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Polyflavonoid tannins - From a cause of CCA soft-rot failure to the "missing link" between lignin and microdistribution theories
1986 - IRG/WP 3359
Polyflavonoid tannins are proven to be fast-reacting with CCA solutions and hence, to be strong competitors of the structural wood constituents for fixation of CCA preservatives. The consequence of this effect is that even relatively small amounts of tannin cause severe undertreatment of the structural wood constituents which in turn badly affects the long term durability of CCA-treated timber. Th...
A Pizzi, W E Conradie, M Bariska


Ultrastructure of degraded, CCA-treated Pinus radiata wood from a marine pile
1990 - IRG/WP 1461
During an inspection of marine piles, 12 years after installation, severe degradation was noted on one of them in the vicinity of a corroded eye-bolt. The wood was dark brown in colour and tended to crumble easily. Wood fragments were examined by light microscopy and scanning and transmission electron microscopy and were also analysed for carbohydrates and lignin. Light microscopy showed numerous ...
A P Singh, M E Hedley


Photo-discoloration and Degradation of Wood and its Stabilisation by Modification with Benzoyl Chloride
2004 - IRG/WP 04-40274
Photo degradation of Pinus roxburghii (chir pine) and Hevea brasiliensis (rubber wood) was studied under artificial accelerated weathering conditions in a Xenon test chamber. The irradiated samples were analyzed for color changes and chemical changes. Analysis of colour changes in wood surfaces by UV-Vis. irradiation was carried out using a colour measuring (CIELAB) system and chemical changes ...
K K Pandey


Sludge formation in timber treatment with CCA preservatives. Origin and elimination
1984 - IRG/WP 3276
The exact distributions between lignin and holocellulose and retentions on wood of copper, chromium and arsenic as a function of various sets of conditions in a factorial experiment in which combinations of three temperatures of treatment, three CCA solution concentrations, four pH's of the initial CCA solution and two timber species, namely Pinus radiata and Eucalyptus grandis, are repor...
A Pizzi, W E Conradie, A Jansen


Kinetic of the wood degradation produced by wood decay fung
1993 - IRG/WP 93-20016
The degradation degree of a wooden structure has a direct influence on its loss of mechanical strength. It's necessary to deepen in non destructive techniques which permit to extrapolate the results obtained in laboratory to structural timber used in the building's construction. This work studies the relationship existing between the pulse velocity of ultrasonic waves and the wei...
M T De Troya, A M Navarrete, A Sanchez, V Bucur


Screening of lignin peroxidase from white-rot fungi
1998 - IRG/WP 98-10274
Since lignin peroxidase was first found in the ligninolytic culture of Phanerochaete chrysosporium, it has been regarded as an enzyme responsible for the lignin biodegradation and studied comprehensively. As the results of these studies its unique characteristics have been revealed. On the other hand, the features of lignin peroxidase produced by other white-rot fungi have not been studied so much...
I Momohara


Degradation of the gelatinous-layer in aspen and rubber wood by the blue stain fungus Lasiodiplodia theobromae
1996 - IRG/WP 96-10168
Studies on the degradative ability of the blue stain fungus Lasiodiplodia theobromae Pat. have shown several strains to cause significant weight losses (i.e. ca 20%) in the temperate and tropical wood species, aspen (Populus tremula) and rubber wood (Hevea brasiliensis). In addition to the consumption of soluble carbohydrates and extractives, major changes in the ultrastructure of fibre cell walls...
O Encinas, G F Daniel


The possible significance of the lignin content and lignin type on the performance of CCA-treated timber in ground contact
1988 - IRG/WP 1357
The lignin in wood samples of Alstonia scholaris, Octomeles sumatrana and a Simaruba species have been analysed. These timbers are characterised by a high lignin content and low syringyl:guaiacyl ratios. Decay tests with two soft rot fungi showed that the timbers were less susceptible than timbers with a low lignin content and higher syringyl:guaiacyl ratios. Numerous data for field performance of...
T Nilsson, J R Obst, G F Daniel


Study of the degradation of retified wood through ultrasonic and gravimetric techniques
1994 - IRG/WP 94-40030
One of the non-polluting processes that increase the natural durability of wood is a thermal treatment in an atmosphere poor in oxygen, producing what is normally denominated "retified wood". In this study the validity of a non-destructive technique (ultrasound) in order to determine the biodegradation suffered by wood across time has been studied. For this reason, the behavior of a wood species (...
D T De Troya, A M Navarrete


Identification of terminal structures in cellulose degraded by the brown-rot fungus Postia placenta
1989 - IRG/WP 1389
To gain insight into the biochemical mechanism employed by brown-rot fungi to depolymerize cellulose, we identified the end-groups of chemically pure cellulose that had been depolymerized by the brown-rot fungus, Postia placenta. The depolymerized cellulose was acid hydrolyzed and the anion fractions isolated by ion chromatography. Sugar acids were identified by gas chromatographic and mass spectr...
T K Kirk, T L Highley, R E Ibach, M D Mozuch


Practical consequences of the clarification of the chemical mechanism of CCA fixation to wood
1983 - IRG/WP 3220
Practical consequences derived from the chemical investigation of the mechanism of fixation of CCA to the wood constituents are discussed. Among these, formulas for the calculation of the time of hexavalent chrome fixation are presented. Furthermore, three parameters are shown to be important to the long-term effectiveness of CCA-treated timber: (i) the temperature of treatment, (ii) the initial p...
A Pizzi


UV-microspectrophotometry of lignin and accessory compounds in wood cell walls of conifers
1999 - IRG/WP 99-20171
The distribution of lignin in the cell wall of conifer tracheids was determined by UV-VIS microspectro-photometer. Wood sections of one micron thickness were measured between the wavelength 240 and 700 nm. Spectral analyses revealed that the conifer lignin associated with the tracheid secondary wall and middle lamella is composed of guiacylpropane units which exhibit a characteristic UV absorption...
G Kleist, G Koch, J Bauch


Changed permeability and surface properties of hornbeam wood due to its degradation by erosive strain of Phanerochaete chrysosporium
2004 - IRG/WP 04-40290
Specimens of hornbeam wood were submitted to a medium-term degradations by erosive fungus Phanerochaete chrysosporium. Biodegradations of specimens resulted in their apparent structural alterations, changes in permeability and increased intensity of interactions with polar liquids. Modified physical properties of biodegraded wood may significantly influence its penetration with polar media and che...
R Solár, S Kurjatko, L Reinprecht, M Mamon, V Vacek


Natural weathering of wood in a sunny climate effects on surface chemistry and paint adhesion
1997 - IRG/WP 97-20109
Radiata pine veneers and blocks were exposed to natural weathering under Australian summer conditions over a period of 30 days. Infrared spectroscopy revealed that there was perceptible surface delignification after 4 hours exposure, substantial surface delignification after 3 days exposure and almost complete surface delignification after 6 days. Viscometry determinations on holocellulose samples...
P D Evans, P D Thay, K J Schmalzl


Enzyme systems of bacterial isolates from ponded logs - Potentials of pectin and/or starch degradation
2000 - IRG/WP 00-10378
This paper deals with the degradation potentials of wood constituents by the bacterial isolates from ponded logs. The potentials to degrade pectin as a constituent of pit-tori as well as starch existing in ray parenchyma cells in the areas of sap- and transition wood with the isolates were examined. The pectinase activity was investigated by means of the degradation degree of a carrot strip used a...
S Doi, S Ohta


Moisture uptake and volumetric swelling as probable factors also affecting leaching in CCA-treated wood. A preliminary study of treated Eucalyptus saligna sapwood
2003 - IRG/WP 03-30318 IRG/WP 03-30318
A number of factors affecting leaching of CCA from treated wood have been variously investigated and discussed. However, the possible effects of moisture movement in treated timbers on leaching have not received attention yet. The present study examines and compares moisture uptake and volumetric swelling in CCA-treated and untreated sapwood of Eucalyptus saligna, and tries to establish a correl...
R Venkatasamy


Reaction of osmium tetroxide with a diphenolic compound as a model substance for demethylated lignin
1986 - IRG/WP 1303
By using caffeic acid as a model substance for diphenolic moieties of demethylated lignin it was found that electron dense particles called by the authors "osmiophilic particles" in former papers are reaction products of OsO4 with the model substance. By these products it is possible to indicate the enzymatic demethylation of lignin taking place during wood decay. The appearance of the electron de...
K Messner, E Srebotnik


The effect of hemicellulose degradation on the mechanical properties of wood during brown rot decay
2001 - IRG/WP 01-20219
Incipient decay of wood by brown rot fungi causes measurable strength losses in wood before measurable weight loss occurs. Previous studies have shown that the high levels of strength loss that occur during incipient brown rot decay may be related to loss in hemicellulose. This paper investigates the effect of decay on hemicellulose composition and the relationship to the mechanical properties of ...
S F Curling, C A Clausen, J E Winandy


Chemical and biological studies of organotin treated and painted wood stakes after outdoor exposure
1987 - IRG/WP 3419
Organotin based wood preservatives containing tributyltin oxide (TBTO) or tributyltin naphthenate (TBTN) are used in Sweden mainly for double-vacuum treatments of window joinery of Pinus sylvestris. After impregnation the joinery is painted or stained in different colours. To evaluate this effect (different colours on the degree of degradation of TBTO and TBTN, effected by different temperatures i...
M-L Edlund, B Henningsson


Evidence for wood cell wall degradation by the blue stain fungus Botryodiplodia theobromae Pat
1994 - IRG/WP 94-10077
Botryodiplodia theobromae Pat., a world wide ubiquitous polyfagus sapstain fungus, was found able to destroy the cell walls of birch fibres (Betula verrucosa Ehrh.) but not Caribbean (Pinus caribaea var. hondurensis Barr. and Golf.) and Scots pine (Pinus sylvestris L.) tracheids. The fungus caused characteristic erosion of fibre cell walls similar to soft rot type 2; destruction of the S1 - S2 int...
O Encinas, G F Daniel


Étude in vitro de la colonisation et de la dégradation structurale du bois d'aubier de Pin sylvestre par la Mérule: Serpula lacrymans Schum. ex Fr. S. F. Gray
1979 - IRG/WP 198
The degradation of Scots pine sapwood cell walls by Serpula lacrymans, a brown rot fungus, is observed after various periods of exposure from two weeks to twelve weeks. The observation by microscopy shows that the hyphae of Serpula rapidly invade the wood tissues as cell wall degradation starts. That deterioration is not gradual, it is observed to be very irregular as well within the whole of the ...
D Dirol


Moisture requirements and wood degradation of pine and spruce wood by some Basidiomycetes-fungi
1989 - IRG/WP 1406
The minimum moisture requirements for the growth of the brown rot fungi, Coniophora puteana, Gloeophyllum trabeum and Serpula lacrymans were near or above the fibre saturation point of pine and spruce, sap and heartwood, during 160 days incubation according to the standard method EN 113. The moisture of wood for the optimum growth of Coniophora puteana and Serpula lacrymans was about 35-80% and fo...
H Viitanen, A-C Ritschkoff


Formation of soft rot cavities in relation to concentric layers in wood fibre walls
1983 - IRG/WP 1185
A large number of timber species attacked by soft rot have been examined using light microscopy. The S2 layers in a large number of the timbers exhibited special structural features in the form of thin concentric layers. Several observations indicate that these layers may be characterised as "weak" zones by being more easily degradable than the surrounding wall layers. The chemical structure of th...
T Nilsson, G F Daniel


Microbial breakdown mechanisms. Mini-Symposium at the 18th IRG meeting, Honey Harbour, Ontario, Canada
1987 - IRG/WP 1327
An understanding of how micro-organisms cause chemical alternation to wood is essential for effective wood preservation. Investigation of the Microbial Breakdown of wood is a very dynamic research field and is increasing in importance as several biocides are being examined as alternativesw to classic wood preservatives. These biocides often do not possess broad spectrum activity. It is esential th...
L E Leightley


Wood-based composites exposed to fungal degradation: Laboratory results
2001 - IRG/WP 01-40215
Oriented strandboard (OSB) and laminated veneer lumber (LVL) are widely used as residential construction materials. The durability of OSB and LVL against biological degradation has not been studied comprehensively. The objective of this research was to investigate the durability of OSB and LVL when exposed to wood decay fungi. Fourteen brown-rot and eight white-rot wood decay fungi were screened f...
V W Yang, B Illman, L A Ferge, R J Ross


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