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Factors Affecting Performance of Preserved Wood Decking Against Decay Fungi
2015 - IRG/WP 15-30663
Decking is the largest market for residential preserved wood in the United States. Preserved decking must be resistant to colonization by decay fungi initiating from spores, and occasionally from mycelia due to elevated soil levels or adjacent untreated wood. The most vulnerable parts of a preserved wood deck are untreated, or under-treated, wood that becomes exposed by field cuts and checking. Fi...
R Stirling, P I Morris


The effect of preservative treatment on mechanical strength and structural integrity of wood
2015 - IRG/WP 15-30667
The use of wood for demanding construction applications is increasing in Europe. Wooden constructions are frequently designed of susceptible conifer wood, which is endangered by wood decay fungi in wet applications. Therefore in many cases treating wood with preservatives is unavoidable to ensure the desired service life. However, chemical treatment of wood can result in changes of its mechanical ...
M Humar, D Kržišnik, C Brischke


Search for an anti-sapstain treatment for fresh radiata pine wood in compliance with European BPD norms: Field Tests
2015 - IRG/WP 15-30673
In response to the impending restrictions on the use of pesticide active ingredients developed to control the staining of fresh wood, as a result of regulation issued in 2009 by the European Union, a project was proposed to test an alternative anti-sapstain treatment that meets both the European restrictions and the performance required for an export-quality radiata pine fresh wood treatment. A se...
P Montes C, T Hanke W


Buffered Amine Oxide Treatment Systems for Imparting Water Based Azoles/Insecticides in Douglas Fir and Eucalyptus
2015 - IRG/WP 15-40707
In today’s world, wood remains the most versatile, practical and sustainable building material. In contemporary countries, wood is a well-managed renewable resource that has a remarkably small carbon footprint compared to those of steel, aluminium, composites, and concrete. These alternative materials have continued to emerge as viable building materials given the durability issues of untreate...
R W Clawson Jr


A Green and Novel Technology for Recovering Copper and Wood from Treated Waste - Part I
2015 - IRG/WP 15-50309
Preservative treatment of wood extends its service life. The US consumes about 70 million pounds of copper and produces about 7 billion board feet of treated wood annually. Burning and reusing CCA and copper treated wood wastes are disallowed by US EPA due to health and environmental concerns. Millions of pounds of copper and wood are disposed by landfill annually. The objective of this study was...
S Chen


Environmental Fate of Micronized Copper
2015 - IRG/WP 15-50310
The environmental fate of wood preservatives is an important aspect to estimate the health and environmental impact. Although biocides from treated wood may be released into the soil, water or air, the latter pathway is frequently neglected in favour of leaching studies. Nonetheless, wood dust is well known to cause a variety of adverse health effects, in particular diseases to the respiratory tra...
C Civardi, L Schlagenhauf, J Benz, C Hirsch, J Van den Bulcke, M Schubert, J Van Acker, P Wick,


Recycling of used railroad ties via two-staged pyrolysis for fractionation of wood preservatives and bio-oil: pyrolytic characterization by TGA and Py-GC/MS
2015 - IRG/WP 15-50311
Creosote and copper naphthenate (CuNap) (in an oil carrier) treated railroad tie materials (crossties or sleepers) were initially heat-treated at 200 – 300 oC and subsequently pyrolyzed via thermogravimetric analysis (TGA) and pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) to recover wood preservatives and produce a higher quality bio-oil. Preservative-desorptive temperatures at 200 a...
Pyoungchung Kim, J Lloyd, Jae-Woo Kim, N Labbe


Effect of exposure site on metal migration from copper azole, alkaline copper quat or chromated copper arsenate treated southern pine decking
2015 - IRG/WP 15-50313
Metal migration from chromated copper arsenate, copper azole or alkaline copper quaternary compound treated southern pine lumber was assessed at sites in Mississippi and Oregon. Metal levels tended to be consistently higher in decks exposed in Mississippi. Rainfall characteristics did differ slightly at the two sites, but the levels did not appear to be of a magnitude that might affect metal mobi...
J J Morrell, H M Barnes


Above-ground performance of a buffered amine oxide treatment system against Mastotermes darwiniensis
2016 - IRG/WP 16-10855
Above-ground H2 field tests against Mastotermes darwiniensis were conducted in far north Queensland to assess the efficacy of buffered amine oxide treatments in the softwoods Pinus sylvestris and P. radiata, and the hardwoods Eucalyptus regnans and E. diversicolor. Untreated hardwoods and slash pine bait wood (P. elliottii) were severely attacked or destroyed, while untreated P. sylvestris was mod...
L J Cookson, R W Clawson Jr


The copper-transporting ATPase pump and its potential role in copper-tolerance
2016 - IRG/WP 16-10859
Copper-tolerant brown-rot decay fungi exploit intricate mechanisms to neutralize the efficacy of copper-containing preservative formulations. The production and accumulation of oxalate is the most widely recognized theory regarding the mechanism of copper-tolerance in these fungi. The role of oxalate, however, may be only one part of a series of necessary components required for this complex mecha...
K M Ohno, C A Clausen, F Green III, G Stanosz


Production of reactive oxygen species in the presence of oxidized iron and oxalate under conditions mimicking brown-rot fungal degradation of wood
2016 - IRG/WP 16-10861
The biochemical role of oxalate in the fungal solubilization of iron is well known, but additional information is needed on the role that oxalate plays in the brown-rot decay of lignocellulose. In this study iron sequestration from iron and iron oxide-hydroxides was assessed with regard to the function of a chelator-mediated Fenton (CMF) reaction and the generation of reactive oxygen species (ROS)...
Yuan Zhu, Liangpeng Zhuang, B Goodell, Jinzhen Cao, J Mahaney


Release of Copper from Pressure Treated Wood
2016 - IRG/WP 16-20584
Micronized copper based wood preservatives including micronized copper quat (MCQ) and micronized copper azole (MCA) have been introduced commercially to the North American market since 2006 as alternatives to alkaline copper quat (ACQ) or soluble copper azole (CA) preservatives. Unlike ACQ or CA, MCQ and MCA use dispersed particulate copper particles rather than soluble ionic copper to make treat...
Jun Zhang, J Horton


Performance of copper treated poles and posts after three to fifteen years of exposure
2016 - IRG/WP 16-20595
Copper based wood preservatives are one of the most important wood preservatives for heavy-duty applications. Wood treated with copper-based preservatives performs excellent if applied according to preservative specifications. If used improperly premature failures might appear. In order to elucidate properties of copper treated wood in use, utility poles and posts treated with copper-based preserv...
M Humar, N Thaler


Moisture monitoring in WW2 partisan hospital Franja
2016 - IRG/WP 16-20596
Material climate of wood used for construction of WW2 Partisan hospital Franja was monitored for approximately one year. Partisan hospital is located in the bottom of tiny gorge Pasice in Slovenia. Hence, wood moisture content on eight respective location and wood temperature was determined twice per day with Scanntronik equipment Gigamodul and Thermofox. The results clearly showed that despite of...
M Humar, N Thaler, B Lesar, A Žagar


Effects of fungal exposure on air and liquid permeability of nanosilver- and nanozincoxide-impregnated Paulownia wood
2016 - IRG/WP 16-30680
Effects of aqueous dispersion of silver and zinc-oxide nano-particles on air and liquid permeability of Paulownia wood exposed to T. versicolor were studied in the present research project. Specimens were also heat-treated at 100 and 150°C and compared with the control specimens. Permeability values were measured when the moisture content of the specimens was 12%. Results showed significant incre...
H R Taghiyari, A Kalantari, M Ghorbani Kookandeh, F Bavaneghi, M Akhtari


Evidence for a role for precipitated copper on the chemistry of micronized copper treatments
2016 - IRG/WP 16-30690
Micronized copper preservative treatments of softwoods, result in mobile copper being formed by reaction of the basic copper carbonate (BCC) with the carboxylic acid functional groups in hemicellulose and pectic substances present in wood. Typically, the amount of reacted copper formed is approximately 0.3% Cu m/m. In this paper, two examples are discussed where remaining unreacted basic copper ca...
Wei Xue, P Kennepohl, J N R Ruddick


Effect of Nano-Silane on Permeability in MDF as a Result of Susceptibility to Moulds and Fungi
2016 - IRG/WP 16-40716
Effects were studied of vapor chamber on specific gas permeability of nanosilane-treated medium-density fiberboards (MDF). Size range of nanoparticles was 20 – 80 nm. Nano-silane (NS) was used at four consumption levels of 0, 50, 100, and 150 g/kg dry wood fibers. Density of all treatments was kept constant at 0.67 g/cm3. Specimens were kept for 18 weeks in vaporized chamber; their specific gas ...
H R Taghiyari, J Norton, A Moradiyan, M Sadegh Taher Tolou Del, H Siahposht, B Moradi-Malek, M Noferesti


Untreated and copper-treated wood soaked in sodium oxalate: Effects of decay by copper-tolerant and copper-sensitive fungi
2017 - IRG/WP 17-10888
Copper is widely used as the primary component in wood protectants because it demonstrates a broad range of biocidal properties. However, a key concern with using copper in wood preservative formulations is the possibility for brown-rot basidiomycetes to resist the toxic effect. Many brown-rot basidiomycetes have evolved mechanisms, like the production and accumulation of oxalate, which helps thes...
K M Ohno, G T Kirker, A B Bishell, C A Clausen


Development of a new method for wood hydrophobizing and fixation of copper compounds by chemical hardening of vegetable based modified oils
2016 - IRG/WP 16-40754
Wood products with ground and direct water contact, but without sufficient biological durability, have to be protected against biological degradation by fungi and other microorganisms. Due to European legislation (Biocidal Products Regulation 528/2012), the selection of possible chemical agents, which are still allowed to be used, is diminishing rapidly. The use of previously widely applied, very ...
C Swaboda, M Fischer, K Jacobs


Overview of the treated wood quality control program in the United States with the recent challenges and advances
2017 - IRG/WP 17-20616
In the past two decades, there have been significant and rapid changes in wood protection technologies for residential applications which have moved away from long established heavy duty metal oxide based products such as chromated copper arsenate (CCA). The successor generation of wood protection systems usually contain copper as the primary biocide, in combination with carbon-based co-biocides s...
L Jin


Activity of Two Strobilurin Fungicides Against Three Species of Decay Fungi in Agar Plate Tests
2017 - IRG/WP 17-30704
The objective of this study was to examine the toxicity of strobilurin fungicides against wood decay fungi in order to assess their potential to act as a co-biocide for copper-based wood protection. Two strobilurin fungicides, Heritage (50% azoxystrobin active ingredient) and Insignia (20% pyraclostrobin active ingredients), and copper sulfate pentahydrate were tested against one white rot fungus...
J D Tang, T Ciaramitaro, M Tomaso-Peterson, S V Diehl


Field Performance of Refractory Species Treated with MCA
2017 - IRG/WP 17-30706
Micronized copper azole (MCA) has been used extensively over the past decade to preserve southern pine, and other wide sapwood species. Treatment of refractory species is less common, in part due to concerns about treatability and resulting efficacy. To address these concerns, white spruce and Pacific silver fir stakes, and lodgepole pine and red pine posts, were pressure-treated with multiple ret...
R Stirling, J K Ingram, P I Morris


Effects of Nano-Wollastonite Impregnation on Fire Properties of Some Thermally-Treated Solid Wood Species
2017 - IRG/WP 17-40771
The effects of nano-wollastonite (NW) suspension impregnation on the fire-retarding properties of heat-treated solid wood of three species (beech, poplar, fir) were studied. Heat treatment was performed at two temperatures of 180 °C and 200 °C. Impregnation was carried out at a pressure of 3 bars for 30 min. The fire properties included ignition time, glowing time, back-darkening, back-splitting...
H R Taghiyari, R Hossinpourpia, S Adamopoulos, A Jahangiri, D Rabie


Controlled deposition of copper nanoparticles using wood inherent architecture as natural template
2017 - IRG/WP 17-40783
As one of the most abundant renewable biomass resources, wood can be used as templates for synthesizing functional nanoparticles with controlled shapes and sizes. In this study, copper nanoparticles were synthesized with controlled shapes and sizes using poplar wood as the natural inexpensive and renewable templates. The crystal structure and morphologies of the copper nanoparticles were character...
Youming Dong, Kaili Wang, Yutao Yan, Jianzhang Li, M Hughes, Shifeng Zhang


Treatability of beechwood railway sleepers with potential creosote substitutes
2017 - IRG/WP 17-40790
Maintenance of an efficient railway infrastructure still requires the use of wooden railway sleepers, particularly because wooden sleepers have more favourable properties for intensified vibrations than concrete or steel sleepers. Creosote, used for decades for the impregnation of railway sleepers, will possibly no longer be available for this application due to European legislation. This reveals ...
N Pfabigan, E Habla, R Gründlinger


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