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Durability of some alternatives to preservative-treated wood. Progress report 2: Results from field tests after 5 years’exposure
2007 - IRG/WP 07-30442
A number of alternatives to preservative-treated wood have been tested according to EN 252 (stake test) and a specially designed ground-proximity field test, the latter in Sweden as well as in Hawaii, USA. Seven untreated wood species and four alternative wood treatments labelled as environmentally friendly (acetylation, linseed oil, heat treatment, vinyl polymer) were included in the study. Four ...
M-L Edlund, J Jermer


Primary Study on Compressed Preservative-treated Wood (CPW) for Outdoor Applications
2008 - IRG/WP 08-40412
In this study, the compressed wood samples pre-treated with hot water bath or water spraying were immersed in the ammoniacal copper quat –type D (ACQ-D) preservative solution to get compressed preservative-treated wood (CPW). The liquid absorption and the recovery rate of compression deformation of the compressed wood was determined, as well as the surface hardness, the distribution of density a...
Jinzhen Cao, Jia Mao


Termite resistance of DMDHEU-treated wood
2008 - IRG/WP 08-40401
Chemical wood modification with dimethyloldihydroxy-ethyleneurea (DMDHEU) or its derivatives are applicable to both solid lumber and wood-based composites. Advantages of DMDHEU-based modification are an increase of dimensional stability and high durability against white, brown and soft rot fungi. At higher chemical loadings, the hardness of the wood is considerably increased. Due to the durabil...
H Militz, S Schaffert, B C Peters, C J Fitzgerald


Effects of acetic acid and nitric acid pre-treatment on copper content of spruce wood treated with CBA-A and CCA
2008 - IRG/WP 08-40406
This work investigates the effects of nitric acid and acetic acid on compression strength values and copper retention contents of refractory spruce wood (Picea oriental L.) treated with the waterborne preservative Copper azole, (CBA-A, Tanalith-E 3492) and copper / chrom / arsenic (CCA). Before the CBA-A and CCA treatment, the samples were immersed in 500 ml of nitric and acetic acid solutions for...
S Yildiz, E Dizman, Ü C Yildiz


Effect of steam on fixation of Cu-amine preservative treated wood
2008 - IRG/WP 08-50251
The rates of copper fixation in copper amine preservative treated wood were investigated with different fixation conditions (20° with drying and 50° without drying) and post-steaming. We also measured the degree of leaching for other biocide components (azoles, quatz, and Cu-HDO). Treatments conditioned at 20° with drying required 50 days or more to fix in woods. While copper was stabilized i...
Sung-Mo Kang, In-Yong Hwang, Suk-Kuwon Kim


Thermochemical Remediation of Preservative-Treated Wood
2008 - IRG/WP 08-50254
Remediation methods continue to be developed and refined for CCA-treated wood in order to divert this material from landfills and create secondary products from the wood fiber. A two-step thermochemical remediation method was developed to assess the efficiency of metal removal from CCA-treated spruce flakes. Nearly all the metals (As, Cr, and Cu) were thermochemically extracted from chromated copp...
R Sabo, C A Clausen, J E Winandy


Leachability of Arsenic, Chromium and Copper from Weathered Treated Wood
2008 - IRG/WP 08-50255
The objective of this study was to quantify the loss of arsenic, chromium and copper from weathered treated wood under normal field conditions as most residential structures currently in service in the U.S. have been constructed at least 3 years ago. For comparison, leaching from different retention levels of weathered CCA treated wood (low, medium and high) is compared to leaching from new ACQ tr...
A R Hasan, Ligang Hu, H M Solo-Gabriele, Yong Cai, L A Fieber


Laboratory Studies on Copper Availability in Wood Treated with Soluble Amine Copper and Micronized Copper Systems
2008 - IRG/WP 08-30489
A laboratory method has been employed to investigate the level of soluble copper in wood treated with various copper-based preservative systems, such as micronized copper (particulate copper) and amine copper solutions. This report describes the methodology and preliminary results on determination of the soluble copper in the treating solutions and the treated wood by these systems, as well as th...
L Jin, P Walcheski, A Preston


Performance of dip and pressure treated wood in termite ground proximity exposures in Hilo, HI, and Colombia
2008 - IRG/WP 08-30491
A number of preservative systems were evaluated for their ability to control termite attack when applied as both dip and pressure treatments. With dip treatments, better performance was observed with southern pine than spruce-pine-fir using the same solution strength treatment, probably as a result of the about 50% greater uptake with southern pine and associated deeper preservative penetration. B...
P Walcheski, A Zahora


Alkaline copper treated wood for use in residential decking
2008 - IRG/WP 08-30490
Alkaline copper quaternary ammonium compound (ACQ) treated decking was exposed in a field experiment and the mobile copper assessed based on that collected in the leachate. The amount of copper which leached was modeled after 4 years. The results showed that boards which leached most chemical initially provided the greatest loss over four years. The reduction in the mobility of copper with time wa...
J N R Ruddick


High Temperature Treated Wood
2008 - IRG/WP 08-40429
High temperature can modify internal structure and physic-chemical properties of wood by a controlled pyrolysis process. Such treatment, among other changes in properties, modifies the wood color in a way that resembles exotic species, increasing its market value. The main objective of this work is to determine the changes in wood properties caused by the effect of temperature and time, in order t...
C C Borges, A L Barbosa, R Faber de Campos, S T Targas


Corrosion of fastener and connector in contact with alkaline copper treated wood – it is a problem
2008 - IRG/WP 08-40437
For many decades, chromated copper arsenate (CCA) was the most common wood preservative used in North America for residential and industrial applications. Since December 31, 2003, the use of CCA for residential application was voluntarily terminated. One of the most widely accepted alternative wood preservatives in Western Canada is Alkaline Copper Quaternary Compound (ACQ). This paper will compar...
J N R Ruddick


Comparison of laboratory and natural exposure leaching of copper from wood treated with three wood preservatives
2008 - IRG/WP 08-50258
Standard and non-standard laboratory and field leaching tests were used to compare copper leaching from wood treated to above ground and ground contact specified retentions for three wood preservative systems, CCA-C, ACQ-D and a micronized copper formulation with quat DDAC as co-biocide. Copper leaching was highest for the ACQ formulation. Percent leaching was lowest for the micronized copper sy...
P A Cooper, Y T Ung


Evaluation of Water Repellency of Treated Wood Using Several Alternative Methods
2009 - IRG/WP 09-20419
In this study, the results of water repellency testing using a digital swellometer method for water-borne organic-preservative systems with water repellent additives are reported. The findings suggest that the traditional method of using matched untreated controls as a reference developed from historic solvent-based treatments for determination anti-swelling efficacy (ASE) may underestimate the a...
L Jin, A F Preston


The Promotion of Timber and Timber Product uses in China - Government's Role in Regulation and Standardization
2009 - IRG/WP 09-20424
Chinese Government always pays special attention to resource and environmental issues, therefore, resource saving and environmental protection are part of the basic state policies. This paper provides a brief summary of the key policies which guide the practices in promoting timber conservation and efficient utilization in order to meeting social demands of the wood uses. In the paper, the develop...
Liu Nengwen


Leaching performance, decay and termite resistance of wood treated with boron compounds incorporated with phenol-formaldehyde resin
2009 - IRG/WP 09-30503
A resol-type phenol-formaldehyde (PF) resin was synthesized and designed to penetrate wood incorporated with boron compounds in order to immobilize boron in wood. The leaching performance, decay and termite resistance of treated wood was investigated. Three kinds of boron compounds, that is, boric acid (BA), borax (BX) and disodium octaborate tetrahydrate (DOT), were selected to mix with PF and tw...
Liping Yu, Jinzhen Cao


Resistance to decay fungi of ammonium borate oleate treated wood
2009 - IRG/WP 09-30505
Ammonium borate oleate molecule (ABO) produced from reaction between boric acid, ammonia and oleic acid was tested as wood preservative treatment against brown and white rot fungi according to European standards. This compound was prepared according to a previous study which has proved existence of synthesis reaction and effectiveness against termites (Lyon et al. 2007b). Four solutions of ABO in ...
F Lyon, M-F Thevenon, A Pizzi, J Gril


Re-Distribution of Copper in the Cell Walls of Wood Treated with Micronized Copper Quat
2009 - IRG/WP 09-30506
Wood treated with copper-based preservatives to be used in ground contact may fail to inhibit soft rot fungi if penetration of copper into the cell wall is insufficient. Preservatives containing soluble copper are known to penetrate the cell wall; however, it is not known whether preservatives containing particulate copper will also migrate into the cell wall in sufficient quantities to control so...
R Stirling, J Drummond


Thermal behavior of zinc borate-treated wood
2009 - IRG/WP 09-30511
The objective of this study was to investigate the thermal behavior of zinc borate (ZnB)-treated solid wood by thermal analysis (TA). Thermogravimetry (TG) and differential thermogravimetry (DTG) curves obtained from TA showed that ZnB-treated wood specimens had higher char yields and lower maximum thermal decomposition temperature than untreated wood specimens. Reducing thermal decomposition temp...
E Terzi, H Sutcu, S N Kartal


Mold-resistance Effect of Bamboo Wood Treated with CCC-organic Complexes
2009 - IRG/WP 09-30514
Mold resistant effect of CCA, ACQ, CuAz, CCC and the compound of CCC and propiconazole were researched on bamboo wood of Phyllostachys pubescens were reported in this paper. Results showed that all of the test fungicides could protect bamboo wood better from Penicillam citrinum than from Trichoderma viride and Aspergillus niger. The complex of CCC and propiconazole had the best resisting effect on...
Sun Fangli, Yang Le, Chen Anliang, Bao Binfu, Li Qiao


Micronized Copper Preservative Systems: Observations on the Release of Cupric ion (Cu2+) from Treated Wood and Performance against Wood Decay Fungi
2009 - IRG/WP 09-30519
In an attempt to address the mechanism of action of micronized copper preservatives, a 20-week continuous water leaching study was conducted. The leaching results indicated that, once impregnated in wood, micronized copper preservatives continuously release cupric ion, and the levels of cupric ion released from micronized copper treated wood are higher than those released from CCA treated wood, a...
J Zhang, R Ziobro


Rapid Microwave-Assisted Acid Extraction of Metals from Chromated Copper Arsenate (CCA)-Treated Southern Pine Wood
2009 - IRG/WP 09-50262
The effects of acid concentration, reaction time, and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with three different acids (i.e., acetic acid, oxalic acid, and phosphoric acid) was investigated using in microwave reactor. Oxalic acid wa...
Bin Yu, Chung Y Hse, T F Shupe


Factors affecting sodium hypochlorite extraction of CCA preservative components from out of service treated wood for recycling
2009 - IRG/WP 09-50263
Significant amounts of chromated copper arsenate (CCA) treated wood products such as utility poles and residential constructions remain in service. There is an increasing public concern about environmental contamination from CCA treated wood when it is removed from service for reuse or recycling, placed in landfills or burned in commercial incinerators. In this paper, we investigate the effects of...
E D Gezer, P A Cooper


Wettability and bonding strength of wood thermally-treated with different combinations of soy oil and chemical additives
2009 - IRG/WP 09-40454
Thermal treatment is a method which has gained wider acceptability as an alternative to the chemical treatment in wood preservation. In order to maximize the benefits of this technique several options have been adopted including the use of soy oil in transferring the heat to the wood. Available information on thermal treatment in general and the oil method in particular show that there are still n...
L Awoyemi, P A Cooper, T Ung


Barefoot-heat-impact of oil-heat-treated wood: An important thermal property of decking boards
2009 - IRG/WP 09-40458
In this study the phenomenon of sensual heat impression was examined, when walking with bare feet on sun exposed wood based decking boards. A suitable method for measuring the heat flux from decking boards into an artificial foot was developed. The method and measuring device is described as well as results from measuring three different decking board materials: Oil-heat-treated spruce (OHT), untr...
A O Rapp, C R Welzbacher, C Brischke


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