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Bio-based thermoset resins for bonding and eco-friendly preservation in the wood industry
2013 - IRG/WP 13-40650
Yellow dextrins and tannins were used in wood adhesives formulation to substitute resins based on formaldehyde. Several formulations were carried out in alkaline aqueous media by varying the weight fraction of two compounds from 10% to 30%. The cross-linking was performed using epichlorohydrin as a reticulant agent. Rheological behaviours and initial adhesion of three liquid formulations, before r...
C Motillon, A Allal, A Visse, F Charrier, B Charrier, A Baldé


Improving dimensional stability of thermally treated wood by secondary modification – potential and limitations
2014 - IRG/WP 14-40664
The potential of treating thermally modified wood with melamine resin to improve the dimensional stabilization is tested in this research. Two different boards of poplar (Populus ssp.) were cut into two halves. One half of each board was thermally modified (T1 and T2) in a commercial process, the other half was used as untreated reference material. The material was thermally modified using the vac...
G Behr, K-C Mahnert, S Bollmus, H Militz


Lignin Modification to Produce Sustainable Polyurethane Resin for Wood Coatings
2014 - IRG/WP 14-40682
The use of lignin as the most abundant aromatic natural polymer has been evaluated for use in the production of lignin-based polyurethane resin for coating applications. Coatings are made of resins (ca. 50%), which today are mainly derived from petroleum-based polymers. This study is focused on the development of an environmentally friendly method of modifying lignin to be used as source of natura...
M Nejad, M Arefmanesh, S Chandra, J Mostaghimi, E Master


Fabrication and characterization of MicroPCMs filled wood-plastic composites: Effects of polyethylene glycol on melamine–formaldehyde shell material
2016 - IRG/WP 16-40728
Microencapsulated phase change materials (MicroPCMs) containing dodecanol were fabricated using melamine-formaldehyde (MF) or polyethylene glycol 200 modified melamine-formaldehyde (PMF) resin as the shell materials by in situ polymerization. Wood flour/high-density polyethylene (WF/HDPE) composites with MF shell MicroPCMs (MF-MicroPCMs) or PMF shell MicroPCMs (PMF-MicroPCMs) were prepared, respec...
Xi Guo, Jinzhen Cao


Evaluation of Commercially Available Polyurethane Resin to Develop Non-biocidal Wood Preservation Treatments
2016 - IRG/WP 16-40751
Evaluation of commercially available polyurethane (PU1 and PU2 and polyisocyanate (PNCO) to develop non-biocidal wood preservation treatments have been conducted. A simple method by vacuum impregnation of these resins into beech wood (Fagus sylvatica L) and pine wood (Pinus sylvestris L.) samples followed by varied curing process at ambient temperature, 103oC, and 200oC have been performed. Based ...
M Mubarok, Y Sudo Hadi, J Suryana, I W Darmawan, F Simon, S Dumarcay, C Gérardin, P Gérardin


Improvement of wood properties by impregnation with liquefied spruce bark based resins
2016 - IRG/WP 16-40761
In this paper, biobased phenolic thermosetting resins are designed to be used as wood stabilization treatment. The originality of the study stands in substituting part of phenol by spruce (picea abies) bark: this is achieved by a liquefaction process in phenol in the presence of sulfuric acid as catalyst. Next, thermosetting resins are synthetized from liquefied bark by condensation on formaldehy...
X Duret, E Fredon, E Masson, P Gérardin


Bacterial Degradation of Pentachlorophenol Indicated in Groundwater Undergoing Long Term In-Situ Remediation
2016 - IRG/WP 16-50318
Pentachlorophenol (PCP, Penta) is a worldwide soil and water contaminant. The pervasive use of PCP as a fungicide, herbicide, pesticide, and as preservative for wood products has led to its global distribution. It is a highly effective preventative measure for most invasive insects, bacteria, fungi, and molds, as well as an excellent wood protection treatment. This study examined a known PCP conta...
C E Stokes, H Borazjani, L Prewitt


The Comparison of Weathering Resistance of New Generation Wood-Coating Systems
2017 - IRG/WP 17-40789
In this study, the performance of wood-coating systems containing different UV absorbers was evaluated in artificial weathering conditions. Acrylic-based resin containing three different UV absorbers was applied on oriental beech and scots pine surfaces. Weathering conditions were sustained for 84 days. After the weathering test, the change of color and roughness on the wood surface was measured t...
Ö Özgenç, S Durmaz


The potential and the challenges of acetylated wood in timber bridges - experiences from an ongoing project
2017 - IRG/WP 17-40792
Acetylated wood is known to be a durable and dimensional stable alternative for high performance materials, and has high potential for exterior timber structures. Research has shown that acetylated wood can be effectively bonded by various adhesive types. However, one of the most common used adhesives for timber constructions, Melamine Urea Formaldehyde (MUF), shows a high degree of delamination o...
A Treu, R Bredesen, F Bongers


Natural durability, ethanol-toluene extractives and phenol content prediction of eight wood species from Madagascar using NIRS multispecific models
2018 - IRG/WP 18-10926
Madagascar has nearly 4000 species of trees and shrubs, but wood properties of only 200 species have been studied. Some properties, such as the natural durability or chemical composition are of importance for adequate and optimal use of these timber species. Since durability tests take long time and chemical analyzes can be very expensive, alternative methods such as near infrared spectroscopy (NI...
A R Razafimahatratra, H Rakotovololonalimanana, M-F Thévenon, C Belloncle, G Chaix, T Ramananantoandro


The Study of the Preparation of Overlaid MDF with the Flame Retardant Impregnated Paper
2018 - IRG/WP 18-40848
The preparation of overlaid medium density fiberboard (MDF) was studied. The flame retardant impregnated papers (FRIP) were overlaid on the surface of the MDF for the fire protection. The results showed that: 1) The production of the FRIP was based on the technology of melamine-impregnated paper, which required the viscosity of the impregnated resin lower than 20s. However, with the addition of th...
W Qu, M Wu, Y-Z Wu


Thermally modified timber treated with methacrylate
2018 - IRG/WP 18-40849
Thermally modified timber (TMT) from Scots pine sapwood similar to Thermo-D quality was impregnated with methacrylate resin by the hot-and-cold method and subsequently cured at elevated temperatures. The results showed that methacrylate resin could be used to reduce colouring of painted TMT wood during accelerated weathering probably by hindering the migration of extractives. The resin itself did ...
O Karlsson, O Myronycheva, DJones, D Elustondo, D Sandberg


Accumulation of copper in parenchyma cells in southern pine wood treated with micronized and amine-copper preservatives
2019 - IRG/WP 19-20657
Our previous research used X-ray micro-computed tomography to examine the micro-distribution of copper in southern pine wood treated with a micronized wood preservative (MCA) and an amine-copper preservative (ACQ). We found that copper in wood treated with MCA was mainly concentrated in fusiform rays (rays containing resin canals), and in vertical (axial) resin canals. A similar, although not iden...
D Feng, M L Turner, A Limaye, M A Knackstedt, P D Evans


Use of resin obtained from Italian guayule crops for wood preservation purposes: some preliminary results
2019 - IRG/WP 19-30736
The potential of guayule (Partenium argentatum Gray) as a source of anti-termite, anti-fungal and insect repellent products to be used in wood preservation, has been largely explored in the past. The fact that such products are obtained as byproducts in the process of natural rubber extraction from this plant, thus increasing the profit of the process, together with the ability of this crop to gr...
S Palanti, E Conti, M Russo, F Stefani, C Querci


Biosourced hybrid phenolic resins as coatings for the protection of wood and wood composites
2019 - IRG/WP 19-30745
Biosourced phenolic resins, based on the phenol-formaldheyde (PF) type, were prepared for their application as coating for wood and wood composites protection, especially against fire. The resins were synthesized by combining an organic polymeric matrix with another inorganic phase. The organic phase was prepared substituting phenol by natural phenolic compounds such as lignin and tannins. The ino...
P L de Hoyos-Martínez, R Herrera, J Labid, F Charrier El Bouhtoury


Penetration pathway of oilborne preservative in heartwood of Japanese larch (Larix kaempferi)
2019 - IRG/WP 19-40886
The liquid permeability of Japanese larch (Larix kaempferi) wood is extremely low, especially in the heartwood. It is difficult to achieve the penetration of wood preservatives, which is specified by standards, with pressure treatment of waterborne preservatives. Recently, the protection treatment with an oilborne preservative called “deeper penetration treatment” is commercially available, wh...
H Shibui, T Miyauchi, T Shigeyama, M Ikeda, Y Sugai


Experience Experience from over 20 years of field trials of resin treated wood – Marine borer resistance of MMF and DMDHEU modified wood
2021 - IRG/WP 21-10976
In 1999 a field test of Scots pine treated with MMF (Methylated Melamine Formaldehyde) resin and acetylated Scots pine post treated with MMF resin was started. Six years later a commissioned full NWPC test for BASF of Belmadur® (DMDHEU resin treated wood) was started at the same site. The testing, according to European Standard EN 275, was done in a bay by Kristineberg Marine Research Station o...
M Westin, P Larsson Brelid, A O Rapp, J Habicht


Marine borer resistance of various wood materials in Japan
2021 - IRG/WP 21-10983
Wood resistance against marine borer was intensively studied in the 1940s in Japan, but the research activities on the subject diminished afterward, as the use of wooden marine structures and ships decreased. Today, however, use of wood as a construction material is officially promoted for its environmental benefits. The author started to immerse some wood materials in the seawater pool at PARI ...
M Yamada


Efficiency of three resin fractions from Aucoumea Klaineana Pierre, Canarium schweinfurthii Engl and Dacryodes edulis (G. Don) H. J. Lam from Gabon combined with Tebuconazole as wood preservatives
2022 - IRG/WP 22-10998
Pure resins from Aucoumea Klaineana, Canarium schweinfurthii and Dacryodes edulis were harvested and then hydro-distilled to obtain essential oils and purified resins fractions. Due to the potential leaching and volatility hazards of the compounds that constitute these fractions, resins and essential oils were combined with tebuconazole to produce both antifungal and anti-termite wood preservative...
W F Bedounguindzi, K Candelier, P Edou Engonga, S Dumarcay, M-F Thevenon, P Gerardin


Phenol formaldehyde modification and termite resistance under laboratory testing
2022 - IRG/WP 22-40952
The development of phenol formaldehyde (PF) resins as a means of impregnating solid wood is one that has been explored for several decades, both in terms of conventional impregnation processing (Impreg) or compressional impregnation (Compreg). However, it is only recently with advances in processing conditions that the method truly affords a means of achieving conventional modification for solid t...
L Nunes, A Pitman, M Duarte, B Stefanowski, D Jones


Biological durability for novel composites manufactured from green materials
2022 - IRG/WP 22-40960
Flax and Jute fabrics were used as reinforcements with polyester resin to form composite skins while poplar particleboard was used as a core for making composite sandwich structures by applying vacuum assisted resin transfer molding (VARTM) technique. Mechanical, physical, and biological properties of these novel green composite sandwich structures were evaluated. The results showed that the propo...
A S O Mohareb, A H Hassanin, A A Badr, K T S Hassan, R Farag


Carbon nanotubes and multifunctional silane additive as fillers in PF resin and their effect on the composite flammability
2023 - IRG/WP 23-30783
Adhesive bonds are the most readily modifiable and, at the same time, give the greatest scope for modification of components of lignocellulosic composites. A study of a manufactured lignocellulosic composite based on a phenol-formaldehyde resin and pine veneer with additives modifying the properties of the resin was made. The multifunctional commercial silicon oxide Protectosil 851 and multi-walle...
W L Grzeskowiak, B Mazela, T Prowadzisz


Resistance of phenol formaldehyde impregnated beech (Fagus sylvativa L.) LVL against biodegradation in soil contact
2023 - IRG/WP 23-40965
Alternatives to preservative impregnation are emphasized in Germany and other European countries. Even though these treatments significantly improve wood's resistance to decay, they often do not have a beneficial impact on the dimensional stability. One alternative product, which may be used in ground contact for items like poles and railway sleepers, could be beech (Fagus sylvatica L.) laminated ...
M Slabohm, C Brischke, S Bicke, H Militz


X-ray micro-computed tomography of copper distribution in CA, ACQ and MCA treated wood and changes in microstructure of ACQ-treated southern pine following natural weathering
2024 - IRG/WP 24-20707
We hypothesized that X-ray micro-CT would be able to visualize: (a) the distribution of copper in CA-treated southern pine; and (b) microstructural changes in ACQ-treated southern pine exposed to natural weathering. Small blocks were removed from southern pine samples treated with CA and also southern pine treated with ACQ and MCA. Small blocks were also removed from ACQ-treated boards (flat and p...
D Feng, M Turner, P D Evans


Preliminary investigation of the durability and performance of 1,3-dimethylol-4,5-dihydroxyethylene urea (DMDHEU) treated aspen strandboard
2024 - IRG/WP 24-30804
Wood modification technologies are growing in popularity because of their potential to improve wood properties by permanent covalent chemical modifications rather than chemical impregnation. These features can be utilized in wood composites to help improve dimensional stability and composite resistance to fungal decay. In this study, 1,3-dimethylol-4,5-dihydroxyethylene urea (DMDHEU) was used to m...
S Johnson, F Kamke, G Presley


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