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Efficacy of a novel copper-based organic solvent preservative in laboratory and fungus cellar tests
1995 - IRG/WP 95-30071
The efficacy of Chemicca 4, a novel copper-based organic solvent preservative, was compared with that of other LOSP in pure culture laboratory decay tests and with that of CCA and TBTO in a fungus cellar exposure. It was markedly superior to copper and zinc naphthenates at equivalent metal retentions in laboratory decay tests, and similar in activity to TBTO. After 60 months' fungus cella...
M E Hedley, P N Maynard


The bacterial transformation of organic biocides; a common mechanism?
2006 - IRG/WP 06-10585
It was found that a number of unformulated organic biocides showed a susceptibility to degradation by proteobacteria. Exposure of tebuconazole, a candidate biocide, chlorothalonil and IPBC to a Ralstonia strain was found to result in biocide detoxification, as demonstrated through HPLC and a bioassay. Exposure of the biocides to a previously identified extracellular factor was also found to resu...
D F Wallace, D J Dickinson


Measuring Soil Respiration as a New Approach to Describe the Interaction Between Wood (Treated and Untreated) and Microbiologically Active Soil
2006 - IRG/WP 06-20344
Soil respirometry was employed to examine the relationship between both the performance of copper organic preservatives in contact with and the amount of carbon dioxide evolved from soil and the effect of wood treated with preservatives on carbon turnover in soil. Wood was treated with a range of copper organic preservatives intended for use in ground contact as well as an organic preservative in...
I Stephan, W Mierke


Ionic liquids with organic and inorganic anions as highly active wood preservatives
2006 - IRG/WP 06-30411
Quaternary ammonium tetrafluoroborates, nitrates(V), propionates, acetates and formates with alkoxymethyl substituents were prepared and tested on wood destroying and sapstaining fungi. These new compounds are ionic liquids (ILs), which penetrate very well into Scot pine wood. Alkoxymethyldecyldimethylammonium tetrafluoroborates and nitrates(V) show better microbial activity against Coniophor...
J Zabielska-Matejuk, A Skrzypczak


Degradation of polychlorinated organic biocides by the wood decaying fungi
2008 - IRG/WP 08-50253
Organochlorine biocides such as lindane, pentachlorophenol sodium salt, and polychlorinated biphenyl 153 have been widely used as wood preservatives. Due to their low degradability by soil bacteria, treated waste wood products pose a serious threat to the environment. Consequently, there is an increased need for development of new strategies for their detoxification. In this work, the bioremediati...
I Vidic, L Zupancic-Kralj, K Sepcic, F Pohleven


Durability and fungal colonisation patterns in wood samples after six years in soil contact evaluated with qPCR, microscopy, TGA, chitin- and ergosterol assays
2009 - IRG/WP 09-20402
There is a need to establish new objective and sensitive methods for early detection and quantification of decay fungi in wood materials. Molecular methods have proven to be a useful tool within wood protection issues, however, this field is still poorly explored and so far relatively few have used these methods within the field of wood deterioration. Among the techniques used in the indirect quan...
A Pilgård, G Alfredsen, I Børja, C Björdal


Evaluation of Water Repellency of Treated Wood Using Several Alternative Methods
2009 - IRG/WP 09-20419
In this study, the results of water repellency testing using a digital swellometer method for water-borne organic-preservative systems with water repellent additives are reported. The findings suggest that the traditional method of using matched untreated controls as a reference developed from historic solvent-based treatments for determination anti-swelling efficacy (ASE) may underestimate the a...
L Jin, A F Preston


Mold-resistance Effect of Bamboo Wood Treated with CCC-organic Complexes
2009 - IRG/WP 09-30514
Mold resistant effect of CCA, ACQ, CuAz, CCC and the compound of CCC and propiconazole were researched on bamboo wood of Phyllostachys pubescens were reported in this paper. Results showed that all of the test fungicides could protect bamboo wood better from Penicillam citrinum than from Trichoderma viride and Aspergillus niger. The complex of CCC and propiconazole had the best resisting effect on...
Sun Fangli, Yang Le, Chen Anliang, Bao Binfu, Li Qiao


Hydrofluoroalkanes as carrier solvents for timber preservation
2009 - IRG/WP 09-40463
Hydrofluoroalkanes are a specific category of hydrofluorocarbon (HFC) commonly used in refrigeration applications. Some HFCs hold potential for use as carrier fluids for preservatives used to protect timber above ground. They do not share the most significant disadvantages of currently used carriers for these applications. At ‘conventional’ operating pressures, they are capable of rapid, full ...
M J Kennedy, B Walker, C Erskine


Microscopy evaluation of microbial decay patterns in wood stakes after 6 years in soil contact
2010 - IRG/WP 10-10715
Most studies on wood modification have so far been concerned with service life predictions rather than investigating the decay protection mechanism. Very little is known about the mode of action of these new treatments and about the strategies used by wood degraders in order to utilize the wood material despite a treatment. Access to such knowledge would allow further modification and improvement ...
A Pilgård, C G Björdal


The Relative Performance of an Organic Preservative System under UC3A and UC3B Conditions using Two Test Methods
2010 - IRG/WP 10-20429
Coated L-joints have been used for decades to evaluate the performance of wood preservatives in protected environments. This study was conducted using matched coated and uncoated L-joints to simulate above ground protected and unprotect exposures. When exposed to constant moisture in a greenhouse environment, coated and uncoated L-joints give very similar performance results. In contrast, exposi...
C F Schauwecker, A Zahora, A F Preston


Natural compounds: A review of their use for wood protection
2010 - IRG/WP 10-30545
A lot of research in the field of wood protection has focused on natural compounds but very few of these have been implemented by industry. This review is an attempt to bring together information from selected area of work: - A brief review of the work done on natural products as organic biocides for wood protection. - Table containing information on natural products, their use as organic biocid...
T Singh, A P Singh


Comparison of colour change in wood clear-coating systems including inorganic and organic UV absorbers for exterior use
2010 - IRG/WP 10-40499
The aim of this work is to compare the performance of inorganic and organic UV absorbers used in a wood coating application against weathering. Our study has investigated the colour changes of selected UV absorbers; hombitec 402 RM from the Sachtleben Company as an inorganic UV absorber, tinuvin 477 DW from the Ciba Company as an organic UV absorber. The study was carried out on two wood species; ...
Ö Özgenç, B Forsthuber, A Teischinger, C Hansmann


Microwave-Assisted Organic Acids Extraction of Chromate Copper Arsenate (CCA)-Treated Southern Pine
2010 - IRG/WP 10-50267
The extraction effects of acid concentration, reaction time and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with two different organic acids (i.e., acetic acid and oxalic acid) was investigated using a microwave reactor. Oxalic acid was e...
Bin Yu, Chung Y Hse, T F Shupe


Effect of an antioxidant on the efficacy of organic wood preservatives in an accelerated soil contact decay test
2012 - IRG/WP 12-30583
In comparison to inorganic wood preservatives, organic biocides in transient carriers are considerably less effective when the treated wood is exposed to soil contact. Various oils are used in some formulations with pentachlorophenol to improve the efficacy. However, use of these oils imparts unacceptable properties to products used in residential applications. Consequently, there is a need to de...
D D Nicholas, J Shi, T P Schultz, L Sites


Report on COST E37 Round Robin Tests – Comparison of results from laboratory and field tests
2013 - IRG/WP 13-20535
A round robin involving 15 European participants was set up in 2006. The round robin consists of both a field test according to the double layer test method and a laboratory test with two different preconditioning methods. When comparing EN 84 preconditioning (two weeks water leaching) with natural preconditioning (1 year in field, above ground) according to CEN/TS 15397, no significant difference...
M Westin, E Conti, J Creemers, P-O Flæte, A Gellerich, I Irbe, M Klamer, B Mazela, E Melcher, R Möller, L Nunes, S Palanti, L Reinprecht, E Suttie, H Viitanen


Influence of selected additives on organic fungicides for control of bamboo mold fungi
2013 - IRG/WP 13-30626
In order to assess the long-term efficacy of supplemented organic fungicides in outdoor applications, additives - including the antioxidant butylated hydroxytoluene (BHT) and a UV absorber and free radical scavenger benzotriazole (BTA), were selected to mix with the fungicides propiconazole or tebuconazole. Freshly cut samples from four-year old bamboo stems were treated with combinations of the c...
Sun Fangli, B Goodell, Chen Anliang, Bao Binfu, Zhang Shaoyong


Changes in mechanical and chemical properties of wood exposed outdoors
2014 - IRG/WP 14-20550
The aim of this study was to investigate differences in certain mechanical and chemical properties of three different wood species (common beach (Fagus sylvatica), Norway spruce (Picea abies), and copper-ethanolamine (CuE) impregnated Norway spruce (Picea abies)) that were exposed in use class 3 (CEN, 2006) for periods between 4 and 30 months. The results show, that changes in the investigated me...
N Thaler, C Brischke, D Žlindra, V Vek, M Humar


VOC-free remedial treatment agent on organic solvent basis with surface cleaning by photocatalysis using titanium dioxide
2014 - IRG/WP 14-40651
Due to the EU Regulations according to the harmonisation of the European market of biocidal products and the EU Regulations regarding emissions of volatile organic compounds in residential properties a new VOC free yet organic solvent based remedial treatment agent is introduced including a potential method to clean up the wooden surface of remaining biocides after a remedial treatment using photo...
H Ahl, J Fromm, P Jüngel, E Melcher, M Pallaske


Short-term protection of palm wood against moulds and decay fungi by environment-friendly organic acids
2015 - IRG/WP 15-10843
Felled palm trunks are susceptible to fungi as long as their moisture content is above fibre saturation. During this period, it has to be protected against moulds and decay fungi. The study tested environmental-friendly organic acids for their protecting efficiency. Small samples of Date palm (Phoenix dactylifera) and Oil palm (Elaeis guineensis) wood were treated with weak organic acids and subse...
M Bahmani, O Schmidt


A non-VOC approach of solvent-based wood preservatives for remedial treatment
2016 - IRG/WP 16-30681
Solvent-based wood preservatives are the workhorses in the field of remedial treatment. Due to new European regulations on the indoor air quality there is an increasing pressure on the VOC-content on these solvent-based product types. The transfer of these European regulations into national law is left up to each European member state and handled in different ways. E.g. France has introduced a VO...
M Pallaske, S Hellkamp, P Jüngel


10 year Report on COST E37 Round Robin Tests – Comparison of results from laboratory and field tests
2017 - IRG/WP 17-30718
A round robin involving 15 European participants was set up in 2006. The round robin consisted of both a field test according to the double layer test method and a laboratory test with two different preconditioning methods. The laboratory test results were reported in an earlier IRG paper (IRG/WP13-20535) but are included also in this paper in order to facilitate the comparison with the field test...
M Westin, E Conti, J Creemers, P-O Flæte, A Gellerich, I Irbe, M Klamer, E Melcher, R Moeller, L Nunes, S Palanti, L Reinprecht, E Suttie, H Viitanen


Prevention of fungal damage of oil and date palm wood by organic acids
2017 - IRG/WP 17-10877
Felled palm trunks are susceptible to fungi as long as their moisture content is above fibre saturation. During this period, palm wood has to be protected against mould and rot fungi. Environmental-friendly organic acids are suitable. Small samples of oil palm (Elaeis guineensis) and date palm (Phoenix dactylifera) wood were treated with 1 to 10% solutions of acetic acid and propionic acid, respec...
M Bahmani, O Schmidt


Monitoring of wood preservatives exposed to weathering: Extraction and analysis methods of organic biocides from treated wood and collected rain runoff
2020 - IRG/WP 20-30753
Weathering is the cause of numerous damages for outdoor joineries. Protection of wood using a preservative treatment covered with a coating is a process widely used to limit these damages. However, biocides from preservative treated wood are prone to degradation and leaching, having a direct influence on the joinery service life. This document deals with extraction and analytical methods for bioci...
O Ouali, K Le Ménach, E Raphalen, L Podgorski, S Legay, H Budzinski


Effect of MVOC exposure on mycelial growth of wood rotting fungi
2021 - IRG/WP 21-10977
It is well known that wood rotting fungi produce microbial volatile organic compounds (MVOCs) as metabolites. In our previous studies, we have found that some MVOCs produced by wood rotting fungi are common to fungal species tested in the studies, while others are specific to each species. Furthermore, it has been also shown that each wood rotting fungi do not always produce the same type of MVOCs...
S Horikawa, R Konuma, M Yoshida


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