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Using X-ray scattering to elucidate the mechanisms behind the moisture and fungal decay resistance of epoxybutene modified wood
2019 - IRG/WP 19-40854
Chemical modification of the hydroxyl groups of wood can improve the properties of wood by providing moisture and biological resistance, as well as dimensional stability. Southern pine solid wood was chemically modified to various weight percentage gains (WPG) with epoxybutene (EpB, 8%-38% WPG). After modification, specimens were extracted with a toluene: ethanol (2:1) solution for 2 hours or wate...
R E Ibach, N Plaza


Dimensional stability and decay resistance of montmorillonite- furfuryl alcohol modified wood
2019 - IRG/WP 19-40856
Poplar (Populus cathayana) wood was impregnated successively by organo-montmorillonite (OMMT; in concentration of 2%) and furfuryl alcohol (FA, in concentrations of 15%, 30% and 50%) in a two-step method to prepare OMMT-FA modified wood. The modified wood samples were characterized using X-ray diffraction (XRD) and field emission scanning electron microscopy (FE-SEM). Moreover, wood physical and a...
L Zhang, J Cao


Study on the ability of wood-destroying fungi to grow through chemically modified wood
2019 - IRG/WP 19-40858
Over the last decades, chemical wood modification technologies were developed to increase the resistance against attack by wood-destroying organisms without using biocides. Most of those technologies are based on an impregnation step initially. In most treated wood products, mainly by using solid wood in thicker dimensions as in posts, poles, sleepers, deckings etc. it is known that wood impregnat...
L Emmerich, S Strohbusch, C Brischke, S Bollmus, H Militz


The anti-weathering mechanism of extractives in thermally modified Scots pine
2019 - IRG/WP 19-40880
Results from the electron spin-resonance spectroscopy (ESR) analysis indicated that thermally modification of wood can inhibit the generation of phenoxyl radicals during UV irradiation and consequently lead to the increase of the color stability of wood. In order to clarify the evolution and role of extractives in thermally modified wood during the process of weathering, the compositions of aceton...
H Shen, J Cao


Studying amount, location and state of water in modified wood at moisture levels relevant for fungal degradation
2020 - IRG/WP 20-40889
Water is an essential parameter for fungal degradation of wood, but degradation primarily occurs at high moisture levels at water potential in the range of -4 to -0.1 MPa, which corresponds to 97-99.9% relative humidity. At these moisture levels, water is present in the wood structure both in and outside of cell walls. The majority of previous studies on the interaction between wood and water for ...
M Fredriksson, E Engelund Thybring, Ramunas Digaitis


Elucidation of reactive sites of wood modified with acetic anhydride: Insights from density functional theory calculations
2020 - IRG/WP 20-40892
Density functional theory (DFT) was employed to investigate the interaction of cellulose and lignin with acetic anhydride for explaining the wood modification process. Atoms in molecules (AIM) and reduced density gradient (RDG) along with non-covalent interaction (NCI) plots were used to analyse the intermolecular bonding characteristics. Cellulose was modelled with a cellobiose unit (dimer of glu...
V Ponnuchamy, A Sandak, J Sandak, R Herrera Diaz


Development of procedures for sampling, testing, and classification to determine the biological durability of wood and wood products
2020 - IRG/WP 20-20676
This paper informs about a research project, which deals with several shortcomings and a lack of clarity within EN 350:2016. The project started in January 2020, will run for 3 years, and is operated by the Institute of Wood Technology Dresden (IHD) and the University of Goettingen (UGOE). Determination and classification of durability of wood and wood products against wood-destroying organisms ...
W Scheiding, K Jacobs, S Bollmus, C Brischke


NewSiest-Enhancement of UV stability of thermally modified wood through envelope impregnation with nanobased stabilisers
2020 - IRG/WP 20-40909
Thermal modification is a process which improves the properties of wood, resulting in a material that can be disposed at the end of the product life cycle without presenting an environmental hazard. Thermally modified wood retains as a natural product and the grain, original colour variances and characteristics of wood are still present. However, exposure to daylight causes brightening or greying ...
K Srinivasa, M Petrič


Performance of resin-treated solid wood and laminated veneer lumber (LVL) under marine conditions
2021 - IRG/WP 21-10973
Wood is a traditional building material in the marine environment, where it is exposed to extremely harsh conditions. Most of the indigenous softwood and hardwood species in Europe are not durable against attack by marine organisms. Recently, wood modification has been considered as an alternative to protect non-durable wood species under use class (UC) 5 (EN 335, 2013) conditions. The present stu...
L Emmerich, C Brischke, S Bicke, H Militz


Experience Experience from over 20 years of field trials of resin treated wood – Marine borer resistance of MMF and DMDHEU modified wood
2021 - IRG/WP 21-10976
In 1999 a field test of Scots pine treated with MMF (Methylated Melamine Formaldehyde) resin and acetylated Scots pine post treated with MMF resin was started. Six years later a commissioned full NWPC test for BASF of Belmadur® (DMDHEU resin treated wood) was started at the same site. The testing, according to European Standard EN 275, was done in a bay by Kristineberg Marine Research Station o...
M Westin, P Larsson Brelid, A O Rapp, J Habicht


Influence of weathering on surface roughness of thermally modified wood
2021 - IRG/WP 21-40915
Thermally modified wood is exposed to weathering similarly as other wood-based building materials. It has been reported that if thermally modified wood is exposed to weathering, its moisture performance might decrease fairly fast. The aim of this study was to determine whether this phenomenon is associated with crack formations or roughness. Norway spruce, thermally modified spruce, wax-treated th...
E Kerzic, B Lesar, M Humar


Evaluation of decay and energy properties from thermally modified biomasses during fungal deterioration by NIR-spectrometry
2021 - IRG/WP 21-40922
This study is focused on the prediction of fungal weight loss (WL) and high heating value (HHV) from raw and torrefied waste lignocellulosic feedstocks, according to their exposure duration to wood-destroying fungi, using near infrared spectroscopy (NIR) and chemometrics models. Sugarcane bagasse, coffee husk, eucalyptus and pine shavings were torrefied at 290 °C in a screw reactor, during 5, 7...
B de Freitas Homem de Faria, P Santana Barbosa, J Valente Roque, A de Cassia Oliveira Carneiro, P Rousset, K Candelier, R F Teofilo


Service trial of different materials exposed in jetties at Öresund. Progress report No. 5
2022 - IRG/WP 22-30764
This report contains results of the fifth inspection on the performance of different decking materials – preservative-treated wood, modified wood, natural durable wood, re-cycled plastics and wood-plastic composites (WPCs) - available on the market and exposed since 2013 (some since 2014 and 2016) by the City of Malmö in two jetties near the Øresund Bridge, south of central Malmö in Sweden. T...
J Jermer


Durability against fungal decay of sorbitol and citric acid (SorCA) modified wood
2022 - IRG/WP 22-40928
Most European-grown wood species are susceptible to biological degradation, specifically, they suffer from a poor resistance against wood-destroying fungi. Therefore, prior to outdoor exposure, wood has to be treated either by applying a protective coating on its surface or by full-volume impregnation with antifungal chemicals. However, due to environmental and health concerns, the most frequently...
K Kurkowiak, L Emmerich, H Militz


Optimized composition of alkyd emulsion with nanoparticles of iron oxide for enhancing protection of thermally modified wood
2022 - IRG/WP 22-40940
Thermal treatment is acknowledged as an environmentally friendly method to improve durability of wood and some of its properties, such as biological resistance, dimensional stability, reduced hygroscopy. Despite these improvements, when used outdoors, also thermally treated wood is subjected to the action of environmental factors, like solar radiation, moisture, precipitations, temperature, etc., ...
E Sansonetti, D Cīrule, I Andersone, B Andersons, E Kuka


The Resistance of Some Commercially Thermally Modified American Hardwoods to Termites and Fungi
2022 - IRG/WP 22-40944
Thermally Modified Wood (TMW) is now being produced in the United States but there are few data on the durability of these materials. In this study, commercially-produced thermally modified yellow poplar (Liriodendron tulipifera), red maple (Acer rubrum), and white ash (Fraxinus americana) were evaluated for fungal and termite resistance. The resistance of the three TMW species against Gloeophyllu...
B Cortes, B Bond, A Taylor, J Lloyd


Mechanical Properties of Thermally Modified Wood after twelve Months of Field Exposure
2022 - IRG/WP 22-40945
This study aimed to evaluate the durability and mechanical properties of two different woood species, namely beech (Fagus sp.) and silver fir (Abies alba), from Bosnia and Herzegovina thermally modified at three different temperatures and duration at maximum temperature. Samples of the mentioned wood species wood (Abies alba) were prepared according to EN 408+A1 standard. The maximum 4-point bendi...
R Hasanagić, M Bahmani, L Fathi, M Humar


Moisture sorption behaviour of poplar and thermally modified poplar using dynamic vapour sorption (DVS)
2022 - IRG/WP 22-40947
The moisture sorption behaviour of wood has a critical impact on service life. In Europe, softwood is mostly used to manufacture engineered wood products such as cross-laminated timber (CLT) or glue-laminated timber (GLT or glulam). Yet fast-growing and widespread tree species such as hybrid poplar with or without modification, have potential to meet the increasing demand. This study shows the moi...
X Jiang, J Van den Bulcke, L De Boever, M Minsart, A Mignon, J Van Acker


Durability of thermally modified western hemlock lumber against wood decay fungi
2022 - IRG/WP 22-40954
The chemical modification of wood is gaining popularity as a treatment to increase wood durability in the United States. Further standardization and testing of thermally modified North American species is needed to optimize the production of thermally modified products from regionally available resources. This work measures the impact of thermal modification of western hemlock lumber durability ag...
G Presley, J Cappellazzi, I Eastin


Reducing successful settlement by shipworm larvae on wood that has been modified using furfurylation
2023 - IRG/WP 23-11017
Shipworms are Teredinid bivalves that have a highly modified shell for boring into wood and an elongated, vermiform shape. Teredinids are marine wood-borers, utilising timber as both shelter and as a source of food. Wooden structures in the sea, such as piers and sea defences, are subject to severe damage by these borers, costing billions per year for maintenance and replacement. Traditionally, br...
L Martin, I Guarneri, S Lande, M Westin, S Cragg


Comparison of culturable fungi found on two types of modified wood cladding
2023 - IRG/WP 23-11025
Modified woods are rapidly gaining popularity in the United States and are appearing on more public buildings. Because these are biocide-free products, they can support the growth of non-wood degrading fungi on their surfaces, many of which produce dark pigments and deface the cladding. Even growth of dark pigmented fungi on modified woods yields an even grey-black color, giving the materials a we...
G Presley, J Cappellazzi, B Held, R Blanchette


Above Ground Proximity Decay Field Trial of Modified ACQ-A, Wolman® CA-B and Wolman® CA-C in Taiwan
2023 - IRG/WP 23-30793
An above ground proximity decay field trial was established at Chiayi county, Taiwan in July 2016. The purpose of this study was to generate local field performance data for Taiwan for Slash Pine treated with Wolman® CA-B, Wolman® CA-C and a modified ACQ-A product at AWPA UC3B actives retention. After 6 years of field trial, the efficacy of the wood preservative in preventing decay fungi and ter...
J-Y Gan


Biological durability and wood-water interactions of sorbitol and citric acid modified wood – Effects on the expected service life
2023 - IRG/WP 23-40960
A high level of research activities on sorbitol and citric acid (SorCA) modified wood has been recognized in Europe over the last few years. As this treatment is close to entering an industrial-scale production, it is of interest to investigate how such treated wood performs upon long-term outdoor exposure. Hence, in this study Scots pine (Pinus sylvestris L.) sapwood was modified with aqueous sol...
K Kurkowiak, L Emmerich, H Militz


Adhesion and performance of exterior wood coatings on chemically and thermally modified wood – Results from 5.5 years outdoor exposure
2023 - IRG/WP 23-40964
Non-durable softwood and hardwood species were treated with the water-soluble cyclic N-methylol compounds 1,3-dimethylol-4,5-dihydroxyethyleneurea (DMDHEU) and methylated DMDHEU. One half of the modified specimens were coated with a waterborne acrylic coating system prior a natural weathering for 5.5 years according to EN 927-3 (2020). By frequent evaluations, the impact of chemical modifications ...
L Emmerich, H Militz


Starch modified with silanes – high hydrophobic surface treatment for wood protection
2023 - IRG/WP 23-40981
The great potential of silanes for starch modification and their utility as surface wood protection is still not sufficiently assessed. The work aimed to analyze the crosslinking process's effect on starch modification with silane and tested the hydrophobic properties of surface-treated wood. The starch treatment was modified with methyltrimethoxysilane or N-octyltriethoxysilane. SEM-EDX with a cr...
W Perdoch, M Bajstok, B Mazela, I Siemińska, B Peplińska


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