Tsunoda, M Muin


Optimisation of an analytical method for the determination of total fluoride in preservative-contaminated soils using water steam distillation and an ion-selective electrode
1999 - IRG/WP 99-20153
This paper describes a simple modified procedure for the quantitative fluoride determination of different origin in a soil matrix using a water steam distillation and an ion-selective electrode. Distillation methods generally require a preliminary preparation step like fusing. The modified method presented here is based on the direct distillation of fluoride so that no further sample preparation i...
E Melcher


Studies of the mechanism of chromated-copper preservative. Fixation using electron spin resonance
1992 - IRG/WP 92-3701
Two softwoods and one hardwood species were treated with chromium trioxide, copper sulphate, chromated-copper wood preservative (CCA). The treated wood samples were analyzed during fixation by electron spin resonance (ESR). ESR spectra indicated that more than one Cr(V) species was generated from Cr(VI) soon after CCA treatment. The Cr(V) signal became strong within increased several hours followe...
K Yamamoto, J N R Ruddick


The quantitative determination of N-cyclohexyl-diazeniumdioxide (HDO) containing compounds in treated wood using TD-GC-MS
2001 - IRG/WP 01-20223
Last year we presented the paper (IRG/WP/00-20201) "Determination of N-cyclohexyl-diazeniumdioxide (HDO) containing compounds in treated wood using GC-MS". Based on the intensive discussion at the meeting, the first experiences made with the calibration of the system for this application will be reported. For the quantitative determination of N-cyclohexyl-diazeniumdioxide in treated wood, milled m...
P Jüngel, J Wittenzellner, E Melcher


EPA’s Current Views on Heavy-Duty Wood Preservative Regulation
2003 - IRG/WP 03-50206
This paper describes the current EPA system for regulating pesticides and wood preservatives. In particular it focuses on the voluntary phase-out of CCA for residential uses after December 30, 2003, which was agreed between the CCA manufacturers and EPA. Even though the EPA reached an agreement with industry to phase out CCA for residential uses, EPA is continuing the most rigorous risk assessmen...
F T Sanders


Effect of species composition of preservative-treated Douglas fir plywood on its decay resistance
1978 - IRG/WP 2114
Plywood is now commonly used for constructional purposes in environmental situations where decay by wood-destroying fungi can be a considerable risk. However there seems to be a lack of understanding of the relative durability of plywood, both untreated and when treated with wood preservatives. Part of the reason for this situation has been the difficulty of carrying out laboratory decay tests on ...
R S Smith, P Balcaen


Fouling organisms as indicators of the environmental impact of marine preservative-treated wood
1995 - IRG/WP 95-50063
This study evaluates the use of fouling organisms (epibiota) to assess the environmental impact of preservative treated wood. This paper presents initial findings from treated panels exposed for 6 months at Sagres, Algarve, Portugal. Panels were treated with CCA, two copper-containing quaternary ammonium (ACQ) formulations and creosote, with nominal retentions from 10 to 40 kg/m³ (creosote 25 pcf...
R M Albuquerque, S M Cragg


Marine performance of preservative treated Southern pine panels. - Part 1: Exposure in Newport, Oregon
2000 - IRG/WP 00-10368
The ability of selected wood preservative to protect southern pine sapwood against marine borer attack was evaluated over a 6 year period in Yaquina Bay, Oregon. The site exposed the wood to potential attack by both Teredo navalis and Limnoria spp. Both creosote and CCA provided excellent protection at moderate retentions, while ACQ produced slight differences in performance depending on the coppe...
R G Rhatigan, J J Morrell, A R Zahora


Methods for improving preservative penetration into wood: a review
2002 - IRG/WP 02-40227
Pressure treatment technologies have been available since the mid-1830's, but the processes used for wood treatment are still largely unable to overcome the fundamental limitations of flow through semi-permeable pit membranes. Instead, methods have arisen that attempt to improve treatability of the wood including incising, compression rolling, through boring, or radial drilling. Other a...
J J Morrell, P I Morris


Silicic acid-Boric acid complexes as wood preservatives
2001 - IRG/WP 01-30273
A silicic acid monomer aqueous solution (SAMS) or colloidal silicic acid solution (CSAS) was combined with various metal compounds or boric acid. Agents where SAMS or CSAS was combined with boric acid gave good protection against decay caused by the brown-rot fungus Fomitopsis palustris, the treated wood (Cryptomera japonica D. Don) specimens after the leaching test maintained a high resistance to...
H Yamaguchi


Stability, performance and distribution of propiconazole (R 49362) in acceleratedly aged wood
1991 - IRG/WP 3647
The permanency of propiconazole (R 49362 - WOCOSENÔ technical - Janssen Pharmaceutica) in wood was examined in an 18 month storage test, an evaporative ageing study (EN 73), a volatilization stress experiment, and water-leaching studies (EN 84). The biological efficacy against two brown rot fungi: Coniophora puteana BAM Ebw. 15 and Gloeophyllum trabeum BAM Ebw. 109 was assessed according to the E...
A R Valcke, M Stevens


Accelerated weathering test for the evaluation of wood preservative efficacy
2003 - IRG/WP 03-20262
Wood samples treated with ammonium copper quat (ACQ-1900 and ACQ-2200), Chromated copper arsenate (CCA), Tanalith E 3491 and Wolmanit CX-8 have been studied in accelerated weathering experiments. The weathering experiment was performed by cycles of 2 hours UV-light irradiation followed by water spray for 18 minutes. The changes on the surface of the weathered samples were characterized by FTIR Sp...
A Temiz, M Eikenes, Ü C Yildiz, F G Evans, B Jacobsen


Recovery of copper, chromium, and arsenic compounds from the waste preservative-treated wood
1991 - IRG/WP 3651
In Japan, about 40 percents of waste wood is incinerated and the residue is dumped into the landfill site. The waste preservative-treated wood, which is mixed in nontreated wood, is incinerated in the same way, too. However, it will cause the serious problems that the gases contained with high concentration arsenic compounds are discharged from the smokestacks of the incineration facilities and th...
A Honda, Y Kanjo, A Kimoto, K Koshii, S Kashiwazaki


Differences and their causes of CCA and CCB efficacay among some softwoods and hardwoods
1991 - IRG/WP 3656
Wood blocks from two softwoods and two tropical hardwoods species treated with different concentrations of CCA, CCB, and combinations of CrO3, CuS04, H3BO3 were subjected to the decay by brown rot fungus, Tyromyces palustris. CCA maintained good effect both in softwoods and hardwoods, while CCB and the other combinations lost their effectiveness after leaching. Chemicals leached from CCA treated w...
K Yamamoto, M Rokova


Comparison of Temporal Changes in Metal Leaching and Aquatic Toxicity from Wood Treated with CCA and Alternative Preservatives
2005 - IRG/WP 05-50236
This study compares the temporal variation of chemical leaching and aquatic toxicity of wood treated with chromated copper arsenate (CCA) and other copper-based wood preservatives (alkaline copper quaternary (ACQ), copper boron azole (CBA), copper citrate (CC) and copper dimethyldithiocarbamate (CDDC)). Treated wood blocks were leached for 21 days and the leachate collected was analyzed for prese...
B Dubey, T G Townsend, G Bitton, H M Solo-Gabriele


Preliminary results from the field experiment to determine the performance of preservative treated hardwoods with particular reference to soft rot. The four reference timber
1980 - IRG/WP 3164
The results given in the Tables 1-4 each refer to one of the four reference species treated with four solution concentrations of CCA as recorded from each test site. The species are: Alstonia scholaris, Betula pendula, Fagus sylvatica, Pinus sylvestris. The treatments were: Untreated, 0.66% CCA, 1.53% CCA, 3.01% CCA, 5.60% CCA. Each figure is an average of the ratings recorded for each replicate o...
J F Levy, D J Dickinson


Evaluation of polymeric alkylphenol polysulfide as a new wood preservative compound
2000 - IRG/WP 00-30251
At the 30 th IRG meeting held in Rosenheim, Bavaria, Germany, we reported on a Polymeric Alkylphenol Polysulfide (PXTS) which shows potential as a new non-leachable, environmentally compatible wood preservative compound exhibiting excellent biocidal efficacy. Comparative soil-block test results showed that PXTS was twice as effective as Creosote when evaluated against both white- and brown-rot fun...
J Goswami, A Abramson, R Buff, D D Nicholas


Effect of compression wood on leaching of chromium, copper, and arsenic from CCA-C treated red pine (Pinus resinosa Ait.)
2000 - IRG/WP 00-30232
In this study, the effect of compression wood formation on the release rate of chromium, copper, and arsenic elements from red pine (Pinus resinosa Ait) was investigated. Wood blocks from red pine containing compression and normal wood portions were treated with a 1.0% CCA-C solution and were then allowed to fix at 23 ± ??2°C (74 ± 4°F) for 0, 6, 24, 48, 96, 192, and 336 hours. After each fixa...
S N Kartal, S T Lebow


A diffusion and reaction model for the leaching of Cr-VI from unfixed CCA-treated wood
2001 - IRG/WP 01-50169
A physical model applicable to the leaching of any substance undergoing a first-order fixation reaction with wood is presented. Using this model and a laboratory leaching experiment with small wood samples immersed in water, the radial and tangential diffusion coefficients and the reaction rate constants of Cr-VI in unfixed CCA-treated red pine (Pinus resinosa Ait.) are measured. Reaction rate con...
L Waldron, P A Cooper


Leaching from field test stakes. Part 2: The distribution in and leaching from different parts of test stakes
1994 - IRG/WP 94-50026
Field test stakes treated with Boliden K33 (copper, chromium and arsenic) and Cuprinol Tryck (CT86) (copper and N-alkylbenzyldimethylammoniumchloride) respectively were exposed in ground contact at two different test fields in Sweden and rejected due to decay after 2 to 28 years. Stakes treated with the same preservatives were also exposed during 7 years above ground. The test stakes have been ana...
F G Evans, B Nossen, M-L Edlund


The multi-phase pressure (MPP) process. One-stage CCA treatment and accelerated fixation process - The process as a new concept in preservative treatment
1997 - IRG/WP 97-40078
The background to current commercial CCA treatment schedules used in New Zealand and fixation processing is reviewed. The limitations of these conventional practices with respect to treated product quality and CCA solution handling issues are defined. A novel, patented treatment schedule has been developed using a combination of hydraulic and pneumatic pressure phases and hot (~ 75°C) CCA solutio...
K Nasheri, A J Pendlebury, J A Drysdale, H Pearson, M E Hedley


Review of current wood preservation in Turkey
2003 - IRG/WP 03-30315
The aim of this study was to find out the current potential of the Turkish wood preservation industry, and to make some suggestions for its further proceeding, because the forest products potential and the geographical location combined may give to the wood preservation industry in Turkey a great advantage for exportation treated wood materials to the Middle East Countries. In this study, therefo...
I Usta


The effects of preservative treatment and exposure to wood degrading fungi on fiber reinforced polymer (FRP) materials used for structural wood reinforcement
2001 - IRG/WP 01-40204
Glass fiber reinforced phenolic (GFRP) composite materials are becoming increasingly accepted for use in the construction industry because they combine advantages of both wood and advanced polymeric materials. Addition of only 1-3% FRP in the tension zone, for example, can typically improve the strength of the hybrid system by 200%. As more applications are found for wood/FRP hybrids, (e.g. lamina...
C Tascioglu, B Goodell


The content and mobility of copper, chromium and arsenic in the soil of a wood preserving plant using CCA
1998 - IRG/WP 98-50122
Analyses were carried out on soil and water samples obtained from a wood preserving plant using CCA-type preservatives. The plant has been in operation since 1969. The soil samples were obtained on 8 points from 4 different depths. The estimation of the type of soil was followed by investigations of copper, chromium and arsenic contents, and the mobility of these elements. The soil samples were al...
N Erdin, S N Kartal, A Dilek Dogu, M O Engür


Preservative technique of three commercially important timber species – Sissoo (Dalbergia sissoo), Akasmoni (Acacia auriculiformis) and Ghoraneem (Melia azedarach) of Bangladesh
2005 - IRG/WP 05-40299
Wood is renewable resource and is widely used as construction material in rural and urban areas of Bangladesh. Dalbergia sissoo, Acacia auriculiformis and Melia azedarach, locally known as Sissoo, Akasmoni and Ghoraneem respectively are three important timber species of Bangladesh. These are used for different purposes normally without preservative treatment. Heartwood of Sissoo, Akasmoni and Ghor...
M R Bulbul, M O Hannan, P K Sarker, A A Mahafuz, G N M Ilias


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