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Primary Study on Compressed Preservative-treated Wood (CPW) for Outdoor Applications
2008 - IRG/WP 08-40412
In this study, the compressed wood samples pre-treated with hot water bath or water spraying were immersed in the ammoniacal copper quat –type D (ACQ-D) preservative solution to get compressed preservative-treated wood (CPW). The liquid absorption and the recovery rate of compression deformation of the compressed wood was determined, as well as the surface hardness, the distribution of density a...
Jinzhen Cao, Jia Mao


Above and Below-Ground Copper-Azole and Copper, Chrome Arsenate Depletion from Pinus radiata and Fagus sylvatica at Thirteen New Zealand & Australian Sites
2008 - IRG/WP 08-30460
The objective was to determine the significance of site on preservative depletion from Pinus radiata D. Don and Fagus sylvatica L. 20 x 20 x 500 mm field test stakes treated with a ground contact retention of copper amine plus tebuconazole (CuAz) and copper chrome arsenate (CCA) after approximately 5 years exposure to widely different soil and climate conditions. Site, wood species and their inter...
R Wakeling


The role of chromium in wood preservatives under BPD - a review and the current situation in Europe
2008 - IRG/WP 08-30468
Already during the IRG-meeting in Trømso a paper was presented to give an overview regarding the situation on chromium (JÜNGEL et al. 2006). Already in that year there was an increased attempt to achieve a science-based correct and harmonised solution in Europe regarding the chromium-question by the European Commission. Nevertheless the competent authorities (CAs) and the industry were similarly...
P Jüngel, S Hellkamp


Formation and Structure of Metal Azole Complexes
2008 - IRG/WP 08-30469
Divalent copper and zinc complexes with metal:azole ratio 1:2 were readily formed at room temperature with the fungicides tebuconazole and propiconazole. The structure of copper and zinc tebuconazole acetate and zinc cis-propiconazole chloride were examined by X-ray crystallography. In copper tebuconazole acetate, the copper atom lies on a crystallographic inversion centre and is coordinated to tw...
P D Evans, K J Schmalzl, C M Forsyth, G D Fallon, S Schmid, B Bendixen, S Heimdal


The efficacy of commercial silicones against blue stain and mould fungi in wood
2008 - IRG/WP 08-30471
Scots pine (Pinus sylvestris L.) wood samples were vacuum pressure impregnated with quatsilicone micro emulsion (<40 nm particle size), aminosilicone macro emulsion (110 nm) and silicone macro emulsion with alkyl modified side groups (740 nm) and the resulting material properties were studied. Quatsilicone micro emulsion resulted in maximum bulking (4.8%) and anti-swelling efficiency (21.8%) in...
S C Ghosh, C Mai, H Militz


Preservative treatment of strips of Bambusa balcooa by soaking process using Borax-Boric acid
2008 - IRG/WP 08-30478
Bamboo strips made from Borak bamboo (Bambusa balcooa) were treated with 10% borax-boric acid aqueous solution by soaking process. The moisture contents of the bamboo strips were 12%, 20% and 30%. The strips were soaked for one, two, three, four and five days. The penetration of the solution was investigated by colour test after soaking and drying. Full penetration was observed after three days ...
K Akhter, M W Sheikh, M M Rahman, T A Chowdhury, M H Chowdhury


Bending Properties of Southern Pine Treated with Micronized Preservative Systems
2008 - IRG/WP 08-40414
This study indicates that treatment of southern pine with micronized copper systems have no deleterious effect on the residual strength property values. No statistical differences between wood treated with micronized systems and water-treated controls were noted when means were compared using either Tukey’s test or S-N-K mean comparison tests. Using the more discriminating Least Squares anal...
H M Barnes, G B Lindsey, J Hill, M Pompeo, R Hodge


Effect of steam on fixation of Cu-amine preservative treated wood
2008 - IRG/WP 08-50251
The rates of copper fixation in copper amine preservative treated wood were investigated with different fixation conditions (20° with drying and 50° without drying) and post-steaming. We also measured the degree of leaching for other biocide components (azoles, quatz, and Cu-HDO). Treatments conditioned at 20° with drying required 50 days or more to fix in woods. While copper was stabilized i...
Sung-Mo Kang, In-Yong Hwang, Suk-Kuwon Kim


Thermochemical Remediation of Preservative-Treated Wood
2008 - IRG/WP 08-50254
Remediation methods continue to be developed and refined for CCA-treated wood in order to divert this material from landfills and create secondary products from the wood fiber. A two-step thermochemical remediation method was developed to assess the efficiency of metal removal from CCA-treated spruce flakes. Nearly all the metals (As, Cr, and Cu) were thermochemically extracted from chromated copp...
R Sabo, C A Clausen, J E Winandy


Measurement of wood decay by dynamic MOE in an accelerated soil contact test
2008 - IRG/WP 08-20390
Current laboratory and field testing of preservatives involves various techniques to determine the extent of fungal attack, including visual inspection, mass loss, and static bending and compression strength measurements. The objective of this study was to compare decay measurement by conventional compression strength versus dynamic MOE, employing small wood stakes in an accelerated laboratory so...
Gan Li, D D Nicholas, T P Schultz


Above Ground Field Testing – Influence of test method and location on the relative performance of various preservative systems
2008 - IRG/WP 08-20393
Standardized above ground tests such as the lap-joint or test deck methods can be very slow in producing useful information on the relative performance of wood preservative systems. It often requires many years for decay to develop in wood treated to sub-optimal concentrations of standardized preservatives, making relative comparisons of performance between new systems and established preservativ...
A Zahora


Australian trials on the efficacy of micronized copper
2008 - IRG/WP 08-30480
Alkaline copper quat (ACQ) is an established wood preservative that is formulated with solubilised copper in amine solvent. This paper describes three separate trials in Australia that investigated whether substituting soluble copper with micronized copper affects performance. ACQ and micronized copper quat (MCQ) gave similar performance in Pinus radiata against four brown-rotting fungi in a soil-...
L J Cookson, J W Creffield, K J McCarthy, D K Scown


Effectiveness of MOQ® OX 50 (CCB-Oxide) wood preservative – Part 2: Field tests
2008 - IRG/WP 08-30483
MOQ® OX 50 is a chromated copper borate preservative known around the world as CCB. In Brazil, this product is the only CCB-oxide type preservative with fungicide and insecticide properties registered at the Brazilian Institute for the Environment and Renewable Resources (IBAMA) that complies with the requirements of the Brazilian and European markets for preserved wood. For over five decades, s...
A Gandolfi Jr, C Salvela, D R Macedo, J M Vidal


Biological efficacy of micronized copper systems
2008 - IRG/WP 08-30485
Soil block, fungal cellar and field stake test data will be presented for micronized copper systems. The copper portion of the formulations is present as a fine dispersion of "micro" particulates while the co-biocide is present as either a soluble quat or an azole containing emulsion. This testing generally used the amine based counterpart as the control preservative system and the micronized fo...
C R McIntyre, M H Freeman


A Comprehensive Review of Copper as a Biocide, with a Focus on Micronized Copper
2008 - IRG/WP 08-30486
This paper reviews the wood preservative biocide active ingredient copper and delvers into new and previously unpublished data regarding the new micronized formulations which are now in vogue and widespread use in N. America in all residential treated lumber markets. Included in this review is the overall discussion of copper containing formulations used for pressure treated wood used over the las...
M H Freeman, C R McIntyre


Polymeric Betaine as a Wood Preservative
2008 - IRG/WP 08-30487
Didecyl polyoxyethyl ammonium borate (DPAB), also known as Polymeric Betaine, was developed as a co-biocide for chromium-free copper based wood preservatives in Europe in the 1980’s. This paper summarizes the properties of DPAB as a wood preservative. Unique properties related to the betaine nature of DPAB are discussed in terms of the structure-property relationship. Physical properties of D...
H Härtner, S Schmitt, Futong Cui, H M Barnes


Biological Performance of micronized copper wood preservative formulations in field and laboratory tests
2008 - IRG/WP 08-30488
Micronized Copper wood preservative formulations with different co-biocides were exposed to brown rot fungi in an 8-week AWPA E10 soil block decay test and two AWPA E7 ground-contact decay tests in Hawaii. The micronized copper formulations performed well against decay at or above the AWPA UC3 and UC4 retentions stipulated by the ICC-ES. Micronized copper preservatives performed comparably to a ...
G M Larkin, J Zhang, D L Richter, R J Ziobro, P E Laks


Field Stake Performance of Parallel Strand Lumber Treated with Waterborne Copper Naphthenate
2008 - IRG/WP 08-40435
Wood and wood products have been considered a premium building material for residential and industrial structures for many centuries. More recently, structural composite lumber (SCL) products have played an increasing role in satisfying the needs of the building industry. However, both wood and wood composites are naturally biodegradable materials which require enhanced durability when used in ce...
G P Merrick, M H Freeman, J A Brient


Wood preservative obtained by recycling – preliminary selection of leaching inhibitor
2008 - IRG/WP 08-50252
Based on recycling of used household batteries, a process was developed to enable the recovery of major manufacturing components, leading to a solution of zinc (32 g.l-1) and manganese (15 g.l-1) salts, free of heavy metals. The potential use of the above solution as wood preservative was demonstrated by means of assays both of fungicidal activity -using white and brown rot fungi- and of insectici...
C Ibáñez, C Mantero, G Cecchetto, M Rabinovich, M Cerdeiras


Durability and fungal colonisation patterns in wood samples after six years in soil contact evaluated with qPCR, microscopy, TGA, chitin- and ergosterol assays
2009 - IRG/WP 09-20402
There is a need to establish new objective and sensitive methods for early detection and quantification of decay fungi in wood materials. Molecular methods have proven to be a useful tool within wood protection issues, however, this field is still poorly explored and so far relatively few have used these methods within the field of wood deterioration. Among the techniques used in the indirect quan...
A Pilgård, G Alfredsen, I Børja, C Björdal


Effect of Preservative Treatment on Fungal Colonization of Teak, Redwood, and Western Red Cedar
2009 - IRG/WP 09-20404
Fungal flora present in preservative treated samples or non-treated samples from sapwood and heartwood of teak, western red cedar, redwood, and southern yellow pine was assessed after 6 to 18 months of exposure near Hilo, Hawaii. The objectives were to compare fungal composition and diversity between treated and non-treated samples, and to examine the use of molecular techniques for assessing fung...
Y Cabrera, C Freitag, J J Morrell


Copper to quat ratio in alkaline copper quat (ACQ) wood preservative - Effects on fixation and leaching of preservative components in red pine
2009 - IRG/WP 09-30496
This study investigates the effect of the relative proportion of copper oxide (CuO) to didecy dimethyl ammonium carbonate (DDACb) in an alkaline copper quat (ACQ) formulation on the rate of copper fixation or stabilization and the resistance of treated wood to leaching of copper and quat (DDACb). Red pine samples were treated with ACQ, having CuO to DDACb ratios of 2:1 (the normal ratio for ACQ-D...
S Pankras, P A Cooper, T Ung, L Awoyemi


Laboratory study on the termiticidal efficacy of Eremophilone oil
2009 - IRG/WP 09-30497
A novel timber preservative formulation, Termilone® TT, is being developed by BioProspect Limited. This environmentally friendly preservative formulation incorporates Eremophilone oil, extracted from Eremophila mitchellii, as the active ingredient. Chemical analysis performed on Pinus radiata sapwood specimens treated with the Termilone® TT formulation revealed that the Eremophilone oil is relat...
D K Scown, J W Creffield, R Spooner-Hart


Impact of an Antioxidant on the Efficacy of Quaternary Ammonium Compounds (Quats) and Triazoles – Seven Year Above-Ground Study
2009 - IRG/WP 09-30504
It has been reported that antioxidants have great potential for use with organic biocides in the area of wood protection. This paper demonstrates the impact of a low level of the antioxidant butylated hydroxytoluene (BHT) on the efficacy of quat-based and triazole-based formulations. A seven year lap joint test revealed a positive effect of BHT on the efficacy of quat-based formulations, especiall...
Xiao Jiang, D Biro, W Holcombe


Laboratory and above ground exposure efficacy of silicon-boron treatments
2009 - IRG/WP 09-30510
The study deals with silicon compounds, namely tetraethoxysilane (TEOS), phenyltriethoxysilane (PhTES) and methyltriethoxysilane (MTES) at concentrations of 23, 16 and 10% in combination with 1.2-1.5% boric acid. The aim with the study was to combine the chemical approach with the necessary biological tests of the impregnated wood. The tested silicon-boron combinations ensured mass loss less than ...
N Terziev, D Panov, A Temiz, S Palanti, E Feci, G Daniel


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