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Leaching of the copper component from full scale decking boards during one summer season
2009 - IRG/WP 09-50260
The leaching of copper has been tested in laboratory and in outside exposure for freshly treated pine sapwood samples with three different copper preservatives, Cu HDO, copper quat and copper triazoles. We found in the laboratory leaching test that a fixation with warming to 60 °C (140 °F) for 48 hours without drying and then drying in the laboratory in room temperature gave the lowest leaching of copper. We also found that surface treatments with wood oils reduced the leaching, and that washing of the surface before testing had no effect. Full scale decking board samples (0.25 m2) were then exposed outdoors for rain. The rain water was collected and analysed for copper. After one summer season (about 600 mm rain) we found that the leaching differ for the three preservatives. All samples with a water borne surface treatment had the lowest leaching, about half the amount of untreated.
F G Evans


Component leaching from CCA, ACQ and a micronized copper quat (MCQ) system as affected by leaching protocol
2009 - IRG/WP 09-50261
Leaching results for Cu, Cr and As (CCA) and Cu (ACQ and MCQ) from southern pine are compared for laboratory tests (AWPA E11, and draft OECD methods I and II) and natural weathering of horizontally and vertically oriented lumber samples over two seasons. This paper expands on results and comparison of results presented at the IRG regional meeting in Costa Rica in Dec 2008 (Cooper and Ung 2008) a...
P A Cooper, Y T Ung


Material properties of furfurylated wood for window production
2009 - IRG/WP 09-40480
Wood modification with furfuryl alcohol is an extensively investigated process and already produced commercially. Furfurylated wood is in the focus of a European project on its use for the production of high performance windows. Different wood species were treated with furfuryl alcohol and tested on water uptake, dimensional changes, leaching in water, resistance to fungal degradation, and ecotoxi...
A Treu, A Pilgård, S Puttmann, A Krause


Utilidad práctica de mini estacas en ensayos de campo
2008 - IRG/WP 08-20395
For testing chemicals for the wood against degradation agents of biotic, known as preservatives, both testing in the laboratory and in the fields are used. Field trials (Cemetery stakes) are often accepted as more "real" whose frequency of observation is set to more or less a year in temperate climates and six months or less in tropical situations, taking into accounts the aggressiveness of the so...
O Encinas, J V Puentes, N K Sarmiento, N Mora


Natural durability of African Padauk and Niove. Comparison of new trials and former data from the CIRAD database
2010 - IRG/WP 10-10743
African Padauk (Pterocarpus soyauxii) and Niove (Staudia kamerunensis) were tested in laboratory against Basidiomycetes. The results were calculated according to the requirements of EN 350-1 (1994) and XP CEN/TS 15083-1 (2006). Padauk samples showed a high durability and very small variations between trees and within tree. Niove presented a high durability, but with notable differences according ...
Y N N’Kolo Meze’e, N Leménager, C Baudassé, M-F Thévenon


Mobility of Copper from MCQ in Shell-Treated Wood Exposed Above Ground
2010 - IRG/WP 10-30534
Most Canadian treated decking in service has been given just a thin shell of preservative treatment but it has still performed very well. This is because copper migrated into checks and prevented germination of basidiospores on the freshly exposed untreated wood. Unlike soluble copper systems, MCQ has its copper primarily in the form of small basic copper carbonate particles. For MCQ to be effecti...
R Stirling, P I Morris


Treatment of Scots pine wood with oil in water and water in oil emulsion systems: Effects on boron leaching and water absorption
2010 - IRG/WP 10-30535
The aim of this study was to investigate the water absorption and water repellent efficiency of oils and oil water emulsions [oil-in-water (O/W) and water-in-oil (W/O)] and possibilities of reducing the amount of boron leaching from treated wood. Scots pine wood samples treated with waste or sunflower oil and water formulations contained 3%BA. The level of water absorption and water repellent effi...
E D Tomak, Ü C Yildiz, A Can


Distribution and availability of preservative components in ACQ treated wood - effects of coatings and weathering
2010 - IRG/WP 10-30537
Copper and quaternary ammonium compound (quat) distributions across lumber (gradients) and availability, as measured by amount removed by intensive leaching of wood flour, were measured in ACQ treated southern pine lumber. Samples were evaluated just after treatment and stabilization, or after 3 years of laboratory storage, or after 3 years of natural weathering exposure. The objective was to in...
T Ung, M Nejad, P Cooper


Copper distribution in soil leached from full scale decking boards during one year
2010 - IRG/WP 10-50265
The distribution of copper in the soil under exposed decking boards after one year has been analysed. The decking boards were impregnated with copper HDO, copper quat and copper triazoles. The decking boards were pine sapwood and pressure treated in a full cell process, fixed by heating and then dried. The samples were not surface treated. Each decking sample of five boards (0.25 m2) was placed on...
F G Evans


Combined Effect of Boric Acid and Waste Oil Treatment on Boron Leaching
2010 - IRG/WP 10-50268
In this study it was aimed to investigate the boron leaching amounts in Scots pine wood samples treated with boric acid (BA) and waste oil (WO) alone or by dual treatment. The level of water absorption and water repellent efficiency were determined with cyclical wetting tests, total of 336 hours. Wood samples that have both covered and uncovered transversal section were impregnated with 3% boric a...
Ü C Yildiz, E Dizman


Above ground testing at tropical test sites, what have we learned?
2011 - IRG/WP 11-20473
Three different above ground test methods have been utilized at a selection of five tropical and sub-tropical test sites with a variety of treated and untreated material. The results show that a multi-site approach to above ground field tests presents the opportunity for exposure to un-predicted biodeterioration hazards, which may be important for developmental products of poorly characterized fu...
A Preston, A Zahora, Y Cabrera, L Jin, C Schauwecker, P Walcheski


Sample Origin Influencing the Leachability of Wood Preservatives
2011 - IRG/WP 11-20474
The aim of this study is to see if the raw material influences fixation and leachability of wood preservatives. Moving towards more eco-friendly and –concious society, the wood industries must adjust itself to new rules and regulations. Greener solutions in wood protection are being tested and introduced, older systems are being improved, but questions still arise concerning some elements curren...
K Kängsepp. E Larnøy, P Meier


A Method for Studying Boron Redistribution and Leaching in Timber Framing
2011 - IRG/WP 11-20476
In typical New Zealand timber framed house construction, the timber framing has a vapour permeable building wrap applied to the exterior and a cladding applied over 20 mm battens. An interior lining usually of gypsum plasterboard is then fixed once the timber framing has a moisture content of < 20%. Timber framing within the building envelope is not expected to be wet in-service or exposed to a le...
J A Drysdale, N Marston, M E Hedley


Influence of wood swelling agents on penetration and copper leaching of copper-ethanolamine based wood preservatives
2011 - IRG/WP 11-30556
Copper ethanolamine based preservatives are currently the most important solutions for impregnation of wood in ground contact in Europe. One of the issues related to those and similar water based solutions is insufficient penetration to refractory wood species like Norway spruce. In order to elucidate this issue, commercial copper ethanolamine based solution was supplemented with five different wo...
M Humar, N Thaler, B Lesar


Ten Year Field Tests of Borate-Treated Wood Against Subterranean Termites
2011 - IRG/WP 11-30557
In the mid 1990s, Forintek Canada Corp. initiated a study of the termite resistance of borate-treated lumber above ground, protected from rain in Canada, Japan and Hawaii. Predominant termite species at three test were Reticulitermes flavipes in Canada, and Coptotermes formosanus in both Japan and Hawaii. The material included hemlock and amabilis fir lumber treated with disodium octaborate tetrah...
P I Morris, J K Grace, K Tsunoda


Effect of P/F ratio, PF concentration and treating method on boron leaching from wood treated with PF modified boron compounds
2011 - IRG/WP 11-30559
In order to immobilize boron in wood, three kinds of resol-type phenol-formaldehyde (PF) resin with different P/F ratios were synthesized in laboratory and incorporated with three types of boron compounds to treat wood. The used boron compounds included boric acid (BA), borax (BX) and disodium octaborate tetrahydrate (DOT). The leaching test of boron from wood blocks was performed according to the...
Liping Yu, Jinzhen Cao


The durability of acetylated radiata pine sapwood (Accoya). Results from five years testing
2011 - IRG/WP 11-30560
New Zealand grown radiata pine sapwood was modified using the Accsys PLC acetylation process (Accoya). Following treatment, various test samples were exposed in the Scion Accelerated Field Test facility (Fungus Cellar) and in exterior ground contact field tests. In the Fungus Cellar, performance was compared with that of radiata pine treated with CCA to Hazard Classes H3.2 (0.37% m/m Cu+Cr+As) and...
M Hedley, D Page, J van der Waals, K Nasheri, G Durbin


Fixed Borates Anyone?
2011 - IRG/WP 11-30563
The quest for a borate based preservative system that resists leaching or is “fixed” has long been a research goal. Boron fixation has been attempted with numerous strategies but there have been problems associated with past methods. This paper discusses new fixation systems based on bio-materials and presents up to five year outdoor exposure testing on full-size decks. Generally, the new f...
C R McIntyre, M A Lake


Standardized Field Trials with Micronized Copper
2011 - IRG/WP 11-30564
In 2008, an extensive review of all available data from standardized tests of micronized copper systems was published and there has been considerable work since then. This paper discusses over 20 field stake trials underway in well-known sites such as Gainesville, FL, Hilo, HI and the Dorman and Saucier sites in MS as well as tests from Australia and New Zealand. In addition, 4 ground proximity ...
C R McIntyre, M H Freeman


Durability of modified wood in UC3 and UC4. Results from lab tests and 5 years testing in 3 fields
2011 - IRG/WP 11-40562
In 2005 an extensive test program including field tests was set up in order to obtain more data on the durability and long term performance of modified wood and semi-durable wood species. One of the main challenges for modified wood is to predict accurate service life time in UC3 (use class 3, above ground) and UC4 (use class 4, in soil or fresh water contact). So far, data from in-service condi...
M Westin, G Alfredsen


Characterizing long term leaching behaviour of copper from preservative treated wood in a practical exposure scenario
2011 - IRG/WP 11-50278
To investigate the prediction of the long term emission of copper from preservative treated wood in a Use Class Class 3 scenario, treated boards were exposed vertically above ground to natural weather conditions. The study included two products; an amine copper ACQ-type formulation, air-dried after treatment to a 22 kg/m3 retention, and the same formulation which was hot oil vacuum dried after tre...
T Mark Venås, M Klamer


Copper Migration from Micronized Copper Preservatives Treated Wood in soil contact:
2011 - IRG/WP 11-50280
Emerging formulations of preservatives made with micronized basic copper carbonates with azoles and/or quat to control copper tolerant fungi have been used to replace formulations containing soluble copper to reduce the leaching of copper and the corrosion of metal in contact with wood. This study proposes to use laboratory soil leaching test AWPA standard (E20-08) to estimate the amount of copper...
Lei Wang, D P Kamdem


Durability of timber products – Part 2: Proposal for an IRGWP - Durability Database
2012 - IRG/WP 12-20497
A proposal for a web-based platform for scientific exchange of test data in the field of wood durability and wood protection has been made. The overall aim of the durability data base is to improve the usability of existing test data and to create an added value for durability research and service life prediction. The database allows for test results from standardized and non-standardized laborat...
C Brischke, L Meyer, G Alfredsen, M Humar, L Francis


Durability of timber products –Part 1: Inventory and evaluation of above ground data
2012 - IRG/WP12-20498
The material-inherent resistance of wood is one of the most important qualities influencing the durability of timber. Hence, it has also a major effect on the service life to be expected from a timber construction. In addition, design details and the respective climatic conditions determine durability and make it impossible to treat wood durability as an absolute value. Moreover, the reference mag...
C Brischke, L Meyer, G Alfredsen, M Humar, L Francis, P O Flæte, P Larsson Brelid


Tannin resin-boron associations: Leaching and biological resistance
2012 - IRG/WP 12-30587
The easy leaching of boron in wood preservation formulations has allowed to use this fungicide only for short term applications. The recently discovered adduct with flavonoids allows boron to resist longer periods of time within wood and consequently extend its life. Two different leaching treatments were compared and the fungal and termite decay was examined. The biological tests have shown extre...
G Tondi, S Wieland, N Lemenager, A Petutschnigg, A Pizzi, M-F Thevenon


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