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An appraisal of anti-sapstain chemicals in Queensland, Australia
1985 - IRG/WP 3331
Eleven formulations were tested in the field for effectiveness against sapstain, mould and fungi on Pinus elliottii in Queensland. The commercially used sodium pentachlorophenoxide (0.5% a.i.) and Captafol (0.2% a.i.) performed well. Busan 1009 (0.3% a.i.), Protek T (5.0% a.i.), Woodgard E.S. and E.C. (0.8% a.i.), together with sodium tetrachlorophenoxide (0.5% a.i.) offer potential as anti-sapsta...
L E Leightley


Biological test, AAS and EPR study of copper monoethanolamine complex with quaternary ammonium compounds as a wood preservative
2003 - IRG/WP 03-30321
Experiments were carried out on the wood preservative with a strong fungicidal activity based on Cu(II) carbonate, 2-aminoethanol (monoethanolamine) and quaternary ammonium compound (QAC). The object of the performed investigations was sapwood of Scots pine (Pinus sylvestris L.) treated with Cu-EA-QAC formulation. Mycological investigations were carried out according to EN 113 and EN 84 standards....
B Mazela, I Polus, S K Hoffmann, J Goslar


A review of the efficacy and uses of deltamethrin for wood preservation
1996 - IRG/WP 96-30105
The synthetic pyrethroid deltamethrin, is one of the most active insecticides available for protecting and curing wood from attack by beetles and termites. Freshly felled trees can be protected against bark beetles by spraying to run off with a 0.025% Al solution (K-Otek EC25) with negligible leaching. Alternatively, sawn timber may be dipped in a 0.0125% Al solution for short to medium term prote...
A J Adams, J L Lindars


Inorganic preservative levels in soil under treated wood decks after 8 years natural exposure in Borås, Sweden
2005 - IRG/WP 05-50233
Inorganic preservative components (Cu, Cr and As) were measured to a depth of 150 mm under deck structures made with Scots pine lumber treated with several different wood preservatives and installed in Borås Sweden 8 years ago. Higher contaminant levels were observed mainly under the drip lines and in the top 50 mm of soil. Under CCA treated decks, soil arsenic concentrations increased from ba...
P A Cooper, Y T Ung, M-L Edlund, J Jermer


After 18 years, preservative dipping and brush treating continue to provide protection to shingles of western wood species
1997 - IRG/WP 97-30156
The presence of residual preservation in dip-treated and brush-treated shingles of various species from the western United States was assessed 18 years after installation using Aspergillus bioassays. The performance of western redcedar (Thuja plicata) was compared to western hemlock (Tsuga heterophylla), sugar pine (Pinus lambertiana) and western larch (Larix occidentalis). Untreated shingles of a...
T C Scheffer, D J Miller, J J Morrell


Progress report on "Studies on the effect of salinity on the growth and mortality of teredinids"
1976 - IRG/WP 418
An open flow aquarium was constructed at Forest Products Research Centre in 1972 in order to study the effect of salinity on the growth and mortality of teredinids. To determine the reliability of results obtained during salinity experiments, the growth rate of teredinids in the aquarium were compared with the growth rate of the same species living under natural conditions in the harbour in 1973. ...
S M Rayner


Evaluation of wood preservatives for Nordic wood preservation class AB
2002 - IRG/WP 02-30297
In the Nordic countries there are restrictions in the use of wood preservatives based on chromium and arsenic. For above ground use, class AB according to the Nordic system, only copper based preservatives are allowed in Sweden. Thus several new preservatives, copper based or metal free are now used. They have been approved by the Nordic Wood Preservation Council after passing laboratory tests ag...
M-L Edlund, J Jermer


A field test on susceptibility of wood-based board materials to moulds
1989 - IRG/WP 3545
A field test on susceptibility of wood-based board materials to mould growth was carried out under practical, but severe, service-conditions. A total of 19 commercially available composite boards were investigated. It was found that all board materials tested were not completely immune to mould attack. Test results revealed that among the three main categories of wood-based boards involved, partic...
Qiao Wang, B Henningsson


Uptake of copper by mycelium of wood decay fungi growing on copper S-substituted thioglycolate containing nutrient media
1998 - IRG/WP 98-10291
Mycelia of Trametes versicolor, Coniophora puteana and Poria monticola were grown on potato dextrose agar (PDA) media, containing various concentrations of copper N,N-dimethyldithiocarbamoylacetate (which may be regarded as a copper S-substituted thioglycolate). The tested copper compound revealed relatively low fungicidal activity. After 13-18 day growing period, we determined concentrations of a...
M Humar, M Petric, F Pohleven, P Kalan


Soft rot test of copper/chrome/arsenic treated heartwood of three Malaysian timbers by the vermiculite-burial method. (+ correction document of 25 July 1990)
1990 - IRG/WP 2354
Heartwood of copper-chrome-arsenic (CCA) treated kempas (Koompassia malaccensis), tualang (Koompassia excelsa) and keruing (Dipterocarpus spec.) was found to be susceptible to soft rot in recent pole surveys. Standardized heartwood blocks were impregnated with 0 to 6.3% (w/v) CCA and challenged to decay for twelve weeks by a mixed inocula of Chaetomium globosum, Glenospora graphii, Humicula grisea...
R-D Peek, A H H Wong


The effect of copper/chrome/arsenic (CCA) treated timber on soil fungi
1981 - IRG/WP 1131
The aim of this investigation was to study the effect of CCA treated wood on the microflora of soil with particular reference to copper tolerant soft rot fungi. The IRG collaborative field experiment was designed to monitor the performance of a range of preservative treated hardwoods with particular reference to soft rot in CCA treated timber (Dickinson 1976) and site 33 of this experiment was use...
R J Murphy, D J Dickinson


FTIR characterization of copper ethanolamine - wood interaction
1999 - IRG/WP 99-20154
The interaction of copper ethanolamine (Cu-EA) and wood components was studied by using Fourier transform infrared spectroscopy (FTIR). In Cu-EA treated wood, significant reduction was noticed on the band attributed to carbonyl vibration from carboxylic groups at 1735±5 cm-1 and an increase in band intensity was obtained from carbonyl in carboxylate at 1595±5 cm-1. The same observation was made ...
Jun Zhang, D P Kamdem


Changes of EPR spectra of wood, impregnated with copper based preservatives, during exposure to Antrodia vaillantii
2000 - IRG/WP 00-10355
Spruce wood (Picea abies) samples were impregnated with two different aqueous solutions: copper(II) octanoate with ethanolamine or copper(II) sulfate (cCu = 1,0 x 10-2 mol/l). Impregnated and unimpregnated test pieces were exposed to wood rotting fungus Antrodia vaillantii. Some strains of this fungus are known as copper tolerant. After four weeks of exposure to A. vaillantii, we could not detect ...
M Humar, M Petric, F Pohleven, M Šentjurc


Influence of water-borne preservatives on water repellency and the impact of addition of water repellent additives
1992 - IRG/WP 92-3704
The primary goal of a desirable wood preservative system is to effectively control decay fungi and other biodeteriogens in service. The water repellent nature of a given system may play an important role in the protection of wood. In this study, the water repellency of several water-borne preservative systems has been evaluated by measurements of tangential swelling during immersion. The systems i...
L Jin, D M Roberts, A F Preston


Surface checking of CCA-treated radiata pine decking timber exposed to natural weathering
2000 - IRG/WP 00-40165
A field trial was established at four locations in Australia to assess the effect of CCA and CCA-wax treatment on the checking (cracking) of radiata pine decking timber exposed to natural weathering. Untreated decking timber and timber that had been pressure treated with water acted as controls. After 1 year's exposure the number and sizes of checks occurring in treated timber and control...
P D Evans, P J Beutel, C F Donnelly, R B Cunningham


The development of a new boron-based wood preservative
1995 - IRG/WP 95-30085
The paper describes a new boron based wood preservative for the treatment of green timber. The product offers many benefits over conventional boron diffusion treatment including: 1. high viscosity, high concentration formulation; 2. permits dip treatment of a wide range of sawn board and pole sizes at ambient temperatures; 3. permits full cross section diffusion of borates without block stacking a...
P Turner, D Conradie


Study on leaching of a magnesium fluorosilicate product (SF salt) from wood-boards by rain in the open and by artificial shower
1976 - IRG/WP 264
The test was performed in 1961 to obtain information about (1) the comparative leaching effect of natural rain and of artificial shower in the laboratory; (2) the comparative leaching effect on the active ingredient in proportion to the dye-stuff of the product. The results show that a continuos light rainfall with low precipitation has a much stronger leaching effect than short heavy showers with...
S Cymorek


Differential retention and leaching of CCA (C) in sapwood and heartwood of Kenyan-grown blue gum (Eucalyptus saligna) and black wattle (Acacia mearnsii)
2005 - IRG/WP 05-30371
Retention and leaching of CCA(C) in small samples of sapwood and heartwood of Kenyan-grown blue gum (Eucalyptus saligna) and black wattle (Acacia mearnsii) were tested under laboratory conditions. Clear samples (100mm x 30mm x 40mm) were removed from the sapwood and heartwood of sampled defect-free and sound plantation trees of the two species. These were separately air-dried to 15% MC, end-seal...
R Venkatasamy


The examination of preservative-treated radiata pine using electron spin resonance spectroscopy
1987 - IRG/WP 3423
Electron spin resonance spectroscopy (ESR) may be used to characterise the molecular environment of chemical species containing unpaired electrons. These species include free radicals, bi-radicals, point defects in solids, localised crystal imperfections and many transition metal ions. ESR has previously been applied to the examination of wood weathering or wood pyrolysis and now FRI and Massey Un...
D V Plackett, E W Ainscough, A M Brodie


A technique for measuring preservative loss or redistribution during leaching
1983 - IRG/WP 2199
Radiata pine sapwood stakes were treated with benzalkonium chloride (AAC) or copper-chrome-arsenate (CCA). After fixation and drying the outer 2 mm and 2-4 mm layers were removed from one radial longitudinal face. The planed face was coated with a waterproof coating and AAC-treated stakes were leached for 6, 12 or 18 weeks; 12 weeks for the CCA-treated stakes. After airdrying three 2 mm layers (0-...
J A Drysdale


Chemically modified tannin and tannin-copper complexes as preservatives for wood
2001 - IRG/WP 01-30271
The efficacy of Mimosa tannin, chemically modified tannin, and tannin-copper complexes as wood preservatives was studied. When the tannin-ammonia-CuCl2 solutions were impregnated into wood specimens in a one-step procedure, a large quantity of the tannin-copper complex was fixed in the specimens. Little of the complex was leached from specimens by a weathering treatment, and these specimens showed...
H Yamaguchi


The movement of iron into field test stakes
1987 - IRG/WP 2284
Failed and sacrificial stakes recovered from the Westham Island field test site were examined for their iron content. Varying amounts were recorded, which were greatest in the failed stakes. The possible role of the iron taken up by the below ground portion of the stakes, in accelerating the decay process and/or the preservative leaching is under investigation. The reaction of the iron with the ch...
J N R Ruddick, P I Morris


Amine copper reaction with wood components: acidity versus copper adsorption
1997 - IRG/WP 97-30161
The bonding sites for copper in wood from CCA, as well as ammoniacal/amine based systems, has long been a topic of investigation. Both phenolic and carboxylic functional groups have been discussed as potential bonding sites for copper. However, no consensus on the adsorption mechanism has been realized. Thus, the selective adsorption of copper in southern yellow pine from ethanolamine-copper solut...
S M Thomason, E A Pasek


Copper based wood preservative - A new approach using fixation with resin acids of rosin
2000 - IRG/WP 00-30249
Copper soaps with carboxylic acid groups of resin acids of rosin were shown to be potential long-term wood preservatives. The principle involved is the attachment of copper to the network formed by the inorganic part of the preservative (rosin) through the -COOH groups. The mechanisms of fixation have been studied, and it has been shown that this association could be obtained : (1) by forming the ...
C Roussel, J P Haluk, A Pizzi, M-F Thévenon


Studies in an accelerated soil bed facility on the decay susceptibility of U.K. grown spruce and pine poles treated with copper/chrome/arsenic (CCA) by pressurised sap-displacement. Part 1: Setting up of soil beds and initial soft rot results
1990 - IRG/WP 2344
The paper describes the methodology used in the construction and early operation of an accelerated soil bed facility used to examine the decay susceptibility of U.K. grown Scots and Corsican pine and Sitka and Norway spruce treated with C.C.A. by high pressure sap-displacememt. The design and control of the facility as well as the preparation, soil exposure and soft rot decay analysis of quarter p...
A Bruce, S D Hainey, G M Smith, B King, P D Evans


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