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Soft rot decay in acetylated wood. Chemical and anatomical changes in decayed wood
2002 - IRG/WP 02-40231
Acetylated Beech (Fagus sylvatica) and Scots Pine (Pinus sylvestris) wood were studied in soil beds under laboratory conditions for longer periods. High mass losses and dynamic MOE losses were measured in non-acetylated wood and at lower weight percent gains (WPG). Rapid losses of lignin, holocellulose and ?-cellulose occurred in non-acetylated beech wood and no losses were detected at the highest...
B Mohebby, H Militz


Rapid analysis - chances and limitations
1999 - IRG/WP 99-50130
The reuse of wood out of service in the particle board industry demands a proper handling and separation of assortments with differing content and nature of preservative. A pre-selection based on visual and olfactorial characteristics can be carried out for certain assortments like sleepers, poles, etc. Problems arise from diffuse and less intensive treated wood which is regularly dip-treated or b...
A Peylo, R-D Peek


Effect of wood species on decomposition efficiency of metham sodium
1992 - IRG/WP 92-3699
The effect of wood species and temperature on efficiency of metham sodium (32.1% sodium N-methyldithiocarbamate) decomposition to methylisothiocyanate (MITC) was investigated on 10 hardwoods and 9 conifers over a 144 hour period. Gas chromatographic analyses of headspace samples and ethyl acetate extracts of the wood revealed that decomposition never approached the theoretical decomposition effici...
J J Morrell


Unsuitability of the limiting dose as a criterion for assessing the toxicity of preservatives to wood-destroying fungi
1974 - IRG/WP 243
In the majority of methods for investigating preservatives for wood-destroying fungi their toxicity is assessed by determining what is called the "limiting dose". This normally denotes a range of preservative solution concentrations or retentions of dry preservative in the timber, the lower value serving to indicate the amount of preservative at which is observed the expected effect, e.g. the grow...
D A Belenkov


Analysis of D-glucose metabolism of wood decay fungi using 13C-NMR and 13C-labeled substrates
2003 - IRG/WP 03-10475
D-Glucose metabolism is thought to be important during wood decay by fungi, not only for anabolic and catabolic purposes of central metabolism, but also as a potential source of peroxide required by extracellular peroxidases. There has been some confusion in the literature as to whether this peroxide-generating activity is of the glucose 1-oxidase or pyranose 2-oxidase (glucose 2-oxidase) type wi...
T H de Koker, M D Mozuch, P J Kersten


Statistical evaluation of 'micro-bending' samples for classification of wood attacking fungi
1992 - IRG/WP 92-1544
Micro-specimens from both hardwood and softwood were exposed to selected species of field isolated fungi. The strength reduction and weight loss caused by these fungi were determined. A statistical procedure was then developed to classify the fungi into brown-, white-rot, or non-decay fungal categories based on these data. The procedure reveals the extent of hazard a fungus poses to wood members. ...
B Goodell, Jing Liu, A Homola, J Jellison, J Shottafer


Analysis of water repellents in wood treated with water borne formulations using FTIR
2000 - IRG/WP 00-40176
The use of aqueous water repellent emulsion formulations has increased significantly in the wood treatment industry. These products are primarily used to enhance the weathering characteristics of wood products treated with water borne preservatives systems used in exterior above ground applications. They are also used in pole treatments to improve climbing characteristics and in low VOC millwork t...
P J Walcheski, L Jin


Copper naphthenate-treated Southern Pine pole stubs in field exposure: - Part 1: Gradient & biodeterioration analysis 12 years after treatment
2000 - IRG/WP 00-30242
Naphthenates have been used for the preservation of timber and cellulose since their original identification in Russia in the early 1880's as part of a series of petroleum characterizations. Later work in the development of copper naphthenate as a heavy-duty preservative for poles led to the development of various treating cycles similar to other oil-borne systems. Recent work concerning ...
H M Barnes, M H Freeman


Evidence for the participation of the osmiophilic particles in the enzymatic demethylation of lignin
1984 - IRG/WP 1239
Transmission electron microscopic observations of the white-rot fungi Trametes hirsuta and Phanerochaete chrysosporium grown on a series of wood pulp with a graded lignin content and mycelium from the clarified centre of an agar-medium containing lignin (E1-effluent from the bleaching process) showed that osmiophilic particles are only induced by native lignin. Taking into account that the osmioph...
K Messner, H Stachelberger


Determination procedure for wood preservatives in waste wood - statistics of sampling and analysis
1998 - IRG/WP 98-50121
In a RTD research programme funded by the German Federal Environmental Agency (UBA - Report No. 126-06-010103) a standardised and validated procedure was developed for sampling and analysing wood preservative components in waste wood. For this investigation a realistic quantity of waste wood from house demolition was used and 80 components analysed. The examination of single wood pieces and woodch...
P Stolz, J Krooss, U Thurmarm, R-D Peek, H Giese


Application of (n-a)-radiography for determination of boron in wood impregnated with boron-containing antispetics
1975 - IRG/WP 351
The method of (n-a)-radiography for quantitative determination of boron is based on creation of defective regions (tracks) in a polymer (the detector), which form during passage of a particles through the detector, these particles being produced in the reaction 10B(n, a)7Li when the test specimen in contact with the detector is irradiated with neutrons. Etching of the detector with an appropriate ...
N A Dubinskaya, M Ya Tsel'millere


Degradation of lignin model compounds with coordinated copper in the presence of peroxide
1998 - IRG/WP 98-10282
A novel diffusible system capable of decomposing lignin model compounds with copper, coordinators and peroxides has been proposed. When pyridine was used as a copper coordinator, two synthetic dyes, Poly-R and RBBR were intensively decolorized with Cu(II) and H2O2 in aqueous solutions at room temperature. Although reactions with Cu(II) and H2O2 produce a strong oxidant, hydroxyl radical, via a Fen...
K Koller, K Messner, T Watanabe


Economical analysis of the chemicals used on remediation copper, chromium and arsenic from out of service CCA-treated utility poles in Turkey
2004 - IRG/WP 04-50217
There are 20.7 million hectare forested area in Turkey. However, the wood products supplies do not meet demand. One of the wooden products is the utility poles. In Turkey, impregnation of utility poles has been started since 1960's and 5 million utility poles have been used until today since then. Although life time of the utility poles may vary depending on climatic conditions, average s...
E D Gezer, D Toksoy, Ü C Yildiz


Comparative studies on the species effects of wood preservatives
1989 - IRG/WP 3521
For the examination of the resistance against fungal attack, wood blocks of 3 softwood species were treated with CCA (type 3), CFK, AAC and IF-1000 independently. The wood blocks were exposed to the fungal decay with Tyromyces palustris. The degradation of the wood blocks treated with these preservatives was quite widely different among wood species examined in this study. Hem-fir treated with CCA...
K Yamamoto, S Matsuoka


X-ray photoelectron spectroscopic analysis of CCA treated wood
1992 - IRG/WP 92-3700
Ponderosa pine and Douglas-fir wood sections were treated with CCA preservative. To elucidate the mechanism of fixation of the CCA, the wood surface was analyzed by X-ray photoelectron spectroscopy (XPS). CCA treatment increased C1 (carbon bonded to carbon and/or hydrogen) and decreased C2 (carbon bonded to one oxygen) in XPS C1s spectra, both in unextracted and pre-extracted sections. This sugges...
J N R Ruddick, K Yamamoto, P C Wong, K A R Mitchell


Analysis of contaminants in waste wood
2001 - IRG/WP 01-50179
Waste wood is increasingly used as fuel in Sweden. It is of Swedish origin as well as imported, Mainly from Germany and the Netherlands. The major chemical contaminants are surface treatments (paints etc) and wood preservatives. The surface treatments contribute in particular to contaminants of zinc and lead. In some cases zinc has been found to cause severe deposits in the furnaces. Surface treat...
J Jermer, A Ekvall, C Tullin


The rôle of lignin in the nutrition of several Australian termites
1983 - IRG/WP 1191
The ability of Nasutitermes exitiosus (Hill), Coptotermes acinaciformis (Frogatt), Coptotermes lacteus (Froggatt) and Mastotermes darwiniensis (Froggatt) to degrade 14C-lignin preparations was examined. The lower termites were unable to degrade lignin. Nasutitermes exitiosus was able to cause a 5-8% degradation of hardwood lignins and a synthetic lignin. It failed to degrade the lignin of Pinus ra...
L J Cookson


Laboratory evaluation of chlorothalonil against the Formosan subterannean termite
1992 - IRG/WP 92-1559
The fungicide chlorothalonil was evaluated as a wood preservative to prevent attack by the Formosan subterranean termite, Coptotermes formosanus Shiraki (Isoptera: Rhinotermitidae). Southern yellow pine wafers treated with chlorothalonil (CTL) in P9 oil, CTL + chlorpyrifos in P9 oil, or CTL in xylene were conditioned by evaporative aging at 40° C for 4 weeks and exposed to termite attack in a mod...
J K Grace, P E Laks, R T Yamamoto


A technique for the rapid assessment of wood surface degradation during weathering
1987 - IRG/WP 2281
Radiate pine (Pinus radiata D. Don) sapwood samples taken from four trees were converted into thin strips 100 x 10 x 0.085 (85 µm) mm³, (longitudinal x radial x tangential) in size and exposed in preweighed hatches to the weather inclined at 45° facing equatorially for 10, 20, 40, 60, 80 and 100 days. Significant (P < 0.001) weight losses occurred with time over the exposure period. Differen...
P D Evans, D Abbott, S Thein


A reliable spot test for TCMTB in wood
1992 - IRG/WP 92-2391
Test specimens of slash pine (Pinus elliottii) and spotted gum (Eucalyptus maculata) were treated with aqueous emulsions of Busan 30WB and Busan 31, containing the fungicide TCMTB (2-(Thiocyanomethylthio)benzothiazole), or with solutions of TCMTB in toluene. These and matching untreated specimens were subjected to a wide range of procedures in an attempt to reveal TCMTB penetration patterns. Most ...
D E Ferlazzo, M J Kennedy


Application of energy dispersive X-ray fluorescence spectrometry to the quantitative analysis of organotin preservative solutions and treated wood
1978 - IRG/WP 3125
One technique frequently used for the quantitative analysis of material containing inorganic compounds is energy dispersive X-ray fluorescence spectrometry. It has been shown previously that this technique can be readily used to determine the retentions of chromated copper arsenate and ammoniacal copper arsenate treated wood. This paper reports the results of a preliminary study to determine wheth...
J N R Ruddick


Toxic value estimation of wood preservatives by using the probit analysis
1990 - IRG/WP 2348
As it was assumed from previous experiments, the probit analysis appears to be the most suitable method of all used to estimate the toxic value of wood preservatives. With the help of the classical agar-block method the probit analysis was tested for its suitability in: 1) fungitoxic value estimation of the WR-3 preservative (quaternary ammonium compound + borate), as compared to different test fu...
J Wazny, K J Krajewski


Non-destructive stress wave measurement of decay and termite attack in experimental wood units
1986 - IRG/WP 2256
The purpose of this study was to determine if stress wave analysis could be used to monitor the degradation of wood specimens exposed to the brown-rot decay fungi (Gloeophyllum trabeum) and of wood specimens subjected to attack by subterranean termites. One hundred fifty 3/4 by 3/4 by 12 in. Southern pine specimens were used for exposure to brown-rot decay fungi and two hundred twenty-five 3/4 by ...
R F Pellerin, R C De Groot, G R Esenther


Lignin degradation by a non-enzymatic system supposed to be active in white rot fungi
2000 - IRG/WP 00-10340
Electron microscopic investigations have shown that ligninolytic enzymes of white-rot fungi are only able to penetrate the wood cell wall in late stages of degradation. Thus, the selective degradation of lignin of certain white-rot fungi can only be explained on the basis of a low molecular weight, highly diffusible system. A system, consisting of copper, a coordination compound and either H2O2 or...
P Lamaipis, W Gindl, T Watanabe, K Messner


Rapid loss of lignin at wood surfaces during natural weathering
1992 - IRG/WP 92-2390
Thin veneers of radiata pine (Pinus radiata D. Don) were exposed to natural weathering over a period of 30 days. Incident UV radiation was monitored at the test site. FTIR internal reflectance spectroscopy was used to study the chemical changes taking place at the veneer surface during weathering. Spectra obtained show that after only 3 days exposure there was substantial delignification at veneer...
P D Evans, K J Schmalzl, A J Michell


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