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Effectiveness of sol-gel treatments coupled with copper and boron against subterranean termites
2009 - IRG/WP 09-30493
Wood modification by sol-gel treatments shows many positive features, like antimicrobial properties. Wood was also successfully modified with alkoxysilanes enhancing its resistance against soil micro-organisms. Silver, copper, zinc compounds, boric acid or organic biocides such as alkylammonium compounds may be added to the sol-gel to enhance its biocidal properties. Nevertheless, if some of these...
E Feci, L Nunes, S Palanti, S Duarte, G Predieri, F Vignali


Copper to quat ratio in alkaline copper quat (ACQ) wood preservative - Effects on fixation and leaching of preservative components in red pine
2009 - IRG/WP 09-30496
This study investigates the effect of the relative proportion of copper oxide (CuO) to didecy dimethyl ammonium carbonate (DDACb) in an alkaline copper quat (ACQ) formulation on the rate of copper fixation or stabilization and the resistance of treated wood to leaching of copper and quat (DDACb). Red pine samples were treated with ACQ, having CuO to DDACb ratios of 2:1 (the normal ratio for ACQ-D...
S Pankras, P A Cooper, T Ung, L Awoyemi


Leaching performance, decay and termite resistance of wood treated with boron compounds incorporated with phenol-formaldehyde resin
2009 - IRG/WP 09-30503
A resol-type phenol-formaldehyde (PF) resin was synthesized and designed to penetrate wood incorporated with boron compounds in order to immobilize boron in wood. The leaching performance, decay and termite resistance of treated wood was investigated. Three kinds of boron compounds, that is, boric acid (BA), borax (BX) and disodium octaborate tetrahydrate (DOT), were selected to mix with PF and tw...
Liping Yu, Jinzhen Cao


Laboratory test of some formulations against stain and mould fungi isolated from bamboo wood
2009 - IRG/WP 09-30508
To screen the effective anti-mould formulations, fungicides such as carbendazim, tebuconazole, fludioxonil, difenoconazole, prochloraz, benomyl and 8-hydroxy-quinoline copper (copper oxine) were selected to conduct the laboratory test of fungicidal activity by method of inhibition zone against Botryodiplodia theobromae Pat., Fusarium sp., Alternaria tenuis Nees., Penicillium purpurogenum Stoll, Tr...
Xingxia Ma, Airui Sun, Mingliang Jiang, Daochun Qin


Leaching properties of copper and triazole
2009 - IRG/WP 09-30509
The leaching rate of copper and triazole (such as tebuconazole and propiconazole) in different preservative formulations was determined according to AWPA E11-06. Of all copper triazole and ACQ formulations, copper fixation rate of ammonia based was higher than that of ethanolamine based and the mixture of them. Copper fixation rate at relatively higher retention was slight higher than that at lowe...
Zhiqiang Li, Xiaowen Li, Ying Zhang, Mingliang Jiang


Micronized Copper Preservative Systems: Observations on the Release of Cupric ion (Cu2+) from Treated Wood and Performance against Wood Decay Fungi
2009 - IRG/WP 09-30519
In an attempt to address the mechanism of action of micronized copper preservatives, a 20-week continuous water leaching study was conducted. The leaching results indicated that, once impregnated in wood, micronized copper preservatives continuously release cupric ion, and the levels of cupric ion released from micronized copper treated wood are higher than those released from CCA treated wood, a...
J Zhang, R Ziobro


Environmental Emission of Wood Preservatives: Interpretation of Data Relevant to BPD Risk Assessments
2009 - IRG/WP 09-50259
The risk assessments for the use of wood preservatives proposed by the OECD and used under the Biocidal Products Directive (BPD) (98/8/EC) require the derivation of leaching rates for active substances. These rates are to be used as input data in to agreed exposure scenarios. The leaching rates can be derived from laboratory testing and from field testing. The relationship between laboratory and f...
D G Cantrell


Leaching of the copper component from full scale decking boards during one summer season
2009 - IRG/WP 09-50260
The leaching of copper has been tested in laboratory and in outside exposure for freshly treated pine sapwood samples with three different copper preservatives, Cu HDO, copper quat and copper triazoles. We found in the laboratory leaching test that a fixation with warming to 60 °C (140 °F) for 48 hours without drying and then drying in the laboratory in room temperature gave the lowest leaching of copper. We also found that surface treatments with wood oils reduced the leaching, and that washing of the surface before testing had no effect. Full scale decking board samples (0.25 m2) were then exposed outdoors for rain. The rain water was collected and analysed for copper. After one summer season (about 600 mm rain) we found that the leaching differ for the three preservatives. All samples with a water borne surface treatment had the lowest leaching, about half the amount of untreated.
F G Evans


Component leaching from CCA, ACQ and a micronized copper quat (MCQ) system as affected by leaching protocol
2009 - IRG/WP 09-50261
Leaching results for Cu, Cr and As (CCA) and Cu (ACQ and MCQ) from southern pine are compared for laboratory tests (AWPA E11, and draft OECD methods I and II) and natural weathering of horizontally and vertically oriented lumber samples over two seasons. This paper expands on results and comparison of results presented at the IRG regional meeting in Costa Rica in Dec 2008 (Cooper and Ung 2008) a...
P A Cooper, Y T Ung


Estimating the heat treatment intensity through various properties of thermally modified timber (TMT)
2009 - IRG/WP 09-40459
The suitability of different measures for prediction of the heat treatment intensity was investigated. Therefore, the resistance to impact milling (RIM), the lightness L*, the equilibrium moisture content (EMC), the anti swelling efficiency (ASE) and the total amount of soluble carbohydrates (TSC) of heat treated specimens were correlated with corresponding fungal resistance achieved by heat treat...
C R Welzbacher, C Brischke, A O Rapp


Biological Performance of Boron-based Chemicals Treated Wood Composites
2009 - IRG/WP 09-40464
In this study, the biological performance of wood-based composites panels treated with boron containing chemicals against to a fungus was determined. Boric acid, borax, zinc borate and agricultural borate (Tarım-bor™), developed and patented by National Boron Research Institute, were mixed with wood chips or fibers and then particleboard, medium strand board and middle density fiberboar...
Ü C Yıldız, H Kalaycıoğlu, S Yıldız, A Temiz, E Tomak Dizman, A Çavdar Dönmez


Termite Resistant Properties of Wood and Natural Fiber Plastic Composites - AWPA E1 Test Data
2009 - IRG/WP 09-40466
This paper deals with resistance properties of wood plastic composites against Formosan Subterranean Termites (FSTs) based on the AWPA E1 test standard. Sixteen laboratory WPC formulations, four WPC commercial materials, and southern pine (Pinus sp.) wood control were tested for termite mortality, sample weight loss, and sample damage rating. The results show that FSTs did attack WPC products in ...
Q Wu, T Shupe, J Curole, K Ragon, M Voitier, M Freeman, D Ring


Material properties of furfurylated wood for window production
2009 - IRG/WP 09-40480
Wood modification with furfuryl alcohol is an extensively investigated process and already produced commercially. Furfurylated wood is in the focus of a European project on its use for the production of high performance windows. Different wood species were treated with furfuryl alcohol and tested on water uptake, dimensional changes, leaching in water, resistance to fungal degradation, and ecotoxi...
A Treu, A Pilgård, S Puttmann, A Krause


Seasonal shifts of fungal community structure at the interface of treated or untreated wood and soil
2010 - IRG/WP 10-10721
Many wood species are degraded rapidly in soil by the fungal community. In order to preserve wood and structures in which it is used, chemical preservatives are used. Little is known about the interaction of treated wood and the surrounding soil fungal community. For this work, presented at IRG 41, wooden specimens (Pinus sylvestris sapwood, sizes 25 mm x 50 mm x 500 mm (longitudinal)) were treate...
M Noll, I Stephan


Glued laminated poles - Progress report after 30 years testing
2010 - IRG/WP 10-20427
In 1979 a number of glued laminated poles treated with CCA and creosote were placed in a greenhouse at Uppsala, at the Simlångsdalen test field in southern Sweden and in a power lane in Vuollerim in northern Sweden in order to study their resistance against biological degradation. The tests have shown that the best performance will be obtained if each lamination is treated with a water-borne pre...
Ö Bergman, J Jermer


The Relative Performance of an Organic Preservative System under UC3A and UC3B Conditions using Two Test Methods
2010 - IRG/WP 10-20429
Coated L-joints have been used for decades to evaluate the performance of wood preservatives in protected environments. This study was conducted using matched coated and uncoated L-joints to simulate above ground protected and unprotect exposures. When exposed to constant moisture in a greenhouse environment, coated and uncoated L-joints give very similar performance results. In contrast, exposi...
C F Schauwecker, A Zahora, A F Preston


Determination of a fixation time of wood preservatives: A discussion paper
2010 - IRG/WP 10-20436
The intention of that paper is to initiate a discussion on the basis of a French method in combination with a German approach regarding the need of a method for the determination of a fixation time and especially to obtain input as well as ideas concerning a possible test design. Since no harmonised European approach exists up to now concerning the determination of a fixation time, CEN TC 38 (2009...
E Raphalen, E Melcher


Service life prediction of wooden components – Part 1: Determination of dose-response functions for above ground decay
2010 - IRG/WP 10-20439
Scots pine sapwood (Pinus sylvestris L.) and Douglas fir heartwood (Pseudotsuga menziesii Franco) specimens were exposed in double layer field trials at 24 different European test sites under different exposure conditions (in total 28 test sets). The material climate in terms of wood moisture content (MC) and wood temperature was automatically recorded over a period of up to eight years and compar...
C Brischke, A O Rapp


Impact of climate change on wood deterioration - Challenges and solutions for cultural heritage
2010 - IRG/WP 10-20441
Deterioration of wood in cultural assets follows the same physiological mechanisms as in modern structures. Therefore rules and data for prediction of service life derived from old wooden structures can be used to model the service life of recent wooden structures and vice versa. The latter is done in this paper: From experimental test set ups in the field spread over Europe, climatic data, wood t...
C Brischke, A O Rapp, M Hasan, R Despot


Stress wave and visual analysis of treated and non treated fence posts after 15 years in field test
2010 - IRG/WP 10-20449
Wood preservation may play an important role in protecting tropical rain forest. Basically, it can reduce pressure on natural resources by increasing wood durability. Field tests are conducted to simulate final use of woods under different environmental conditions. Visual analysis, non destructive testing, and non destructive evaluation techniques were applied to assess wood resistance and chemica...
A Florian da Costa, R Faustino Teles, J Costa Gonçalves


Development of microbiological test methods for the wooden packaging of foodstuffs
2010 - IRG/WP 10-20453
Whereas different sampling methods already exist for analysing contaminated surfaces or packaging made of plastic or paper, there is no methodology that enables the sampling and quantification of microorganisms in packaging made of wood. The objective of this study was to compare the most commonly used microbiological methods and to develop a reliable quality control test adapted to wooden packagi...
I Le Bayon, H Callot, M Kutnik, C Denis, A-M Revol-Junelles, J-B Millière, M Giraud, M Gabillé, N Passédat


Improved analysis of field test data related to service life prediction of tropical wood species
2010 - IRG/WP 10-20458
Long field trials of wood in ground contact give valuable data on the natural durability of the material. The European Standard EN 350 gives guidance on how to perform these durability classification, but is limited to the use of averages of in-service life of a set of specimens compared to a reference set. Starting from a database of visual assessment of field stake testing, it is possible to obt...
J Van den Bulcke, A Wong, Ling Wang Choon, Yoon Soo Kim, J Van Acker


Synthesis of novelty borate compounds for wood preservatives: Laboratory test of leachability and decay resistance
2010 - IRG/WP 10-30520
A novel series of ammonium tetraphenylborate (ATB) and borate chemical compounds (BBC) were synthesized as wood preservatives. The leaching rates and decay resistance of boron formulations containing ATB and BBC were conducted. The laboratory leaching results showed that boron leaching rate of treated wood by ATB formulations was from 2.1% - 6.7%, while that of BBC formulations from 23.3% -59.0%. ...
Zhiqiang Li, Mingliang Jiang, Xingxia Ma


Comparison of Bifenthrin Formulations for Their Skin and Eye Irritation Potential Using the Pollen Tube Growth Test
2010 - IRG/WP 10-30521
The Pollen Tube Growth Test (PTGT) is an effective screening method for measuring the potential of a chemical formulation to affect living cells. The PTGT has been compared against other types of testing, and it shows a good correlation with, for example, the Draize rabbit eye test and the human skin patch assay. It measures the EC50, which is the effective concentration at which 50% growth is o...
S Millward, P Lobb


Evaluation of ACQ-D treated Chinese fir and Mongolian Scots pine with different post-treatments after 20 months of exposure
2010 - IRG/WP 10-30530
The performance of alkaline copper quat-type D (ACQ-D) treated Chinese fir (Cunninghamia lanceolata Hook.) and Mongolian Scots pine (Pinus sylvestris Linn. var. mongolica Litv.) stakes after 20 months exposure in Chengdu and Guangzhou of southern China were evaluated according to AWPA standard E07-07. The ACQ-D treatments used two concentration levels (0.5 and 1.0%) and four different post-treatme...
Lili Yu, Jinzhen Cao, Wei Gao, Haitao Su


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