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Removal of nano- and micronized-copper from treated wood by chelating agents
2013 - IRG/WP 13-50294
Micronized and nano-copper (Cu)-based and arsenic and chromium-free systems have received much attention for wood protection in recent years. Because they have different fixation, and micro-distribution properties, such copper systems may be more or less subject to release using known remediation methods than soluble forms of Cu. This study evaluated Cu recovery from wood treated with micronized- ...
S N Kartal, E Terzi, B Woodward, C A Clausen, S T Lebow


Conclusions and Summary Report Environmental Life Cycle Assessment of Marine Pilings
2013 - IRG/WP 13-50298
The Treated Wood Council has completed a quantitative evaluation of the environmental impacts associated with the national production, use, and disposition of treated wood, concrete, galvanized steel, and plastic marine piles using life cycle assessment (LCA) methodologies and following ISO 14044 standards. The results for treated wood piles are significant. • Less Energy & Resource Use: Tre...
AquAeTer, Inc.


Durability of alternatives to CCA-treated wood - Results from field tests after 11 years exposure
2013 - IRG/WP 13-30633
The present study was initiated as a consequence of restrictions against the use of CCA-type wood preservatives in Sweden in the 1990s. New copper-based formulations were introduced on the market and to some extent, also alternatives to preservative-treated wood, such as thermally and chemically modified and linseed oil treated wood as well as heartwood of non-tropical naturally durable wood s...
P Larsson Brelid, M-L Edlund


Field trials results of preservative treated ground contact stake conducted in Korea
2014 - IRG/WP 14-30640
The field trials results from Korea preservative treated ground contact stake are reported. There was two site which was in southern area(Anmeon) and east area (Jungsun) of Korea. The CUAZ, CCA and CBHDO preservatives were use in this study. The sapwood of Japanese red pine stake was treated with these preservatives according to Korea standard method and then installed in 2003. Every year the insp...
Dong Won Son, Won Jung Hwang, Hyun-mi Lee, Dong-heub Lee, Sang-bum Park


Resistance to Decay Fungi of Scots Pine Impregnated with Natural and Chemical Preservatives
2014 - IRG/WP 14-30650
In this study, heart-wood and sap-wood specimens of the Scots pine which is naturally grown in Turkey were treated with natural (valex) and some chemical preservatives such as CCA - C (Copper / Chrome / Arsenic), CBA - A (Copper / Boron / Azole). The wood protective efficacies of these preservatives were investigated by means of fungi decay test (EN 113). As a result of the study it was found t...
S Yildiz, U B Şimşek


Hydroponic Phytoremediation of Chromated Copper Arsenate (CCA) and Copper Contaminated Water
2014 - IRG/WP 14-50304
The removal of selected metals by duckweed (Lemna minor) and parrotfeather (Myriophyllum aquaticum) from a simulated aqueous environment contaminated with Chromated Copper Arsenate (CCA) and copper sulfate was studied in a controlled laboratory experiment. The duckweed and parrotfeather’s tissues were analyzed to evaluate the removal of copper (Cu), chromium (Cr), and arsenic (As) from CCA cont...
C Keith, H Borazjani, S Diehl, Y Su, Fengxian Han, B Baldwin


Practical extraction of metals from CCA-treated wood
2014 - IRG/WP 14-50305
The extraction effects of acid concentration, reaction time and temperature in a microwave reactor on recovery of chromated copper arsenate (CCA)-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from CCA-treated southern pine wood samples with three different wood particle sizes (i.e., (1) 0.5 cm3, (2) 0.5x05x1.0 cm, and (3) 0.5x0.5x1.5 cm) was investigated using a m...
Bin Yu, Chung Y Hse, T F Shupe


Laboratory Study of Relative Leachability of Chromated Copper Arsenate Preservative from Treated Woods among Soil Types of Sarawak
2014 - IRG/WP 14-50307
Wood and soils are important natural resources from the environment and serves mankind well respectively as structural materials and natural platform erecting such materials. With shortfalls of naturally durable timber species for protected in-ground uses under Malaysian environments, Chromated Copper Arsenate (CCA) treated woods are widely used instead, incurring serious potential threats of pres...
A H H Wong, P K F Chong


Durability of treated wood Corymbia torelliana and Eucalyptus grandis x Eucalyptus urophylla against subterranean termite
2015 - IRG/WP 15-20563
This work aimed to analyze the durability of woods against termite Nasutitermes corniger Motsch. Fence posts from this study were collected in Pinheiros, north of Espírito Santo state, Brazil. Used the Corymbia torelliana and Eucalyptus grandis x Eucalyptus urophylla species with 11 and 9 years, respectively and plant spacing of 3.00 x 2.00 m. Were used 72 samples from discs removed the 0.50 m of...
D Junior Verly Lopes, J Benigno Paes, P N de Medeiros Neto, G dos Santos Bobadilha


Effect of exposure site on metal migration from copper azole, alkaline copper quat or chromated copper arsenate treated southern pine decking
2015 - IRG/WP 15-50313
Metal migration from chromated copper arsenate, copper azole or alkaline copper quaternary compound treated southern pine lumber was assessed at sites in Mississippi and Oregon. Metal levels tended to be consistently higher in decks exposed in Mississippi. Rainfall characteristics did differ slightly at the two sites, but the levels did not appear to be of a magnitude that might affect metal mobi...
J J Morrell, H M Barnes


CCA Treated Wood, Will It Last 100 Years?
2016 - IRG/WP 16-20575
Copper, chrome and arsenate (CCA) treated wood has a very successful history of use in New Zealand, for at least 60 years. In many parts of the world, CCA has been used for timber treatment since the mid-1930s. In this report, data are presented on the performance of CCA treated pine stakes and poles. Results from ground contact durability tests at Scion and other overseas test performance data su...
T Singh, D Page


Properties of Wood Plastic Composites Made of Recycled HDPE and Remediated Wood Flour from CCA/CCB Treated Wood Removed from Service
2016 - IRG/WP 16-40747
Chromated copper arsenate (CCA) and copper, chromium and boron (CCB) have been widely used in pressure treated wood as a heavy duty preservative to protect wood against insects and fungi for more than 60 years. Although many attempts have been done to solve the problems related to out-service treated wood, the problem still remains. Only a few studies were done to utilize the out-of service treate...
E D Gezer, S Akbaş, M Tufan, A Temiz


A Case Study of Long-term CCA Preservative Leaching from Treated Hardwood Poles in a Humid Tropical Condition
2016 - IRG/WP 16-50324
Chromated copper arsenate (CCA)-treated Malaysian hardwoods have long been used as utility poles, posts, construction piles and motorway fencing in soil contact exposed to the threats of decay fungi and termites. Despite global concerns citing predominantly temperate conditions of long-term leaching of CCA toxic heavy metals from wood into surrounding soils and groundwater since the 1990’s, the ...
A H H Wong, W S M Chin


10 year Report on COST E37 Round Robin Tests – Comparison of results from laboratory and field tests
2017 - IRG/WP 17-30718
A round robin involving 15 European participants was set up in 2006. The round robin consisted of both a field test according to the double layer test method and a laboratory test with two different preconditioning methods. The laboratory test results were reported in an earlier IRG paper (IRG/WP13-20535) but are included also in this paper in order to facilitate the comparison with the field test...
M Westin, E Conti, J Creemers, P-O Flæte, A Gellerich, I Irbe, M Klamer, E Melcher, R Moeller, L Nunes, S Palanti, L Reinprecht, E Suttie, H Viitanen


Overview of the treated wood quality control program in the United States with the recent challenges and advances
2017 - IRG/WP 17-20616
In the past two decades, there have been significant and rapid changes in wood protection technologies for residential applications which have moved away from long established heavy duty metal oxide based products such as chromated copper arsenate (CCA). The successor generation of wood protection systems usually contain copper as the primary biocide, in combination with carbon-based co-biocides s...
L Jin


The Effects of Pre-Microwave Treatment on Retention Levels And Some Mechanical Properties of Spruce Wood Treated with CCA
2017 - IRG/WP 17-40800
Microwave (MW) treatment of wood has been evaluated in recent years for different purposes by several scientists. Microwave conditioning improves permeability, reduces density and heat conductivity and changes dimensional stability. Furthermore, it could even improve the permeability of refractory wood species such as spruce and Douglas fir. In this study, MW pre-treatment was applied to spruce wo...
E D Gezer, S Kuştaş, S Durmaz


Review of Leaching Experiments of CCA-Treated Wood and Wood Treated with Copper-based Alternatives
2017 - IRG/WP 17-50330
The objective of this study was to compare leaching rates of various wood preservatives from treated wood and the tests used to gather this information. The preservatives compared included CCA and the copper-based alternatives, MCQ, ACQ, and MCA. The tests compared included AWPA E11, SPLP, TCLP, and environmental leaching tests. Among all of the tests evaluated, environmental tests most closely si...
A Jones, J Marini, H Solo-Gabriele


Can CCA be substituted as reference preservative?
2018 - IRG/WP 18-20641
While field testing of wood protective formulations remains probably the best method to find out the effective preservative concentration, the use of chrome-copper arsenate (CCA) as reference becomes debatable due to environmental and legislative reasons. This emerges from the European standardization bodies who have discussed reference alternatives that can omit the use of CCA. The present debate...
N Terziev, M Jebrane, P Larsson Brelid, N Morsing, P-O Flaete, P Torniainen, J S Kim, G Daniel


CCA wood preservative: Trust with destiny
2019 - IRG/WP 19-30731
This paper traces the history of Copper-Chrome-Arsenic (CCA) and its current status in India and worldwide. CCA was invented as ASCU at the Forest Research Institute, Dehra Dun in 1933 by Dr. Sonti Kamesam. Although its efficacy was doubted by the British colonial rulers resulting in several hiccups at home, the patent rights were purchased by US Bell Telephone Co. and it was adopted by the US woo...
S Kumar


The iron reduction by chemical components of wood blocks decayed by wood rotting fungi
2021 - IRG/WP 21-10979
Brown-rot fungi, a group of wood rotting fungi, is well known to be one of major microorganisms that cause the deterioration of wooden buildings in Japan and have been considered to use chelator-mediated Fenton (CMF) reaction in concert with hydrolytic and redox enzymes for degradation of wood cell wall. CMF can be described as a non-enzymatic degradation system that utilizes hydroxyl radicals pro...
R R Kondo, Y Horikawa, K Ando, B Goodell, M Yoshida


Application of an Ultrasound-based Instrument to Evaluate Condition of Drywood Termite Infested Timber Components
2022 - IRG/WP 22-11000
The characteristics of ultrasound waves propagation from non-destructive ultrasound-based instrument on drywood termite infested wooden components were investigated. Features of wave propagation such as time-of-flight, velocity, and peak energy on three orthogonal wooden plane (longitudinal, radial, and transversal) were studied. The wooden components used on this study came from a traditional woo...
S Fauziyyah, L Karlinasari, D Nandika, R Wimmer


Copper-octanoate - a potential reference preservative replacement for CCA in field test standards?
2022 - IRG/WP 22-20688
Finding a CCA reference replacement for use in standardised test methods is of high priority since this chemical is being phased out and may in the near future be banned also for experimental and approval purposes. In this paper we assess the possibility to replace CCA reference preservative with an historical copper octanoate product. There is a huge amount of lab and field test data available fo...
R Ringman, M Westin, M Klamer, A Christof, F Friese


Glued laminated poles - Progress report after 43 years of testing
2023 - IRG/WP 23-20692
In 1979, a number of glued laminated poles treated with CCA and creosote were placed in a greenhouse in Uppsala, in the Simlångsdalen test field in south-western Sweden and in a power lane in Vuollerim in northern Sweden, in order to study their resistance against biological degradation. The test poles were treated in a two-step process. All laminations of Scots pine (Pinus sylvestris) were first...
J Jermer, M Westin, N Terziev


A six-year ground proximity trial of TRU-CORE treatments at Innisfail, Queensland
2023 - IRG/WP 23-30775
This article describes an H3 (above ground outdoor) ground proximity field trial that compares the performance against decay fungi of TRU-CORE (also known as the Buffered Amine Oxide Enhancement System) Copper Quat (CQ) with CCA and commodity Alkaline Copper Quat (commodity-CQ) treatments, all in Pinus radiata. The retentions achieved reflected commercial practice, where higher mean retentions are...
L Cookson


Challenges in managing very long-term field tests
2023 - IRG/WP 23-30779
Field testing of wood preservatives has been on-going in Petawawa, Ontario, Canada since at least 1937. Many of the treated roundwood posts from these early experiments are still in test, and include preservatives still used today, including creosote, copper naphthenate, pentachlorophenol and CCA. Performance data from selected experiments more than 50 years old are reported and we discuss some of...
R Stirling, D Wong


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