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Synthesis of boric acid ammonium oleate salt for wood preservation: Leachability and termite resistance test
2007 - IRG/WP 07-30435
A new chemical compound coupling boric acid and oleic acid through a joint of ammonium salt has been produced and its synthesis followed and validated by Fourier Transformed Infra Red (FTIR). This compound named ammonium borate oleate (BAO) combining biocidal properties of boron and water repellence of fatty acids has then been studied as a wood preservative. Synthesis of BAO involved different...
F Lyon, A Pizzi, Y Imamura, M F Thevenon, S N Kartal, J Gril


Development of boron/linseed oil combined treatment as a low-toxic wood protection. Evaluation of boron fixation and resistance to termites according to Japanese and European standards
2007 - IRG/WP 07-30448
Combinations of boric acid as a first step of treatment and linseed oil as a second step have been performed in order to enhance boron retention to leaching and wood resistance to termites. Classic leaching and termites resistance standards are inappropriate to evaluate this combination which can be considered as both a wood core preservation treatment and a coating. Japanese Industrial Standard...
F Lyon, M-F Thevenon, Y Imamura, J Gril, A Pizzi


Oxidative stress and lignin peroxidase production in Phanerochaete chrysosporium
2008 - IRG/WP 08-10655
In Phanerochaete chrysosporium liquid cultures, the induction of lignin peroxidases is directly related to accumulation of reactive oxygen species at the mitochondrial level. In this study, we demonstrate that the expression of the mitochondrial thiol-related antioxidant system is not directly coupled to the LiPs expression. When the antioxidant systems are not able to cope with ROS accumulation, ...
M Morel, L Diss, C Fourrey, M Chalot, M Droux, J P Jacquot, E Gelhaye


Investigation into the antifungal properties of herbal remedies for potential use in the wood preservation industry
2008 - IRG/WP 08-30462
The efficacy of herbal remedies as potential antifungal agents was evaluated against two sapstain and three decay fungi. Sapstain fungi included Sphaeropsis sapinea, and Leptographium procerum, and decay fungi were Oligoporus placenta, Coniophora puteana, and Schizophyllum commune. Out of six herbal remedies tested, three showed moderate to high antifungal activity. Caprylic acid had high antif...
D O’Callahan


Effect of amphiphilic antioxidant alkyl ammonium ascorbate on inhibition of fungal growth: Application to wood preservatives formulation
2008 - IRG/WP 08-30466
Amphiphilic surfactants were synthesized from ascorbic acid and different fatty amines and evaluated for formulation of wood preservation products. Characterization of physicochemical properties of the new compounds indicated classical behavior of cationic surfactants. Antioxidant properties, estimated using methyl linoleate oxidation inhibition method, were similar to that of ascorbic acid teste...
C Gérardin , T Koumbi Mounanga, P Gérardin


The role of chromium in wood preservatives under BPD - a review and the current situation in Europe
2008 - IRG/WP 08-30468
Already during the IRG-meeting in Trømso a paper was presented to give an overview regarding the situation on chromium (JÜNGEL et al. 2006). Already in that year there was an increased attempt to achieve a science-based correct and harmonised solution in Europe regarding the chromium-question by the European Commission. Nevertheless the competent authorities (CAs) and the industry were similarly...
P Jüngel, S Hellkamp


Preservative treatment of strips of Bambusa balcooa by soaking process using Borax-Boric acid
2008 - IRG/WP 08-30478
Bamboo strips made from Borak bamboo (Bambusa balcooa) were treated with 10% borax-boric acid aqueous solution by soaking process. The moisture contents of the bamboo strips were 12%, 20% and 30%. The strips were soaked for one, two, three, four and five days. The penetration of the solution was investigated by colour test after soaking and drying. Full penetration was observed after three days ...
K Akhter, M W Sheikh, M M Rahman, T A Chowdhury, M H Chowdhury


Effects of acetic acid and nitric acid pre-treatment on copper content of spruce wood treated with CBA-A and CCA
2008 - IRG/WP 08-40406
This work investigates the effects of nitric acid and acetic acid on compression strength values and copper retention contents of refractory spruce wood (Picea oriental L.) treated with the waterborne preservative Copper azole, (CBA-A, Tanalith-E 3492) and copper / chrom / arsenic (CCA). Before the CBA-A and CCA treatment, the samples were immersed in 500 ml of nitric and acetic acid solutions for...
S Yildiz, E Dizman, Ü C Yildiz


Chemical Analysis in Production Quality Control at Wood Treatment Plants
2008 - IRG/WP 08-20396
Analysis methods for quality control analysis in wood treatment plants have evolved with the changes in treatment preservative chemistries and analytical instrument technology. The basic hydrometer specific gravity measurements used for solution strength and classic wet chemistry methods for wood have given way to instrumental techniques such as X-ray fluorescence, automatic titrator, and HPLC. No...
P Walcheski, L Jin


Multifactorial Antimicrobial Wood Protectants
2008 - IRG/WP 08-30484
It is unlikely that a single antimicrobial compound, whether synthetic or natural, will provide the ‘magic bullet’ for eliminating multiple biological agents affecting wood products. Development of synergistic combinations of selected compounds, especially those derived from natural sources, is recognized as a promising approach to improved wood protection. Recent adoption of effective fungici...
R D Coleman, C A Clausen


Degradation of wood veneers by Fenton’s reagents: effects of low molecular weight phenolic compounds on hydrogen peroxide decay and tensile strength loss
2009 - IRG/WP 09-20400
Pine wood (Pinus sylvestris) veneers strips were incubated in acetate buffer containing hydrogen peroxide and iron to mimic mechanisms of brown rot decay and assess the degradation of cellulose through analysis of the tensile properties of the decayed wood. The tensile properties of thin wood strips treated with Fenton system reagents or precursors were determined and correlated to weight loss as ...
Yanjun Xie, R Well, Zefang Xiao, B Goodell, J Jellison, H Militz, C Mai


Laboratory and above ground exposure efficacy of silicon-boron treatments
2009 - IRG/WP 09-30510
The study deals with silicon compounds, namely tetraethoxysilane (TEOS), phenyltriethoxysilane (PhTES) and methyltriethoxysilane (MTES) at concentrations of 23, 16 and 10% in combination with 1.2-1.5% boric acid. The aim with the study was to combine the chemical approach with the necessary biological tests of the impregnated wood. The tested silicon-boron combinations ensured mass loss less than ...
N Terziev, D Panov, A Temiz, S Palanti, E Feci, G Daniel


Rapid Microwave-Assisted Acid Extraction of Metals from Chromated Copper Arsenate (CCA)-Treated Southern Pine Wood
2009 - IRG/WP 09-50262
The effects of acid concentration, reaction time, and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with three different acids (i.e., acetic acid, oxalic acid, and phosphoric acid) was investigated using in microwave reactor. Oxalic acid wa...
Bin Yu, Chung Y Hse, T F Shupe


Material properties of furfurylated wood for window production
2009 - IRG/WP 09-40480
Wood modification with furfuryl alcohol is an extensively investigated process and already produced commercially. Furfurylated wood is in the focus of a European project on its use for the production of high performance windows. Different wood species were treated with furfuryl alcohol and tested on water uptake, dimensional changes, leaching in water, resistance to fungal degradation, and ecotoxi...
A Treu, A Pilgård, S Puttmann, A Krause


Measurements of rot fungal activity as a function of moisture content by isothermal calorimetry
2010 - IRG/WP 10-20428
Measurements of heat production rate have been made on wood samples with the brown rot fungus Postia placenta at different moisture contents. The results clearly indicate that the heat production rate (a measure of respiration rate and activity) is moisture dependent. When the moisture content is decreased, less heat is produced, and when the moisture content is increased, more heat is produced. I...
L Wadsö, A Pilgård, G Alfredsen


Photostabilization of Wood with Higher Molecular Weight UV Absorbers
2010 - IRG/WP 10-30524
Higher molecular weight UV absorbers were created by reacting the epoxy-functionalized UV absorber 2-hydroxy-4(2,3-epoxypropoxy)-benzophenone (HEPBP) with maleic, phthalic or succinic anhydride. The ability of the UV absorbers to photostabilize wood was then examined. FTIR-spectroscopy confirmed that HEPBP reacted with phthalic anhydride to create a polyester that preserved the UV-absorbing benzop...
P D Evans, M J Chowdhury


Antifungal and wood preservative efficacy of IPBC is enhanced by α - aminoisobutyric acid
2010 - IRG/WP 10-30544
There is currently a need to reduce the biocide content of wood preservatives, without decreasing efficacy. The nonmetabolised amino acid analogue α-aminoisobutyric acid (AIB) acts as a translocated inhibitor of mycelial spread in basidiomycete wood decay fungi, although it does not kill the organism. Factorial combinations of AIB with either the azole fungicide tebuconazole, or 3-iodo-2-...
P Bota, E Baines, A Mead, S C Watkinson


Sorption properties of wood impregnated with aqueous solution of boric acid and montan wax emulsion
2010 - IRG/WP 10-40492
Non-biocidal techniques for wood protection become more and more important, nowadays. One of the possible treatments is use of water repellents. In the present research influence of, one of the possible water repellent, the montan wax emulsion, on the moisturizing and the sorption characteristic of impregnated wood was investigated. To achieve a better protection against wood decay fungi, montan w...
B Lesar, M Humar


Influence addition of boron compounds to adhesives on the bonding quality and fungicidal properties of glued wood
2010 - IRG/WP 10-40497
Wood is one of the most important construction materials. However, users of wood face two issues: limited dimensions and insufficient durability. These issues have been overcome with the development of bonding and wood preservation. The preservation of glued wood is elucidated in this paper. Through the addition of boric acid to adhesives, we tried to improve the fungicidal properties of glued woo...
M Humar, B Lesar, A Ugovsek, M Kariz, P Kralj, M Šernek


Effect of borax-boric acid Treatment of simul (Bombax ceiba) Veneers on Glue-Bond Quality of Plywood
2010 - IRG/WP 10-40525
The glue-bond quality of plywood made of treated simul (Bombax ceiba) veneers was investigated. The veneers were treated with cold and hot water solution of borax-boric acid (BB) of different concentrations and treatment durations. The plywoods were made at three different pressures in hot press using urea formaldehyde glue. The glue-bond strength of untreated plywood in dry shear-test was found t...
K Akhter, Md Abul Hashem, S Akhter


Preservative Treatment of simul (Bombax ceiba) Veneers with Hot and Cold Water Solution of borax-boric acid by Soaking Process
2010 - IRG/WP 10-40528
Veneers of simul (Bombax ceiba) were treated with different concentrations of water- borne preservatives borax-boric acid (BB) by soaking process for different time periods. In the case of hot water treatment, it was found that the average retention of preservative chemicals increased gradually with the increasing treatment period from 20 minutes to 60 minutes. Similar trend was observed in the ca...
K Akhter, Md Abul Hashem, S Akhter


Combined Effect of Boric Acid and Waste Oil Treatment on Boron Leaching
2010 - IRG/WP 10-50268
In this study it was aimed to investigate the boron leaching amounts in Scots pine wood samples treated with boric acid (BA) and waste oil (WO) alone or by dual treatment. The level of water absorption and water repellent efficiency were determined with cyclical wetting tests, total of 336 hours. Wood samples that have both covered and uncovered transversal section were impregnated with 3% boric a...
Ü C Yildiz, E Dizman


Climate change and wood protection, increasing demand of long life wood products and decreasing production of treated wood
2010 - IRG/WP 10-50269
Several new topics related to wood protection sector has appeared in Japan, as the awareness of climate change becomes bigger and bigger. The “Basic act for housing (2006)” and the “Long-life housing promotion act (2009)” were enforced to form a safe and high quality housing stock and to form a long-service-life housing respectively. Despite of the favorable background for wood protection ...
K Yamamoto, H Kato


Isolation and evaluation of Lactobacillus brevis from chilli waste for potential use as a wood preservative
2011 - IRG/WP 11-10749
Lactic acid bacteria were isolated from chilli waste and evaluated for their ability to arrest wood rotting basidiomycetes. In previous work a quick screening method using 96 well plates and measuring absorbance to determine fungal growth was developed specifically to investigate the efficacy of isolated bacteria against wood decay fungi. Using this method, one bacterium (isolate C11) was identif...
D O’Callahan, T Singh, I R McDonald


Design, synthesis, characterisation and effectiveness of ‘Locked-in-Boron’ chemicals for H3.2 level of wood protection
2011 - IRG/WP 11-30577
Boratrane molecules with five-membered and six-membered molecular ring systems, and with various ring substituents were synthesised, characterised and formulated for wood treatment for accelerated laboratory bioassays using wood decay fungi as test organisms. Six-membered ring boratranes showed lower efficacy in laboratory assays than five-membered ring boratranes. One alkyl-substituted boratran...
R Franich, H Kroese, S Gallagher, S Hill, B Kelly, G Billett, R Meder, W Rae


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