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Influence of hydrophobic agents on the leachability of boron
1995 - IRG/WP 95-30064
Besides its low mammalian toxicity and a broad range of activity towards both fungi and insects, boron shows a high diffusibility, encouraging it to treat wood species of low permeability. However, its difussibility is at the same time responsible for a high risk of leaching, known since long. Nevertheless quantitative data about this process are only rarely available. Therefore, the leaching of b...
A Peylo, H Willeitner


Diffusion modeling of inorganic wood preservative leaching in service
2005 - IRG/WP 05-50224-5
To evaluate the potential environmental and health implications of leaching of inorganic wood preservatives in service under different conditions, there is a need for a predictive model that provides estimates of the rate and extent of leaching over a wide range of product dimensions and exposure conditions. In this paper, we show that the leaching behavior of inorganic preservative components fr...
L Waldron, P A Cooper, Y T Ung


Biological Safety Evaluation of Animal Contact of Preservative-Treated Wood
2003 - IRG/WP 03-50196
Biological safety of preservative-treated woods that could be contacted to human and animal was evaluated for rat and rabbit exposed to CCA-, ACQ- and CCFZ-treated woods. The accumulation of preservatives ingredient in the rat’s plasma and viscera, and the transforming function of replacing preservatives were examined in this study. The result indicated that preservative-treated wood did not bri...
Dong-heub Lee, Dong-won Son, Myung Jae Lee, Chang Ho Kang, Cheon Ho Kim, Eui-Bai Jeung


Artificial weathering exposure as an alternative for standard ageing according to EN 84 (leaching) and EN 73 (evaporation)
2002 - IRG/WP 02-20254
In order to verify potential weaknesses of wood preservatives fungal tests are carried out after ageing of wood preservative treated test blocks. The European standard EN 599 as a framework for efficacy assessment of wood preservatives includes the use of two ageing methods prior to fungal testing, namely a leaching method (EN 84) and an evaporation method (EN 73). The European research project "F...
J Van Acker, M Grinda, D J Dickinson


Performance of Borate-treated lumber in a four-year, above-ground termite field test in Hawaii
2001 - IRG/WP 01-30265
We report the fourth year of field study results from a protected above-ground field test in Hawaii simulating the sill plate (dodai) used in conventional Japanese housing construction. Field tests were established in both Hawaii and Japan to examine the efficacy of disodium octaborate tetrahydrate (DOT, 2% and 3% shell and through) wood treatments. In Hawaii, chromated copper arsenate (CCA, 4 kg/...
J K Grace, R J Oshiro, A Byrne, P I Morris, K Tsunoda


Leaching from CCA-treated wood submerged in seawater: Effect of high loadings, and a comparison between laboratory and marine conditions
1996 - IRG/WP 96-50080
This study of leaching examined the following variables: CCA loading; marine versus laboratory exposure and length of submergence. Blocks of Pinus sylvestris were treated to a range of nominal retentions from 15 to 50 kg/m³. Each block was then divided into three cubes and all transverse faces were sealed. All cubes were allowed to fix at ambient temperature for a minimum of one week. One set of ...
R M Albuquerque, S M Cragg, J D Icely


Influence of surface coating on the leachability of boric acid and bifluorides from spruce wood
1995 - IRG/WP 95-50050
In the Netherlands, window joinery made from non-durable timber species (spruce) are widely protected with preservative rods. These rods contain non-fixing wood preservatives (e.g. bifluorides or boric acid). This reseach was performed to show the possible influence of a coating system to hinder the leaching of the active ingredients. The results of the leaching tests show, that bifluorides and ev...
W J Homan, H Militz


Field fencepost test of several species treated with water-borne preservatives by rural methods
1986 - IRG/WP 3385
Fencepost field results in ground-contact treated by rural methods: immersion-diffusion and sap displacement by evaporation are analyzed. Copper-chrome-arsenic and copper-fluor-chrome preservatives were used in two concentrations. The wooden species studied were: Pinus pinaster, Eucalyptus globulus and Quercus rubra. For each of the test units decay index evolution was analyzed after five years ex...
M V Baonza Merino


Which substrate to use in a laboratory test with soft rot micro-fungi: vermiculite or unsterile soil?
1991 - IRG/WP 2372
A draft European Standard is being proposed by CEN TC 38 in which a vermiculite-burial and a soil-burial test to be carried out in succession are required. Various experiments with both procedures were set up with CCA, CC and propiconazole-formulations. The results show that vermiculite and unsterile soil yield comparable threshold values against soft rot. This poses the question of whether a two-...
A R Valcke


Influence of variable lignin content amongst hardwoods on soft-rot susceptibility and performance of CCA preservative
1982 - IRG/WP 1151
This paper presents the outline of an argument, based on both new and established data, which relates varying lignin content to variation of soft-rot susceptibility between hardwood species and of performance of CCA preservatives in controlling soft-rot. Although more data need to be generated to prove this relationship, sufficient evidence exists for the hypothesis to be given close attention, pa...
J A Butcher, T Nilsson


Determination of the amine to copper ratio remaining in wood after leaching
2002 - IRG/WP 02-30285
The effectiveness of the protection and the environmental impact of the treated wood are two of the most important aspects that need to be understood for all preservatives. Both are particularly influenced by the loss of biocidal components from treated wood. For amine copper preservatives, copper fixation determines the leaching resistance of the copper and amine compounds formed in wood. Previou...
N Lucas, J N R Ruddick


Utilization of coconut timber from north Sulawesi, Indonesia. Part 2: Treatability
1994 - IRG/WP 94-40025
Under tropical conditions coconut wood is quickly degraded by mold and blue stain fungi. Low density wood in ground contact is commonly decomposed by wood destroying fungi within a period of only a few months, higher density wood from the outer stem regions within 24 to 30 months (MOSTEIRO, CASIN, SERIBAN 1976; McQUIRE 1975). Moreover, according to McQUIRE (1975) green wood of lower density is hig...
R-D Peek


Decay and termite resistance of wood treated with boron-containing quaternary ammonia compound, didecyl dimethyl ammonium tetrafluoroborate (DBF) incorporated with acryl-silicon type resin
2004 - IRG/WP 04-30334
This study evaluates the decay and termite resistance of surface-treated wood with didecyl dimethyl ammonium tetrafluoroborate (DBF) incorporated with acryl-silicon type resin emulsion. DBF is a quaternary ammonia compound and contains boric tetrafluoride (BF4-) as a counter ion in its chemical structure. In the study, DBF was incorporated with an acryl-silicon type resin to increase water-resista...
S N Kartal, W J Hwang, K Shinoda, Y Imamura


Co-operative research project on L-joint testing. Progress report to March 1985
1985 - IRG/WP 2236
It was originally intended that each participant would expose L-joints in the main trial on 1 April 1983 with the first sampling at 8 months (1 December 1983) and the second sampling at 18 months (1 October 1984). In the event, some participants have had to vary this schedule. Results after the first sampling have been received from CTFT (8 months), BAM (12 months) and Sipad-IRC (8 months) and aft...
J K Carey, A F Bravery


Electricity pole treatments - Wedding Bells State Forest. Inspection September 1983
1985 - IRG/WP 3334
A survey to study the extent of soft rot in hardwood poles in N.S.W. was commenced in 1975. The results of the survey, published in 1982, indicated that a number of factors contributed towards soft rot attack on poles in service. A detailed rest on pole treatments and maintenance procedures was established in 1976, at a site in Wedding Bells State Forest near Coffs Harbour. The site selected was k...
R S Johnstone, R H Eldridge


Six-year Report on the Performance of Borate-treated Lumber in an Above-ground Termite Field Test in Hawaii
2004 - IRG/WP 04-30343
We report the fifth and sixth years of field study results from a protected above-ground field test in Hawaii simulating the sill plate (dodai) used in conventional Japanese housing construction. Field tests were established in both Hawaii and Japan to examine the efficacy of disodium octaborate tetrahydrate (DOT, 2% and 3% BAE shell and through) wood treatments. In Hawaii, chromated copper arsen...
J K Grace, A Byrne, P I Morris, K Tsunoda


Leaching of arsenic, copper and chrome from preservative-treated timber in playground equipment
1984 - IRG/WP 3149
Samples were taken from CCA-treated timber in sand play boxes and other play ground equipment. Sand was also sampled. Sand and wood samples were analysed for copper, chrome and arsenic by AAS. About 20-25% of the arsenic had leached from the timber after 2-4 year's exposure in the playgrounds. Very little of the copper and chrome had been leached. Sand collected in the close vicinity of t...
B Henningsson, B Carlsson


IRG/COIPM INTERNATIONAL MARINE TEST - to determine the effect of timber substrate on the effectiveness of water-borne salt preservatives in sea-water. Progress Report 5: Interim report
1980 - IRG/WP 454
Wood samples (15 x 2 x 2 cm³) were treated with one copper/chrome/arsenic (CCA) and one copper/chrome/boron (CCB) preservative using the following concentrations - O, 3, 6, 10%. Treated samples of three reference wood species - Alstonia scholaris, Fagus sylvatica, Pinus sylvestris were supplied to all participants. Additional local species were chosen by participants and included in the test at t...
R A Eaton


Simulation test of subchronic inhalation toxicity of TBTO vapours in the air
1987 - IRG/WP 3454
The test was carried out in a wainscotted room of a normal size. Wooden panelling had been treated with one coat of basic preserving agent and, after the installation, with 2 coats of stain. Laboratory animals (rats) were kept in this room for 90 days. For the same period a control group of test animals was kept in a room of equal size where there was no panelling. During the test, concentration o...
V Skubic, S Kobal, J Stupar, R Ajlec, J Korošin, G R Pecenko


Marine wood-borer test with preservatives on the coasts of Turkey
1995 - IRG/WP 95-10091
Marine wood-borer tests were carried out on the coasts of Turkey (Marmara, Mediterranean Sea and Black Sea). Sapwood blocks of 8 x 15 x 30 cm³ in size from Scots pine, Bornmüller's fir oriental beech and sessile oak were used. The test blocks were treated with CCB-salts by full cell process and coal tar creosote by empty cell process. The test blocks were installed on exposure sites bef...
A Bobat


Fixation of CCA preservatives in cocos-, oil- and rattan-palm
1986 - IRG/WP 3371
In previous tests with jubaea-palm almost no fixation of a CCA-preservative Type B could be achieved, consequently, further leaching tests were carried out with samples of 1 cocos-, 1 oil- and 2 rattan-palms from Malaysia. A good fixation of chromium and copper took place in cocos-palm after 4 weeks storage at 28°C. Nevertheless the fixation was slower than in pine-wood and demanded an elevated t...
H Willeitner, K Brandt


Assessing the bioresistance conferred to solid wood by chemical modification
1997 - IRG/WP 97-40099
The chemical modification of wood using straight chain alkyl anhydrides can considerably enhance its durability. This paper presents an assessment of the effectiveness of these modifiers in improving the biological resistance of a susceptible softwood when exposed to four different basidiomycete fungi, soft rots and the larvae of the house longhorn beetle (Hylotrupes bajulus). It was clear that so...
E D Suttie, C A S Hill, D Jones, R J Orsler


Penetration as Key Factor for Determining the Performance of Wood Preservatives
2004 - IRG/WP 04-20293
Stakes of Scots pine sapwood with a dimension of 4 x 4 x 75 cm³ were impregnated with preservatives containing 2 % of propiconazole which had passed the EN 113 test criteria without any problems. The penetration of the colourless preservative was determined successfully by a fungal screening test described by Sutter (1978). The test revealed the insufficient penetration behaviour within the gi...
H Leithoff, I Stephan, R-D Peek


Variations in the virulence of test strains of Coniophora puteana (Schum ex Fr) Karst
1982 - IRG/WP 2185
In laboratory experiments using petri-dishes and small wood blocks (30 x 10 x 5 mm³) 6 different isolates of Coniophora puteana strain BAM 15 were compared with strain FPRL 11E for growth rate and decay capability. Only the recently received strain from EMPA was suitably active giving 24% weight loss after 6 weeks compared with 38.1% for 11E. Collation of data from standard test records revealed ...
A F Bravery, J K Carey, W Worley


Sediment toxicity study of marine piles treated with CCA-C
1995 - IRG/WP 95-50040-35
A study was undertaken to demonstrate the effects of 10-day exposure to sediments mixed with leachate from chromated copper arsenate Type-C (CCA-C) southern pine marine piles treated to a retention of 40 kg/m³ (2.5 pcf) and untreated southern pine piles on the benthic amphipod, Ampelisca abdita. The biological endpoint used to establish effects was organism survival. Leachate obtained during a 28...
W J Baldwin, E A Pasek, P D Osborne


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