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Effect of P/F ratio, PF concentration and treating method on boron leaching from wood treated with PF modified boron compounds
2011 - IRG/WP 11-30559
In order to immobilize boron in wood, three kinds of resol-type phenol-formaldehyde (PF) resin with different P/F ratios were synthesized in laboratory and incorporated with three types of boron compounds to treat wood. The used boron compounds included boric acid (BA), borax (BX) and disodium octaborate tetrahydrate (DOT). The leaching test of boron from wood blocks was performed according to the...
Liping Yu, Jinzhen Cao


The case for using borates in termite control in tropical Australia
2011 - IRG/WP 11-30573
A brief historical overview of boron based wood preservatives efficacy against subterranean termite management worldwide, and in Australia, is presented. The boron based compounds to be used in H2 hazard conditions, may be applied as a surface treatment by dip, flood coat or spray, and rapidly penetrates to the centre of timber substrates, whether containing sapwood or heartwood. However, section ...
B M Ahmed (Shiday), J R J French


Smart hydrogels from low molecular weight amphiphilic compounds: toward a solution to decrease leachability and increase efficacy of boron preservatives?
2012 - IRG/WP 12-30589
A new catanionic system associating amphiphilic carnosine (AlaHisC8) and lauric acid forms supramolecular hydrogel at very low concentration. This gel was investigated and we have checked the validity of the concept of hydrogels utilization to reduce boron leachability and to develop new wood protection treatments. Impregnation with 5% aqueous borax solution (w/w) and 0.3% gelator agent (...
F Obounou Akong, P Gérardin, C Gérardin-Charbonnier


Evaluation of Five Novel Organotin(IV) Complexes as Wood Preservatives
2012 - IRG/WP 12-30590
Three selected non durable tropical wood species namely Alstonia scholaris (pulai), Macaranga triloba (mahang) and Hevea brasiliensis (rubber) were chemically impregnated with five novel organotin(IV) complexes using vacuum-pressure treatment method. The objectives of this study were to determine the treatability and efficacy of novel organotin(IV) complexes against white and brown rot decay fungi...
M M Rahman, I Jusoh, M A Affan, A Husaini


Stabilization of IPBC in wood through the use of organosilicon compounds
2012 - IRG/WP 12-30597
The aim of the research was to increase durability of wood treated with 3-Iodo-2-propynyl butylcarbamate (IPBC). The study used a blend of silanes. Biological examination against microfungi was performed to determine resistance of Scots pine wood treated with the tested formulations. Chemical analysis by the Electrospray Ionization Mass Spectrometry (ESI-MS) of water extracts from the leaching per...
B Mazela, W Perdoch


The Effects of Industrial-Scale Heat Treatment and Impregnation with Boron Compounds on Water Uptake and Tangential Swelling of Some Wood Species
2012 - IRG/WP 12-40599
This study evaluated the effects of boron impregnation and heat treatment on water uptake and tangential swelling of spruce (Picea orientalis), pine (Pinus nigra), beech (Fagus orientalis) and poplar (Populus deltoides) wood species. The samples (10 x 5 x 40 - tangential x radial x longitudinal cm) were impregnated with 4 % boric acid and 4 % borax according to the ASTM D-1413 standard method. Aft...
A Can, S Yildiz, Ü C Yildiz


Termite resistance of wood impregnated with phenol-formaldehyde (PF) modified boron compounds
2012 - IRG/WP 12-30604
In order to investigate the effect of phenol-formaldehyde (PF) modified boron compounds on termite resistance of two main plantation-grown wood species, namely, Masson pine (Pinus massoniana Lamb.) and Chinese fir (Cunninghamia lanceolata (Lamb.) Hook.), laboratory termite tests and field tests were carried out according to AWPA standard E1-97 and AWPC protocols/2007. Different concentrations of b...
Jinzhen CAO, Liping YU, Xuexiang HE


Developing Analytical Methods for Determination of Quaternary Ammonium Compounds (DDAC) using HPLC and HPLC-MS (Application to treating solution and preservatives treated wood)
2013 - IRG/WP 13-20516
Korea preservative treating industry has mainly used alkaline copper quaternary (ACQ) expected over 80% of market share in Korea. ACQ employs dodecyl dimethyl ammonium chloride (DDAC) and benzyl dimethyl dodecyl ammonium chloride (DBAC) for active ingredient along with copper. The strongly increasing domestic applications for wood preservatives require developing accurate and reproducible analytic...
Sung-Mo Kang, Kwon-Min Kim, Won-Mo Koo, Myeong-Won Cho


Performance of biocide-free preservative-protective systems modified with organosilicon compounds
2013 - IRG/WP 13-30628
The objective of the research was to determine the influence of organosilicon compounds in preservative-protective systems on the selected properties of pine wood aimed for outdoor use. The investigations were made for biocide-free systems based on alkyd resin and natural oils modified with alkylalkoxy-, amino- and glycidoxysilanes. The special attention was paid on the influence of hydrophobic pr...
B Mazela, P Hochmańska, T Krystofiak


Fire resistance of wood treated with potassium carbonate and silanes
2014 - IRG/WP 14-30657
This paper reports on the effect that organosilicon compounds and potassium carbonate and urea (PCU) have on wood flammability. The study focus on reducing wood flammability by promoting char formation through manipulation of the condensed phase decomposition chemistry. Potassium carbonate is known as an effective fire retardant, however it is easily leached out from wood and increases its hygrosc...
B Mazela, M Broda, W Perdoch


Reducing Extractives Stain in Western Red Cedar Sidewall Shingles
2014 - IRG/WP 14-30654
One of the aesthetic challenges that western red cedar shingles face is extractives redistribution stain, particularly in unpainted sidewall applications. Dip and pressure treatments with a mixture of quaternary ammonium compounds and alkyl amine oxides were investigated for their ability to prevent this stain. After nine months of exposure in Vancouver, extractives stain was present on nearly all...
R Stirling


Above ground field testing: results of experiments in Brazil after one year
2015 - IRG/WP 15-30660
After the development of new products they need to be field-tested to assess their efficacy under diverse conditions of climate, comparing them with a preservative with proven efficacy. In some testing sites, decay occurs very slowly. The solution would be to bring these tests to locations that are conducive to biodeterioration, like tropical climates. Tropical sites provide higher temperature and...
M F Natale, J M Vidal


Antifungal properties of wood treated with IPBC and organosilicone compounds against Coniophora puteana
2015 - IRG/WP 15-30676
The aim of the research was to increase durability of Scots pine wood treated with 3-Iodo-2-propynyl butylcarbamate (IPBC) through organosilicon compounds. The IPBC was combined with organosilicon compounds (alkylsilane and alkylsilane with amino groups) for supporting its antifungal properties. The mycological examination against Coniophora puteana was performed to determine the resistance of woo...
W Perdoch, B Mazela, A Waśkiewicz


Bio-friendly preservative systems for enhanced wood durability - the first periodic report on DURAWOOD
2015 - IRG/WP 15-30677
The objective of the paper is the DURAWOOD scientific project carried out within Polish-Norwegian Research Programme, which lasts from September 2013 till August 2016. The aim of the project concentrates on the developing of a new, eco-friendly and biocide-free wood protective systems as an alternative to traditional, commonly used preservatives or coatings, containing biocides. Several wood prese...
B Mazela, M Broda, W Perdoch, L Ross Gobakken, I Ratajczak, G Cofta, W Grześkowiak, A Komasa, A Przybył


Characterization of waste from Pinus radiata generated during industrial thermal-treatment
2016 - IRG/WP 16-20586
The thermal-treatment is an established chemical-free process to modify wood, improving the durability and physical properties of wood through its service life. During the hydro-thermolysis several reactions from wood components occur, releasing volatile and non-volatile compounds from wood to the chamber. Once the process is accomplished, solid residues agglomerate below the wood load and gaseous...
R Herrera, D Thomas da Silva, R Llano-Ponte, J Labidi


Insight in moisture dynamics of wood treated with organosilicon compounds
2016 - IRG/WP 16-20598
The SILEX project “Improving sustainability of construction materials using innovative Silicon based treatment” is a Life+ project with reference LIFE+11 ENV/BE/1046 and started in April 2013. This project intends to demonstrate that a new class of compounds can be used for wood treatment for an extended service life combined with enhanced new testing methodology. The project aims at demonstra...
J Van Acker, J Van den Bulcke, I De Windt, S Colpaert, S De Rocker, S Salvati, J-P Lecomte


Assessment of the biological durability of wood treated with organosilicon compounds
2016 - IRG/WP 16-30685
The European wood construction market is in need of environmentally friendly wood-based products whose service life meets the expectations of end users. Non-biocidal silicon-based water repellents, which can be applied to different materials, help minimize their vulnerability/susceptibility to liquid water. Consequently, they have the potential of increasing wood’s resistance against decay fungi...
M Kutnik, M Montibus, S Derocker, S Salivati, J-P Lecomte


Development of a new method for wood hydrophobizing and fixation of copper compounds by chemical hardening of vegetable based modified oils
2016 - IRG/WP 16-40754
Wood products with ground and direct water contact, but without sufficient biological durability, have to be protected against biological degradation by fungi and other microorganisms. Due to European legislation (Biocidal Products Regulation 528/2012), the selection of possible chemical agents, which are still allowed to be used, is diminishing rapidly. The use of previously widely applied, very ...
C Swaboda, M Fischer, K Jacobs


Influence of organosilicon compounds and nanocellulose treatment on dimensional stability of waterlogged elm wood
2017 - IRG/WP 17-10891
Commonly used agents for waterlogged wood consolidation (including the most popular polyethylene glycol) have proved ineffective and even dangerous to the preserved objects, jeopardising their integrity. Finding new, effective alternatives for safe preservation of wooden cultural heritage is therefore of key importance. The future conservation agents should, first and foremost, provide the integri...
M Broda, B Mazela, I Dąbek, A Dutkiewicz, H Maciejewski, R Markiewicz, M Grzeszkowiak, S Jurga


Organosilicon-based impregnation hydrophobers for wood
2017 - IRG/WP 17-40808
The SILEX project “Improving sustainability of construction materials using innovative Silicon based treatment” is a Life+ project with reference LIFE+11 ENV/BE/1046 and started in April 2013. This project intends to demonstrate that a new class of compounds can be used for wood treatment for an extended service life combined with enhanced new testing methodology. The project aims at demonstra...
J-P Lecomte, J Van Acker, J Van den Bulcke, M Kutnik, M Montibus, S Salvati, S Derocker


Chemical composition and termiticidal activity of Khaya ivorensis stem bark extracts on woods
2018 - IRG/WP 18-30723
The genus Khaya is extractives rich, but the extractives in the stem bark are among the most abundant, accessible and utilised materials in Nigeria. These extractives are of considerable interest for wood protection because of their pesticidal properties. In this study, the chemical constituents of Khaya ivorensis stem bark (KISB) and their termiticidal activity were investigated on Triplochiton s...
G A Adedeji, O Y Ogunsanwo, F S Eguankun, T O Elufioye


Enhancing service life performance of oak decking and cladding using organosilicon treatments
2018 - IRG/WP 18-40838
The Life+ project SILEX, in full “Improving sustainability of construction materials using innovative Silicon based treatment” started in April 2013 and was finalized mid 2017. The aim of this project was to demonstrate that a new class of compounds can be used for wood treatment for an extended service life combined with enhanced new testing methodology. Ultimately, it was the intention to de...
J Van Acker, J Van den Bulcke, J-P Lecomte


Non-stochiometric oxidation and ROS generation promoted by guaiacol lignin structures and lignocelluose surfaces may be a component of brown rot fungal degradation mechanisms
2019 - IRG/WP 19-10937
Model guaiacol compounds representing lignin monomers, as well as DHP-lignin and wood flour of controlled particle size were used to assess iron reduction at the pH of the natural wood cell wall. All compounds functioned as electron donors for ferric iron, with the lignin monomers demonstrating capacity for non-stochiometric reduction of iron with multiple moles of ferric ion reduced per mole of l...
Y Tamarua, M Yoshidaa, L D Eltisb, B Goodell


Identification of Antifungal Compounds in Konjac Flying Powder and Assessment against Wood Decay Fungi
2019 - IRG/WP 19-30737
The antifungal activity of konjac (Amorphophallus rivieri) flying powder (a by-product produced during mechanical processing of konjac flour) ethanol extract was evaluated against wood decay fungi in culture. Compounds associated with antifungal activity in the extracts were isolated and purified by silica gel column chromatography. The antifungal active fractions were identified by ultra-high-per...
Z Bi, F Yang, Y Lei, J J Morrell, L Yan


Extraction, identification and antifungal activity of polar extractives originated from various wood species
2020 - IRG/WP 20-20673
Extractives are non-cell wall small molecules present in wood and other lignocellulosic materials that can be removed by solvents. Although they represent a minor fraction in comparison with the structural cell wall components, they are an important source of functional groups or molecules with bioactivity or antioxidant properties, that could be used in medicine, cosmetic or wood preservation. T...
R Herrera, F Poohphajai, J Labidi, S Willför, A Sandak


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